Electrochemistry

Subject : Chemistry Paper Set : 1

Standard : 12 Electrochemistry Date : 18-05-2025
Total Mark : 800 Time : 0H:0M

(8) Ag/AgCl(s)/KCl electrode is

............ Chemistry - Section A (MCQ) ............
(A) Reversible w.r.t cation (B) Reversible w.r.t Cl− ion
(1) Equivalent conductance of an electrolyte containing N aF at (C) Reversible w.r.t K + ion (D) Reversible w.r.t Ag + ion
infinite dilution is 90.1 (9) The solubility product of AgCl under standard conditions of
Ohm−1 cm2 . If N aF is replaced by KF what is the value of temperature is given by
equivalent conductance? ........... Ohm−1 cm2
(A) 1.6 × 10−5 (B) 1.5 × 10−8
(A) 90.1 (B) 111.2
(C) 3.2 × 10−10 (D) 1.5 × 10−10
(C) 0 (D) 222.4
(10) Number of moles of oxygen gas evolved by electrolysis of
(2) Electrical conductance through metals is called metallic or 180 g of water ?
electronic conductance and is due to the movement of (A) 2.5 (B) 5.0
electrons. The electronic conductance depends on
(A) the nature of metal (C) 7.5 (D) 10.0
(11) Which one is not called a anode reaction from the following
(B) the number of valance electrons per atom
(A) Cl− → 12 Cl2 + e− (B) Cu → Cu+2 + 2e−
(C) change in temperature
(C) Hg + → Hg +2 + e− (D) Zn2+ + 2e− → Zn
(D) all of these (12) 2.5 F of electricity are passed through a CuSO4 solution.
(3) Conductivity of a strong electrolyte The number of gm equivalent of Cu deposited on anode is
....
(A) Increases on dilution
(A) 0 (B) 1.25
(B) Does not change considerably on dilution
(C) 2.5 (D) 5.0
(C) Decreases on dilution (13) In the experiment set up for the measurement of EMF of a
(D) Depends on density half cell using a reference electrode and a salt bridge, when
the salt bridge is removed, the voltage
(4) Zn gives hydrogen gas with H2 SO4 and HCl but not with
(A) Does not change
HN O3 because
(A) N O2 is reduced in preference to H3 O+ (B) Decreases to half the value

(B) HN O3 is weaker acid than H2 SO4 and HCl (C) Increase to maximum

(C) Znacts as oxidising agent when reacts with HN O3 (D) Drops to zero

(D) In electrochemical series Znis placed above the (14) What current strength in amp. will be required to liberate
hydrogen 10 g of chlorine from N aCl solution in one hour ............. amp
(A) 8 (B) 6
(5) The value of x from the given data is
(C) 7.55 (D) 6.55
(15) Select the incorrect statement for dry cell
(A) M n is reduced from M n+4 to M n+3
(B) N H3 gas liberated out
(A) 0.325 (B) 0.65
(C) Zn is used as anode
(C) 0.25 (D) None of these
(6) How many atoms of calcium will be deposited from molten (D) Paste of N H4 Cl and ZnCl2 is used
CaCl2 by a current of 25 milli amperes flowing for (16) The standard potential of a Co+2 | Co electrode is −0.28 V
60 seconds and the standard potential of the cell
(A) 4.68 × 1018 (B) 4.68 × 1015 P t | T i2+ (aq.) , T i3+ (aq.) || Co2+ (aq.) | Co (s) is 0.09 V .
(C) 4.68 × 1012 (D) 4.68 × 109 what is the standard potential of the T i2+ (aq.) |T i(aq.)
3+

electrode ........... V
(7) The unit of equivalent conductivity is
(A) −0.37 (B) 0.37
(A) ohm cm
(C) −0.19 (D) 0.19
(B) ohm−1 cm2 (gm equivalent)−1
(17) The strongest reducing agent of the alkali metal is
(C) ohm cm2 (gm equivalent) (A) Li (B) N a
(D) S cm−2 (C) K (D) Cs

1
(18) The metal which is the best conductor of electricity is (28) The addition of a polar solvent to a solid electrolyte results in
(A) Iron (B) Copper (A) Polarization (B) Association
(C) Silver (D) Aluminium (C) Ionization (D) Non-liberation of heat
(19) During an electrolysis of conc. H2 SO4 , perdisulphuric acid (29) For the cell reaction
(H2 S2 O8 ) and O2 form at anode in equimolar amount. The Cu2+ (C1 aq) + Zn(s) ⇒ Zn2+ (C2 aq) + Cu(s) of an
mole of H2 that will form simultaneously at other electrode electrochemical cell, the change in free energy at a given
will be (Given : 2H2 SO4 → H2 S2 O8 + 2H + + 2e− ) temperature is a function of
(A) thrice of O2 (B) twice of O2 (A) ln (C1 ) (B) ln (C2 )
(C) equal to O2 (D) half of O2 (C) ln (C1 + C2 ) (D) ln (C2 /C1 )

(20) (i) Copper metal dissolves in 1M silver nitrate solution and (30) The magnitude of the change in oxidising power of the
crystals of silver metal get deposited. M nO4− /M n2+ couple is x × 10−4 V , if the H +
(ii) Silver metal does not react with 1M zinc nitrate solution concentration is decreased from 1 M to 10−4 M at 25◦ C.
(iii) Zinc metal dissolves in 1M copper sulphate solution and (Assume concentration of M nO4− and M n2+ to be same on
copper metal gets depositedHence the order of decreasing change in H + concentration). The value of x is ....... .
strength of the three metals as reducing agents will be (Rounded off to the nearest
 integer)
[ Given : 2.303RT = 0.059
(A) Cu > Ag > Zn (B) Ag > Cu > Zn F
(A) 3776 (B) 3800
(C) Zn > Cu > Ag (D) Cu > Zn > Ag
(C) 4276 (D) 1552
(21) What is the e.m.f . of the cell .............. V

Cr/Cr3+ (1.0 M ) || Co+2 (1.0 M )/Co (31) The equivalent conductance at infinite dilution ∧0 for
[E o for Cr3+ /Cr = −0.74 V and Co+2 /Co = −0.28 V ] electrolytes BA and CA are 140 and 120 S cm2 eq −1 . The
equivalent conductance at infinite dilution for BX is
(A) −0.46 (B) −1.02
198 S cm2 eq −1 . The ∧0 (in S cm2 eq −1 ) of CX is
(C) +0.46 (D) +166 (A) 178 (B) 198
(22) 5 amperes is passed through a solution of zinc sulphate for (C) 218 (D) 130
40 minutes. Find the amount of zinc deposited at the
cathode ............. gm (32) Consider the following E 0 values :
E 0 F e3+ /F e2+ = +0.77 V
(A) 40.65 (B) 4.065
E 0 Sn2+ /Sn = −0.14 V Under standard conditions the
(C) 0.4065 (D) 65.04 potential for the reaction
Sn(s) + 2F e3+ (aq) → 2F e2+ (sq) + Sn2+ (aq) is ............ V
(23) The standard reduction electrode potentials of four
elements are (A) 0.91 (B) 1.40
A = −0.250 V B = −0.136 V C = −0.126 V D = −0.402 V (C) 1.68 (D) 0.63
The element that displaces A from its compounds is
(33) The pressure of H2 required to make the potential of H2 −
(A) B (B) C electrode zero in pure water at 298 K is
(C) D (D) None of these (A) 10−10 atm (B) 10−4 atm
Θ (C) 10−14 atm (D) 10−12 atm
(24) In acidic medium M nO 4 is an oxidising agent
Θ ⊕ (34) Given are E o values for some half reactions
M nO 4 + 8H + 5e− → M n+2 + 4H2 O
⊕ I2 + 2e− → 2I − ; E o = 0.54 V
If H ion concentration is doubled, electrode potential of the M nO4− + 8H + + 5e− → M n2+ + 4H2 O ; E o = 1.52 V
half cell will F e3+ + e− → F e2+ ; E o = 0.77 V
(A) increase by 28.46 mV (B) decrease by 28.46 mV Sn4+ + 2e− → Sn2+ ; E o = 0.1 V
(C) increase by 14.23 mV (D) decrease by 142.3 mV The strongest reducant and oxidant respectively are
(A) Sn+4 , M nO4− (B) M n2+ , Sn4+
(25) When an electric current is passed through acidulated water
112ml of hydrogen gas at N.T.P. collect at the cathode in (C) Sn+2 , M nO4− (D) I 2 , Sn2+
965 seconds. The current passed, in amperes is (35) The standard electrode potentials
(A) 1.0 (B) 0.5 E o (I2 /I − ) , E ◦ (Br− /Br2 ) and E o (F e/F e2+ )
are respectively +0.54 V , −1.09 V and 0.44 V . On the basis
(C) 0.1 (D) 2.0
of above data which of the following process is
(26) The dissociation constant of acetic acid is 1.6 × 10−5 and non-spontaneous
ΛoCH3 COOH 370.6 × 10−4 mho m2 mol−1 The specific (A) Br2 + 2I − → 2Br− + I2 (B) F e+Br2 → F e2+ +2Br−
conductance of 0.01 molar acetic acid solution will be
(C) F e + I2 → F e2+ + 2I − (D) I2 + 2Br− → 2I − + Br2
approx
(A) 1.50 × 10−4 Scm2 mol−1 (B) 1.50 × 10−6 Scm2 mol−1 (36) Which of the following statements about galvanic cell is
incorrect
(C) 1.50 × 10−8 Scm2 mol−1 (D) 1.50 × 10−11 Scm2 mol−1 (A) Anode is positive
(27) The name of equation showing relation between electrode (B) Oxidation occurs at the electrode with lower reduction
potential (E)standard electrode potential (E o ) and potential
concentration of ions in solution is
(A) Kohlrausch’s equation (B) Nernst’s equation (C) Cathode is positive
(C) Ohm’s equation (D) Faraday’s equation (D) Reduction occurs at cathode

2
(37) A standard hydrogen electrode has zero electrode potential (47) On diluting the concentration of Cl− ions by ten times in a
because calomel electrode, its reduction potential at 298 K is -
(A) Hydrogen is easiest to oxidise (A) increased by 0.059 V (B) decreased by 0.059 V
(B) The electrode potential is assumed to be zero (C) increased by 0.0295 V (D) decreased by 0.0295 V
(C) Hydrogen atom has only one electron (48) The cell reaction involving quinhydrone electrode is:- ............ V
What will be the electrode potential at pH = 3
(D) Hydrogen is the lightest element
(38) P t (s) | H2 (g) | H + (P H = 2) || H + (P H =
1 atm
3) | H2 (g) | P t (s) cell reaction will be
1 atm
(A) spontaneous (B) nonspontaneous
(C) equilibrium (D) None of these
(39) What is the standard cell potential for the cell (A) 1.48 (B) 1.20
Zn/Zn2+ (1M ) || Cu2+ (1M )/Cu E o for
(C) 1.10 (D) 1.30
Zn/Zn2+ (1M ) = −0.76 V and Cu2+ /Cu = +0.34 V
(49) The quantity of electricity needed to liberate 0.5 gram
(A) −0.76 + (−0.34) = −0.42 V
equivalent of an element is
(B) −0.34 + 0.76 = +0.42 V (A) 48250 Faradays (B) 48250 Coulombs
(C) 0.34 − (−0.76) = 1.10 V (C) 193000 Faradays (D) 193000 Coulombs
(D) −0.76 − (+0.34) = −1.10 V
Column I Column II
(40) Saturated solution of KN O3 is used to make salt bridge Λc
(A) Kohlrausch (P ) m
because Λo
law can
m

(A) Mobility of K ⊕ is greater than that of N O3Θ calculate

(B) Mobility of N O3Θ is greater than that of K ⊕ (B) Molar con- (Q) 1
R
× l
A
ductance
(C) Mobilities of K ⊕ and N O3Θ are almost the same
Λm
(D) KN O3 is highly soluble in water (50) (C) Specific (R) Λom of ca3 (P O4 )2
(41) The emf of the cell conduc-
Ag|Ag + (0.1 M )||Ag + (1 M )|Ag at 298 K is ............ V tance
Kappa
(A) 0.0059 (B) 0.059 → (k)
(C) 5.9 (D) 0.59 (D) Degree of (S) k×1000
M
(42) E o of a cell aA + bB → cC + dD is ionization
c d A B
of weak
nF log [A]a [B]b
(A) − RT [C] [D]
(B) −RT log [a]
[a] [b]
electrolyte
C
[d]D

(C) − RT
c D c D
Which of the following option show correct matches
nF log [A]a [B]b (D) − RT
nF log [a]A [B]b
[C] [d] [C] [d]

(A) (A − R), (B − P ), (C − Q), (D − S)

(43) When 1 F of electricity is passed through acidulated water,
O2 evolved is ............. dm3 (B) (A − S), (B − P ), (C − Q), (D − R)
(A) 11.2 (B) 5.6
(C) (A − R), (B − S), (C − Q), (D − P )
(C) 22.4 (D) 1
(D) (A − P ), (B − S), (C − Q), (D − R)
(44) To protect iron against corrosion, the most durable metal
plating on it, is (51) When the sample of copper with zinc impurity is to be
(A) Nickel plating (B) Tin plating purified by electrolysis, the appropriate electrodes are
Cathode , Anode
(C) Copper plating (D) Zinc plating (A) Pure zinc , Pure copper
(45) The cell potential for Zn Zn (aq)∥Snx+ Sn is 0.801 V at
2+
(B) Impure sample , Pure copper
298 K. The reaction quotient for the above reaction is 10−2 .
The number of electrons involved in the given (C) Impure zinc , Impure sample
electrochemical cell reaction is. .... (Given
(D) Pure copper, impure sample
2+ |Zn = −0.763 V, ESnx+ |Sn = +0.008 V and
0 0
EZn


2.303 RT
F = 0.06 V (52) In a electrochemical cell
(A) 8 (B) 9 (A) Potential energy changes into kinetic energy
(C) 3 (D) 2 (B) Kinetic energy changes into potential energy
(46) In an experiment, 0.04 F was passed through 400 mL of a (C) Chemical energy changes into electrical energy
1 M solution of N aCl . What would be the pH of the
solution after the electrolysis ? (Change in volume will be (D) Electrical energy changes into chemical energy
negligible) (53) Specific conductance of 0.2 M electrolyte solution at 20 o C
(A) 8 (B) 10 temperature is 2.48 × 10−4 ohm−1 cm−1 then the molar
(C) 13 (D) 6 conductance of solution will be ............ ohm−1 cm2 mol−1

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 (A) 1.24 (B) 2.48 (A) CuSO4 (aq) + F e(s) → F eSO4 (aq) + Cu(s)
(C) 1.24 (D) 4.96 (B) F eSO4 (aq) + Zn(s) → ZnSO4 (aq) + F e(s)
(54) On passing electric current in an electrolyte solution H2 gas (C) 2CuSO4 (aq) + 2Ag(s) → 2Cu(s) + Ag2 SO4 (aq)
is liberated at cathode then electrolyte could be
(D) CuSO4 (aq) + Zn(s) → ZnSO4 (aq) + Cu(s)
(A) M gCl2 (B) AuCl3
(C) CuCl2 (D) AgN O3 (63) How much time is required for complete decomposition of
(55) At 25 C , the molar conductivity at infinite dilution for
o 4 moles of water using 4 ampere current ?
electrolytes KOH, KCl and BaCl2 are (A) 3.86 × 105 sec (B) 1.93 × 105 sec
248 × 10−4 , 126 × 10−4 and 280 × 10−4 Sm2 mol−1 (C) 96500 sec (D) 48250 sec
respectively calculate Λ∞
m for Ba(OH)2 (in Sm mol
2 −1
)
(A) 324 × 10 −4
(B) 524 × 10 −4 (64) In which cell the free energy of a chemical reaction is
directly converted into electricity ?
(C) 402 × 10−4 (D) 262 × 10−4
(A) Leclanche cell (B) Concentration cell
(56) The nature of charge on resulting colloidal particles when
F eCl3 is added to excess of hot water is : (C) Fuel cell (D) Lead storage battery
(A) Positive (65) When lead storage battery is charged
(B) Sometimes positive and sometimes negative (A) Lead dioxide dissolves
(C) Neutral (B) Sulphuric acid is regenerated
(D) Negative (C) The lead electrode becomes coated with lead sulphate
(57) Two solutions of X and Y electrolytes are taken in two (D) The amount of sulphuric acid decreases
beakers and diluted by adding 500 mL of water. Λm of X
increases by 1.5 times while that of Y increases by 20 times, (66) What is the amount of chlorine evolved when 2 amperes of
what could be the electrolytes X and Y ? current is passed for 30 minutes in an aqueous solution of
(A) X → N aCl, Y → KCl N aCl ............. g
(A) 66 (B) 1.32
(B) X → N aCl, Y → CH3 COOH
(C) 33 (D) 99
(C) X → KOH, Y → N aOH
(D) X → CH3 COOH, Y → N aCl (67) For a reaction ,A + B 2 → B + A+2 ; E o = 0.2955 V Hence
equilibrium constant of the reaction is at 25 o C
(58) Standard reduction potentials at 25o C of (A) 10 (B) 1010
Li+ |Li, Ba2+ | Ba, N a+ | N a and M g 2+ |M g are
−3.05, −2.90, −2.71 and −2.37 volt respectively. Which (C) −10 (D) 10−10
one of the following is the strongest oxidising agent
(68) If hydrogen electrode dipped in 2 solution of pH = 3 and
(A) N a+ (B) Li+
pH = 6 and salt bridge is connected the e.m.f. of resulting
(C) Ba2+ (D) M g 2+ cell is ............ V
(A) 0.177 (B) 0.3
(59) If x is specific resistance (in S −1 cm) of the electrolyte
solution and y is the molarity of the solution, then Λm (in (C) 0.052 (D) 0.104
S cm2 mol−1 ) is given by
(A) 1000x (B) 1000 xy (69) Which of the following metal does not react with the
y
solution of copper sulphate
(C) 1000
xy (D) xy
1000 (A) M g (B) F e
(60) The standard electrode potentlal (E − ) values of (C) Zn (D) Ag
Al3+ /Al, Ag+ /Ag, K+ /K and Cr3+ /Cr are −1.66 V, 0.80 V
−2.93 V and −0.74 V, respectively. The correct decreasing (70) Conductivity of a solution is directly proportional to
order of reducing power of the metal is (A) Dilution (B) Number of ions
(A) Ag > Cr > Al > K (B) K > Al > Cr > Ag
(C) Current density (D) Volume of the solution
(C) K > Al > Ag > Cr (D) Al > K > Ag > Cr
(71) A device that converts energy of combustion of fuels like
(61) What will be the molar conductance at infinite dilution for hydrogen and methane, directly into electrical energy is
N H4 OH if at infinite dilution the molar conductances of known as
Ba(OH)2 , BaCl2 and N H4 Cl are 523.28, 280.0 and (A) dynamo (B) N i − Cd cell
129.8 ohm−1 cm2 mol−1 respectively.
(A) 502.88 (B) 373.68 (C) fuel cell (D) electrolytic cell.

(C) 251.44 (D) 226.96 (72) On electrolysing a solution of dilute H2 SO4 between
platinum electrodes, the gas evolved at the anode is
(62) At 298 K, the standard electrode potentials of Cu2+ /
Cu, Zn2+ /Zn, F e2+ /F e and Ag + /Ag are 0.34 V , (A) SO2 (B) IF5
−0.76 V, −0.44 V and 0.80 V , respectively. (C) O2 (D) H2
On the basis of standard electrode potential, predict which
of the following reaction can not occur ? (73) Kohlrausch’s law states that at

4
 (A) For strong electrolyte, molar conductane varies linearly (81) Consider the following complexes
with concentration of electrolyte (a) K2 P tCl6 (b) P tCl4 .2N H3
(c) P tCl4 .3N H3 (d) P tCl4 .5N H3
(B) Infinite dilution, each ion makes definite contribution to Their electrical conductances in aqueous solutions are
molar conductance of an electrolyte whatever be the
(A) 256, 0, 97, 404 (B) 404, 0, 97, 256
nature of the other ion of the electrolyte
(C) 256, 97, 0, 404 (D) 404, 97, 256, 0
(C) At all concentration, each ion makes definite
contribution to molar conductance of an electrolyte (82) The mass deposited at an electrode is directly proportional
whatever be the nature of the other ion of the to
electrolyte (A) Atomic weight (B) Equivalent weight
(D) Molar conductance increases with decrease in (C) Molecular weight (D) Atomic number
concentration (83) How many faraday are needed to reduce a mole of M nO4−
(74) Given E o Ag+ /Ag = 0.80 V, E o M g2+ /M g = −2.37 V, to M n2+
E o Cu2+ /Cu = 0.34 V, E o Hg2+ /Hg = 0.79 V. (A) 4 (B) 5
Which of the following statements is correct ?
(C) 3 (D) 10
(A) AgN O3 can be stored in copper vessel
(84) For electroplating a spoon, it is placed in the voltameter at
(B) M g(N O3 )2 can not be stored in copper vessel
(A) The position of anode
(C) CuCl2 can be stored in silver vessel
(B) The position of cathode
(D) HgCl2 can be stored in copper vessel
(C) Exactly in the middle of anode and the cathode
(75) The resistance of 0.01 N N aCl solution at 25 o C is 200Ω.
(D) Anywhere in the electrolyte
Cell constant of conductivity cell is 1 cm−1 . The equivalent
conductance is (85) Calculate the current (in mA ) required to deposit 0.195 g of
(A) 5 × 102 Ω−1 cm2 eq −1 platinum metal in 5.0 hours from a solution of [P tCl6 ]2− :
(atomic weight : P t = 195 )
(B) 6 × 103 Ω−1 cm2 eq −1
(A) 310 (B) 31
(C) 7 × 104 Ω−1 cm2 eq −1
(C) 21.44 (D) 5.36
(D) 8 × 105 Ω−1 cm2 eq −1 (86) With the help of following reactions, arrange metals A, B, D
(76) If one end of a piece of a metal is heated, the other end and E in decreasing order of their reactivity
becomes hot after some time. This is due to (I) B + AN O3 −→ BN O3 + A
(A) Energised electrons moving to the other part of the (II) A + HCl −→ ACl + 12 H2
metal (III) D + ECl −→ DCl + E
(IV ) D + HN O3 −→ H2 gas is not evolved
(B) Resistance of the metal
(A) B > D > E > A (B) B > A > D > E
(C) Mobility of atoms in the metal
(C) E > D > B > A (D) None of these
(D) Minor perturbation in the energy of atoms (87) If 0.5 amp current is passed through acidified silver nitrate
(77) λClCH2 COON a = 224 ohm−1 cm2 gmeq −1 , solution for 10 minutes. The mass of silver deposited on
λN aCl = 38.2 ohm−1 cm2 gmeq −1 , cathode, is ........... g (eq. wt. of silver nitrate = 108)
λHCl = 203 ohm−1 cm2 gmeq −1 , (A) 0.235 (B) 0.336
What is the value of λClCH2 COOH ..............
(C) 0.536 (D) 0.636
Ohm−1 cm2 gm eq−1
(A) 288.5 (B) 289.5 (88) The unit of cell constant is
(A) ohm−1 cm−1 (B) ohm cm
(C) 388.5 (D) 59.5
(78) When lead storage battery is charged (C) cm (D) cm−1
(A) Lead dioxide dissolves (89) Calculate the electrode potential at 298 o K for Zn|Zn++
electrode in which the activity of zinc ions is 0.001 M and
(B) Sulphuric acid is regenerated E o Zn/Zn++ is −0.74 volts ............ V
(C) The lead electrode becomes coated with lead sulphate (A) 0.38 (B) 0.83
(D) The amount of sulphuric acid decreases (C) 0.40 (D) 0.45
(79) Incorrect statement from the following statements during (90) In a hydrogen -oxygen fuel cell, combustion of hydrogen
the discharge of lead storage battery is occurs to
(A) P bO2 is reduced (A) Produce high purity water
(B) P b is oxidised (B) Create potential difference between the two electrodes
(C) equivalent mass of H2 SO4 is 98 (C) Generate heat
(D) Extent of discharging is independent of H2 SO4 (D) Remove adsorbed oxygen from electrode surfaces
(80) The standard electrode potential is measured by (91) A depolarizer used in dry cell batteries is
(A) Electrometer (B) Voltmeter (A) Ammonium chloride (B) Manganese dioxide
(C) Pyrometer (D) Galvanometer (C) Potassium hydroxide (D) Sodium phosphate

5
 (92) Which one of the following material conducts electricity (102) In a galvanic cell, the electrons flow from
(A) Diamond (A) Anode to cathode through the solution
(B) Crystalline sodium chloride (B) Cathode to anode through the solution
(C) Barium sulphate (C) Anode to cathode through the external circuit
(D) Fused potassium chloride (D) Cathode to anode through the external circuit
(93) For the cell, ........... kJ (103) P t|H2 (1 atm) |H + (0.001 M ) ||H + (0.1 M ) |H2 (1 atm)|P t
(aq) (0.4 M )||Sn(aq) (0.04 M )|Sn(S) ,
M n(S) |M n+2 +2
What will be the value of Ecell for this cell? ............. V
Calculate free energy change (∆G) at 298 K . (A) 0.1182 (B) −0.1182
Given :EMo
n+2 |M n = − 1.18 V ; ESn+2 |Sn = − 0.14 volt
o
(C) 0.0591 (D) −0.0591
2.303 RT
= 0.06
F
(104) ∧∞
AgCl can be obtained
(A) 180.93 (B) −194.93 √
(A) by extraplotation of the graph ∧ and C to zero
(C) −180.93 (D) None of these
concentration
(94) Iron is protected by coating it with a thin layer of
(B) by known values of ∧∞ of AgN O3 , HCl and HN O3
(A) Cu (B) Zn
(C) both (A) and (B)
(C) P b (D) M g
(D) None of these
(95) Which of the following statement is true for an
electrochemical cell (105) The chemical reaction, 2AgCl(s) + H2 (g) →
(A) H2 is cathode and Cuis anode 2HCl(aq) + 2Ag(s) taking place in a galvanic cell is
represented by the notation
(B) H2 is anode and Cu is cathode
(A) P t|H2 (g), 1 bar|1 M KCl(aq)|AgCl (s)|Ag (s)
(C) Reduction occurs at H2 electrode
(B)
(D) Oxidation occurs at Cu electrode P t (s)|H2 (g), 1 bar| 1 M HCl (aq)||1 M Ag + (aq)|Ag (s)
(96) The conductivity of strong electrolyte is (C) P t (s)|H2 (g), 1 bar| 1 M HCl (aq)|AgCl (s)|Ag (s)
(A) Increase on dilution slightly (D) P t (s)|H2 (g), 1 bar| 1 M HCl (aq)|Ag (s)|AgCl (s)
(B) Decrease on dilution (106) The increase in equivalent conductance of an electrolyte
(C) Does not change with dilution solution with dilution is due to the increase in
(A) Ionic attraction
(D) Depend upon density of electrolytes itself
(B) Molecular attraction
(97) A certain quantity of electricity is passed through an
aqueous solution of AgN O3 and cupric salt solution (C) Degree of association of the electrolyte
connected in series. The amount of Ag deposited is 1.08 gm, (D) Degree of ionisation of the electrolyte
the amount of copper deposited is ............. g (atomic weight
of Cu = 63.5 ; Ag = 108) (107) A cell from the following which converts electrical energy
(A) 0.6454 (B) 6.354 into chemical energy
(A) Dry cell (B) Electrochemical cell
(C) 0.3177 (D) 3.177
(C) Electrolytic cell (D) None of these
(98) What pressure (bar) of H2 would be required to make emf of
hydrogen electrode zero in pure water at 25◦ C ? (108) The electric conduction of a salt solution in water depends
on the
(A) 10 −14
(B) 10 −7
(A) Shape of its molecules
(C) 1 (D) 0.5
(B) Size of its molecules
(99) When Zn piece is kept in CuSO4 solution, the copper get
precipitated due to standard potential of zinc is (C) Size of solvent molecules
(A) > copper (B) < copper (D) Extent of its ionization
(C) > sulphate (D) < sulphate (109) Then during electrolysis of a solution of AgN O3 , 9650
coulombs of charge pass through the electroplating bath,
(100) Copper sulphate solution is electrolysed between two
the mass of silver deposited in the cathode will be .............. g
platinum electrodes. A current is passed until 1.6 g of
oxygen is liberated at anode. The amount of copper (A) 1.08 (B) 10.8
deposited at the cathode during the same period is .............. g (C) 21.6 (D) 108
[At. mass of Cu = 63.6]
(110) M n O4−1 + 8 H + + 5e− → M n+2 (aq) + 4H2 O(l) ;
(A) 6.36 (B) 63.6 (aq) (aq)
o
(C) 12.7 (D) 3.2 E1 = 1.51 V
M nO2 (s) + 4H + (aq) + 2e− → M n+2 (aq) + 2H2 O(l) ;
(101) 96500 coulombs of electric current liberates from CuSO4 E2o = 1.21 V
solution .............. gm Cu M nO4−1 (aq) + 4H + (aq) + 3e− → M nO2 (s) + 3H2 O(l) ;
(A) 63.5 (B) 31.75 E3o ?
(C) 96500 (D) 100 value of E3o will be ............ V

6
 (A) 1 (B) 2.42 (120) Molar ionic conductivities of divalent cation and anion are
57 S cm2 mol−1 and 73 S cm2 mol−1 respectively. The molar
(C) 2.61 (D) 1.71 conductivity of solution of an electrolyte with the above
(111) In aqueous solution, strong electrolytes cation and anion will be :
(A) Are partially ionized (A) 65 S cm2 mol−1 (B) 130 s cm2 mol−1

(B) Do not ionise (C) 187 S cm2 mol−1 (D) 260 s cm2 mol−1
(121) During electrolysis, the species discharged at cathode are
(C) Ionise almost completely
(A) Ions (B) Cation
(D) Form polymers
(C) Anion (D) All of these
(112) Which one of the following statement is true for a
(122) If 1 A of current is passed through CuSO4 solution for 10
electrochemical cell
seconds, then the number of copper ions deposited at the
(A) H2 is cathode and Cu is anode cathode will be about
(B) H2 is anode and Cu is cathode (A) 1.6 × 1019 (B) 3.1 × 1019
(C) Reduction occurs at H2 electrode (C) 4.8 × 1019 (D) 6.2 × 1019
(D) Oxidation occurs at Cu electrode (123) During electrolysis of aqueous N aOH, 4 g of O2 gas is
liberated at N T P at anode, H2 gas liberated at cathode is
(113) Limiting molar conductivity of CH3 COOH (i.e. ............... litres
Λom (CH3 COOH) is equal to (A) 2.8 (B) 5.6
(A) Λom (CH3 COOH) + Λom (CH3 COON a) − Λom (N aOH) (C) 11.2 (D) 22.4
(B) Λom (CH3 COON a) + Λom (HCl) − Λom (N aCl) (124) Which of the following is displaced by F e
(A) Ag (B) Hg
(C) Λom (CH3 COON a) + Λom (N aCl) − Λom (N aOH)
(C) Zn (D) Both (a) and (b)
(D) Λom (N aOH) + Λom (N aCl) − Λom (CH3 COON a)
(125) The correct order of reduction potentials of the following
(114) The oxidation potential of a hydrogen electrode at pH = 10 pairs is
and PH2 = 1 atm will be ............ V A. Cl2 /Cl− B. I2 /I − C. Ag + /Ag D. N a+ /N a E. Li+ /Li
Choose the correct answer from the options given below.
(A) 0.059 (B) 0.59
(A) A > C > B > D > E
(C) 0 (D) 0.51
(B) A > B > C > D > E
(115) The electrode potentials for
Cu2+ (aq) + e− → Cu+ (aq) (C) A > C > B > E > D
and Cu+ (aq) + e− → Cu(s)
(D) A > B > C > E > D
are +0.15 V and +0.50 V respectively. The value of will be
............ V (126) The resistance of 0.5 M solution of an electrolyte in a cell
(A) 0.500 (B) 0.325 was found to be 50 Ω. If the electrodes in the cell are 2.2 cm
apart and have an area of 4.4 cm2 then the molar
(C) 0.650 (D) 0.150 conductivity (in S m2 mol−1 ) of the solution is
(116) The equivalent conductance of M /32 solution of a weak (A) 0.2 (B) 0.02
monobasic acid is 8.0 mho cm2 and at infinite dilution is
400 mho cm2 . The dissociation constant of this acid is (C) 0.002 (D) 0.001
(A) 1.25 × 10−6 (B) 6.25 × 10−4 (127) When a certain conductivity cell was filled with 0.1 M KCl ,
it had a resistance of 85 Ω at 25 o C . When the same cell was
(C) 1.25 × 10−4 (D) 1.25 × 10−5
filled with an aqueous solution of 0.052 M unknown
(117) Mass in grams of copper deposited by passing 9.6487 A electrolyte, the resistance was 96 Ω . Calculate the molar
current through a voltmeter containing copper sulphate conductivity of the unknown electrolyte at this
solution for 100 seconds is (Given : Molar mass of concentration ............. Ω−1 cm2 mol−1 (Given : Specific
Cu : 63 g mol−1 , 1 F = 96487C ) conductance of 0.1 M KCl = 1.29 × 10−2 Ω−1 cm−1 )
(A) 0.315 g (B) 31.5 g (A) 120 (B) 219.65
(C) 0.0315 g (D) 3.15 g (C) 200.35 (D) None of these
(118) The standard EM F for the given cell reaction (128) A current of 0.4 amp is passed through excess of molten
Zn + Cu2+ = Cu + Zn2+ is 1.10 V at 25o C. The EM F for M gCl2 for 9.65 × 104 sec. The mass of M g deposited at the
the cell reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ cathode is .............. gm
solutions are used, at 25 o C is ..........V (A) 0.4 (B) 2.4
(A) 1.10 (B) 0.110
(C) 4.8 (D) 9.6
(C) −1.10 (D) −0.110 (129) Which one of the following statements is correct
(119) The molar conductivity of 0.007 M acetic acid is (A) The oxidation number of oxygen in KO2 is zero
20 S cm2 mol−1 . What is the dissociation constant of acetic
acid? (In ×10−5 mol L−1 ) (B) The specific conductance of an electrolyte solution
[Λ◦H+ = 350 S cm2 mol−1 , Λ◦CH3 COO− = 50 S cm2 mol−1 ] decreases with increase in dilution

(A) 175 (B) 2.50 (C) Sn2+ oxidises F e3+

(C) 1.75 (D) 250 (D) Zn/ZnSO4 is a reference electrode

7
(130) The standard potential of a Co+2 |Co electrode is −0.28 V (A) Increase in the concentration of Ag + ions
and the standard potential of the cell
P t|T i2+ (aq), T i3+ (aq)||Co2+ (aq)|Co(s) is 0.09 V . What is (B) Increase in the concentration of Sn2+ ions
the standard oxidation potential of the T i2+(aq.) | T i(aq.)
3+
(C) Increase in size of the silver rod
electrode ? ............. V
(A) −0.37 (B) 0.37 (D) None of these
(139) On electrolysis of aqueous solution of KI in presence of
(C) −0.19 (D) 0.19
platinum electrodes
(131) On electrolysis of aqueous solution of KI in presence of (a) Hydrogen gas is released at cathode
platinum electrodes (b) Oxygen gas is released at anode
(a) Hydrogen gas is released at cathode (c) pOH of solution decreases
(b) Oxygen gas is released at anode. (d) There is deposition of potassium at cathode
(c) pOH of solution decreases Choose the correct option from following
(d) There is deposition of potassium at cathode (A) a, b (B) only a
Choose the correct option from following (C) a, c (D) a, c, d
(A) a, b (B) only a
(140) Which of the following is not used to construct salt bridge
(C) a, c (D) a, c, d (A) CH3 COOK (B) KCl

(132) What will be the electromotive force of following cell (C) N H4 N O3 (D) KN O3
F e|F e+2 (0.2 M ) || Au+3 (0.02 M ) |Au, if ........... V (141) Electricity required for liberating 710 g of Cl2 (g) by
EFo e+2 /F e = −0.44 V and EAu/Au
o
+3 = −1.50 V electrolyzing a concentrated solution of N aCl will be
(A) 1.914 (B) 1.047 (A) 1.93 × 105 C (B) 1.93 × 106 C

(C) 1.91 (D) 1.927 (C) 9.65 × 106 C (D) 9.65 × 105 C
(142) Calculate ΛHOAc using appropriate molar conductances of
∞
(133) Which one of the following metals cannot evolve H2 from the electrolytes listed above at infinite dilution in H2 O at
acids or H2 O or from its compounds 25 o C
(A) Hg (B) Al
ElectrolyteKCl KN O3 HCl N aOAc N aCl
(C) P b (D) F e
:
(134) Assertion: Electrical conductivity of copper increases with
increase in temperature
Reason: The electrical conductivity of metals is due to Λ∞ (Scm2149.9
mol−1 ): 145.0 426.2 91.0 126.5
motion of electrons.
(A) If both Assertion and Reason are correct and the Reason (A) 517.2 (B) 552.7
is a correct explanation of the Assertion.
(C) 390.7 (D) 217.5
(B) If both Assertion and Reason are correct but Reason is (143) Pure conc. HN O3 makes iron passive as the surface is
not a correct explanation of the Assertion. covered with protective layer of
(C) If the Assertion is correct but Reason is incorrect. (A) F e2 O3 (B) F eO
(D) If the Assertion is incorrect but the Reason is correct. (C) F e3 O4 (D) F e(N O3 )3
(144) The standard reduction potentials of Cu2+ , Zn2+ , Sn2+
(135) Degree of ionisation of a solution depends upon and Ag + are 0.34, −0.76, −0.14 and 0.80 V respectively.
(A) Temperature The storage that is possible without any reaction is for
(B) Nature of the electrolyte (under standard condition) :
(A) CuSO4 solution in a zinc vessel
(C) Nature of the solvent
(B) AgN O3 solution in a zinc vessel
(D) All of these
(C) AgN O3 solution in a tin vessel
(136) At 298 K the emf of cell is ............ V (D) CuSO4 solution in a silver vessel
P t|H2(2 atm) |H(0.02
⊕ ⊕
M ) ||H(0.1 M ) |H2(1 atm) |P t
(145) E.C.E. of Cu and Ag are 7 × 10−6 and 1.2 × 10−6 .A certain
(A) 0.05 (B) 0.0295
current deposits 14 gm of Cu. Amount of Ag deposited is
(C) 0.1 (D) 0.059 .............. gm
(A) 1.2 (B) 1.6
(137) 0.50 L of a 0.60 M CuSO4 solution is electrolyzed for a
period of 30.0 min using a current of 4.60 A. If inert (C) 2.4 (D) 1.8
electrodes are used, what is the final concentration of Cu2+ (146) The electrolytic decomposition of dilute sulphonic acid with
remaining in the solution ? ............. M platinum electrode in cathodic reaction is
(A) 0.342 (B) 0.544 (A) Oxidation
(C) 0.389 (D) 0.514 (B) Reduction

(138) Which will increase the voltage of the cell (C) Oxidation and reduction both
Sn(s) + 2Ag + (aq) → Sn2+ (aq) + 2Ag(s) (D) Neutralisation

8
 √
(147) At 25◦ C, the molar conductance at infinite dilution for the (155) For strong electrolyte ∧m = ∧om − 10 C . Then calculate
strong electrolytes N aOH, N aCl and BaCl2 are ∧m at 0.01 M if its value at 0.16 M is 200 Scm2 mol−1 ................
248 × 10−4 , 126 × 10−4 and 280 × 10−4 Sm2 mol−1 S cm2 mol−1
respectively. λom Ba(OH)2 in Sm2 mol−1 is
(156) How many coulombs are provided by a current of 0.010 mA
(A) 362 × 10 −4
(B) 402 × 10 −4 in the calculator battery that can operate for 1000 hours ?

(C) 524 × 10 −4
(D) 568 × 10−4 (157) The resistance of conductivity cell containing 0.01 M KCl
solution at 298 K is 1750 Ω. If the conductively of
(148) What is the potential of a cell containing two hydrogen
0.01 M KCl solution at 298 K is 0.152 × 10−3 S cm−1 , then
electrodes the negative one in contact with 10 M H and−8 +
the cell constant of the conductivity cell is
positive one in contact with 0.025 M H + .............. V
.......... × 10−3 cm−1 .
(A) 0.18 (B) 0.28
(158) The conductance of a 0.0015M aqueous solution of a weak
(C) 0.38 (D) 0.48
monobasic acid was determined by using a conductivity cell
(149) Consider the cell whose emf is 1.01 V . consisting of platinized Pt electrodes. The distance between
+
Haq Ag + Ag the electrodes is 120 cm with an area of cross section of
H2 (P t)
1 atm pH = 4 xM 1 cm2 . The conductance of this solution was found to be
What is the value of x ? ........... M × 10−7 S. The pH of the
( give : EAg
o
+ |Ag = +0.8
2.303 RT
= 0.06)
5
solution is 4 . The value of limiting
F molar conductivity Λ0m of this weak monobasic acid in
(A) 0.05 (B) 0.69 aqueous solution is Z × 102 S cm−1 mol−1 . The value of Z is
(C) 0.15 (D) 0.31 (159) Given l/a = 0.5 cm−1 , R = 50 ohm, N = 1.0. The
(150) The logarithm of equilibrium constant for the reaction equivalent conductance of the electrolytic cell is ................
P d2+ + 4Cl− ⇌ P dCl42− is (Nearest integer) Ohm−1 cm2 gm eq−1
Given : 2.303RT = 0.06V
F
− (160) A solution of F e2 (SO4 )3 is electrolyzed for ′ x′ min with a
P d2+ + 2e ⇌ P d(s) E ◦ = 0.83 V
(aq) current of 1.5 A to deposit 0.3482 g of F e. The value of x is
P dCl42− (aq) + 2e− ⇌ P d(s) + 4Cl− (aq) ........ [nearest integer]
E ◦ = 0.65 V Given : 1 F = 96500 C mol−1
(A) 3 (B) 4 Atomic mass of F e = 56 g mol−1
(C) 12 (D) 6
(161) The equilibrium constant for the reaction
Zn(s) + Sn2+ (aq) ⇌ Zn2+ (aq) + Sn(s) is 1 × 1020 at 298K.
.......... Chemistry - Section B (NUMERIC) .......... The magnitude of standard electrode potential of Sn/Sn2+
if EZn
0
2+//nn = −0.76V is ............ × 10
−2
V . (Nearest
(151) The limiting molar conductivities of N aI, N aN O3 and integer)
AgN O3 are 12.7, 12.0 and 13.3 m Sm2 mol−1 , respectively Given : 2.303RT = 0.059 V
(all at 25◦ C ). The limiting molar conductivity of AgI at this F

temperature is .... m Sm2 mol−1 (162) How many minutes are required to deliver 3.21 × 106
Columbs using a current of 500 A used in the commercial
(152) Following figure shows dependence of molar conductance
0 production of chlorine?
of two electrolytes on concentration. Λ m is the limiting
molar conductivity.The number of Incorrect statement(s) (163) Emf of the following cell at 298 K in V is
from the following is ........... x × 10−2 .Zn Zn2+ (0.1 M )∥Ag + (0.01 M ) Ag The value of
0
(A) Λ m for electrolyte A is obtained by extrapolation x is .... .
√ (Rounded off to the nearest integer)
(B) For electrolyte B, vx Λm vs c graph is a straight line
0 [Given : EZn 0
= −0.76 V ; EAg
0
+ /A =
with intercept equal to Λ m
+2 /Z
n g
2.303RT
(C) At infinite dilution, the value of degree of dissociation +0.80 V ; F = 0.059]
approach zero for electrolyte B. (164) For the galvanic cell,
0
(D) Λ m for any electrolyte A or B can be calculated using Zn(s) + Cu2+ (0.02M) → Zn2+ (0.04M) + Cu(s)
λ◦ for individual ions. E
hcell = ...... × 10 V(N earestinteger)
−2

Use : E0Cu/Cu2+ = −0.34 V, E02n/Zn2+ = +0.76 V


2.303RT
F = 0.059 V
(165) The limiting molar conductivities ∧0 for N aCl, KBr and
KCl are 126, 152 and 150 S cm2 mol−1 respectively. The ∧0
for N aBr is ............ S cm2 mol−1
(166) A current being passed for two hour through a solution of
an acid liberating 11.2 litre of oxygen at N T P at anode.
(153) The resistance of 0.05 M solution of oxalic acid is 200 ohm What will be the amount of copper deposited at the
and cell constant is 2.0 cm−1 , the equivalent conductance cathode by the same current when passed through a
[S cm2 eq −1 ] will be solution of copper sulphate for the same time ........... g
(154) On passing electric current through molten aluminium (167) All the energy released from the reaction
chloride, 11.2 litre of Cl2 is liberated at N T P at anode. The X → Y · ∆T G0 = −193 kJ mol−1 is used for oxidizing
quantity of aluminium deposited at cathode is .............. g (at. M + as M + → M 3+ + 2e− , E 0 = −0.25 V .
wt. of Al = 27) Under standard conditions, the number of moles of

9
  oxidized when−1one
 mole of X is converted to Y is through a solution of N i (N O3 )2 for ’ x ’ seconds to coat the
+
M
F = 96500 C mol desired layer. The value of x is .......... (Nearest integer)
( ρN i (density of Nickel) is 10 gmL−1 , Molar mass of Nickel is
(168) Conductivity of 0.001 M aq.solution of N a2 SO4 is found to 60 gmol−1 F = 96500 C mol−1 )
be 2.6 × 10−3 S cm−1 at 25 o C. If limiting molar
conductance of N a+ is 50 S cm2 mol−1 , then limiting molar (183) When 0.1 mol M nO42− is oxidised the quantity of electricity
conductance of SO42− will be .............. S cm2 mol−1 (neglect required to completely oxidise M nO42− to M nO4− is ........ C.
conductivity of water). ∞

(184) Given that 1
3 m Fe
λ 3+
= 68 ohm−1 cm−1 eq −1 and
(169) The value of one Faraday is .............. C mol −1
∞

1
2 λm SO4
2−
= 80 ohm−1 cm−1 eq −1 What will be value of
(170) The density of Cu is 8.94 g cm−3 . The quantity of electricity ∞
needed to plate an area 10 cm × 10 cm to a thickness of λeq (F e2 (SO4 )3 ) ? ............ ohm−1 cm2 eq−1
10−2 cm using CuSO4 solution would be, if atomic mass of (185) 0.5 N solution of a salt placed between two platinum
Cu is 63.5 .................. C electrodes 2.0 cm apart and of area of cross section 4.0 cm2
(171) At 298 K, a 1 litre solution containing 10 m mol of Cr2 O7 2− has a resistance of 25 ohms . Calculate the equivalent
and 100 m mol of Cr3+ shows a pH of 3.0. conductivity of solution ................. Ω−1 cm2 eq−1
Given : Cr2 O72− → Cr3+ ; E 0 = 1.330 V and o
2.303RT
= 0.059 V (186) The limiting molar conductivity Λ for N aCl, KBr and KCl
F o
The potential for the half cell reaction is x × 10−3 V . The are 126, 152 and 150 S cm2 mol−1 respectively. The Λ for
value of x is ........ N aBr is (in S cm2 mol−1 ).

(172) Alkanes can be made by electrolysis of aquesus solution of (187) The standard reduction potentials at 298 K for the following
potassium salt of carboxylic acid. Find the weight of all half cells are given below :
gases evolved at ST P by passing 20 amp current for Cr2 O7 2− + 14H+ + 6e− → 2Cr3+ + 7H2 O, E◦ = 1.33 V
9650 sec during elctrolysis of CH3 COO− K + (aq) reaction
.......... g [Ignore parallel or side reaction] Fe3+ (aq) + 3e− → FeE◦ = −0.04 V
Ni2+ (aq) + 2e− → NiE◦ = −0.25 V
(173) The specific conductance of 0.0025 M acetic acid is
5 × 10−5 S cm−1 at a certain temperature. The dissociation Ag+ (aq) + e− → AgE◦ = 0.80 V
constant of acetic acid is ...... 10−7 . (Nearest integer) Au3+ (aq) + 3e− → AuE◦ = 1.40 V
Consider limiting molar conductivity of CH3 COOH as
400 S cm2 mol−1 Consider the given electrochemical reactions, The number
of metal(s) which will be oxidized be Cr2 O7 2− , in aqueous
(174) During electrolysis of aq. N aCl , if 3 mole of H2 O are solution is. . . . . .
electrolysed then how much charge is required if current
efficiency is 75 % .............. F (188) 2H + (aq) + 2e− → H2 (g).The standard electrode potential
for the above reaction is (in volts)
(175) Ionic conductance of Ga+3 ions and N O3− ions at infinite
dilution are 120 Ω−1 cm2 mol−1 and 50 Ω−1 cm2 mol−1 (189) The amount of charge required to liberate 9 gm of
respectively. Equivalent conductance of Ga(N O3 )3 at aluminium (atomic weight = 27 and valency = 3) in the
infinite dilution will be ........... Ω−1 cm2 eq−1 process of electrolysis is ......... coulombs (Faraday’s number
= 96500 coulombs/gm equivalent)
(176) How many Faradays are required to generate one gram
atom of magnesium from M gCl2 (190) In an electrochemical reaction of lead, at standard
temperature, if E(P 0
b2+ /P b) = m Volt and E(P b4+ /P b) = n
0
(177) To deposit 0.6354 gm of copper by electrolysis of aqueous
Volt, then the value of E(P 0
b2+ /P b4+ ) is given by m − xn. The
cupric sulphate solution, the amount of electricity required
value of x is ............ (Nearest integer)
(in coulombs) is
(191) The molar conductivities at infinite dilution of barium
(178) In a metal oxide, there is 20% oxygen by weight. Its
chloride, sulphuric arid and hydrochloric acid are 280, 860
equivalent weight is
and 426 Scm2 mol−1 respectively. The molar conductivity at
(179) 1 × 10−5 M AgNO 3 is added to 1 L of saturated solution of infinite dilution of barium sulphate is ...... Scm2 mol−1 (
AgBr. The conductivity of this solution at 298 K is Round off to the Nearest Integer).
......... × 10−8 S m−1
[ Given : Ksp (AgBr) = 4.9 × 10−13 at 298K (192) The quantity of charge required to obtain 1 mole of
λ0Ag+ = 6 × 10−3 Sm2 mol−1 aluminium from Al2 O3 is ............ F
λ0Br− = 8 × 10−3 Sm2 mol−1 i (193) An acidic solution of dichromate is electrolyzed for 8
λ0N O− = 7 × 10−3 Sm2 mol−1 minutes using 2 A current. As per the following equation
3
Cr2 O72− + 14H + + 6e− → 2Cr3+ + 7H2 O
(180) 4 g of copper was dissolved in concentrated nitric acid. The The amount of Cr3+ obtained was 0.104 g. The
copper nitrate solution on strong heating gave 5 g of its efficiency of the process(in%) is
oxide. The equivalent weight of copper is (Take : F = 96000 C, At. mass of chromium = 52 )

(181) How long would it take to reduce completely 80 mL of (194) To deposit one litre of hydrogen at 22.4 atmosphere from
0.1 M F e2 (SO4 )3 to F eSO4 by passing = a current of acidulaled water, the quantity of electricity that must pass
2 Amp ? ........... sec through is ............. coulomb
(182) A metal surface of 100 cm2 area has to be coated with nickel (195) The number of coulombs required for the deposition of
layer of thickness 0.001 mm. A current of 2 A was passed 107.870 g of silver is

10
(196) Resistance of a decimolar solution between two electrodes
0.02 meter apart and 0.0004 m2 in area was found to be
50 ohm. Specific conductance (k) is : ........... S m−1
(197) What is E o for electrode represented by
P t, O2 (1 atm) / 2H + (1 m) ............. V
(198) The resistance of a conductivity cell with cell constant
1.14 cm−1 , containing 0.001 M KCl at 298 K is 1500 Ω. The
molar conductivity of 0.001 M KCl solution at 298 K in
S cm2 mol−1 is ...... . (Integer answer)
(199) The charge required for the reduction of 1 mol of M nO4− to
M nO2 is ............ F
(200) Standard electrode potential of N HE at 298 K is .............. V

11
 Electrochemistry

Subject : Chemistry Paper Set : 1

Electrochemistry Date : 18-05-2025
Standard : 12
Total Mark : 800 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1-A 2-D 3-B 4-B 5-A 6-A 7-B 8-B 9-D 10 - B

11 - D 12 - C 13 - D 14 - C 15 - B 16 - B 17 - A 18 - C 19 - A 20 - C
21 - C 22 - B 23 - C 24 - A 25 - A 26 - A 27 - B 28 - C 29 - D 30 - A
31 - A 32 - A 33 - C 34 - C 35 - D 36 - A 37 - B 38 - B 39 - C 40 - C
41 - B 42 - A 43 - B 44 - D 45 - D 46 - C 47 - A 48 - A 49 - B 50 - C
51 - D 52 - C 53 - C 54 - A 55 - B 56 - A 57 - B 58 - D 59 - C 60 - B
61 - C 62 - C 63 - B 64 - C 65 - B 66 - B 67 - B 68 - A 69 - D 70 - B
71 - C 72 - C 73 - B 74 - C 75 - A 76 - A 77 - C 78 - B 79 - D 80 - B
81 - A 82 - B 83 - B 84 - B 85 - C 86 - B 87 - B 88 - D 89 - B 90 - B
91 - B 92 - D 93 - B 94 - B 95 - B 96 - A 97 - C 98 - A 99 - B 100 - A
101 - B 102 - C 103 - A 104 - B 105 - B 106 - D 107 - C 108 - D 109 - B 110 - D
111 - C 112 - B 113 - B 114 - B 115 - B 116 - D 117 - A 118 - A 119 - C 120 - B
121 - B 122 - B 123 - B 124 - D 125 - A 126 - C 127 - B 128 - C 129 - B 130 - B
131 - C 132 - D 133 - A 134 - D 135 - D 136 - A 137 - D 138 - A 139 - C 140 - A
141 - B 142 - C 143 - C 144 - D 145 - C 146 - B 147 - C 148 - C 149 - D 150 - D

Chemistry - Section B (NUMERIC)

151 - 14 152 - 2 153 - 100 154 - 9 155 - 203 156 - 36 157 - 266 158 - 6 159 - 10 160 - 20
161 - 17 162 - 107 163 - 147 164 - 109 165 - 128 166 - 63 167 - 4 168 - 160 169 - 96500 170 - 27172
171 - 917 172 - 120 173 - 66 174 - 4 175 - 90 176 - 2 177 - 1930 178 - 32 179 - 14 180 - 32
181 - 772 182 - 161 183 - 9650 184 - 148 185 - 40 186 - 128 187 - 3 188 - 0 189 - 96500 190 - 2
191 - 288 192 - 3 193 - 60 194 - 193000 195 - 96500 196 - 1 197 - 0 198 - 760 199 - 3 200 - 0

12
 Electrochemistry

Subject : Chemistry Paper Set : 1

Electrochemistry Date : 18-05-2025
Standard : 12
Total Mark : 800 (Solutions) Time : 0H:0M

(4) Zn gives hydrogen gas with H2 SO4 and HCl but not with
............ Chemistry - Section A (MCQ) ............
HN O3 because
(A) N O2 is reduced in preference to H3 O+
(1) Equivalent conductance of an electrolyte containing N aF at
infinite dilution is 90.1 (B) HN O3 is weaker acid than H2 SO4 and HCl
Ohm−1 cm2 . If N aF is replaced by KF what is the value of (C) Znacts as oxidising agent when reacts with HN O3
equivalent conductance? ........... Ohm−1 cm2
(A) 90.1 (B) 111.2 (D) In electrochemical series Znis placed above the
hydrogen
(C) 0 (D) 222.4
Solution:(Correct Answer:B)
Solution:(Correct Answer:A) (b)4Zn + 10HN O3 → 4Zn(N O3 )2 + N H4 N O3 + 3H2 O
Because at infinite dilution the equivalent conductance of
strong electrolytes furnishing same number of ions is same. (5) The value of x from the given data is

(2) Electrical conductance through metals is called metallic or

electronic conductance and is due to the movement of
electrons. The electronic conductance depends on
(A) the nature of metal (A) 0.325 (B) 0.65
(B) the number of valance electrons per atom (C) 0.25 (D) None of these
(C) change in temperature
Solution:(Correct Answer:A)
(D) all of these n E◦ +n E◦
E◦3 = 1 1n3 2 2 = 1×0.15+1×0.5
2
X volt = 0.325 volt
Solution:(Correct Answer:D)
Nature of electrolyte: The conductance of an electrolyte (6) How many atoms of calcium will be deposited from molten
depends upon the number of ions present in the solution. CaCl2 by a current of 25 milli amperes flowing for
Therefore, the greater the number of ions in the solution the 60 seconds
greater is the conductance. (A) 4.68 × 1018 (B) 4.68 × 1015
Concentration of the solution: The molar conductance of
electrolytic solution varies with the concentration of the (C) 4.68 × 1012 (D) 4.68 × 109
electrolyte. In general, the molar conductance of an
Solution:(Correct Answer:A)
electrolyte increases with decrease in concentration or
increase in dilution.nature of the Temperature: The Quantity of electricity passed = 25×60
1000 = 1.5
conductivity of an electrolyte depends upon the ∴ 1.5 C will deposit Ca = 2×96500
1
× 1.5 mol
temperature. With increase in temperature, the
1
= 2×96500 × 1.5 × 6.02 × 1023 = 4.68 × 1018 atoms
conductivity of an electrolyte increases.
Valence electrons per atom present in metals describes the (7) The unit of equivalent conductivity is
electric conductance of it. Nature and structure is also a (A) ohm cm
significant factors which influences electrical conductance.
(B) ohm−1 cm2 (gm equivalent)−1
(3) Conductivity of a strong electrolyte (C) ohm cm2 (gm equivalent)
(A) Increases on dilution (D) S cm−2
(B) Does not change considerably on dilution
Solution:(Correct Answer:B)
(C) Decreases on dilution Aeq = k × 1000/c = k × 100/C
(D) Depends on density where Aeq = equivalent conductance
C = concentration in eq/L

Solution:(Correct Answer:B) ∴ Units of Aeq are ohm−1 cm2 g − eq −1
(b)Strong electrolyte ionize completely at all dilutions and
the number of ions does not increase on dilution. A small (8) Ag/AgCl(s)/KCl electrode is
increase in ∧m volume with dilution is due to the weakening (A) Reversible w.r.t cation (B) Reversible w.r.t Cl− ion
of electrostatic attraction between the ions on dilution. (C) Reversible w.r.t K + ion (D) Reversible w.r.t Ag + ion

13
 Solution:(Correct Answer:B) Solution:(Correct Answer:D)
Electrode reaction (d)It connect two solutions and complete the circuit.
AgCl(s) + e− → Ag(s) + Cl−
∴ electrode is reversible w.r.t. chloride ion (14) What current strength in amp. will be required to liberate
10 g of chlorine from N aCl solution in one hour ............. amp
(9) The solubility product of AgCl under standard conditions of (A) 8 (B) 6
temperature is given by
(C) 7.55 (D) 6.55
(A) 1.6 × 10−5 (B) 1.5 × 10−8
(C) 3.2 × 10−10 (D) 1.5 × 10−10 Solution:(Correct Answer:C)

Solution:(Correct Answer:D) (15) Select the incorrect statement for dry cell
−
AgCl(s) + e− → Ag(s) + Cl(aq.) E ◦ = 0.22V . . . ..(1) (A) M n is reduced from M n+4 to M n+3
− ◦
Ag(aq.) + e → Ag(s) E = 0.80V
+

− ◦ (B) N H3 gas liberated out

Ag(s) → Ag((a.)
+
) + e . . . ..E = −0.80V . . . ..(2)
Adding equation (1) and (2), we get (C) Zn is used as anode
−
AgCl(s) → Ag(aq. +
) + Cl(aq. ) E ◦ = −0.58V (D) Paste of N H4 Cl and ZnCl2 is used
From Nernst equation,
◦
Ecell = Ecell − RTnF ln K
Solution:(Correct Answer:B)
0 = −0.58 − 8.314×298×2.303
1×96500 log K M nO4 + N H4 + e− → M nO (OH) + N H3 , N H3 combine
⇒ log K = 0.0591
0.58
= −9.81 with Zn+2 , present in paste to form [Zn(N H3 )4 ]+2
⇒ K = 1.5 × 10−10 complex ion.
Hence the solubility product of AgCl is 1.5 × 10−10 .
(16) The standard potential of a Co+2 | Co electrode is −0.28 V
(10) Number of moles of oxygen gas evolved by electrolysis of and the standard potential of the cell
180 g of water ? P t | T i2+ (aq.) , T i3+ (aq.) || Co2+ (aq.) | Co (s) is 0.09 V .
(A) 2.5 (B) 5.0 what is the standard potential of the T i2+ (aq.) |T i(aq.)
3+

electrode ........... V
(C) 7.5 (D) 10.0
(A) −0.37 (B) 0.37
Solution:(Correct Answer:B)
(C) −0.19 (D) 0.19
Water decomposition can be represented as:
2H2 O → 2H2 + O2 Solution:(Correct Answer:B)
2 moles (or 2 × 18 = 36 g) of water gives one mole of o
Ecell = ECo o
2+ | Co − ET i3+ | T i2+
o

oxygen. 0.09 = − 0.28 − ET i3+ |T i2+

o

180 g water will produce 180

36 mol of oxygen == 5 mol of − ETo i2+ |T i3+ = 0.37 V ETo i3+ |T i2+ = − 0.37 V
oxygen. ETo i2+ |T i3+ = 0.37 V
Hence, option B is correct.
(17) The strongest reducing agent of the alkali metal is
(11) Which one is not called a anode reaction from the following (A) Li (B) N a
(A) Cl− → 12 Cl2 + e− (B) Cu → Cu+2 + 2e−
(C) K (D) Cs
(C) Hg + → Hg +2 + e− (D) Zn2+ + 2e− → Zn
Solution:(Correct Answer:A)
Solution:(Correct Answer:D)
(a)Lithium is the strongest reducing agent of the alkali
(d) It shows reduction reaction. metals.

(18) The metal which is the best conductor of electricity is

(A) Iron (B) Copper
(12) 2.5 F of electricity are passed through a CuSO4 solution. (C) Silver (D) Aluminium
The number of gm equivalent of Cu deposited on anode is
.... Solution:(Correct Answer:C)
(A) 0 (B) 1.25 It’s Obvious.
(C) 2.5 (D) 5.0 (19) During an electrolysis of conc. H2 SO4 , perdisulphuric acid
Solution:(Correct Answer:C) (H2 S2 O8 ) and O2 form at anode in equimolar amount. The
(c) 1 F obtained from 1 g equivalent mole of H2 that will form simultaneously at other electrode
∴ 2.5 F obtained from 2.5 g equivalent. will be (Given : 2H2 SO4 → H2 S2 O8 + 2H + + 2e− )
(A) thrice of O2 (B) twice of O2
(13) In the experiment set up for the measurement of EMF of a
(C) equal to O2 (D) half of O2
half cell using a reference electrode and a salt bridge, when
the salt bridge is removed, the voltage Solution:(Correct Answer:A)
 
(A) Does not change 2H2 SO4 → H2 S2 O8 + 2H+ + 2e−
Anode
2H O → O2 + 4H+ + 4e−
(B) Decreases to half the value  2
Cathode 2H2 O → H2 + 2OH− − 2e− × 3
(C) Increase to maximum Net : 2H2 SO4 + 8H2 O → H2 S2 O8 + O2 + 3H2 + 6H+ + 6OH−
(D) Drops to zero Hence ratio of nO2 and nH2 is 1 : 3

14
(20) (i) Copper metal dissolves in 1M silver nitrate solution and Solution:(Correct Answer:A)
crystals of silver metal get deposited. Reduction at cathode: 2H + (aq) + 2e− → H2 (g)
(ii) Silver metal does not react with 1M zinc nitrate solution At N.T.P, 22.4 L (or 22400mL ) of H2 = 1 mole of H2
(iii) Zinc metal dissolves in 1M copper sulphate solution and 112 mL of H2 = 22400
112
× 1 = 0.005 mole of H2
copper metal gets depositedHence the order of decreasing Moles of H2 produced = 96500(C/mole − ) × mole ratio
I(A)×t(s)
strength of the three metals as reducing agents will be I(A)×965 s
0.005 mol = × 1 mol H2
(A) Cu > Ag > Zn (B) Ag > Cu > Zn 96500(C/mole− ) 2 mole−
I = 1A
(C) Zn > Cu > Ag (D) Cu > Zn > Ag
Solution:(Correct Answer:C) (26) The dissociation constant of acetic acid is 1.6 × 10−5 and
It’s obvious. ΛoCH3 COOH 370.6 × 10−4 mho m2 mol−1 The specific
conductance of 0.01 molar acetic acid solution will be
(21) What is the e.m.f . of the cell .............. V approx
Cr/Cr3+ (1.0 M ) || Co+2 (1.0 M )/Co (A) 1.50 × 10−4 Scm2 mol−1 (B) 1.50 × 10−6 Scm2 mol−1
[E o for Cr3+ /Cr = −0.74 V and Co+2 /Co = −0.28 V ]
(C) 1.50 × 10−8 Scm2 mol−1 (D) 1.50 × 10−11 Scm2 mol−1
(A) −0.46 (B) −1.02
(C) +0.46 (D) +166 Solution:(Correct Answer:A)
α= Λ M
Λ◦
Solution:(Correct Answer:C) q M q p
−5
Q=1 α = KCa = 1.6×10 0.01 = 1.6 × 10−3 = 4.2 × 10−2
∴ Ecell = E◦cell = (E◦RP )cathode − (E◦RP )anode ΛM = α ΛoM = 4.2 × 10−2 × 370.6 × 10−4
= (−0.28) − (−0.74) K = Λ1000
m ×M

= +0.46 V −2
= 4.2×10 ×370.6×10
−4
×0.01
1000

(22) 5 amperes is passed through a solution of zinc sulphate for

40 minutes. Find the amount of zinc deposited at the (27) The name of equation showing relation between electrode
cathode ............. gm potential (E)standard electrode potential (E o ) and
concentration of ions in solution is
(A) 40.65 (B) 4.065
(A) Kohlrausch’s equation (B) Nernst’s equation
(C) 0.4065 (D) 65.04
(C) Ohm’s equation (D) Faraday’s equation
Solution:(Correct Answer:B)
(b) W = zit; Solution:(Correct Answer:B)
W = 32.69×5×60×40
96500
(b)Nernst’s equation shows relation between E and E o .
= 4.065 gm.
(28) The addition of a polar solvent to a solid electrolyte results in
(23) The standard reduction electrode potentials of four
(A) Polarization (B) Association
elements are
A = −0.250 V B = −0.136 V C = −0.126 V D = −0.402 V (C) Ionization (D) Non-liberation of heat
The element that displaces A from its compounds is
(A) B (B) C Solution:(Correct Answer:C)
(c)When polar solvent added in to solid electrolyte than it is
(C) D (D) None of these
ionised.
Solution:(Correct Answer:C)
(c) A is displace from D because D have a E o = −0.402 V . (29) For the cell reaction
Cu2+ (C1 aq) + Zn(s) ⇒ Zn2+ (C2 aq) + Cu(s) of an
Θ
electrochemical cell, the change in free energy at a given
(24) In acidic medium M nO 4 is an oxidising agent temperature is a function of
⊕
Θ
M nO 4 + 8H + 5e− → M n+2 + 4H2 O (A) ln (C1 ) (B) ln (C2 )
⊕
If H ion concentration is doubled, electrode potential of the (C) ln (C1 + C2 ) (D) ln (C2 /C1 )
half cell will
(A) increase by 28.46 mV (B) decrease by 28.46 mV Solution:(Correct Answer:D)
(C) increase by 14.23 mV (D) decrease by 142.3 mV (d)Ecell = Ecell
o
nF ln C1 and∆G= −nF Ecell
− RT C2

hence ∆G is the function of ln CC2

.
Solution:(Correct Answer:A) 1

E = E o + 0.0591 log [H ⊕ ]8
(30) The magnitude of the change in oxidising power of the
n
E − E = 5 8 log 2
◦ 0.0591

= 0.02846 V M nO4− /M n2+ couple is x × 10−4 V , if the H +

= 28.46 mV concentration is decreased from 1 M to 10−4 M at 25◦ C.
(Assume concentration of M nO4− and M n2+ to be same on
(25) When an electric current is passed through acidulated water change in H + concentration). The value of x is ....... .
112ml of hydrogen gas at N.T.P. collect at the cathode in (Rounded off to the nearest
 integer)
965 seconds. The current passed, in amperes is [ Given : 2.303RT
F = 0.059
(A) 1.0 (B) 0.5 (A) 3776 (B) 3800
(C) 0.1 (D) 2.0 (C) 4276 (D) 1552

15
 Solution:(Correct Answer:A) Solution:(Correct Answer:C)
Eqn is- Larger the value of E o red larger is tendency for reduction
M nO4− + H ⊕ + 5e− → M n+2 + 4H2 O and consequently stronger will be the oxidant. Similarly,
Nernst equation: smaller the value of E o red larger the tendency for
[M n+2 ]  1 8 oxidation and consequently stronger will be the reductant
5 log [M nO − ] H +
− 0.059
0
Ecell = ECell
4

(I) Given [H ⊕ ] = 1 M (35) The standard electrode potentials

[M n+2 ] E o (I2 /I − ) , E ◦ (Br− /Br2 ) and E o (F e/F e2+ )
5 log [M nO − ]
E1 = E 0 − 0.059
4
are respectively +0.54 V , −1.09 V and 0.44 V . On the basis
(II) Now : [H ⊕ ] = 10−4 M
of above data which of the following process is
[M n+2 ]
5 log [M nO − ] × (10−4 )8
E2 = E 0 − 0.059 non-spontaneous
1

(A) Br2 + 2I − → 2Br− + I2 (B) F e+Br2 → F e2+ +2Br−

4

5 log [M nO − ] + 5 log 10
M n+2 −32
= E 0 − 0.059 0.059

(C) F e + I2 → F e2+ + 2I − (D) I2 + 2Br− → 2I − + Br2

4

therefore : |E1 − E2 | = 0.059

5 × 32
= 0.3776 V = 3776 × 10−4 Solution:(Correct Answer:D)
x = 3776
For I2 +2Br−
 → 2I + Br2 o 
−

Ecell = ERp cathode − ERP
o o

(31) The equivalent conductance at infinite dilution ∧0 for anode

electrolytes BA and CA are 140 and 120 S cm2 eq −1 . The ∵ Eocell is negative hence this reaction is non-spontaneous
equivalent conductance at infinite dilution for BX is
198 S cm2 eq −1 . The ∧0 (in S cm2 eq −1 ) of CX is (36) Which of the following statements about galvanic cell is
(A) 178 (B) 198 incorrect
(A) Anode is positive
(C) 218 (D) 130
(B) Oxidation occurs at the electrode with lower reduction
Solution:(Correct Answer:A) potential
∧oCX = ∧oCA + ∧oBX − ∧oBA
(C) Cathode is positive
= 120 + 198 − 140
= 178 S cm2 eq−1 (D) Reduction occurs at cathode

(32) Consider the following E 0 values : Solution:(Correct Answer:A)

E 0 F e3+ /F e2+ = +0.77 V (a)Anode has negative polarity.
E 0 Sn2+ /Sn = −0.14 V Under standard conditions the
potential for the reaction (37) A standard hydrogen electrode has zero electrode potential
Sn(s) + 2F e3+ (aq) → 2F e2+ (sq) + Sn2+ (aq) is ............ V because
(A) 0.91 (B) 1.40 (A) Hydrogen is easiest to oxidise

(C) 1.68 (D) 0.63 (B) The electrode potential is assumed to be zero
(C) Hydrogen atom has only one electron
Solution:(Correct Answer:A)
(a)For Sn(s) + 2F e3+ (D) Hydrogen is the lightest element
(aq) → 2F e(aq) + Sn(aq)
2+ 2+

0 0 0
ECell = ESn/Sn 2+ + EF e3+ /F e2+ = (0.14) + (0.77)
Solution:(Correct Answer:B)
ECell = 0.91 V olts.
Potential is a relative term i.e. it is always measured with
(33) The pressure of H2 required to make the potential of H2 − respect to a reference. In electrochemistry, hydrogen is
electrode zero in pure water at 298 K is taken to be the reference to measure the potential and
hence to form a basis for comparison with all other
(A) 10−10 atm (B) 10−4 atm
electrode reactions, hydrogen’s standard electrode
(C) 10−14 atm (D) 10−12 atm potential is declared to be zero volts at all temperatures.

Solution:(Correct Answer:C) (38) P t (s) | H2 (g) | H + (P H = 2) || H + (P H =

2H+ + 2e− −→ H2 (g) 1 atm
3) | H2 (g) | P t (s) cell reaction will be
log [HM+2]2
P
EH + /H2 = − 0.0591
2 1 atm

log
PH2 P
= 0, [HH+2]2 0
= 10 = 1 (A) spontaneous (B) nonspontaneous
[H + ]2
P H2 = [H ] + 2 (C) equilibrium (D) None of these
For pure H2 O; H + = 10−7 M

2 Solution:(Correct Answer:B)
PH2 = 10−7 = 10−14 atm
[H + ]anode
0
Ecell = Ecell − 0.0591
n log10 [H + ]cathode
(34) Given are E o values for some half reactions This is a special type of cell in which we have E 0 = 0
I2 + 2e− → 2I − ; E o = 0.54 V because same type of species/ions are present in cathode
M nO4− + 8H + + 5e− → M n2+ + 4H2 O ; E o = 1.52 V and anode. It is called a concentration cell.
F e3+ + e− → F e2+ ; E o = 0.77 V = − 0.0591 log10 10
−2

1 10−3
Sn4+ + 2e− → Sn2+ ; E o = 0.1 V = −0.0591
The strongest reducant and oxidant respectively are = −ve
(A) Sn+4 , M nO4− (B) M n2+ , Sn4+ Since Ecell is negative, reaction is non-spontaneous as ∆G
(C) Sn+2 , M nO4− (D) I 2 , Sn2+ is +ve.

16
(39) What is the standard cell potential for the cell Solution:(Correct Answer:D)
Zn/Zn2+ (1M ) || Cu2+ (1M )/Cu E o for Galvanisation is the process of applying a protective zinc
Zn/Zn2+ (1M ) = −0.76 V and Cu2+ /Cu = +0.34 V coating to iron or steel, to prevent rusting. The most
(A) −0.76 + (−0.34) = −0.42 V common method is hot dip galvanizing, in which steel
sections are submerged in a bath of molten zinc. Hence,
(B) −0.34 + 0.76 = +0.42 V zinc plating is the most durable metal plating on iron to
(C) 0.34 − (−0.76) = 1.10 V protect against corrosion.
(D) −0.76 − (+0.34) = −1.10 V (45) The cell potential for Zn Zn2+ (aq)∥Snx+ Sn is 0.801 V at
298 K. The reaction quotient for the above reaction is 10−2 .
Solution:(Correct Answer:C) The number of electrons involved in the given
(c) E o = Ecathode − Eanode electrochemical cell reaction is. .... (Given
2+ |Zn = −0.763 V, ESnx+ |Sn = +0.008 V and
0 0
E o = 0.34 − (−0.76); EZn


E o = 1.10 volt. 2.303 RT
F = 0.06 V
(A) 8 (B) 9
(40) Saturated solution of KN O3 is used to make salt bridge
because (C) 3 (D) 2
(A) Mobility of K ⊕ is greater than that of N O3Θ Solution:(Correct Answer:D)
(B) Mobility of N O3Θ is greater than that of K ⊕ E = E 0 − 2.303RT
nF log Q
Here, E = +0.801 V, E 0 = 0.008 − (−0.763)
(C) Mobilities of K ⊕ and N O3Θ are almost the same = +0.771 V
n log 10
−2
(D) KN O3 is highly soluble in water ∴ 0.801 = +0.771 − 0.06
n=4
Solution:(Correct Answer:C)
(46) In an experiment, 0.04 F was passed through 400 mL of a
1 M solution of N aCl . What would be the pH of the
(41) The emf of the cell solution after the electrolysis ? (Change in volume will be
Ag|Ag + (0.1 M )||Ag + (1 M )|Ag at 298 K is ............ V negligible)
(A) 0.0059 (B) 0.059 (A) 8 (B) 10
(C) 5.9 (D) 0.59 (C) 13 (D) 6
Solution:(Correct Answer:B) Solution:(Correct Answer:C)
At anode Electrolysis of aq. N aCl gives hydrogen gas at cathode and
Ag(s) → Ag+ (0.1 M) + e− chlorine gas at. anode, the electrolyte solution contains
At cathode NaOH after electrolysis.
Ag+ (1 M) + e− → Ag(s) Number of equivalents of N aOH formed = 0.04
Ecell = E0cen − 0.0591 log10 (0.1 M) Normality, N = 0.04×1000 = 0.1
n (1 M)  − 400
OH = 0.1 M
Ecell = − 1 log 10−1
0.0591
pOH = 1 ∴ pH = 13
(42) E o of a cell aA + bB → cC + dD is (47) On diluting the concentration of Cl− ions by ten times in a
(A) − RT log [C]c [D]d
(B) −RT log [a]A [b]B
calomel electrode, its reduction potential at 298 K is -
nF [A]a [B]b [a]C [d]D
c D c D
(A) increased by 0.059 V (B) decreased by 0.059 V
(C) − RT
nF log [A]a [B]b
[C] [d]
(D) − RT
nF log [a]A [B]b
[C] [d]
(C) increased by 0.0295 V (D) decreased by 0.0295 V
Solution:(Correct Answer:A) Solution:(Correct Answer:A)
It’s obvious.
(48) The cell reaction involving quinhydrone electrode is:- ............ V
(43) When 1 F of electricity is passed through acidulated water, What will be the electrode potential at pH = 3
O2 evolved is ............. dm3
(A) 11.2 (B) 5.6
(C) 22.4 (D) 1

Solution:(Correct Answer:B)
(b)Reaction for electrolysis of water is
2H2 O ⇌ 4H + + 2O2− (A) 1.48 (B) 1.20
2O2− → O2 + 4e−
4e− + 4H + → 2H2 (C) 1.10 (D) 1.30
n = 4 so 4 Faraday charge will liberate Solution:(Correct Answer:A)
1 mole = 22.4 dm3 oxygen ◦  2
E = E − 0.06 log H+
4 = 5.6 dm O2 .
∴ 1 Faraday charge will liberate 22.4 3 2
⇒ E = 1.3 − 0.06 log 10−3 ⇒ E = 1.48 V
(44) To protect iron against corrosion, the most durable metal (49) The quantity of electricity needed to liberate 0.5 gram
plating on it, is equivalent of an element is
(A) Nickel plating (B) Tin plating (A) 48250 Faradays (B) 48250 Coulombs
(C) Copper plating (D) Zinc plating (C) 193000 Faradays (D) 193000 Coulombs

17
 Solution:(Correct Answer:B) (54) On passing electric current in an electrolyte solution H2 gas
(b)Electricity required is liberated at cathode then electrolyte could be
= No. of gm equivalent ×96500 coulombs (A) M gCl2 (B) AuCl3
= 0.5 × 96500 = 48250 C .
(C) CuCl2 (D) AgN O3
Column I Column II Solution:(Correct Answer:A)
Λc
(A) Kohlrausch (P ) m
Λo (55) At 25 o C , the molar conductivity at infinite dilution for
law can
m
electrolytes KOH, KCl and BaCl2 are
calculate
248 × 10−4 , 126 × 10−4 and 280 × 10−4 Sm2 mol−1
(B) Molar con- (Q) 1
R
× l
A
respectively calculate Λ∞m for Ba(OH)2 (in Sm mol
2 −1
)
ductance (A) 324 × 10 −4
(B) 524 × 10 −4
Λm
(C) 402 × 10−4 (D) 262 × 10−4
(50) (C) Specific (R) Λom of ca3 (P O4 )2
conduc- Solution:(Correct Answer:B)
tance BaCl2 + 2KOH → K(OH)2 + 2KCl
Kappa λ∞ ∞ ∞ ∞
mBa(OH)2 = λmBaCl2 + 2λmKOH − 2λmKCl
→ (k)
= 280 × 10−4 + 2 × 248 × 10−4 − 2 × 126 × 10−4
(D) Degree of (S) k×1000
M = (280 + 496 − 252) × 10−4
ionization = 524 × 10−4 Sm2 mol−1
of weak
electrolyte (56) The nature of charge on resulting colloidal particles when
Which of the following option show correct matches F eCl3 is added to excess of hot water is :
(A) (A − R), (B − P ), (C − Q), (D − S) (A) Positive
(B) (A − S), (B − P ), (C − Q), (D − R) (B) Sometimes positive and sometimes negative
(C) (A − R), (B − S), (C − Q), (D − P ) (C) Neutral
(D) (A − P ), (B − S), (C − Q), (D − R) (D) Negative
Solution:(Correct Answer:A)
Solution:(Correct Answer:C)
If F eCl3 is added to hot water, a positively charged sol,
(51) When the sample of copper with zinc impurity is to be hydrated ferric oxide is formed
purified by electrolysis, the appropriate electrodes are due to adsorption of F e3+ ions.
Cathode , Anode F e2 O3 .xH2 O/F e3+
Positively charged.
(A) Pure zinc , Pure copper
(B) Impure sample , Pure copper (57) Two solutions of X and Y electrolytes are taken in two
beakers and diluted by adding 500 mL of water. Λm of X
(C) Impure zinc , Impure sample increases by 1.5 times while that of Y increases by 20 times,
(D) Pure copper, impure sample what could be the electrolytes X and Y ?
(A) X → N aCl, Y → KCl
Solution:(Correct Answer:D)
(B) X → N aCl, Y → CH3 COOH
(d) Impure metal made anode while pure metal made
cathode. (C) X → KOH, Y → N aOH
(D) X → CH3 COOH, Y → N aCl
(52) In a electrochemical cell
(A) Potential energy changes into kinetic energy Solution:(Correct Answer:B)
On dilution ∧m of strong electrolyte increases gradually
(B) Kinetic energy changes into potential energy
while that of weak electrolyte increases fastly.
(C) Chemical energy changes into electrical energy
(58) Standard reduction potentials at 25o C of
(D) Electrical energy changes into chemical energy Li+ |Li, Ba2+ | Ba, N a+ | N a and M g 2+ |M g are
−3.05, −2.90, −2.71 and −2.37 volt respectively. Which
Solution:(Correct Answer:C) one of the following is the strongest oxidising agent
(c)In the electrochemical cell chemical energy changes into (A) N a+ (B) Li+
electrical energy.
(C) Ba2+ (D) M g 2+
(53) Specific conductance of 0.2 M electrolyte solution at 20 C o
Solution:(Correct Answer:D)
temperature is 2.48 × 10−4 ohm−1 cm−1 then the molar
(d)The oxidizing character i.e. acceptance of electrons
conductance of solution will be ............ ohm−1 cm2 mol−1
increases with the reduction potential.
(A) 1.24 (B) 2.48
(C) 1.24 (D) 4.96 (59) If x is specific resistance (in S −1 cm) of the electrolyte
solution and y is the molarity of the solution, then Λm (in
Solution:(Correct Answer:C) S cm2 mol−1 ) is given by
(A) 1000x (B) 1000 xy
κ × 1000 y
∧m =
M (C) 1000
xy (D) xy
1000

18
 Solution:(Correct Answer:C) (64) In which cell the free energy of a chemical reaction is
k = ρ1 directly converted into electricity ?
∧m = k×1000 (A) Leclanche cell (B) Concentration cell
M
(C) Fuel cell (D) Lead storage battery
(60) The standard electrode potentlal (E − ) values of
Al3+ /Al, Ag+ /Ag, K+ /K and Cr3+ /Cr are −1.66 V, 0.80 V Solution:(Correct Answer:C)
−2.93 V and −0.74 V, respectively. The correct decreasing (c)Fuel cell converts the chemical energy into electrical
order of reducing power of the metal is energy.
(A) Ag > Cr > Al > K (B) K > Al > Cr > Ag
(65) When lead storage battery is charged
(C) K > Al > Ag > Cr (D) Al > K > Ag > Cr
(A) Lead dioxide dissolves
Solution:(Correct Answer:B) (B) Sulphuric acid is regenerated
Reducing power of metal ∝ SRP
1
(C) The lead electrode becomes coated with lead sulphate
K > Al > Cr > Ag
(D) The amount of sulphuric acid decreases
(61) What will be the molar conductance at infinite dilution for Solution:(Correct Answer:B)
N H4 OH if at infinite dilution the molar conductances of
Anode −PbSO− 4 + 2e → Pb + SO4
− 2−
Ba(OH)2 , BaCl2 and N H4 Cl are 523.28, 280.0 and
Cathode −PbSO4 + 2H2 O → PbO2 + 4H+ + SO2−
4 + 2e
−
129.8 ohm−1 cm2 mol−1 respectively.
(A) 502.88 (B) 373.68 (66) What is the amount of chlorine evolved when 2 amperes of
(C) 251.44 (D) 226.96 current is passed for 30 minutes in an aqueous solution of
N aCl ............. g
Solution:(Correct Answer:C) (A) 66 (B) 1.32
o o o o
Λ N H4 OH = Λ N H4 Cl + 12 Λ Ba(OH)2 − 1
2 Λ BaCl2 (C) 33 (D) 99
= 129.8 + 12 × 523.28 − 12 × 280
= 129.8 + 261.64 − 140 Solution:(Correct Answer:B)
= 391.44 − 140 = 254.44 (b)At Andoe Cl− → 12 Cl2 + e−
ECl2 = 35.5×2
2 = 35.5
ECl2 ×I×t
(62) At 298 K, the standard electrode potentials of Cu2+ / WCl2 = 96500 = 35.5×2×30×60
96500 = 1.32 gm.
Cu, Zn2+ /Zn, F e2+ /F e and Ag + /Ag are 0.34 V ,
−0.76 V, −0.44 V and 0.80 V , respectively. (67) For a reaction ,A + B 2 → B + A+2 ; E o = 0.2955 V Hence
On the basis of standard electrode potential, predict which equilibrium constant of the reaction is at 25 o C
of the following reaction can not occur ? (A) 10 (B) 1010
(A) CuSO4 (aq) + F e(s) → F eSO4 (aq) + Cu(s) (C) −10 (D) 10−10
(B) F eSO4 (aq) + Zn(s) → ZnSO4 (aq) + F e(s)
Solution:(Correct Answer:B)
(C) 2CuSO4 (aq) + 2Ag(s) → 2Cu(s) + Ag2 SO4 (aq) E◦ = 0.0591
2 log10 Keq
(D) CuSO4 (aq) + Zn(s) → ZnSO4 (aq) + Cu(s) 0.2955 = 0.0591
2 log Keq . ⇒ Keq. = 1010

(68) If hydrogen electrode dipped in 2 solution of pH = 3 and

Solution:(Correct Answer:C)
pH = 6 and salt bridge is connected the e.m.f. of resulting
SRP: EZn ◦ ◦ ◦ ◦
2+ /2n < EF e2+ /F e < ECu2+ /au < EAg + /Ag cell is ............ V
Reactivity order: Zn > F e > Cu > Ag (A) 0.177 (B) 0.3
In case of displacement reaction, more reactive metals
(lower SRP) can displace less reactive metals (higher SRP) (C) 0.052 (D) 0.104
from their salt solution. Solution:(Correct Answer:A)
CuSO4(aq) + 2Ag(s) → Cu(s) + Ag2 SO4(aq) −6

Reaction is not possible as Ag is less reactive metal compare (a)Ecell = −0.059 log 10
10−3 = −0.059 log 10
−3

to Cu. = − 0.059 × (−3) = 0.177 V .

(69) Which of the following metal does not react with the
(63) How much time is required for complete decomposition of solution of copper sulphate
4 moles of water using 4 ampere current ?
(A) M g (B) F e
(A) 3.86 × 105 sec (B) 1.93 × 105 sec
(C) Zn (D) Ag
(C) 96500 sec (D) 48250 sec
Solution:(Correct Answer:D)
Solution:(Correct Answer:B) Metal Zinc sodium and F e will replace Cu from copper
H
2 O −→ H2 + 2 O2
+1 −2 0 1 0
 sulphate as it is more reactive.
from 1 molecule exchange of By reactivity series of metal only the metals which lie above
electrons = 2 = valency factor Cu can displace Cu from its compound.
mole ×.f = W I×t
E = 96500 REACTIVITY SERIES
4 × 2 = 96500
4×t
K > N a > Ca > M g > Al > Zn > F e > N i >
t = 96500 × 2 Sn > P b > HY DROGEN > Cu > Hg > Ag > Au >
= 1.93 × 105 seconds. Pt

19
(70) Conductivity of a solution is directly proportional to Solution:(Correct Answer:A)
(A) Dilution (B) Number of ions (a) λ = k × V = R1 × al × V = 1
200 × 1 × 10, 000
= 5 × 102 Ω−1 cm2 eq.−1
(C) Current density (D) Volume of the solution
Solution:(Correct Answer:B) (76) If one end of a piece of a metal is heated, the other end
(b) Conductivity of a solution is directly proportional to the becomes hot after some time. This is due to
number of ions. (A) Energised electrons moving to the other part of the
metal
(71) A device that converts energy of combustion of fuels like
hydrogen and methane, directly into electrical energy is (B) Resistance of the metal
known as (C) Mobility of atoms in the metal
(A) dynamo (B) N i − Cd cell
(D) Minor perturbation in the energy of atoms
(C) fuel cell (D) electrolytic cell.
Solution:(Correct Answer:C) Solution:(Correct Answer:A)
Fuel cell converts combustion energy to electrical energy. A metal is characterised by the presence of free electrons
which move faster due to increase of temperature.
(72) On electrolysing a solution of dilute H2 SO4 between
platinum electrodes, the gas evolved at the anode is (77) λClCH2 COON a = 224 ohm−1 cm2 gmeq −1 ,
(A) SO2 (B) IF5 λN aCl = 38.2 ohm−1 cm2 gmeq −1 ,
λHCl = 203 ohm−1 cm2 gmeq −1 ,
(C) O2 (D) H2
What is the value of λClCH2 COOH ..............
Solution:(Correct Answer:C) Ohm−1 cm2 gm eq−1
(c)In between dilute H2 SO4 and platinum electrode O2 gas (A) 288.5 (B) 289.5
evolve at anode.
(C) 388.5 (D) 59.5
(73) Kohlrausch’s law states that at
Solution:(Correct Answer:C)
(A) For strong electrolyte, molar conductane varies linearly
(c)ClCH2 COON a + HCl → ClCH2 COOH + N aCl
with concentration of electrolyte
λClCH2 COON a + λHCl = λClCH2 COOH + λN aCl
(B) Infinite dilution, each ion makes definite contribution to 224 + 203 = λClCH2 COOH + 38.2
molar conductance of an electrolyte whatever be the λClCH2 COOH = 427 − 38.2 = 388.8 ohm−1 cm2 gmeq −1 .
nature of the other ion of the electrolyte
(C) At all concentration, each ion makes definite (78) When lead storage battery is charged
contribution to molar conductance of an electrolyte (A) Lead dioxide dissolves
whatever be the nature of the other ion of the
(B) Sulphuric acid is regenerated
electrolyte
(C) The lead electrode becomes coated with lead sulphate
(D) Molar conductance increases with decrease in
concentration (D) The amount of sulphuric acid decreases
Solution:(Correct Answer:B)
Solution:(Correct Answer:B)
Kohlrausch’s law states that at Infinite dilution, each ion
(b)During charging of a lead storage battery, the reaction at
makes definite contribution to equivalent conductance of
the anode and cathode are
an electrolyte whatever be the nature of the other ion of
Anode: P bSO4 + 2e− → P b + SO42−
the electrolyte
Cathode: P bSO4 + 2H2 O → P bO2 + 4H + + SO42− + 2e−
(74) Given E o Ag+ /Ag = 0.80 V, E o M g2+ /M g = −2.37 V, In both the reactions H2 SO4 is regenerated.
E o Cu2+ /Cu = 0.34 V, E o Hg2+ /Hg = 0.79 V.
Which of the following statements is correct ? (79) Incorrect statement from the following statements during
(A) AgN O3 can be stored in copper vessel the discharge of lead storage battery is
(A) P bO2 is reduced
(B) M g(N O3 )2 can not be stored in copper vessel
(B) P b is oxidised
(C) CuCl2 can be stored in silver vessel
(C) equivalent mass of H2 SO4 is 98
(D) HgCl2 can be stored in copper vessel
(D) Extent of discharging is independent of H2 SO4
Solution:(Correct Answer:C)
Solution:(Correct Answer:D)
(75) The resistance of 0.01 N N aCl solution at 25 o C is 200Ω.
Cell constant of conductivity cell is 1 cm−1 . The equivalent
conductance is (80) The standard electrode potential is measured by
(A) 5 × 102 Ω−1 cm2 eq −1 (A) Electrometer (B) Voltmeter

(B) 6 × 103 Ω−1 cm2 eq −1 (C) Pyrometer (D) Galvanometer

(C) 7 × 104 Ω−1 cm2 eq −1 Solution:(Correct Answer:B)

(D) 8 × 10 Ω
5 −1 2
cm eq −1 It’s obvious.

20
(81) Consider the following complexes (87) If 0.5 amp current is passed through acidified silver nitrate
(a) K2 P tCl6 (b) P tCl4 .2N H3 solution for 10 minutes. The mass of silver deposited on
(c) P tCl4 .3N H3 (d) P tCl4 .5N H3 cathode, is ........... g (eq. wt. of silver nitrate = 108)
Their electrical conductances in aqueous solutions are (A) 0.235 (B) 0.336
(A) 256, 0, 97, 404 (B) 404, 0, 97, 256
(C) 0.536 (D) 0.636
(C) 256, 97, 0, 404 (D) 404, 97, 256, 0
Solution:(Correct Answer:B)
Solution:(Correct Answer:A) Weight of silver accumulated W = ZIT
(a) Total ions = 3 W = (108 × 0.5 × 10 × 60)/(96500)
(b) Total ions = 0 W = 0.33 g
(c) Total ions = 2
(d) Total ions = 4 (88) The unit of cell constant is
(A) ohm−1 cm−1 (B) ohm cm
(82) The mass deposited at an electrode is directly proportional (C) cm (D) cm−1
to
(A) Atomic weight (B) Equivalent weight Solution:(Correct Answer:D)
The cell constant, known as K, refers to a theoretical
(C) Molecular weight (D) Atomic number
electrode consisting of two 1 cm square plates 1 cm apart. A
Solution:(Correct Answer:B) cell constant has units of 1/cm (per centimeter), where the
It’s obvious. number refers to the ratio of the distance between the
electrode plates to the surface area of the plate.
(83) How many faraday are needed to reduce a mole of M nO4−
(89) Calculate the electrode potential at 298 o K for Zn|Zn++
to M n2+
electrode in which the activity of zinc ions is 0.001 M and
(A) 4 (B) 5
E o Zn/Zn++ is −0.74 volts ............ V
(C) 3 (D) 10 (A) 0.38 (B) 0.83
Solution:(Correct Answer:B) (C) 0.40 (D) 0.45
Faraday of electricity is required to reduce 1 mole of M nO4−
Solution:(Correct Answer:B)
ions to M n2+ ions.
M nO4− + 5e− → M n2+ Electrode reaction : Zn2+ (0.001 M ) + 2e− → Zn(s)
The oxidation number of M n in M nO4− is +7.
◦
E(Zn2+ /Zn) = E(Zn 2+ /Zn) −
0.0591
n log [Zn12+ ] =
The oxidation number of M n in M n2+ is +2. −0.74 − 2 log [10−3 ]
0.0591 1

The change in the oxidation number is 7 − 2 = 5. = −0.74 − 0.02955 × 3 = −0.74 − 0.08865 = −0.82865 V

(84) For electroplating a spoon, it is placed in the voltameter at (90) In a hydrogen -oxygen fuel cell, combustion of hydrogen
occurs to
(A) The position of anode
(A) Produce high purity water
(B) The position of cathode
(B) Create potential difference between the two electrodes
(C) Exactly in the middle of anode and the cathode
(C) Generate heat
(D) Anywhere in the electrolyte
(D) Remove adsorbed oxygen from electrode surfaces
Solution:(Correct Answer:B) Solution:(Correct Answer:B)
(b) Positive ions get deposited on cathode. (b)In hydrogen-oxygen fuel cell following reactions take
place to create potential difference between two
(85) Calculate the current (in mA ) required to deposit 0.195 g of
electrodes.
platinum metal in 5.0 hours from a solution of [P tCl6 ]2− :
2H2(g) + 4OH − (aq) → 4H2 O(l) + 4e−
(atomic weight : P t = 195 )
O2(g) + 2H2 O(l) + 4e− → 4OH − (aq)
(A) 310 (B) 31
Overall reaction = 2H2(g) + O2(g) → 2H2 O(l)
(C) 21.44 (D) 5.36 the net reaction is the same as burning (Combustion) of
hydrogen to form water.
Solution:(Correct Answer:C)
W
E = 96500 , 195 × 4 =
I×t 0.195 5×60×60×I
96500
(91) A depolarizer used in dry cell batteries is
I = 21.44 (A) Ammonium chloride (B) Manganese dioxide
(C) Potassium hydroxide (D) Sodium phosphate
(86) With the help of following reactions, arrange metals A, B, D
and E in decreasing order of their reactivity Solution:(Correct Answer:B)
(I) B + AN O3 −→ BN O3 + A (b)M nO2 is used in dry batteries cell.
(II) A + HCl −→ ACl + 12 H2
(III) D + ECl −→ DCl + E (92) Which one of the following material conducts electricity
(IV ) D + HN O3 −→ H2 gas is not evolved (A) Diamond
(A) B > D > E > A (B) B > A > D > E
(B) Crystalline sodium chloride
(C) E > D > B > A (D) None of these
(C) Barium sulphate
Solution:(Correct Answer:B)
(D) Fused potassium chloride

21
 Solution:(Correct Answer:D) Solution:(Correct Answer:A)
(d)Generally fussed potassium chloride flow the electric 2e− + 2H+ (aq) → H2 ( g)
conductivity. E = E0 − 0.059
PH2
n log [H+ ]2
P
(93) For the cell, ........... kJ 0=0− 0.059
2 log (10−7
H2
)2
P
(aq) (0.4 M )||Sn(aq) (0.04 M )|Sn(S) ,
M n(S) |M n+2 log (10−7
+2 H2
)2
=0
Calculate free energy change (∆G) at 298 K . P H2
=1
Given :EMo
n+2 |M n = − 1.18 V ; ESn+2 |Sn = − 0.14 volt
o 10−14
2.303 RT PH2 = 10−14 bar
F = 0.06
(A) 180.93 (B) −194.93 (99) When Zn piece is kept in CuSO4 solution, the copper get
precipitated due to standard potential of zinc is
(C) −180.93 (D) None of these (A) > copper (B) < copper
Solution:(Correct Answer:B) (C) > sulphate (D) < sulphate
Solution:(Correct Answer:B)
(94) Iron is protected by coating it with a thin layer of (b)Standard potential of Zinc < Copper.
(A) Cu (B) Zn
(100) Copper sulphate solution is electrolysed between two
(C) P b (D) M g platinum electrodes. A current is passed until 1.6 g of
oxygen is liberated at anode. The amount of copper
Solution:(Correct Answer:B) deposited at the cathode during the same period is .............. g
[At. mass of Cu = 63.6]
(95) Which of the following statement is true for an (A) 6.36 (B) 63.6
electrochemical cell
(C) 12.7 (D) 3.2
(A) H2 is cathode and Cuis anode
Solution:(Correct Answer:A)
(B) H2 is anode and Cu is cathode
For O2 , m = E×Q m
nF and Q = E × nF = 0.2 F
(C) Reduction occurs at H2 electrode For Cu, m = E×Q nF = 2×F × 0.2 F = 6.36 g
63.5

(D) Oxidation occurs at Cu electrode Hence; (1) is correct.

(101) 96500 coulombs of electric current liberates from CuSO4
Solution:(Correct Answer:B) solution .............. gm Cu
(b)Elements with lower reduction potential act as anode. (A) 63.5 (B) 31.75
His placed above Cu in electrochemical series so it has
lesser reduction potential and thus act as anode and Cu act (C) 96500 (D) 100
as cathode. Solution:(Correct Answer:B)
(b)Cu++ + 2e− → Cu; ECu = 63.55
2 = 31.75 gm Cu.
(96) The conductivity of strong electrolyte is
(102) In a galvanic cell, the electrons flow from
(A) Increase on dilution slightly
(A) Anode to cathode through the solution
(B) Decrease on dilution
(B) Cathode to anode through the solution
(C) Does not change with dilution
(C) Anode to cathode through the external circuit
(D) Depend upon density of electrolytes itself
(D) Cathode to anode through the external circuit
Solution:(Correct Answer:A) Solution:(Correct Answer:C)
(a)Generally strong electrolyte on dilution shows (c)In a galvanic cell, the electrons flow from anode to
conductivity characters. cathode through the external circuit. At anode (−ve pole)
oxidation and at cathode (+ pole) reduction takes place.
(97) A certain quantity of electricity is passed through an
(103) P t|H2 (1 atm) |H + (0.001 M ) ||H + (0.1 M ) |H2 (1 atm)|P t
aqueous solution of AgN O3 and cupric salt solution
What will be the value of Ecell for this cell? ............. V
connected in series. The amount of Ag deposited is 1.08 gm,
the amount of copper deposited is ............. g (atomic weight (A) 0.1182 (B) −0.1182
of Cu = 63.5 ; Ag = 108) (C) 0.0591 (D) −0.0591
(A) 0.6454 (B) 6.354 Solution:(Correct Answer:A)
(C) 0.3177 (D) 3.177 Ecell = 0.0591 log CC21 = 0.0591 log 0.001
0.1

Ecell = 0.1182 V
Solution:(Correct Answer:C)
Eq.wt.of Cu (104) ∧∞
AgCl can be obtained
(c) Wt.of Cu
Wt.ofAg = Eq.wt.of Ag
Wt. of Cu
= 63.5/2
1.08 108 √
Wt. of Cu = 0.3177 gm. (A) by extraplotation of the graph ∧ and C to zero
concentration
(98) What pressure (bar) of H2 would be required to make emf of
(B) by known values of ∧∞ of AgN O3 , HCl and HN O3
hydrogen electrode zero in pure water at 25◦ C ?
(A) 10−14 (B) 10−7 (C) both (A) and (B)
(C) 1 (D) 0.5 (D) None of these

22
 Solution:(Correct Answer:B) (110) M n O4−1 + 8 H + + 5e− → M n+2 (aq) + 4H2 O(l) ;
(aq) (aq)

(105) The chemical reaction, 2AgCl(s) + H2 (g) → E1o = 1.51 V

2HCl(aq) + 2Ag(s) taking place in a galvanic cell is M nO2 (s) + 4H + (aq) + 2e− → M n+2 (aq) + 2H2 O(l) ;
represented by the notation E2o = 1.21 V
M nO4−1 (aq) + 4H + (aq) + 3e− → M nO2 (s) + 3H2 O(l) ;
(A) P t|H2 (g), 1 bar|1 M KCl(aq)|AgCl (s)|Ag (s)
E3o ?
(B) value of E3o will be ............ V
P t (s)|H2 (g), 1 bar| 1 M HCl (aq)||1 M Ag + (aq)|Ag (s) (A) 1 (B) 2.42
(C) P t (s)|H2 (g), 1 bar| 1 M HCl (aq)|AgCl (s)|Ag (s) (C) 2.61 (D) 1.71
(D) P t (s)|H2 (g), 1 bar| 1 M HCl (aq)|Ag (s)|AgCl (s) Solution:(Correct Answer:D)
Solution:(Correct Answer:B)
(111) In aqueous solution, strong electrolytes
(b) 2AgCl(s) + H2(g) → 2HCl(aq.) + 2Ag(s)
The activities of solids and liquids are takes as unity and at (A) Are partially ionized
low concentrations, the activity of a solute is approximated (B) Do not ionise
to its molarity.
Th cell reaction will be (C) Ionise almost completely
P t(s) |H2(g) , 1 bar|H(aq) 1 M |AgCl(aq) 1 M |Ag(s) (D) Form polymers
+

(106) The increase in equivalent conductance of an electrolyte Solution:(Correct Answer:C)

solution with dilution is due to the increase in (c)Strong electrolytes are almost completely ionised in polar
(A) Ionic attraction solvent.
(B) Molecular attraction (112) Which one of the following statement is true for a
(C) Degree of association of the electrolyte electrochemical cell
(A) H2 is cathode and Cu is anode
(D) Degree of ionisation of the electrolyte
(B) H2 is anode and Cu is cathode
Solution:(Correct Answer:D)
On dilution, the number of charge carriers per m3 decreases (C) Reduction occurs at H2 electrode
but the volume increases. Consequently, the ionic mobility (D) Oxidation occurs at Cu electrode
increases which increase equivalent conductance.
Solution:(Correct Answer:B)
(107) A cell from the following which converts electrical energy (b)In electrochemical cell H2 release at anode and Cu is
into chemical energy deposit at the cathode.
(A) Dry cell (B) Electrochemical cell
(113) Limiting molar conductivity of CH3 COOH (i.e.
(C) Electrolytic cell (D) None of these
Λom (CH3 COOH) is equal to
Solution:(Correct Answer:C)
(A) Λom (CH3 COOH) + Λom (CH3 COON a) − Λom (N aOH)
(c)In the electrolytic cell electrical energy change into
chemical energy. (B) Λom (CH3 COON a) + Λom (HCl) − Λom (N aCl)

(108) The electric conduction of a salt solution in water depends (C) Λom (CH3 COON a) + Λom (N aCl) − Λom (N aOH)
on the (D) Λom (N aOH) + Λom (N aCl) − Λom (CH3 COON a)
(A) Shape of its molecules
(B) Size of its molecules Solution:(Correct Answer:B)

(C) Size of solvent molecules (114) The oxidation potential of a hydrogen electrode at pH = 10
(D) Extent of its ionization and PH2 = 1 atm will be ............ V
(A) 0.059 (B) 0.59
Solution:(Correct Answer:D)
Higher the number of ions in solution, higher would be the (C) 0 (D) 0.51
conductivity of the solution as the number of charge Solution:(Correct Answer:B)
carriers would increase. Hence, higher the degree of [H+ ]
ionization greater would be the number of ions in solution. EOP = EoOP − 0.059
1 log 1/2
pH
2

[H+ ] = 10−10 , PH2 = 1

(109) Then during electrolysis of a solution of AgN O3 , 9650
coulombs of charge pass through the electroplating bath, EOP = 0.59 V
the mass of silver deposited in the cathode will be .............. g
(115) The electrode potentials for
(A) 1.08 (B) 10.8 Cu2+ (aq) + e− → Cu+ (aq)
(C) 21.6 (D) 108 and Cu+ (aq) + e− → Cu(s)
are +0.15 V and +0.50 V respectively. The value of will be
Solution:(Correct Answer:B) ............ V
+e−
(b) Ag + −−−→ Ag, 96500 C will liberate silver = 108 gm. (A) 0.500 (B) 0.325
9650 C will liberate silver = 10.8 gm. (C) 0.650 (D) 0.150

23
 Solution:(Correct Answer:B) α = ΛΛ∞
m 20
= 400 = 0.05
m
Given = Ka = Cα 2

(1) Cu2+(aq) + e → Cu(aq) ∆G1 = −1 × 0.15 × F

− +
= 0.007 × (0.05)2
(2) Cu+ = 7 × 10−3 × 25 × 10−4
(aq) + e → Cu(s) ∆G2 = −1 × 0.50 × F
−
= 175 × 10−7
Cu+2
(aq) + 2e → Cu E =?
− ◦
= 1.75 × 10−5
∆G3 = −2 × F × E3 ◦

eq. (1)+ eq. (2) = eq. (3) (120) Molar ionic conductivities of divalent cation and anion are
∆G3 = ∆G1 + ∆G2 57 S cm2 mol−1 and 73 S cm2 mol−1 respectively. The molar
−2 × F × E◦3 = −1 × 0.15 × F + (−1 × 0.5 × F) conductivity of solution of an electrolyte with the above
⇒ E◦3 = 0.325 V cation and anion will be :
(A) 65 S cm2 mol−1 (B) 130 s cm2 mol−1
(116) The equivalent conductance of M /32 solution of a weak
monobasic acid is 8.0 mho cm2 and at infinite dilution is (C) 187 S cm2 mol−1 (D) 260 s cm2 mol−1
400 mho cm2 . The dissociation constant of this acid is Solution:(Correct Answer:B)
(A) 1.25 × 10−6 (B) 6.25 × 10−4
C = 57Scm mol
2 −1
Λ+2
(C) 1.25 × 10−4 (D) 1.25 × 10−5
A = 73Scm mol
2 −1
Λ+2
Solution:(Correct Answer:D) ΛSolution = λC + Λ−2
+2
A

Degree of dissociation, α = ΛΛ∞ = 57 + 73 = 130

o

Where, Λ and Λ are equivalent conductances at a given

o ∞
(121) During electrolysis, the species discharged at cathode are
concentration and at infinite dilution respectively.
8.0
α = 400 = 2 × 10−2 (A) Ions (B) Cation
From Ostwald’s dilution law (for weak monobasic acid) (C) Anion (D) All of these
Cα2
Ka = (1−α)
Solution:(Correct Answer:B)
= Cα2 (∵ 1 >> α)

2 (b)During electrolysis cation discharged at cathode and
1
= 32 2 × 10−2 anion discharged at anode.
= 1.25 × 10−5
(122) If 1 A of current is passed through CuSO4 solution for 10
(117) Mass in grams of copper deposited by passing 9.6487 A seconds, then the number of copper ions deposited at the
current through a voltmeter containing copper sulphate cathode will be about
solution for 100 seconds is (Given : Molar mass of (A) 1.6 × 1019 (B) 3.1 × 1019
Cu : 63 g mol−1 , 1 F = 96487C )
(C) 4.8 × 1019 (D) 6.2 × 1019
(A) 0.315 g (B) 31.5 g
Solution:(Correct Answer:B)
(C) 0.0315 g (D) 3.15 g
(b) Total charge supplied = 1 × 10 = 10 C
Solution:(Correct Answer:A) 2 electronic charge (3.2 × 10−19 C) liberates one Cu+2 ion
Cu2+ (aq) + 2e− → Cu(s) Number of Cu+2 ions liberated by 10 C charge
−19 × 10= 3.1 × 10
1 19
Mass of Cu deposited = 3.2×10
×i×t
(w)= MnF (123) During electrolysis of aqueous N aOH, 4 g of O2 gas is
= 63×9.6487×100
2×96487 liberated at N T P at anode, H2 gas liberated at cathode is
= 0.315 g ............... litres
(A) 2.8 (B) 5.6
(118) The standard EM F for the given cell reaction
(C) 11.2 (D) 22.4
Zn + Cu2+ = Cu + Zn2+ is 1.10 V at 25o C. The EM F for
the cell reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ Solution:(Correct Answer:B)
solutions are used, at 25 o C is ..........V It’s obvious.
(A) 1.10 (B) 0.110
(124) Which of the following is displaced by F e
(C) −1.10 (D) −0.110
(A) Ag (B) Hg
Solution:(Correct Answer:A) (C) Zn (D) Both (a) and (b)
++
(a)Ecell = Ecell
o
− 0.059 log (Cu
(Zn )
2 ++ )
Solution:(Correct Answer:D)
= 1.10 − 0.059
2 log 0.1
0.1 = 1.10 V . (a, b) Because these comes after the F e in electrochemical
series.
(119) The molar conductivity of 0.007 M acetic acid is
20 S cm2 mol−1 . What is the dissociation constant of acetic (125) The correct order of reduction potentials of the following
acid? (In ×10−5 mol L−1 ) pairs is
[Λ◦H+ = 350 S cm2 mol−1 , Λ◦CH3 COO− = 50 S cm2 mol−1 ] A. Cl2 /Cl− B. I2 /I − C. Ag + /Ag D. N a+ /N a E. Li+ /Li
(A) 175 (B) 2.50 Choose the correct answer from the options given below.
(A) A > C > B > D > E
(C) 1.75 (D) 250
(B) A > B > C > D > E
Solution:(Correct Answer:C)
(Λ∞ (C) A > C > B > E > D
m )CH3 COOH = 50 + 350
= 400 (D) A > B > C > E > D

24
 Solution:(Correct Answer:A) (131) On electrolysis of aqueous solution of KI in presence of
◦
ECl − = +1.36 V
platinum electrodes
2 /Cl
◦
EI2 /I − = +0.54 V (a) Hydrogen gas is released at cathode
◦
EAg + /Ag = +0.80 V
(b) Oxygen gas is released at anode.
◦ (c) pOH of solution decreases
EN a+ /N a = −2.71 V
◦
ELi + /Li = −3.05 V
(d) There is deposition of potassium at cathode
Choose the correct option from following
(126) The resistance of 0.5 M solution of an electrolyte in a cell (A) a, b (B) only a
was found to be 50 Ω. If the electrodes in the cell are 2.2 cm
(C) a, c (D) a, c, d
apart and have an area of 4.4 cm2 then the molar
conductivity (in S m2 mol−1 ) of the solution is Solution:(Correct Answer:C)
(A) 0.2 (B) 0.02
(C) 0.002 (D) 0.001 (132) What will be the electromotive force of following cell
F e|F e+2 (0.2 M ) || Au+3 (0.02 M ) |Au, if ........... V
Solution:(Correct Answer:C) EFo e+2 /F e = −0.44 V and EAu/Au +3 = −1.50 V
o
K = GG∗
⇒ K = 501
× 4.4
2.2 (A) 1.914 (B) 1.047
⇒ K = 0.01 S/cm (C) 1.91 (D) 1.927
⇒ K = 1 S/m
⇒ Λm = 10M K = 10 0.5×1 = 2 × 10−3
3 −3
Solution:(Correct Answer:D)

(127) When a certain conductivity cell was filled with 0.1 M KCl , (133) Which one of the following metals cannot evolve H2 from
it had a resistance of 85 Ω at 25 o C . When the same cell was acids or H2 O or from its compounds
filled with an aqueous solution of 0.052 M unknown (A) Hg (B) Al
electrolyte, the resistance was 96 Ω . Calculate the molar
conductivity of the unknown electrolyte at this (C) P b (D) F e
concentration ............. Ω−1 cm2 mol−1 (Given : Specific
conductance of 0.1 M KCl = 1.29 × 10−2 Ω−1 cm−1 ) Solution:(Correct Answer:A)
(A) 120 (B) 219.65 (a)Hg has greater reduction potential than that of H + and
hence cannot displace hydrogen from acid.
(C) 200.35 (D) None of these
Solution:(Correct Answer:B) (134) Assertion: Electrical conductivity of copper increases with
increase in temperature
(128) A current of 0.4 amp is passed through excess of molten Reason: The electrical conductivity of metals is due to
M gCl2 for 9.65 × 104 sec. The mass of M g deposited at the motion of electrons.
cathode is .............. gm (A) If both Assertion and Reason are correct and the Reason
(A) 0.4 (B) 2.4 is a correct explanation of the Assertion.

(C) 4.8 (D) 9.6 (B) If both Assertion and Reason are correct but Reason is
not a correct explanation of the Assertion.
Solution:(Correct Answer:C)
(C) If the Assertion is correct but Reason is incorrect.
(129) Which one of the following statements is correct (D) If the Assertion is incorrect but the Reason is correct.
(A) The oxidation number of oxygen in KO2 is zero
Solution:(Correct Answer:D)
(B) The specific conductance of an electrolyte solution
Electrical conductivity of every metal decreases with
decreases with increase in dilution
increase in temperature due to increase in molecular motion
(C) Sn2+ oxidises F e3+ which increases resistance.
(D) Zn/ZnSO4 is a reference electrode
(135) Degree of ionisation of a solution depends upon
Solution:(Correct Answer:B) (A) Temperature
It’s obvious.
(B) Nature of the electrolyte
(130) The standard potential of a Co+2 |Co electrode is −0.28 V (C) Nature of the solvent
and the standard potential of the cell
(D) All of these
P t|T i2+ (aq), T i3+ (aq)||Co2+ (aq)|Co(s) is 0.09 V . What is
the standard oxidation potential of the T i2+(aq.) | T i(aq.)
3+
Solution:(Correct Answer:D)
electrode ? ............. V
(A) −0.37 (B) 0.37 (d)The degree of ionization depend upon the nature of the
solute the size of the solute molecules and the
(C) −0.19 (D) 0.19 concentration of the solution.
Solution:(Correct Answer:B)
(136) At 298 K the emf of cell is ............ V
Eocell = EoCo2+ |Co − EoT i3+ |T i2+
P t|H2(2 atm) |H(0.02
⊕ ⊕
M ) ||H(0.1 M ) |H2(1 atm) |P t
0.09 = − 0.28 − EoT i3+ | T i2+
− EoT i2+ |T i3+ = 0.37 V EoT i3+ |T i2+ = − 0.37 V (A) 0.05 (B) 0.0295
EoT i2+ |T i3+ = 0.37 V (C) 0.1 (D) 0.059

25
 Solution:(Correct Answer:A) (142) Calculate Λ∞HOAc using appropriate molar conductances of
H2 (g) + 2H+ (aq) → 2H+ (aq) + H2 (g) the electrolytes listed above at infinite dilution in H2 O at
2 atm 0.1 M 0.02 M 1 atm 25 o C
(0.02)2 ×1
E = 0 − 1 log 2×(0.1)2
0.0591

= − 0.0591 log 0.2×0.2 ElectrolyteKCl KN O3 HCl N aOAc N aCl

:
2 2
= − 2 log 100
0.0591 2

= − 0.0591
2 (0.3010 − 2)
= − 0.0591
2 (−1.7)
E = − 0.05 V Λ∞ (Scm2149.9
mol−1 ): 145.0 426.2 91.0 126.5

(137) 0.50 L of a 0.60 M CuSO4 solution is electrolyzed for a (A) 517.2 (B) 552.7
period of 30.0 min using a current of 4.60 A. If inert
electrodes are used, what is the final concentration of Cu2+ (C) 390.7 (D) 217.5
remaining in the solution ? ............. M Solution:(Correct Answer:C)
(A) 0.342 (B) 0.544 (c)Λ∞ ∞ ∞ ∞
HOAC = ΛN aOAC + ΛHCl − ΛN aCl
(C) 0.389 (D) 0.514 = 91.0 + 426.2 − 126.5 = 390.7

Solution:(Correct Answer:D) (143) Pure conc. HN O3 makes iron passive as the surface is
covered with protective layer of
Cu deposited = 63.52 ×
4.6×30×60
= 2.72 g
96500
(A) F e2 O3 (B) F eO
Cu Left in solution = 0.6 × 0.5 × 63.5 − 2.72
=  g 16.33
 16.33 (C) F e3 O4 (D) F e(N O3 )3
Cu+2 = 63.5×0.5 = 0.514 M
Solution:(Correct Answer:C)
(c)The passivity of iron is due to the formation of a thin
(138) Which will increase the voltage of the cell
insoluble and invisible iron film on surface which prevents its
Sn(s) + 2Ag + (aq) → Sn2+ (aq) + 2Ag(s)
further reactions. The film is due to the formation of F e3 O4 .
(A) Increase in the concentration of Ag + ions
(144) The standard reduction potentials of Cu2+ , Zn2+ , Sn2+
(B) Increase in the concentration of Sn2+ ions and Ag + are 0.34, −0.76, −0.14 and 0.80 V respectively.
(C) Increase in size of the silver rod The storage that is possible without any reaction is for
(under standard condition) :
(D) None of these
(A) CuSO4 solution in a zinc vessel
Solution:(Correct Answer:A) (B) AgN O3 solution in a zinc vessel
(Ag + )
(a)Ecell = o
Ecell + 0.059
2 log (Sn2+ ) . (C) AgN O3 solution in a tin vessel
(D) CuSO4 solution in a silver vessel
(139) On electrolysis of aqueous solution of KI in presence of
platinum electrodes Solution:(Correct Answer:D)
(a) Hydrogen gas is released at cathode Cu2+ &Zn2+ &Sn2+ &Ag +
(b) Oxygen gas is released at anode 0.34& − 0.76& − 0.14&0.80
(c) pOH of solution decreases
(d) There is deposition of potassium at cathode As the value of EoAg+ > EoCu2+ in aqueous condition so it can
Choose the correct option from following not be reduce in container.
(A) a, b (B) only a
(C) a, c (D) a, c, d

Solution:(Correct Answer:C)

(140) Which of the following is not used to construct salt bridge

(A) CH3 COOK (B) KCl (145) E.C.E. of Cu and Ag are 7 × 10−6 and 1.2 × 10−6 .A certain
current deposits 14 gm of Cu. Amount of Ag deposited is
(C) N H4 N O3 (D) KN O3 .............. gm
(A) 1.2 (B) 1.6
Solution:(Correct Answer:A)
It’s obvious. (C) 2.4 (D) 1.8
Solution:(Correct Answer:C)
(141) Electricity required for liberating 710 g of Cl2 (g) by (c) m1
= Z1
== > m2 = m1 Z2
= 14×1.2×10−6
= 2.4 g
electrolyzing a concentrated solution of N aCl will be m2 Z2 Z1 7×10−6

(A) 1.93 × 105 C (B) 1.93 × 106 C (146) The electrolytic decomposition of dilute sulphonic acid with
platinum electrode in cathodic reaction is
(C) 9.65 × 106 C (D) 9.65 × 105 C
(A) Oxidation
Solution:(Correct Answer:B)
(B) Reduction
E
W = 96500 ×Q
35.5
710 = 96500 ×Q (C) Oxidation and reduction both
Q = 1930000 = 1.93 × 106 C (D) Neutralisation

26
 Solution:(Correct Answer:B) P dCl42− (aq) + 2e− ⇌ P d(s) + 4Cl− (aq)
P t electrodes are inert. They won’t play any part in the E ◦ = 0.65 V
reaction at either electrodes. Dil −H2 SO4 implies that both (A) 3 (B) 4
H2 SO4 and H2 O are involved in the electrolyte. H + from (C) 12 (D) 6
H2 SO4 and H + from H2 O will be attracted to the cathode.
2H + + 2e− → H2 Solution:(Correct Answer:D)
This is a gain of electrons and so, the reaction is reduction. ∆G◦ = −RT ℓnK
⇒ Cathodic reaction in electrolytes of dil. H2 SO4 with P t −nF E
electrodes is reduction. cell = −RT × 2.303 (log10 K)
o

0.06 × n = log K
ECell
(147) At 25◦ C, the molar conductance at infinite dilution for the
P d+2 (aq.) + 2e− ⇌ P d(s), Ecat,red
o
= 0.83
strong electrolytes N aOH, N aCl and BaCl2 are
248 × 10−4 , 126 × 10−4 and 280 × 10−4 Sm2 mol−1 P d(s) + 4Cl (aq. ) ⇌ P dCl4 , (aq) + 2e− , EAnode,Oxid
− 2− 0
=
respectively. λom Ba(OH)2 in Sm2 mol−1 is 0.65
Net Reaction → P d2+ (aq.) +4Cl− (aq.) ⇌ P dCl42− (aq.)
◦
(A) 362 × 10−4 (B) 402 × 10−4 Ecell 0
= Ecat,reed − EAndode,oxid
0
◦
Ecell = 0.83 − 0.65
(C) 524 × 10−4 (D) 568 × 10−4 ◦
Ecell = 0.18
Also n = 2
Solution:(Correct Answer:C)
Using equation (1), (2) and (3) log K = 6
Given,
λom (N aOH) = 280 × 10−4 Sm2 mol−1
λom (N aCl) = 126 × 10−4 Sm2 mol−1 . . . . . . . . . . Chemistry - Section B (NUMERIC) . . . . . . . . . .
−4 −1
λm (BaCl2 ) = 280 × 10 Sm mol
o 2

The reaction for the formation of Ba(OH)2 can be written (151) The limiting molar conductivities of N aI, N aN O3 and
as AgN O3 are 12.7, 12.0 and 13.3 m Sm2 mol−1 , respectively
BaCl2 + 2N aOH → Ba(OH)2 + 2N aCl (all at 25◦ C ). The limiting molar conductivity of AgI at this
∵ λm Ba(OH)2 = λm BaCl2 + λm N aOH − 2λm N aCl
o o o o
temperature is .... m Sm2 mol−1
−4 −4 −4
∴ λm Ba(OH)2 = 280×10 +2×248×10 −2×126×10
o

= (280 + 496 − 252) × 10−4 Solution:

= 524 × 10−4 Sm2 mol−1
Given
(1) λ∞ 2
m (N aI) = 12.7 m Sm mol
−1
(148) What is the potential of a cell containing two hydrogen
(2) λm (N aN O3 ) = 12.0 m Sm mol−1
∞ 2
electrodes the negative one in contact with 10−8 M H + and
(3) λ∞ 2
m (AgN O3 ) = 13.3 m Sm mol
−1
positive one in contact with 0.025 M H + .............. V ∞
λm (AgI) = (1) + (3) − (2)
(A) 0.18 (B) 0.28 = 12.7 + 13.3 − 12.0
(C) 0.38 (D) 0.48 = 26.0 − 12.0
λ∞m (AgI) = 14.0
Solution:(Correct Answer:C)
(c) 12 H2 → H + (10−8 M ) + e− (oxidation) (152) Following figure shows dependence of molar conductance
H + (0.025 M ) + e− → 12 H2 (reduction) 0
of two electrolytes on concentration. Λ m is the limiting
Cell reaction is :
molar conductivity.The number of Incorrect statement(s)
H + (0.025 M ) → H + (10−8 M ); Ecell = 0.38 V .
from the following is ...........
0
(149) Consider the cell whose emf is 1.01 V . (A) Λ m for electrolyte A is obtained
√ by extrapolation
Haq+
Ag + Ag (B) For electrolyte B, vx Λm vs c graph is a straight line
H2 (P t) 0
1 atm pH = 4 xM with intercept equal to Λ m
What is the value of x ? ........... M (C) At infinite dilution, the value of degree of dissociation
( give : EAgo
+ |Ag = +0.8
2.303 RT
F = 0.06) approach zero for electrolyte B.
0
(A) 0.05 (B) 0.69 (D) Λ m for any electrolyte A or B can be calculated using
λ for individual ions.
◦
(C) 0.15 (D) 0.31
Solution:(Correct Answer:D)
H2 + 2Ag+ −→ 2H+ + 2Ag
(10−4 )
2

2 log 1×x2
E = E ◦ − 0.06
−8
1.01 = 0.8 − 0.03 log 10x2
−8
0.21 = −0.03 log 10x2
−8
−7 = log 10x2
−8
10−7 = 10x2
x = √110 = 0.316 M Solution:
Statement (A) and Statement (C) are incorrect
(150) The logarithm of equilibrium constant for the reaction
P d2+ + 4Cl− ⇌ P dCl42− is (Nearest integer) (153) The resistance of 0.05 M solution of oxalic acid is 200 ohm
Given : 2.303RT
F = 0.06V and cell constant is 2.0 cm−1 , the equivalent conductance
P d2+
(aq) + 2e −
⇌ P d(s) E ◦ = 0.83 V [S cm2 eq −1 ] will be

27
 10−+
Solution: α= 0.0015
Λc
Equivalent conductivity = Normality
k×1000
α = Λm0
k=?
m
10−4 6×10−5 ×1000
R = sA L 0.0015 = 0.0015×Λ◦ m

C = k A1 Λ0m = 6 × 102
k = c A1 = 200 1ohm × 2 cm−1 Z=6
= 0.01 ohm−1 cm−1
(159) Given l/a = 0.5 cm−1 , R = 50 ohm, N = 1.0. The
Equivalent = 100 1
× 1000 × 10
equivalent conductance of the electrolytic cell is ................
= 100 ohm−1 cm−1
Ohm−1 cm2 gm eq−1
(154) On passing electric current through molten aluminium Solution:
chloride, 11.2 litre of Cl2 is liberated at N T P at anode. The (a) l/a = 0.5 cm−1 , R = 50 ohm
quantity of aluminium deposited at cathode is .............. g (at. p = Ra 50
l = 0.5 = 100
wt. of Al = 27) Λ = k × 1000
N = p × N = 100 ×
1 1000 1 1000
1
−1 2 −1
10 ohm cm gm eq
Solution:
11.21 of Cl2 at NTP ⇒ 0.5 mole of Cl2 (160) A solution of F e2 (SO4 )3 is electrolyzed for ′ x′ min with a
Cl2 gives 2 moles of electer 2Cl− + 2e− → Cl2 current of 1.5 A to deposit 0.3482 g of F e. The value of x is
∴ moles of e− = 0.5 × 2 = 1Al3+ + 3e− → AC ........ [nearest integer]
∴ 1 mole of Ac requires 3 moles of e Given : 1 F = 96500 C mol−1
∴ 1 mole e− reduces 31 moles of AC Atomic mass of F e = 56 g mol−1
mole of AC = 13 × 27 = 9 g
Solution:
√
(155) For strong electrolyte ∧m = ∧om − 10 C . Then calculate F e3+ + 3e− −→ F e
∧m at 0.01 M if its value at 0.16 M is 200 Scm2 mol−1 ................ 3F −→ 1 mole F e is deposited
S cm2 mol−1 For 56 g −→ 3 × 96500 (required charge)
For 1 g −→ 3×96500
56 (required charge)
Solution: For 0.3482 g −→ 3×96500
56 × 0.3482
200 = Λom − 10 × 0.40 Q = it
Λom = 204 1800.06 = 1.5 t
Λom 204 − 10 × 0.1 = 203 S cm2 m−1 t = 20 min

(156) How many coulombs are provided by a current of 0.010 mA (161) The equilibrium constant for the reaction
in the calculator battery that can operate for 1000 hours ? Zn(s) + Sn2+ (aq) ⇌ Zn2+ (aq) + Sn(s) is 1 × 1020 at 298K.
The magnitude of standard electrode potential of Sn/Sn2+
Solution: if EZn
0
2+//nn = −0.76V is ............ × 10
−2
V . (Nearest
integer)
Q=i×t
Given : 2.303RT = 0.059 V
= 0.010 × 10−3 × 1000 × 3600 F

= 36 C Solution:
Zn(s) + Sn2+ (aq) ⇌ Zn2+ (aq) + Sn(s)
(157) The resistance of conductivity cell containing 0.01 M KCl
solution at 298 K is 1750 Ω. If the conductively of
RT log10 Keq
∆G0 = −2.303
−nF Ecell
0
= −2.303 RT log10 Keq
0.01 M KCl solution at 298 K is 0.152 × 10−3 S cm−1 , then
2 log10 Keq
0 0 0.059
EZn/Zn 2+ + ESn2+ /Sn =
the cell constant of the conductivity cell is
0.76 + ESn2+ /Sn = 2 log10 1020
0 0.059
.......... × 10−3 cm−1 .
0 0.059×20
0.76 + ESn 2+ /Sn = 2
Solution: 0
ESn2+/Sn = 0.59 − 0.76 = −0.17
K = R1 × cell cons tan t 0
ESn/Sn 2+ = 17 × 10
−2
V
0.152 × 10−3 = 1750
1
cell constant = 17
cell constant = 266 × 10−3
(162) How many minutes are required to deliver 3.21 × 106
(158) The conductance of a 0.0015M aqueous solution of a weak Columbs using a current of 500 A used in the commercial
monobasic acid was determined by using a conductivity cell production of chlorine?
consisting of platinized Pt electrodes. The distance between
Solution:
the electrodes is 120 cm with an area of cross section of
1 cm2 . The conductance of this solution was found to be Charge = Current × Time
5 × 10−7 S. The pH of the =⇒ 3.21 × 106 = 500× Time

solution is 4 . The value of limiting =⇒ Time = 6420 s
molar conductivity Λ0m of this weak monobasic acid in
aqueous solution is Z × 102 S cm−1 mol−1 . The value of Z is =⇒ Time = 107 min

(163) Emf of the following cell at 298 K in V is

Solution: x × 10−2 .Zn Zn2+ (0.1 M )∥Ag + (0.01 M ) Ag The value of
κ = G × aℓ x is .... .
cm2
κ = 5 × 10−7 × 120
1 cm2 = 6 × 10
−5
S cm−1 (Rounded off to the nearest integer)
Λcm = κ×1000
−5
×1000
= 6×100.0015 [Given : EZn 0
+2 /Z = −0.76 V ; EAg
0
+ /A =
C n g

pH = 4, [H ] = 10 = Cα
+ −4
+0.80 V ; F 2.303RT
= 0.059]

28
 Solution: (167) All the energy released from the reaction
Zn(s) → Zn2+ − X → Y · ∆T G0 = −193 kJ mol−1 is used for oxidizing
(aq.) + 2e
+
2Ag(aq.) + 2e− → 2Ag(s) M + as M + → M 3+ + 2e− , E 0 = −0.25 V .
_____________________________________________- Under standard conditions, the number of moles of
M oxidized when−1 one
 mole of X is converted to Y is
+
_____
+
Zn(s) + 2Ag(aq.) → Zn2+ F = 96500 C mol
(aq.) + 2Ag(s)
_____________________________________________-
_____________ Solution:
0
Ecell 0
= EAg + /Ag − Ezn2+ /Zn
0 X −→ Y ∆I G0 = −193KJ/mol
= 0.80 − (−0.76) M + −→ M 3+ + 2e− E 0 = −0.25V
= 1.56 V ∆G0 for the this reaction is
Ecell = 1.56 −0.059 log
[Zn2+ ] ∆G0 = −nF E 0 = −2 × (−0.25) × 96500 = 48250J/mol
2 [Ag + ]2
48.25kJ/mole
2 log (0.01)2
= 1.56 − 0.059 0.1
So the number of moles of M + oxidized using X −→ Y will
= 1.56 − 2 × 3
0.059
be
= 1.56 − 0.0885 193
= 48.25 = 4 moles
= 1.4715
= 147.15 × 10−2 (168) Conductivity of 0.001 M aq.solution of N a2 SO4 is found to
be 2.6 × 10−3 S cm−1 at 25 o C. If limiting molar
(164) For the galvanic cell, conductance of N a+ is 50 S cm2 mol−1 , then limiting molar
Zn(s) + Cu2+ (0.02M) → Zn2+ (0.04M) + Cu(s) conductance of SO42− will be .............. S cm2 mol−1 (neglect
hcell = ...... × 10 V(N earestinteger)
E −2
conductivity of water).
Use : E0Cu/Cu2+ = −0.34 V, E02n/Zn2+ = +0.76 V

2.303RT
F = 0.059 V Solution:



m Na
2λ∞ m SO4
+ λ∞
+ 2−

Solution: 1000(2.6×10−3 )
= = 260 S cm2 mol−1
Galvanic cell: 0.001

Zn(s) + Cu+2
(aq.) → Zn
+2
+ Cu(s)
0.02 M 0.04 M (169) The value of one Faraday is .............. C mol−1
[2n+2 ]
Nernst equation = Fcell = E◦cell − 0.059
2 log [Cu+2 ]
h i Solution:
⇒ Ecell E◦cell − E◦Zn+2 /Zn − 0.059
2 log 0.02
0.04
Faraday’s Constant is given the symbol F and is defined as
⇒ Ecell [0.34 − (−0.76)] − 0.059 the charge in coulumbs (C) of 1 mole of electrons. Faraday’s
2 log
2

⇒ Ecell 1 − 1 − 2 × 0.3010
0.059 constant is approximately 96485 C mol−1 . We can calculate
= 1.0911 = 109.11 × 10−2 (F ) by multiplying

the charge on one electron

= 109 1.602 × 10−19 by Avogadro’s number 6.022 × 1023 .
therefore the Answer is 96500 Cm−1
(165) The limiting molar conductivities ∧0 for N aCl, KBr and
KCl are 126, 152 and 150 S cm2 mol−1 respectively. The ∧0 (170) The density of Cu is 8.94 g cm−3 . The quantity of electricity
for N aBr is ............ S cm2 mol−1 needed to plate an area 10 cm × 10 cm to a thickness of
10−2 cm using CuSO4 solution would be, if atomic mass of
Solution: Cu is 63.5 .................. C
(c)(126 scm2 )∧0N aCl = ∧0N a+ + ∧0Cl− ..... (1)
(152 scm2 )∧0KBr = ∧0K + + ∧0Br− ..... (2) Solution:
(150 scm2 )∧0KCl = ∧0K + + ∧0Cl− ..... (3) W=d×V=d×A×t
By equation (1) + (2) − (3) = 8.94 × 100 × 10−2
∧0N aBr = ∧0N a+ + ∧0Br− = 8.94 g
Ew
= 126 + 152 − 150 = 128 Scm2 mol−1 W = 96500 ×Q
96500 Q
⇒ 8.94 = 63.5/2
(166) A current being passed for two hour through a solution of ⇒ Q = 27172 C
an acid liberating 11.2 litre of oxygen at N T P at anode.
What will be the amount of copper deposited at the
(171) At 298 K, a 1 litre solution containing 10 m mol of Cr2 O7 2−
cathode by the same current when passed through a
and 100 m mol of Cr3+ shows a pH of 3.0.
solution of copper sulphate for the same time ........... g
Given : Cr2 O72− → Cr3+ ; E 0 = 1.330 V and
2.303RT
= 0.059 V
Solution: F
The potential for the half cell reaction is x × 10−3 V . The
At ST P , value of x is ........
1 mole of oxygen gas = 32 g = 22.4 L
Therefore, 11.2 L of O2 = 22.4
32
× 11.2 = 16 g
Solution:
Therefore, MO = EO
MCu ECu
2 Cr2 O72− + 14H + + 6e− → 2Cr3+ + 7H2 O
2 )
( 63 (0.1)2
6 log (10−2 )(10−3 )14
⇒ 16 = 16
MCu
E = 1.33 − 0.059
(2)
⇒ MCu = 63 g E = 1.33 − 0.059
6 × 42 = 0.917
Hence the amount of copper deposited at the cathode is E = 917 × 10−3
63 g. x = 917

29
(172) Alkanes can be made by electrolysis of aquesus solution of (178) In a metal oxide, there is 20% oxygen by weight. Its
potassium salt of carboxylic acid. Find the weight of all equivalent weight is
gases evolved at ST P by passing 20 amp current for
9650 sec during elctrolysis of CH3 COO− K + (aq) reaction Solution:
.......... g [Ignore parallel or side reaction]
(d) O2 % = 20%
Metal % = 80% = 80
× 8 = 32 g of metal.
Solution: 20

2CH3 COO− → C2 H6 ↑ +2CO2 ↑ +2e−

2H+ + 2e− → H2 ↑ (179) 1 × 10−5 M AgNO 3 is added to 1 L of saturated solution of
ne− = 2 Faraday AgBr. The conductivity of this solution at 298 K is
⇒ wgas = 30 + 88 + 2 = 120 g ......... × 10−8 S m−1
[ Given : Ksp (AgBr) = 4.9 × 10−13 at 298K
(173) The specific conductance of 0.0025 M acetic acid is λ0Ag+ = 6 × 10−3 Sm2 mol−1
5 × 10−5 S cm−1 at a certain temperature. The dissociation λ0Br− = 8 × 10−3 Sm2 mol−1 i
constant of acetic acid is ...... 10−7 . (Nearest integer) λ0N O− = 7 × 10−3 Sm2 mol−1
Consider limiting molar conductivity of CH3 COOH as 3

400 S cm2 mol−1

Solution:
−5
Solution:
+
[Ag − ]=
 10 −5
∧m = Ck × 1000 N O3 = 10
Given k = 5 × 10−5 Scm−1 [Br− ] = [AgKsp
+ ] = 4.9 × 10
−8

k
C = 0.0025 M Λm = 1000×M
−5
×103 5×10−2
∧m = 5×10 0.0025 = 2.5×10 −3 For Ag +

= 20 S cm2 mol−1 KAg+

6 × 10−3 = 1000×10 −5
20 1
α = 400 = 20 KAg+ = 6 × 10−5
20 1
α = 400 = 20 ⇒ 6000 × 10−8
1
× 20
1
Cα2
for Br−
0.0025× 20
Ka = 1−α = 19
KBr−
8 × 10−3 = 1000×4.9×10
20
−6
19×20 = 6.6 × 10
0.0025 −8
=
= 66 × 10 −7 KBI− = 39.2 × 10−8
for N O3−
K3
(174) During electrolysis of aq. N aCl , if 3 mole of H2 O are 7 × 10−3 = 1000×10
N o−
−5

electrolysed then how much charge is required if current KN o3 = 7 × 10−5

efficiency is 75 % .............. F = 7000 × 10−8

Conductivity of solution
Solution: ⇒ (6000 + 7000 + 39.2) × 10−8
2H2 O + 2e− −→ H2 + 2OH− ⇒ 13039.2 × 10−8 Sm−1
gm eq. of H2 O = faraday used
3 × 1 = F × 100
75
(180) 4 g of copper was dissolved in concentrated nitric acid. The
F =4 copper nitrate solution on strong heating gave 5 g of its
oxide. The equivalent weight of copper is
(175) Ionic conductance of Ga+3 ions and N O3− ions at infinite
dilution are 120 Ω−1 cm2 mol−1 and 50 Ω−1 cm2 mol−1
Solution:
respectively. Equivalent conductance of Ga(N O3 )3 at
infinite dilution will be ........... Ω−1 cm2 eq−1 (b)In 5 gm CuO, 4 gm Cu and 1 gm O be present.

Solution: Element Wt. At Wt. W t./At.WRatio

t. ̸=


x
Λ◦eq = Λ◦eq cation + Λ◦eq anion
Λ◦m = n × Λ◦eq

(176) How many Faradays are required to generate one gram

.0625
Cu 4 gm 63.5 4/63.5 = 0.0625 =
atom of magnesium from M gCl2 0.0625 1

Solution:
(b) 1 mole of electrons = 1 faraday
.0625
O 1 gm 16 1/16 = 0.0625 =
M g ++ + 2e− → M g ; 2 moles of electrons = 2 faraday. 0.0625 1

(177) To deposit 0.6354 gm of copper by electrolysis of aqueous Emperical formula = CuO of oxide
cupric sulphate solution, the amount of electricity required In this oxide, oxidation no. of Cu = +2
(in coulombs) is Equivalent weight = Molecular weight
Oxidation no. = 2 ≈ 31.75 but
63.5

Equivalent weight should be an

Solution: integeral no.= 32
(d)Cu++ + 2e− → Cu
ECu = 63.54
2 = 31.77 (181) How long would it take to reduce completely 80 mL of
Amount of electricity required to deposit . 0.1 M F e2 (SO4 )3 to F eSO4 by passing = a current of
6354 gm of Cu = 96500×0.6354
31.77 = 1930 Coulombs. 2 Amp ? ........... sec

30
 Solution: (187) The standard reduction potentials at 298 K for the following
+3 +2 half cells are given below :
F e2 (SO4 )3 →F e SO4
(80 ml, 0.1 M) Cr2 O7 2− + 14H+ + 6e− → 2Cr3+ + 7H2 O, E◦ = 1.33 V
Q = [(2 − 3) × 2] × 80×0.1
1000 × 96500 Fe3+ (aq) + 3e− → FeE◦ = −0.04 V
(v − f actor)
Q= 2×80×0.1×96500 Ni2+ (aq) + 2e− → NiE◦ = −0.25 V
1000
Q = It Ag+ (aq) + e− → AgE◦ = 0.80 V
Au3+ (aq) + 3e− → AuE◦ = 1.40 V
(182) A metal surface of 100 cm2 area has to be coated with nickel
layer of thickness 0.001 mm. A current of 2 A was passed Consider the given electrochemical reactions, The number
through a solution of N i (N O3 )2 for ’ x ’ seconds to coat the of metal(s) which will be oxidized be Cr2 O7 2− , in aqueous
desired layer. The value of x is .......... (Nearest integer) solution is. . . . . .
( ρN i (density of Nickel) is 10 gmL−1 , Molar mass of Nickel is
60 gmol−1 F = 96500 C mol−1 ) Solution:
Fe, Ni, Ag will be oxidized due to lower S.R.P .
Solution:
(188) 2H + (aq) + 2e− → H2 (g).The standard electrode potential
W =z×i×t
for the above reaction is (in volts)
Density × volume = E×i×t
96500
( atomic wt.
)×2×x
10 × 100 × 0.0001 = v.f
96500 ( v.f = 2) Solution:
∴ x = 161 sec. (a)Standard electrode potential of Hydrogen is zero.

(183) When 0.1 mol M nO42− is oxidised the quantity of electricity (189) The amount of charge required to liberate 9 gm of
required to completely oxidise M nO42− to M nO4− is ........ C. aluminium (atomic weight = 27 and valency = 3) in the
process of electrolysis is ......... coulombs (Faraday’s number
Solution: = 96500 coulombs/gm equivalent)
The oxidation reaction is
MnO2− Solution:
4 −→ MnO4 + e
− −

0.1mol 1mol (d) Equivalent weight of aluminium = 273 =9

Q = 0.1 × F = 0.1 × 96500C = 9650C So 1 faraday = 96500 C are required to liberate 9 gm of Al.

∞
(190) In an electrochemical reaction of lead, at standard

(184) Given that 1 3+
= 68 ohm−1 cm−1 eq −1 and temperature, if E(P
3 λm F e b2+ /P b) = m Volt and E(P b4+ /P b) = n
0 0
∞

1
2 λm SO4
2−
= 80 ohm−1 cm−1 eq −1 What will be value of Volt, then the value of E(P 0
b2+ /P b4+ ) is given by m − xn. The
∞
λeq (F e2 (SO4 )3 ) ? ............ ohm−1 cm2 eq−1 value of x is ............ (Nearest integer)

Solution:
Solution:
∞

P b2+ + 2e− → P b ∆G01 = −2F E10
λ eg(Al2 (SO4 ))3 = 13 Λ∞
M Al+3 + 12 Λ∞
M SO4
2−
P b4+ + 4e− → P b ∆G02 = −4F E20
= 68 + 80 P b2+ → P b4+ + 2e− ∆G03 = −2F E30
= 148 Ω−1 cm−1 eq−1 ∆G03 = ∆G01 − ∆G02
−2F E30 = 2F (2n − m)
(185) 0.5 N solution of a salt placed between two platinum E30 = m − 2n = m − xn
electrodes 2.0 cm apart and of area of cross section 4.0 cm2 Hence x = 2
has a resistance of 25 ohms . Calculate the equivalent
conductivity of solution ................. Ω−1 cm2 eq−1 (191) The molar conductivities at infinite dilution of barium
chloride, sulphuric arid and hydrochloric acid are 280, 860
Solution: and 426 Scm2 mol−1 respectively. The molar conductivity at

infinite dilution of barium sulphate is ...... Scm2 mol−1 (
Λeq = 1R × Al × 1000
N
1
= 25 × 24 × 1000 Round off to the Nearest Integer).
0.5
= 40 Ω−1 cm2 eq−1
Solution:
o From Kohlrausch’s law


(186) The limiting molar conductivity Λ for N aCl, KBr and KCl Λ∞ ∞ 2+
+ λ∞ 2−
o m (BaSO4 ) = λm Ba m SO4
are 126, 152 and 150 S cm2 mol−1 respectively. The Λ for Λ∞ ∞ ∞ ∞
m (BaSO4 ) = Λm (BaCl2 ) + Λm (H2 SO4 ) − 2Λm (HCl)
N aBr is (in S cm2 mol−1 ). = 280 + 860 − 2(426)
= 288 Scm2 mol−1
Solution:
The limiting molar conductivities of N aCl, KBr and KCl (192) The quantity of charge required to obtain 1 mole of
are 126, 152 and 150 S cm2 mol−1 respectively. aluminium from Al2 O3 is ............ F
The limiting molar conductivity Λ◦ for N aBr is calculated
by the following expression. Solution:
λ∞ ∞ ∞
N aBr = λN aCl + λKBr − λKCl
∞
6e− + 2Al+3 −→ 2Al
∞
λN aBr = 126 + 152 − 150 Hence, 6 F is required to get 2 mole Al and 3 F is required
= 128 S cm2 mol−1 to get 1 mole Al

31
(193) An acidic solution of dichromate is electrolyzed for 8 (200) Standard electrode potential of N HE at 298 K is .............. V
minutes using 2 A current. As per the following equation
Cr2 O72− + 14H + + 6e− → 2Cr3+ + 7H2 O Solution:
The amount of Cr3+ obtained was 0.104 g. The (c)At 298 K standard electrode potential of N HE electrode
efficiency of the process(in%) is is 0.00 V
(Take : F = 96000 C, At. mass of chromium = 52 )

Solution:


Moles of e⊖ = 8×60×296000
Using stoichiometry; theoritically
ne⊖ used n produced
6 = cr+3 2
⇒ ncr+3 produced = 26 × 8×60×2 96000
= 0.02
6
⇒ wtcr+3 theoritically

produced
= 0.026 × 52 g
⇒ % efficiency = 0.02×520.104g
× 100
( 6 )g
= 60%

(194) To deposit one litre of hydrogen at 22.4 atmosphere from

acidulaled water, the quantity of electricity that must pass
through is ............. coulomb

Solution:
(d) V2 = 22.4×1
1 = 22.4 litre at N T P
11.2 litre of H2 is liberated by 96, 500 C
22.4 litre of H2 is liberated by 96500 × 2 = 1, 93, 000 C

(195) The number of coulombs required for the deposition of

107.870 g of silver is

Solution:
(a) Equivalent weight of silver = 107.870 g.
1 Faraday = 96500 coulomb .

(196) Resistance of a decimolar solution between two electrodes

0.02 meter apart and 0.0004 m2 in area was found to be
50 ohm. Specific conductance (k) is : ........... S m−1

Solution:
K = G × G∗
⇒ R = 501
× 0.0004
0.02

⇒ R = 1 Sm −1

(197) What is E o for electrode represented by

P t, O2 (1 atm) / 2H + (1 m) ............. V

Solution:
(b) E o = 0 because hydrogen have zero potential.

(198) The resistance of a conductivity cell with cell constant

1.14 cm−1 , containing 0.001 M KCl at 298 K is 1500 Ω. The
molar conductivity of 0.001 M KCl solution at 298 K in
S cm2 mol−1 is ...... . (Integer answer)

Solution:



K = 1R × ℓ/A = 1
1500 × 1.14 S cm−1
( 1500
1.14
)
⇒ ∧m = 1000 × 0.001 S cm2 mol−1
= 760 S cm mol
2 −1

⇒ 760

(199) The charge required for the reduction of 1 mol of M nO4− to

M nO2 is ............ F

Solution:
M nO4 − + 4H + + 3e− → M nO2 + 2H2 O
So, 3 F of charge will be required to reduce 1 mole of
M nO4− .

32