MUNISH MITTAL CHEMISRY CLASSES

TEST - ATOMIC STRUCTURE

SUBJECTIVE QUESTIONS 8. Which state of the triply ionized Beryllium (Be3+)
1. The Vividh Bharati Station of All India Radio, Delhi has the same orbit radius as that of the ground
broadcasts on a frequency of 1368 kHz (kilo hertz). state of hydrogen atom ?
Calculate the wavelength and wave number of the 9. If the velocity of the electron in first orbit of H atom
electromagnetic radiation emitted by the is 2.18 × 106 m/s,what is its value in third orbit ?
transmitter. 10. Consider Bohr's theory for hydrogen atom. The
2. One quantum is absorbed per gaseous molecule magnitude of angular momentum, orbit radius and
of Br2 for converting into Br atoms. If light absorbed velocity of the electron in nth energy state in a
has wavelength 5000 Å, calculate energy required hydrogen atom are  , r & v respectively. Find out
in kJ/mol. the value of ' x', if product of v, r and  (vr) is
3. The eyes of a certain member of the reptile family directly proportional to nx.
pass a visual signal to the brain when the visual 11. Find the ratio of the time period of 2nd Bohr orbit of
receptors are struck by photons of wavelength He+ amd 4th Bohr orbit of Li2+.
850 nm. If a total energy of 3.15 × 10–14 J is required 12. Calculate the speed of an electron in the ground
to trip the signal, what is the minimum number of state of He+ ion. What fraction of speed of light is
photons that must strike the receptor. (h = 6.6 × this value? How long does it take for the electron
10–34) to complete one revolution around the nucleus.
4. Two bulbs ‘A’ and ‘B’ emit red light and yellow How many times does the electron travel around
light at 8000 Å and 4000Å respectively. The number the nucleus in one second ?
of photons emitted by both the bulbs per second 13. Consider three electron jumps described below
is the same. If the red bulb is labelled as 100 for the hydrogen atom
watts, find the wattage of the yellow bulb. x: n = 3 to n=1
5. The threshold frequency for the ejection of y: n = 4 to n=2
electrons from potassium metal is 5.3 × 1014 s–1. z: n = 5 to n=3
Will the photon of a radiation having energy 3.3 × The photon emitted in which transition x, y or z
10–19 J exhibit photoelectric effect ? (h = 6.626 × will have shortest wavelength.
10–34 Js) 14. A hydrogen sample is prepared in a particular
6. If a light with frequency 4 × 1016 Hz emitted excited state. Photons of energy 2.55 eV get
photoelectrons with double the maximum absorbed into the sample to take some of the
kinetic energy as are emitted by the light of electrons to a further excited state B. Find orbit
frequency 2.5 × 1016 Hz from the same metal numbers of the states A and B. Given the allowed
surface, then what is the threshold frequency energies of hydrogen atom :
( 0) of the metal ? E1 = –13.6 eV, E2 = –3.4 eV, E3 = –1.5 eV, E4 = –
7. If the work function (w) of an arbitrary metal is 3.1 0.85 eV, E5 = –0.54 eV
eV, find its threshold wavelength and the maximum 15. When an electron falls from (n + 2) state to (n)
kinetic energy of the electron emitted when state in a He+ ion the photon emitted has energy
radiation of 300 nm strike the metal surface. (Take 6.172 × 10 –19 joules. What is the value of n.
hc = 12400 eVÅ)
OBJECTIVE TYPE QUESTIONS
4. Electromagnetic radiations of wavelength 242 nm
1. The value of Planck’s constant is 6.63 × 10–34 Js.
is just sufficient to ionise Sodium atom. Then the
The velocity of light is 3 × 108 m/sec. Which value
ionisation energy of Sodium in kJ mole-1 is.
is closest to the wavelength of a quantum of light
(A) 494.65 (B) 400
with frequency of 8 × 1015 sec–1 ?
(C) 247 (D) 600
(A) 5 × 10–18 m (B) 4 × 10–8 m
7 5. Light of wavelength  falls on metal having work
(C) 3 × 10 m (D) 2 × 10–25 m
function hc/0. Photoelectric effect will take place
2. The MRI (magentic resonance imaging) body
scanners used in hospitals operate with 400 MHz only if :
radio frequency. The wavelength corresponding (A)   0 (B)   20
to this radio frequency is (C)   0 (D)   0/2
(A) 0.75 m (B) 0.75 cm 6. A photon of energy h is absorbed by a free
(C) 1.5 m (D) 2 cm electron of a metal having work function w < h.
3. Photon of which light has maximum energy : Then :
(A) red (B) blue
(A) The electron is sure to come out
(C) violet (D) green (B) The electron is sure to come out with a kinetic

:: 4 :: MUNISH MITTAL CHEMISTRY CLASSES

 energy (h – w) 15. Match the following
(C) Either the electron does not come out or it (a) Energy of ground state of He+ (i) + 6.04 eV
comes with a kinetic energy (h – w) (b) Potential energy of  orbit of H-atom (ii) –27.2 eV
(D) It may come out with a kinetic energy less (c) Kinetic energy of  excited state of He+ (iii) 54.4 V
than (h – w) (d) Ionisation potential of He+ (iv) – 54.4 eV
7. A bulb of 40 W is producing a light of wavelength (A) A – (i), B – (ii), C – (iii), D – (iv)
620 nm with 80% of efficiency then the number of (B) A – (iv), B – (iii), C – (ii), D – (i)
photons emitted by the bulb in 20 seconds are (C) A – (iv), B – (ii), C – (i), D – (iii)
(1eV = 1.6 × 10–19 J, hc = 12400 eV Å) (D) A – (ii), B – (iii), C – (i), D – (iv)
(A) 2 × 1018 (B) 1018 16. S1 : Bohr model is applicable for Be2+ ion.
(C) 10 21
(D) 2 × 1021 S2 : Total energy coming out of any light source
is integral multiple of energy of one photon.
8. Correct order of radius of the st orbit of H, He+,
S3 : Number of waves present in unit length is
Li2+, Be3+ is :
wave number.
(A) H > He+> Li2+ > Be3+
S4 : e/m ratio in cathode ray experiment is
(B) Be3+ > Li2+> He+ > H
(C) He+ > Be3+ > Li2+ > H independent of the nature of the gas.
(D) He+ > H > Li2+ > Be3+ (A) F F T T (B) T T F F
(C) F T T T (D) T F F F
9. What is likely to be orbit number for a circular
17. S1 : Potential energy of the two opposite charge
orbit of diameter 20 nm of the hydrogen atom :
system increases with the decrease in distance.
(A) 10 (B) 14
S2 : When an electron make transition from higher
(C) 12 (D) 16
10. Which is the correct relationship : orbit to lower orbit it's kinetic energy increases.
(A) E1 of H = 1/2 E2 of He+ = 1/3 E3 of Li2+ = 1/4 S3 : When an electron make transtition from lower
energy to higher energy state its potential energy
E4 of Be3+
increases.
(B) E1(H) = E2(He+) = E3 (Li2+) = E4(Be3+)
S4 : 11eV photon can free an electron from the 1st
(C) E1(H) = 2E2(He+) = 3E3 (Li2+) = 4E4(Be3+)
excited state of He+ -ion.
(D) No relation
(A) T T T T (B) F T T F
11. If the value of En = – 78.4 kcal/mole, the order of
(C) T F F T (D) F F F F
the orbit in hydrogen atom is :
18.* Choose the correct relations on the basis of Bohr’s
(A) 4 (B) 3
theory.
(C) 2 (D) 1
12. If velocity of an electron in  orbit of H atom is V, 1
(A) Velocity of electron 
what will be the velocity of electron in 3rd orbit of n
Li+2
1
(A) V (B) V/3 (B) Frequency of revolution 
(C) 3 V (D) 9 V n3
13. In a certain electronic transition in the hydrogen (C) Radius of orbit  n2 Z
atoms from an initial state (1) to a final state (2), 1
the difference in the orbital radius (r1 – r2) is 24 (D) Electrostatic force on electron 
n4
times the first Bohr radius. Identify the transition.
(A) 5  1 (B) 25  1 19. The energy of hydrogen atom in its ground state
(C) 8  3 (D) 6  5 is –13.6 eV. The energy of the level corresponding
14. The species which has its fifth ionisation potential to n = 5 is:
equal to 340 V is (A) –0.54 eV (B) –5.40 eV
(A) B+ (B) C+ (C) –0.85 eV (D) –2.72 eV
(C) B (D) C 20. Total no. of lines in Lyman series of H spectrum
will be (where n = no. of orbits)
(A) n (B) n – 1
(C) n – 2 (D) n (n + 1)

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