ish¨ u ysñlï weúßKs $ K%g; gjpg;GhpikAilaJ $ All Rights Reserved]

ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj
mQ¾j úNd. mÍCIKh - 25
Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe Chemistry
Pre-Examination Test (PET) – 25
ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj
Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe-Chemistry Osman Jayasinghe Chemistry

wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2025 wf.daia;=

fy;tpg;; nghJj; juhjug; gj;ju (cau; ju) g; ghPl;ir" 2025 Xf];w;
General Certificate of Education (Adv.Level) Examination, August 2025
ridhk úoHdj II
,urhadtpay; II
Chemistry II Revision 2025 02 S II
meh ;=khs wu;r lshùï ld,h - ñks;a;= 10 hs
%d;W kzpj;jpahyk; Nkyjpf thrpg;G Neuk; - 10 epkplE;fs;;
Three hours Additional Reading Time - 10 minutes
wu;r lshùï ld,h m%Yak m;%h lshjd m%Yak f;dard .ekSug;a ms<s;r
= e ,sùfï § m%uqL;ajh fok m%Yak
ixúOdkh lr .ekSug;a fhdod .kak'

ku ( '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' Bio Maths

 wdj¾;s;d j.=jla imhd we;'  .Kl hka;% Ndú;hg bv fokq fkd,efí'

 id¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1  wej.dâfrda ksh;h" NA = 6.022 × 1023 mol-1
 fuu m%Yak m;%hg ms<s;=re iemhSfï § we,alhs,a ldKav ixlaIsma; wdldrhlska ksrEmKh l< yels h'
H H
WodyrKh ( H–C–C– ldKavh CH3CH2 – f,i ±laúh yels h'
H H
 A fldgi - jHqy.; rpkd
 ish¨ u m%Yakj,g fuu m;%fhau ms<s;=re imhkak'
 Tfí ms<s;=re tla tla m%Yakhg bv i,id we;s ;ekaj, ,súh hq;=h' fï bv m%udKh ms<s;=re ,sùug m%udKj;a nj o
§¾> ms<s;=re n,dfmdfrd;a;= fkdjk nj i,lkak'

 B fldgi iy C fldgi rpkd

 tla tla fldgiska m%Yak fol ne.ska f;dard .ksñka m%Yak y;rlg ms<s;=re imhkak' fï i|yd imhkq ,nk lvodis
Ndú; ;rkak'
 iïmQ¾K m%Yak m;%hg kshñ; ld,h wjika jQ miq A, B iy C fldgiaj,g ms<s;=re" A fldgi uq,ska ;sfnk mßÈ
tla ms<s;=re m;%hla jk fia wuqKd úNd. Yd,dêm;sg Ndr fokak'
 m%Yak m;%fhys B iy C fldgia muKla úNd. Yd,dfjka msg;g f.k hd yels h'

mÍCIlf.a m%fhdackh i|yd muKs' wjidk ,l=Kq

fldgi m%Yak wxlh ,enq ,l=Kq
b,lalfuka
01.
wl=ßka
A 02.
03.
ixfla; wxl
04.
05. W;a;r m;% mÍCIl
B 06. mÍCId lf<a 1
07.
08.
2
C 09. wëCIKh
10.
tl;=j

m%;sY;h

- Chemistry - -01- Osman Jayasinghe

 fï ;Srfha
A fldgi - jHqy.; rpkd lsisjla
fkd ,shkak
m%Yak y;rg u W;a;r imhkak' ^tla tla m%Yakh i|yd kshñ; ,l=Kq m%udKh 10 ls'& fuh
mÍCIljreka
i|yd muKs'
01' (a) my; i|yka m%ldY i;H o ke;fyd;a wi;H o hk nj ;s;a-bß u; i|yka lrkak' fya;= wjYH
ke;'
(i) lef;dav lsrK iy lsrK hk foflys u wxY=j, wdfrdamKh iy ialkaOh w;r
wkqmd;h (e/m) tlu fõ' ''''''''''''''''''''''
(ii) fldm¾ (Cu) mrudKqjl pqïnl lafjdkagï wxlh ml = - 1 jk bf,lafg%dak 6 la we;'
''''''''''''''''''''''
+
(iii) F2ClO whkhg ;,Sh ;%sfldaKdldr yevhla we;' ''''''''''''''''''''''''
(iv) F, S iy Cl uQ,øjH w;=frka i,a*¾ (S) j,g wvqu m<uq whkSlrK Yla;sh we;' ''''''''''''''''''
(v) legdhkj, O%eùlrK n,h iy wekdhkj, O%ejKYS,;dj yd iïnkaO kS;s" KF j,g jvd
LiCl j, øjdxlh by< nj mqfrdal:kh lrhs' ''''''''''''''''''''''
(vi) % a wï,h (HNO2) ys N – O nkaOk fol È.ska iudk h'
khsgi ''''''''''''''''''''''
(vii) CN2−
2 whkh i|yd we¢h yels ¨úia ;s;a-bß jHqy ^iïm%hqla; jHqy& ixLHdj 3 ls' '''''''''''''''''''''''''
(viii) fylafiaka (hexane) j, ;dmdxlh 2,2-vhsó;hs,aìhqfÜka (2,2-dimethylbutane) ys tu
w.hg jvd by< h' ''''''''''''''''''''''
^,l=Kq 32&

(b) (i) ISO4F wKqj i|yd jvd;au ms<s.; yels ¨úia ;s;a-bß jHqyh w¢kak' tys iels,a, my;
olajd we;'
O O
F–S–I–O
O

(ii) by; (i) ys w¢k ,o jHqyfha S iy I mrudKqj, TlaislrK wxl fokak

S – '''''''''''''''''''''''''''''''''''''''''''''''''''''' " I – ''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) HNCO wKqj i|yd mss<s.; yels ^ia:dhs& ¨úia ;s;a-bß jHqyhla my; § we;' fuu wKqj
i|yd ;j;a ¨úia ;s;a-bß jHqy ^iïm%hqla; jHqy& folla we| tajdfha ia:dhs;djhka § we;s
jHqyhg idfmaCIj ±laùug tu jHqy háka ia:dhs fyda wvq ia:dhs fyda wia:dhs jYfhka
,shkak'

H–N=C=O

- Chemistry - -02- Osman Jayasinghe

 fï ;Srfha
(iv) my; i|yka ¨úia ;s;a bß jHqyh yd tys f,an,a lrk ,o iels,a, mokï lrf.k § we;s lsisjla
fkd ,shkak
j.=j iïmQ¾K lrkak' fuh
mÍCIljreka
i|yd muKs'
H O H O
H–N–N=N–N C H – N1 – N2 – N3 – N4 – C

N1 N2 N3 N4
(I) VSEPR hq.,a .Kk
(II) bf,lafg%dak hq., cHdñ;sh
(III) yevh
(IV) uqyqïlrKh

fldgia (v) isg (viii), by; (iv) fldgfiys fok ,o ¨úia ;s;a bß jHqyh u; mokï fõ'
mrudKq f,an,a lsÍu (iv) fldgfiys wdldrhg u fõ'
(v) my; ±lafjk mrudKq fol w;r nkaOk iE§ug iyNd.S jk mrudKql $ uqyqï ldlaIsl
y÷kd.kak'
(I) H – N1 H – '''''''''''''''''''''''''''''''''''''''''''''' N1 – ''''''''''''''''''''''''''''''''''''''''''''''
(II) N1 – N2 N1 – '''''''''''''''''''''''''''''''''''''''''''''' N2 – ''''''''''''''''''''''''''''''''''''''''''''''
(III) N2 – O N2 – '''''''''''''''''''''''''''''''''''''''''''''' O – ''''''''''''''''''''''''''''''''''''''''''''''
(IV) N2 – N3 N2 – '''''''''''''''''''''''''''''''''''''''''''''' N3 – ''''''''''''''''''''''''''''''''''''''''''''''
(V) N3 – N4 N3 – '''''''''''''''''''''''''''''''''''''''''''''' N4 – ''''''''''''''''''''''''''''''''''''''''''''''
(VI) N4 – C N4 – '''''''''''''''''''''''''''''''''''''''''''''' C – ''''''''''''''''''''''''''''''''''''''''''''''
(vi) my; ±lafjk mrudKq fol w;r nkaOk iE§ug iyNd.S jk mrudKql ldlaIsl
y÷kd.kak'
(I) N2 – N3 N2 – '''''''''''''''''''''''''''''''''''''''''''''' N3 – ''''''''''''''''''''''''''''''''''''''''''''''
(II) N4 – C N4 – '''''''''''''''''''''''''''''''''''''''''''''' C – ''''''''''''''''''''''''''''''''''''''''''''''
N4 – '''''''''''''''''''''''''''''''''''''''''''''' C – ''''''''''''''''''''''''''''''''''''''''''''''
(vii) N1 , N2 , N3 iy N4 mrudKq jgd wdikak nkaOk fldaK i|yka lrkak'
N1 '''''''''''''''''''' N2 '''''''''''''''''''' N3 '''''''''''''''''''' N4 ''''''''''''''''''''
(viii) N1 , N2 , N3 yd N4 mrudKq tajdfha úoHq;a RK;djhka jeäjk ms<sfj<g ilikak'
''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' ^,l=Kq 56&

(c) jryka ;=< olajd we;s .=Kh jeäjk ms<sfj<g my; i|yka úfYaI ilikak' fya;= wjYH ke;'
(i) B, O, F, S, Na, Mg ^úoHq;a RK;dj&
''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < '''''''''''''''''''''
(ii) K+ , Mg2+ , Ca2+ , Al3+ , Cl− , S2- ^whksl wrh&
''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' < ''''''''''''''''''''' 100
^,l=Kq 12&

- Chemistry - -03- Osman Jayasinghe

 fï ;Srfha
02' (a) (i) (I) X hkq ;eô,s meye;s whksl ixfhda.hls' th 7 : 2 : 2 wkqmd;fhka we;s uQ,øjH lsisjla
fkd ,shkak
fuh
;=klska iukaú; fõ' ^ridhksl iQ;%h ,sùfï wkqms<sfj<g fkdfõ& fïjdhska folla" mÍCIljreka
i|yd muKs'
wdj¾;s;d j.=fõ tlu wdj¾;hg wh;a f,day fõ' fuu f,day foflka tlla" s
f.dkqjg wh;a jk w;r" wfkl d-f.dkqjg wh;a fõ' d-f.dkqfõ f,dayh úoHq;a
f,daydf,amkfha § nyq,j Ndú; fõ'
X y÷kd.kak' ''''''''''''''''''''''''''''''''''''''''''''''''''''''
(II) Y hkq LKsc wï,hls' th 1:2:4 wkqmd;fhka we;s uQ,øjH ;=klska iukaú; fõ'
^ridhksl iQ;%h ,sùfï wkqms<sfj<g fkdfõ& Y ys we;s tla uQ,øjHhla X ys o wvx.=
fõ' fmdiafmag fmdfydr ksmoùu i|yd Y Ndú; fõ'
Y y÷kd.kak' ''''''''''''''''''''''''''''''''''''''''''''''''''''''
(III) Z hkq lgql .|la we;s ;%s-mrudKql jdhqjls' thg V – yevhla we;' th Y
ksIamdokfha § Ndú; fõ'
Z y÷kd.kak' ''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) X ys wvx.= f,day foflys TlaislrK wxl yd bf,lafg%dksl úkHdi ,shkak'
f,dayh '''''''''''''''''''''' TlaislrK wxlh '''''''''''''''''''''' bf,lafg%dksl úkHdih '''''''''''''''''
f,dayh '''''''''''''''''''''' TlaislrK wxlh '''''''''''''''''''''' bf,lafg%dksl úkHdih '''''''''''''''''
(iii) (I) Z Wmfhda.S fldg Y ksIamdokh lrk l%shdj,sh kï lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(II) Z, O2(g) iuÕ m%;sl%shd lr iEfok jdhqj Y j, idkaø ødjKhl Èh l< úg P
ixfhda.h ,ndfoa' P ixfhda.h c,h iuÕ m%;sl%shd l< úg kej; Y ,ndfoa' P
ixfhda.fha ku iy ridhksl iQ;%h ,shkak'
ku '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ridhksl iQ;%h '''''''''''''''''''''''''''''''''''''
(iv) X, Y yd Z tlg m%;sl%shd l< úg isÿjk m%;sl%shdj i|yd ;=,s; ridhksl iólrK
,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^,l=Kq 50&

(b) BaCl2 , NaI, Pb(NO3)2 , ;kql HCl, Al2(SO4)3, AgNO3 , idkaø NH4OH yd ;kql NH4OH ys c,Sh
ødjK A, B, C, D, E, F, G yd H f,i f,an,a lr we;s fnda;,a wgla ^ms<sfj<g fkdfõ&
YsIHfhl=g fok ,§' tajd y÷kd .ekSu i|yd jrlg ødjK fol ne.ska ñY% lsÍfuka ,enqKq
iuyr m%fhdackj;a ksÍCIK my; olajd we;'
ñY% l< ødjK ksÍCIKh
I A+C WKq c,fhys ødjH ly meye;s wjlafIamhla
II B+C H ys wødjH ly meye;s wjlafIamhla
III A+E WKq c,fhys ødjH iqÿ meye;s wjlafIamhla
IV B+E D ys ødjH iqÿ meye;s wjlafIamhla
V E+F G ys wødjH iqÿ meye;s wjlafIamhla
VI A+F G ys wødjH iqÿ meye;s wjlafIamhla
VII D+G wj¾K ødjKhla
VIII H+G wj¾K ødjKhla

- Chemistry - -04- Osman Jayasinghe

 fï ;Srfha
(i) A isg H y÷kd.kak' lsisjla
fkd ,shkak
fuh
A- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' E- ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' mÍCIljreka
i|yd muKs'
B- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' F- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
C- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' G- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
D- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' H- '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) I isg VI tla tla m%;sl%shdfjys wjlafIam iE§u i|yd ;=,s; ridhksl iólrK fokak'
wjlafIamhla oelaùug i,l=K Ndú; lrkak'
(I) '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(II) ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(III) '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(IV) ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(V) '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
100
(VI) '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^,l=Kq 50&

03' (a) WIaK;ajh 250C § H2CO3(aq) wï,fha ú>gk ksh;

K1 = 4.5 × 10–7 mol dm–3 iy K2 = 4.7 × 10–11 mol dm–3 fõ'
(i) H2CO3(aq) j, m<uq iy fojk ú>gk i|yd iu;=,s; m%;sl%shd ,shkak'

(ii) m<uq ú>gkh i,lñka 250C § 0.05 mol dm–3 H2CO3(aq) ødjKhl H3O+(aq) iy
HCO3−(aq) idkaøKh .Kkh lrkak'

'
- Chemistry - -05- Osman Jayasinghe
 fï ;Srfha
(iii) fojeks ú>gkh i,lñka" ødjKfha [CO2−
3 (aq)] wdikak jYfhka K2 j,g iudk nj
lsisjla
fkd ,shkak
fuh
fmkajkak' .kakd ,o Wml,amk$h i|yka lrkak' mÍCIljreka
i|yd muKs'

^,l=Kq 60&

(b) WIaK;ajh 250C § 0.01 mol dm–3Al3+(aq) whk iy 0.01 mol dm–3 Ag+(aq) whk wvx.= c,Sh
ødjKhla Tng imhd we;' tu ødjKfha 1.0 dm3 lg idkaø PO3−
4 (aq) whk ødjKhla fkdkj;ajd
l,;ñka" ìxÿj ne.ska tl;= lrk ,§'
WIaK;ajh 250C §"
Ksp(AlPO4) = 1.3 × 10–20 mol2 dm–6 iy Ksp (Ag3PO4) = 8.1 × 10–12 mol4 dm–12 fõ'
(i) PO3−
4 (aq) ødjKh tla lsÍfï § isÿ úh yels mßud fjki fkdi,lñka" ñY%Kfhka m<uqj

wjlafIam jk f,day whkh (Al3+ fyda Ag+) l=ula±hs i|yka lrkak' iqÿiq .Kkh lsÍula
mokï lr .ksñka Tnf.a mss<s;=r i|yd fya;= olajkak'

- Chemistry - -06- Osman Jayasinghe

 fï ;Srfha
(ii) fofjks whkh wjlafIam ùu wdrïN jk úg m<uqj wjlafIam jQ whkfha idkaøKh lsisjla
fkd ,shkak
fuh
.Kkh lrkak' mÍCIljreka
i|yd muKs'

100

^,l=Kq 40&
04' (a) wKql iQ;%h C5H10O3 la jQ A ldnksl ixfhda.h jeämqr PCl5 iuÕ m%;sl%shd lr idfmaCI
wKql ialkaOh 155 la jQ B ixfhda. idohs' A ixfhda.h c,Sh Na2CO3 iuÕ CO2 uqla;
lrhs' (C = 12.0 , H = 1.0 , O = 16.0 , Cl = 35.5)
(i) A ixfhda.fha mj;sk l%shdldÍ ldKav ,shkak'

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
A ixfhda.h m%ldY iudjhúl;djh fkdfmkajhs' A ixfhda.h msßãkshï laf,dafrdfl%dafïÜ
iuÕ m%;sl%shd lr C ixfhda.h idohs' C ixfhda.h wefudakSh AgNO3 iuÕ ß§ legm;la
,ndfohs' B ixfhda.h c,h iuÕ m%;sl%shd lr D ixfhda.h idohs' D ixfhda.h uOHidÍh
KOH iuÕ m%;sl%shd l< úg oaú;aj nkaOkhla iys; E M,h ,ndfohs'
(ii) A, B, C, D iy E ys jHqy wod< fldgq ;=< w¢kak'

A B

C D

- Chemistry - -07- Osman Jayasinghe

 fï ;Srfha
F ixfhda.h A ys jhqy iudjhúlhla fõ' F ixfhda.h jeämqr PCl5 iuÕ m%;sl%shd lr lsisjla
fkd ,shkak
fuh
idfmaCI wKql ialkaOh 155 la jQ G ixfhda.h ,ndfohs' F ixfhda.h c,Sh Na2CO3 iuÕ mÍCIljreka
i|yd muKs'
CO2 uqla; fkdlrhs' F ixfhda.h m%ldY iudjhúl;djh fmkajhs' F ixfhda.h idkaø HCl/
ks¾c,Sh ZnCl2 iuÕ msßhï l< úg wdú,;djla ,nd fkdfohs' 2,4-vhsyhsfv%d*Skhs,ayhsv%iSka
(2,4-DNP) iuÕ F ixfhda.h j¾Kj;a wjlafIamhla ,ndfok w;r wefudakSh AgNO3 iuÕ
ߧ levm;la ,ndfohs'
(iii) F ixfhda.fha mj;sk l%shdldÍ ldKav ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) F iy G ys jHqy wod< fldgq ;=< w¢kak'
F G

^,l=Kq 68&

(b) (i) weisfgdaka ;kql c,Sh NaOH iuÕ m%;sl%shd l< úg iEfok H M,fha jHqyh wod< fldgqj
;=< w¢kak'
(ii) H yhsfv%dlaf,daÍla wï,h iuÕ tla l< úg iEfok I M,fha jHqyh wod< fldgqj ;=<
w¢kak'
H I

^,l=Kq 12&

(c) (I) weisfgdaka iy HCN w;r isÿ jk m%;sl%shdfõ § iEfok J M,fha jHqyh wod< fldgqj ;=<
w¢kak'
J

(II) by; m%;sl%shdfjys hdka;%Kh ,shkak'

100

^,l=Kq 20&

- Chemistry - -08- Osman Jayasinghe