BANNARI AMMAN VIDYA NIKETAN MATRIC HR SEC SCHOOL ,

ALATHUKOMBAI.
SECOND HALF PORTION TEST

Class : XII Marks : 150

Subject : Chemistry Time : 3 hr
PART – I
Choose the Correct Answer 16 × 1= 16
27 30
1. Which one of the following particles is used to bombard 13Al to give 15P and a neutron?
a) α particle b) deuteron c) proton d) neutron
2. The reaction 5B8 → 4Be8 takes place due to
a) αdecay b) βdecay c) electron capture d) positron decay
3. Nuclear fusion reaction is the principle of
a) Radio Carbon Dating b) Atom Bomb.
c) Hydrogen Bomb d) both b and c.
4. Which of the following is used as moderator in the nuclear reactor?
a) Heavy Water b) Deuterium c) Some compound of uranium d) Cadmium
235 139 94
5. 92U nucleus disintegrates into 54Xe , 38Sr and x. What will be the product x?
a) 3 neutrons b) 2 neutrons c) αparticle d) βparticle
6. An example of a chelating ligand is ________
a) NO2 b) Chloro c) Bromo d) ethylene diamine
7. The co-ordination Number of Copper in [Cu (en)2] SO4 is ______
a) 2 b) 4 c) 5 d) 0
8. When sodium acetate is added to acetic acid the degree of Ionization of acetic acid _________
a) Decreases b) increases c) becomes zero d) does not change
9. For the titration between HCl and Na2 CO3, the indicator used is________
a) Potassium permanganate b) phenolphthalein c) litmus d) methyl orange
10. The PH of a solution containing 0.001 M HCl solutions is _____________
a) 3 b) 4 c) 6.5 d) 5.6
11. The t1/2 of a particular decay is 69.32 years. The decay constant is
a) 0 per year b) 10 per year c) 0.01 per year d) 0.1 per year
12. 79Au198 is used in curing
a) Kidney scan b) Cancer c) Anemia d) Blood clot
13. 12. In photosynthesis, oxygen present in glucose comes from
a) CO2 b) H2O c) Oxygen and air d) SO2
14. . If 25 % of a radioactive element is left after 40 days, then its half life period is
a) 4 days b) 10 days c) 20 days d) 80 days
15. After 24 hours, 0.125g of the initial quantity 1 g of a radioactive isotope is left out. The half life
period is
a) 24 hours b) 12 hours c) 8 hours d) cannot be determined
16. The oxidation number of nickel in the complex ion, [NiCl4]2- is
a) +1 b) -1 c) +2 d) -11 17.
Nitromethane condenses with acetaldehyde to give
a) nitro propane b) 1 - nitro - 2- propanol c) 2 - nitro - 1- propanol d) 3 - nitropropanol
18. Which among the following dissolves in NaOH?
a) CH3 NO2 b) (CH3)3 C – NO2 c) C6 H5 NO2 d) C6 H5 – O – N = O
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19’. Which of the following will not undergo diazotization
a) m – toluidine b) aniline c) p- amino phenol d) benzylamine
20. Nitrobenzene on electrolytic reduction in conc.sulphuric acid, the intermediate formed is
a) C6 H5 NH – NH C6 H5 b) C6 H5 NH OH c) C6 H5 N = N - C6 H5 d) C6 H5 HSO4
21.CCl3NO2 is used as ___________
a) soil sterilizing agent b) organ synthesis. c)good solvent. d)anti oxidant..
22. The Nitrogen compound used in the preparation of sulpha drug is _____________
a) methylamine b)Nitro methane c) aniline d) Nitrobenzene
23. The Nitrogen compound used in the preparation of sulpha drug is _____________
a) methylamine b)Nitro methane c) aniline d) Nitrobenzene 24.Which
one of the following is a secondary amine ?
(a) aniline (b) diphenyl amine (c) sec.butylamine (d) tert.butylam
25.Oxidation of aniline with acidified potassium dichromate gives
(a) p-benzo quinone (b) benzoic acid c) benzene.d) quinene26.When one coulomb of
electricity is passed through an electrolytic solution, the mass deposited on the electrode is
equal to ...............
(a) equivalent weight (b) molecular weight
(c) electrochemical equivalent (d) one gram
27.When pH of a solution is 4, the hydrogen ion concentration in moles litre-1 is .............
(a) 1 x 10-12 (b) 1 x 10-2 (c) 1 x 10-7 (d) 1 x 10-4
28.The geometry of [Cu(NH3)4]2+ complex ion
a) Linear b) Tetrahedral c) Square planar d) Angular
29. Which is not an anionic complex?
a) [Cu(NH3 )4]Cl2 b) K4 [Fe(CN)6] c) K3 [Fe(CN)6] d) [NiCl4]2-

30.The most penetrating radiations are ------------

a) alpha rays b) beta rays c) . gamma rays d) all are equally penetrating
Write Answers for any FIFTEEN of the following: 15X3 -45
PART-B
31. What is Q value of a nuclear reaction?
32. Explain the principle behind the Hydrogen bomb.
33. State two uses of radio carbon dating.
34. What is binding energy of Nucleus?
35. Define radio activity.
36. What is common ion effect? Give examples.
37. What is Buffer solution? Write the types of Buffer solution.
38. State Kohlrauch’s law
39. State Faraday’s First law.
40. Define equivalent conductance. Give the equation for it.
41. What is called Ostwald dilution law?
42. An aromatic primary Amine A with molecular formula C6H7N undergoes diazotisation to give B. B when
2
 treated hyithpo phosphorous acid give C. Identify A, B and C.
43. Organic compound A of molecular formula C2H5ON treated with Bromine and KOH gives B of molecular
formula CH5N. Identify A and B. .
44.What is Gabriel phthalimide synthesis
45. How is chloropicrin prepared?
46. What is called Mustard oil reaction? . What is Gabriel phthalimide synthesis ?
47. Complete the following nuclear reactions i) 42Mo96 (....., n) 43Tc97 ii) 19 K39 (p,d)--------

48. Calculate the average life of 79Au198 leaving t½ = 150 days.

49.Write note on carbylamine reaction. 50. Define spallation reaction. 51.Define PH .
PART – III
Write any (13 ) in detail: 65, QUESTION IS COMPULSORY PROBLEM
15×5 = 75
50. Differentiate chemical reactions from nuclear reactions.
51. What is nuclear fission? What are controlled and uncontrolled fission reactions? How can the energy
released in such reactions be used for practical purposes?
52. Explain Radiocarbon dating.
53. Explain co-ordination and ionization isomerism with suitable examples.
54. Give the uses of radio active isotopes in the determination of mechanism in chemical reaction
55. Write the postulates of Valence bond theory of Coordination compounds.
56. (Ni(CN)4)2- is diamagnetic whereas Ni(NH3) 4)2+ is paramagnetic explain.
57. Explain Henderson’s equation.
58.Derive the expression for Nernst Equation
59. What are the evidences in favour of Arrheniu’s theory? 60. Explain coordination and ionisation isomerism
with suitable examples.
53. Mention the type of hybridisation and magnetic property of the following complexes using VB theory
a) [FeF6]4 - b) [Fe(CN)6]4-
54. Explain Werner’s theory of co ordination compounds.
55. How chlorophyll is important in environmental chemistry? Mention its function.
56. Derive the expression for Ostwald dilution law.
57. Derive the Nernst equation.
58.Write IUPAC Conventions of the cell.
59. Describe the Daniel cell.
60.Write a note on the reduction of nitro benzene under different conditions.
61. Explain the mechanism of nitration of nitro benzene.
63. Distinguish between primary, secondary, tertiary amines.
64 How are the followimg compounds obtained from benzendiazonium chloride?
i) Phenol ii) Ester iii) P-hydroxy azo benzene iv) Chloro benzene

65 a) Find the pH of a buffer solution containing 0.20 mole per litre CH3COONa and 0.15 mole per litre

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 CH3COOH, Ka for acetic acid is 1.8 x 10-5 b)
Calculate the pH of 0.1 M CH3 COOH solution. Dissociation constant of acetic acid is 1.8 × 10-5
(OR)
c) Ionic conductances at infinite dilution of Al3+ and SO42- are 189 ohm-1 cm2 gm.equiv.-1 and
160 ohm-1 cm2gm.equiv.-1. Calculate equivalent and molar conductance of the electrolyte at infinite
dilution.

d) An electric current is passed through three cells in series containing respectively solutions of copper
sulphate, silver nitrate and potassium iodide. What weights of silver and iodine will be liberated
while 1.25 g of copper is being deposited ?

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