bDkimi.< 6i.Mdo) 4 106Mens © 7708 Suppose the reaction: 4. 28+ Aly Sep) A+R FAR slaw ‘Seep? AB + RV ABs tat See ao E e561 758 © 748 % 18 The ato ofa geet ee ay OF Gist) a Ge OPTIONS 5.5; R= 8.314 Wolk]. a 354im/s 50. Calclie the root memtsquare velocity of molecular chlorine ia rls at 20°C [Cl Saamis ¢.296avs 4. 262m/se. 2158 ‘The eatin NO>+CO + NO* COstaKe "2NO; + NO + NOs (Ki) = slow 4 NOs + CO — CO;-+NOs (ka)—fast (2) R= ks [NOa!” (0) 28x 10-4 Find the order of the renction.(a) Zero order (b) First Jace in two steps. Find the rate law. R= ka [NOs] [CO] (6) R=k [NOs] @) R= ki INO order (¢) Second order ‘The rate constant ofa reaction is k=3.. eae found to be 31.S0mLAni svaflion rte ofan unknown gas is moasured aid found 15 be 31 SOml a a Egan /min Which of the following is dhe unknown gas? effsion rate of Oz is found to be 30.50 ecules have the same root mean squate speed! as ntrogen moleailes have at 95%C? [= e.NOz ‘54. At what temperature will hydrogen mol hON'= 14.0] a. 440.0 B.220,0k c.44.0k 330% ¢.22.0k 5. Catunlme the molculor mese-of« gas whose denstyat 40°C anid 758 mmiig is 1.380 Kefa! [R= 008214L-atmvmol). a. T7Ssphnol b.26.78eMmo1 e, 35.7Og/mol d.44.63g/mol «. $355ehmol 556. The rte cosstant of aro-onderroastins nes the unit (4) 5" (9) mol L's! (o)1* mot s1(@) Lanob) ot urate equation, when the conéentition of reactnis is unity then the rate is eal to (2) specific rate constant (t) averape rate constant (c) instantaneous rate constant (4) None of the above 58. ee Sotesofeeactions, which s the rate determining steps? The simplestreactionb, Themin reaction involving the major? reactant. The slowest reaction The fastest reaction 59, ‘The eneray of activation for a reaction is 10SKJmol. Calculate the speeific rate for the reaction at 300K ifthe frequency factor is 25% 10° sec", R= 8.3140K-'mot" a, 1.3% 10%se0? b, 13.0x10%sec* 6.3.3 x 1D" seo! 33x 10%sec! 4 ofthe following is uniinolecular reaction? (a) 2HI— Ha la(b) NoOs —> NsOs + #8 On (©) Hatt Cla —~ 2HEL (A) RCI + a, Under identical experimental conditions the aCH: b.CO cNO ¢.CO: 50. Which Ch Pls 51. ‘The rate at which a substance react depends on its (a) stomic weight (b) equivalent Weight (c)moleealarweight (A)active Wat Volume will 1.216 of SO! gos occupy st 18°C and 755 ton? [O=16.0;S =320]..1.508L b.137IL eds ¢ O74. 04571, der the reaction in wk bs = 2 = smimonia is twice the rate of consumption of hydrogen ¢. The Fate oF 18 equal to the ‘constimption of n e: ic ia ie bi hi ‘ geil (9 the rate of consumption of hydrogen d. The rite of formation of ammonia is two-thirds the mts sity Of Ox} is 1.43; S I Cea coun ea STP. Determine the density of oxygen at 17°C and 800 torr. a 1.42e/L b L43g/l Ge Given that the activation energy of a reaction was determined to be Ose 4H 98.6K1/ mol at 35°C. What is the: in enthalpy. f thenacion giv fat sn 3 oases [REST Mct] x 8G! b OAK) © aL SAR @BIOKD wo tp foms of Unum foie UF, arson. One fom contains uranium of ight 238, andthe other of tomic weigh rat are the relative rates fusion oft 5 M098 996 semi lative rates of effusion ofthese tvo moleeales?a. 096g b.0981 £.0,996. <. L004 &, A sample of ammonia (NHs) gas is completely decom - mpl lecomposed to nitrogen and hydrogen gases over h 0 tot presantss $66 sang, calculate the partial premiere a ZU pale be aseene oe ay ee ig minklg ©. 433 mmHg. d, 5601 0 | When the concentration of reactant molecules is increased, the rate of reaction inGreases. 1 1 explanation ess he eetant \ roaseskint eer) Of fetes es eed Cece ae ee ee eee car - : ® et is first order, what would be the rate constant at t 1Ominutes a i 0 an ce sy a et te re ae re oe is 1Ominutes, at what temperature will it get there? R= 8314 Jk! mol’OPTIONA, es to (a) Flomogeneous catalytic reaction (B) ic reactions (d) All of the above ‘ letorogeneouis catalytic reactions (6) Aut caialyt a 16. Nica following processes isan example of heterogeneous catalysis (2) Contact piocess (b) | All of the above (d) None of the above own as (@) Auto catalysis 15, ‘the intermediate compound formation theory zenerally app! () Self catalysis (c) Inhibition Hiyceogenotion af vegetable oil {c) 11. The phenomenon of negative catalysis is also kn Enzytne catalysis 18, ane isa substance which (a) Lowers the kinetic energy of reactants (b)Lowers ee ae 4 uw : energy of ection (€) bance th as ofthe catalyst (d) Eanes the ganostaon of i SO 19. Which tre ina Meta sate of fine subdivision are more efficent alts than etal in amps (>) Catalytic poisoning occurs due to blockage of fee valence bonds on the surface (c) Al promoter increas the valence bond on the catalyst surface by changing the crystal lattice (4) All of the above ‘A catalyst; (a) Changes the tree energy of a reaction () Is included in the balanced CSxn + 2FbSi0 . ase wr? s ae St tloot!sce and at 625°C the rate constant is 641 mot" sec, Calculate the activation | (e540 the mate constant Fe this reaction is 1-Timo'see and $ . 154.61/mol . 15.46J/mol | ae. Pie aoa 308K ad TL ialculate the energy of setivation of (Ea) forthe reaction a. 14.42 Jano! d. (©. The selgeity constant fora ertain reaction 5.25 x 10° at 303K and 11,1 x 10° at 314K. Cs 7. the reaction. a 43.84KJ/mol_ b, $3.84KiVmol 6, 63.84KV/mol 4. 73.84K mol | Which of the following represents Arrhenius equation for yariation of rate constant with temperature? ae Wink=22+C IMllogk= y=2-% a Léllonly b.1@ Ml only ce. U& I only d.Alfofthe abbye | 4 ‘The speed of a chemical reactioa _(a) is constant no matter what the temperature is. (b) is independent of the amount of ~~ "contact surface of a solid involved.(c) between gases should in all cases be extremely rapid because the average kinetic energy. | of the molecules is great. ( between ions in aqueous solution is extremely rapid because there are no bonds that need to be i j | broken, aA Using the van der Waal's equation, calculate the pressure exerted by 4.37 mol of molecular chlorine confined in a volume of 51. at 38°C [constants “a” = 6.49atm-L/mol and “b”= 0.0562 Limol].a. 15.0.atm b. 22.8 atm cane atm d.45.Satm e, ats lew for acid hydrolysis fan ester such as CsCOOCiHs in aqueous solution? (a) k [CHCOOGH. (b) k_ are con amen fe sulate the ntmber of collisions per sec in ImL of methane gas at 0*C and 0. atm pressure {Assume the collision diameter to ‘Femain constan)).a.9.87x10 b,8.79x10¥ c, 79810 J. 9.87x10% c. 8.79x10 tant, the order of the reaction is (a) zero ‘onder (b) first order (¢)second 4 ent aiculate the average veto: of nite bisa ¢ 67a d.731nvs ¢. 77 1aVs | When the rate of the reaction is equal to the rate const order (4) third order. =. The pressire in a vessel that contained pure oxygen dropped from 2000 torr 0 1500 torr in 5Smin as the oxygen leaked through a small hole in vacuum, When.the same vessel was filled with another gas, the pressure dropped from 2000 to 1500 tor in 85min, Caleulate the molecular weight of the sevond gas. a 380s/mol b.S7.0g/mol c.67.0g/ol d.71.5g/mol ©. 760g/mol ‘The inversion of cane sugar is represented by CiHnOn + HO — CiHi:O6 + CaBliz0¢ 6 Itisareaction of (@ First onder (b) second order (6) tht order (4) zero order k (CLC+. CHO) (NO) IF The rate of reaction CISC CHO + NO + CHCh + NO+CO js given by equation Rate jcgncentration is expressed in moles/ltre, the units of k are (a) Litre? mole sec! (b) mole litre sec™* (c) mole litre! sec (d) molelitre sec! - I a ch of the following rate laws has an overall order of 0.5 for reaction involving substances X,Y, and Z? (a) Rate — Kk (Ca) (Co) (b) Rate =k (Ca) (C,) €5 (C,) 95 (6) Rate =k (Cx) yy" (Cay (a) Rate k= (Co (CC? o% a isthe rate of reaction and order of a reaction. If the mechanism is 2NO + Ho-> No+ HO2 H202+ H2-> 2H20 sermon pea bial 3 (&) K NO} [i 3 we Fast (NOR DL,3. @ KINO}3 - AAUNIVERSITY OF BENIN, BEND CITY, NIGERIA FACULTY OF PHYSICAU SCIENCES ISTRY DEPARTMENT OF CHE X AMINATION 2022/2023 — DEC. 2023 FIRST SEMESTER B Se (HONS) DEGR ‘CHM 213 - PHYSICAL CHEMISTRY I (3 CREDITS) Time Allowed: 2hrs INSTRUCTION: Ansvier ALL questions i f calculate how much afit 6 ofa substance decomposes in frst 10 minutes in a fist omer reaction, a eeciaes 2 (2) 25.50% (4) 40% remain decomposed after one hour? (a) 37. 75%\(b) 85 . Frnt hong aclu al teens ¢t Sol? GU wpe hag am : able to control a reaction (iii) To be able to establish te mechanism by: which a teaction oecurs (iv) To be tupredict die tate o! a reaction (a) i, in & ii (b) iy H&E IV Ce) RE iv @) 1, i, ihe iv hie othe feeling toms doses «roves: nf Ne bet os els as feet {determining step (c) Elementary process. (d) activated complex?’ (a) Reaction mechanism (b) Rate Unimolecular | 4, Based on the collision model, the atoms at the top of the potential energy “hill” are called; (e) Top of the | hull (b) Activation energy (c) Transition state (4) Stee factor 5. ‘Ageording to chemical kinetic theory.a reaction ean geour (a) Ifthe reactant colle wit proper | octerarion 7 trary eocran: pomess sutton: epergyof collision (e)iCthe Feactants are able t9 font, ‘ofreet transition sate (4) All ofthe above 6 Why Sa minimum energy needed for an effective colision’ (a) Energy is needed to break the bond (b) ‘Energy nevdeto orient the particles corretly () 4 minimum energy is nosded, so tat he particles wil collide many times per second (a) Enough energy is feeded to give off heat in a reaction *- peeps that are formed in one step of reaction mechanism and used up in another step are called () Catalyst (b) Inhibitors (e Intermediates (d) Activation complex. 5A colt wil affect he rate ofthe forward reaction iy changing the(@) Activation eacrgy() Freeney (OFiihatps Gd) Emropy acy Feeds fo overcome fora reaction to occ is called: (a) Activation energy () Energy of vaporaation (¢) Specific heat (8) Potential encigy 1 cee mie of thumb, many reaction deuble is Spe4dfr a 10's ineeace i atroom tempera {aking the nwo temperature o-be 20° and 30%, the advation energy for such fractions would be @ 14K Jmol (6)0.35K Lol (c)6.12K Jmol" (d) 51K ol! 1 Areactca request presence of «strip of metal in he reaction vessel when the reactants are gases, This Hearope he. iM Pe otal) Egiliorias ) Thermodynamic (o) Homogeneous @ Heterogenedus, el 15, ‘Wale pfthe following proceses doesnot involve te se of catalyst (6) Contact, © use oF av prncess (6) Haber roots (c)Onvald process (4) Themmte poveay | Hb CHROME Povsoning (A reduces the asivy ofthe caf (6) Reduces the reaction Fad ofthe reetion (lnerenses the acivaion energy of he reaction (@)incfeases the teniperatre of the reaction35. a 36. 37. 38. 29, i 42. 43. a, 45. - ——-OPTIONE she average rat and instantaneous ae of reaction ae equa @) af hestat (Oat theend CO) inthe mide (4) when two rates have atime interval equal to 22r0 y What isthe energy of actvation of rection whose actin rate at.27 gets double for 10°C rise i temperature [R= 8.3140K: aoe es askinol b 238.98KJimol . 5.36KI/mol d. 53.598KI/mol : aii Cae ind the rate of the reaction when [A] =0.5 rea = rate law is found to be Rek{AY'EB]'”. Fi = weenie: 0 aio 2 Limo)? s!(b) 58%102 (Limot)'@s" () 5. 748x107 (Limo? s* (8) M, [B] = 0.1 M end k-0.03 ae Bee ofoxygen i conned in 10.5. of oxygen mearured over water at 25°C and M40 ort IVP. of H.0 at 25°C is roto R= OAeaiL-omminotk; O=16.010.685¢ 0.9.2ig «1290 d 18s © 25.808 wey i Ten lige, oftydrogen under 1:Gaim prossre is contained in a ylinder which has amoveab'e PS ‘The piston is moved in Panes oe eyancr of gas oceuples 401 atthe same temperature. Celrulate the pressure inthe cytinder, 18.0atm bi 270atm 0. 36.0aim d.45.0atm e. 54.Catm ronncactin: 2A + 8 —» Products the active mass of Bip kept constant and that of Ais doubled. The rate of reaction will thea {o)increase tro times (b)inrease four times () decrease two times, (2) desrease four Himes “Theat of prtcaar reaction becomes three times when th tenypertute is inereased from 298K to 308K. Caleulate the energy Gfaciivation a 838Ki/mol b838KJ/mol ¢. 83.85KW/mol _d. None of theabove Forasccand-rder reaction, what ithe unit ofthe rate ofthe reaction? (a)s* (b) mol L's" (¢) mot"L s* (amok? 12s ‘The rie of eflusion ofa particular gas was measured to be 24.0mL-nin. Under the same conditions the rate of effusion of pure notions gas CH, 147.8 mlstuin, Calculate the molar mass of the unknown gas. a 37.6g/mol_ b.47.8g/mol_¢.50.7g/mol 63.7a/mol ©. 76.3e/mol Forte first order decomposition of NOs, the rate constant is 0.545minr' IF the initial concentration of N.Os is 1.20. mol der?, « 9, (@)4.14 min (b) 3.18 min (€)3.18mar' (@) none calculate the time required for the concentration to drop to 0.49 mol dn A certain amount of gas at 25*C and a pressure of 0.800atm is contained in. a glass vessel, Suppose that the vessel can withstand a pressure of 2.00atmn, How high can you increase the temperature of the gas without bursting the vessel? a 247°C b. 427°C CAC A TAC 6.142 ‘Calealate the kinetic energy (in kilojoules) of amole of CO; at 177°C [Boltzmann constant _k =| 381x107 4M. ja-281 kimoly = | b.468kimot! ¢ S.6f kimot" d. 8.43 Knol e-thg2kimot! ¢— iy K ina rate law expression fora first order reaction a. 1s independent of concentration. Is called the Arshentus ‘constant c. Is dimensionless d, Js independent of the temperature ‘The rate constant of a reaction is 1.2 x 10°sec “' at 303K. Caleulate the rate constant at 313K if the: activation energy for the yeaction is $4.12KJmot! a. 2.31x10' sec! b.2 31x10? sect ¢.2.31x10% see d.23.1x10? sec? All the under listed equation is an expression of Arrhenius equation except 1K=Ae*** ii logk = Tet sag 88M UNE a re 4. [only b.1& Ul only. c. Allof the above d, None of the above ‘The racemization of pinene is a first oder reaction. In the gas phase, the specific rate constant was found to be 2.2 x 10° min“! at 487,5°K and 3.07 x 10° at 510.1°K. From these data estimate the energy of activation, 2. 43.64Kcalmol" b. 53.64 Kealmot " ¢,63.64 Kealmol? d. 73.64 Kealmor" FFor the first order reactions, the rate constant K, has the unit? a.- mat! ‘A gas evolved during the fermentation of glucose has a volume of 0.78L when measured at 20.1°C and 1,00atm. Calculate the ‘yolume of the gas atthe fermentation fomperature of 36.5%C and 1.0Datm pressure.a.0.28L b.0.82L c.280L d $.20L ©. 28.00L ‘Suppose the rexction 2NO2 +P; —» 2NOsP occur by the mechanism: (i) NO» +Fs—rNO3F + F slow step (I) NO:+F,—>NOoF —_ faststep Overall reaction 2NOz + Fs—+ 2NOF “The rate law expression, moteoularity and order of the reaction musi be Rate = “sand (@) k{AJ, 2 and 3 (b) K{NO;} 2, & 3 (©) KINOsIL Fil $20) KINO2][FF3 & 2. {A suitable equation of state for real gases at high temperature and pressure which allows for the Si molecules by a volume factor, b, is a. PV=RP+bT b.PV=RT+bp GPV=RT—b GevoRT tbe PY = ORT b. time’ ¢. (molfy" time d. time molOPTION B One gram-atomic weight of silver was heated from 1O0"C to S0'C a constant pressure. The eat eapacity of the metal at constant pressure was 2: 46ldeg'mol" and constant over the Temperature range, Calculate the entropy change of the metal.) 2,562 Jdeg’!mol" (b) 2.671 ‘deg "mot" (c) 25.62 Jdeg 'mot" (A) 26.71 ‘Ideg’!mol ; . Themolarheat capacity of gaseous oxygen at constant pressure is given by (25.4788 + 13.5988 x 107 T> 42,5148 x 10 t will be the increase in its entropy when the ‘T?) Jdeg'mol. What ter feof one mole of the gas is raised from 25°C to 600°C ? (a) 37.47 Jdeg"'mo!" (b) 65.08 ‘dew mot" (¢) 33.74 Jdeg'!mol (d) 35.24 Sdeg 'mot? {s automatically for enthalpy and entropy both? .. Which thermodynamic function account {@ Helmholtz Free Energy (A) (b) Internal Energy (E)(€) Work Function (@) Gibbs Free Energy. Based on the first law of thermodynamics, which one of the follo (a) For an isothermal process, q = + w (b) For an isochoric process, ywing is correct? AE =-q (c) (c) For an adiabatic process, AE =- w (d) For a cyclic process, q =~ W snstant pressure equivalent to the internal energy plus (a) Entropy (b) Enthalpy (c) Spontaneous |. The total heat content of a system at co the pressure volume energy is known as process (d) isothermal condition.ADRENALINE TUTORIAL EMPIRE OPTION B 29, The first law of thermodynami (a) the total energy of an isolated system remains constant though it may change from one form to another (b) total energy of a system and surroundings remains constant (¢) whenever cocrey ‘of one type disappears, equivalent amount of another type is produced (4) all of the ve. 30, When the total energy in an isothermal cycle is zero, it represen {@) a reversible cycle (b) an adiabatic change (c) a thermodynamic equilibrium (8) an irreversible cycle. 51, ‘The enthalpy change (AH) forthe transition of liquid water to steam is 40.8kImol! at 100°C. Calculate AS* for the process. (a) 9.142 x 103Jmol'K* (b) 108.393 Jmol"K" (c) 109.383 Jmol''K* ‘ ett Me) (@ None of these, Rif 2 Seed 42. Calculate the entropy change when 36g of liquid water evaporates at 373K. [Latent heat of ‘Vaporization of water is 40.63kImol"]. a3 weet (a) 2180K" (b) 215.85 JK (c) 217.85 JK" (@) 33. 1g of water at 373 K is converted into steam at 214.57 aK! iB ‘the same “becomes 1671 ml on boiling, Calculate the change in the ergy toand system (c) am open system (d) a homogenious system. ‘spontaneous reaction? (a) AS(system) — AS(surroundings) >0 0 (6 toning) > Daly (0) AS123 — DEC. 2023 N= . INSTRUCTION: Agswer ALL questions. ‘Time Allowed: hr 1, IF15%@ oF @ substance decemposes in first 10 mimes ita frst order reaction, celeuate how mush of i f ‘would remain decomposed after one tour? (a) 3) 85% (c) 25.50% (2), 40% 2 Which of the following includes all theiaims ofkinetic{? () To measure the rate of a reaction i) To be sb to conerol's reBetion (I) TO able o establish ic mechanism by which a reaction occurs (iv) Tobe GRIC o pcdiee Wie Face Ol remethn (a) (i eid) iy & i PL BAW) i HBT ‘Whith ofthe fetlowing terms describes a proces in which two particles comes together to Forman _ectivated complex? (a) Reaction mechanism (b) Rate determining step (e) Elementary process (8) F unimolecular “4. Based on the collision model: the sioms atthe top ofthe potential energy “ hill &) Activation energy (c) Transition state (d) Ste factor are called: (9) Top ofthe Te Recotieg wo enemicaltinetic theory,» reation can oceur (a) Ifthe reactant eolide With Proper anon cab eins reseant poscese effete enerey SF Colson {I to orient the particles conreetly (e) \ minimom energy is needed, so thatthe particles witl i any times per second (@) Enough energy i needed to give ff heat mareaction = Species tat reformed in one step of reaction mechani and used up in another step argc « Catalyst (6) Inhibitors (¢) Intermediates (4) Activation complex 4 {will affect the rate of the forward reaction by changing the (8) Activation energy (b) Free eneray (©) Fathalpy (2) Tasropy 9. The energy rieedéd to overcome for a reaction te cecur is called; (a) Activation energy (b) Bnergy of i vapotiaatiOn (e) Specific heat (4) Potential encrey. < As a good Tule of thumb, many reaction double in speed for « 10"e ineféase in" at oom tetnperature, ‘Taking the two temperature to be 20° and 30Pe, the activation energy for such reactions would be: @ 148K Jmol" (b)0.35K Lmol~! (¢)6, 2K" (4h) $1 Kool a A reaction sequires the presence ofa sirip of metal in the reaction vessel, when the reactants are gases This isan example of what type of catalysis (a) Equilbritis (b) ‘Thermodynamic (e) Homogeneavs (8) . Katalyst #4 substance which (a) Inerease the equilibrium copcentration ofthe prodsets (b) Changes the equillbriuin constant ofthe reaction (c) Supplies energy womtsteaetion (4) Shortens the time to reach the equilibrium Which of the following processes docs not involve the wse-of «catalyst (e) Contact process (B) Haber process (c) Ostwald process (d) Thermite process Catalytic poisoning (a) reduces the activity of the catalyst (b) Reduces the reaction rate ‘of the reaction (cyinereases the activation energy ofthe reaction (d)incteases the temperature ofOPTION D e change accompanying chemical 39, The part of physical chemistry that d ; m anu alled (4) Thermodynamics (b) ‘Thermochemistry (c) Chemical Kinetics (4) None of them 40, The dimension Kgm?s* represents? (a) Energy (b) Power (c) Force (d) Potential difference 41. The first law of thermodynamics can be expressed as? (a) AE = q + w (b) w= AE — 4 (c) AE q-w(@)q=-AaE-w 42. Thermodynamics as a discipline deals with energy (a) Conversation (b) Generation (c) Storage (@) None of the above. 43, Caleulate the heat of formation of butane for which the heat of combustion at 25°C is -687.98 Keal mol, Given that AHr of CO> is -94.05 Keal mot" and that of HO is — 68.317 Keal mol” | (a) 29.809 Keal. (b) 39.809 Keal. (c) — 29.809 Keal, (d) ~ 59.618 Keal. 4, Second law of thermodynamic gives the definition of _ (@) Pressure (b). Enthalpy (c). Entropy (d). Internal energy 45, What is the ratio of Cp/Cv for gas if the pressure of the gas is proportional to the cube of it temperature and the process is an adiabatic process? (@)2 (b) 3/2 (6) 4/3 (d) 5/3 ee aesi ten tins om ware hole H= baa7 <.561 4734 a8 | a 38.0g/mol aa © 760g/mol 4.1140 ence sou olesues 80g of ethene $0. Cajenlat rage Kinetic er cee 2494.20), 4.3741, ; 7... aa d. 764ms" «. ae velocity at 25°C for gaseous argon atoms. —— Jimotrk, Ar d. S1S,Smaj! S26 velocity of molecular chi ‘ Ealeutate the most 414 fmol) = 35:5] 4 262 ms ».296 : ee ewe * 2007 yl bo: ei <.0SeTHe 41104 ee Fweight of the compound. [R=0: $6. AA sree velocity, average velocity abe 112821224». 1128: 1s 1224 e128? Q ‘the viscosity of gascous Cli at stm pressure and 2095s diameter of the chlorine molecule, {Cl=35.5;R=83) S.16x10"m 6. L03x10"%m de 2. 1.0310 mb, 58, Calculate. the number of collisions per Loam, peste P alec,: i iene be cnet eites ob elfasion of Hs ant Cb gases through fine pin hole: (H < S3Ts RMIT t H1 A 754 748) Gy Doe peeamars ie veel that contained pure oxyE' m bydrapen leaked through i small hole into:s vac ‘Whien the same vessel was filled pressure dropped from 2000 torr to 1500 torr in 85 mai What is the molecular weight of 34. 0gimel b.67.0gimol <. 76.0p/mol 4.1144 @, 152,0g/miol “ dropped from 2000 torr to 1500 tom ‘calelate the avetape kinetic energy in Joules af the molecules in 80g of methane a 4}. 12479 07 b. 1870.65) ©, 2494.20) tage ©. 4988.40) tr 51. Calculate the foot-mean-square velocity of exygen molecules at 16°C: [R = 8.314 ms" b.476ms! ©. 647ms* d.764ms* ©. 952ms" Caloulate the average velocity at 25°C for gaseous stom, (R= 8.314 Hol A= A b,431.5ms! 6, 498.6ms" d. 515.5ms! ©. 63261 ‘Caleulate the most probable velocity of molecular [R=8314 HmelK{C)-355] a.262m/s.b.296 |. Cale the density of ammonie gas (in gratis per 56, The ratio of most probable velocity, average velocity and 142821224 11285151224 6 1.128 GD ‘he viscosity of gascous Ch at Latm pressure and 21 diameter of the chiorine motecule, (C1 =35.5, R= 8. 4. 1.03x10"m °b. S:16x1o#m ¢, LoSKI0"%m 4. 58. Caleilete the number of collisions per second 1.fatm. [Nx =6 02x10” molecules/male, R= 0.0821) 4.180810”. 2.06x10 ¢, 1.110% 4.160% 5 “Using the.yan der Weals equation, caleulate the p at 47AC. [9 = 3.59 Peatm/mol and “b= 0.0427 0 atm bum = 408m 4208, ‘60, At whet temperature have at 359C? (H=1eae TN ae y y ITY, NIGERIA UNIVERSITY OF BENIN, BENIN CITY, FACULTY OF PHYSICAL SCIENCES DEPARTMENT OF CHEMISTRY SESSION FIRST SEMESTER B.Sc. (HONS) DEGREE EXAMINATION 2020/2021 NOVEMBER, 2021 “CHM 213 - PHYSICAL CHEMISTRY (3 CREDITS) ime é sd: 2hrs 15mins INSTRUCTION: Answer ALL questions. Time allowe GIVEN CONSTANTS | R = 8314 Jmol.k; R-=0.0821 Liatm/mol. KR = 8.314 kg. ar/s' kod Na = 602x10® moleeulesimol STP, taum = 101,300 Nm? Molar Volume of a gas at STF ~ 22,400 cm? (22.4.L) Boltamann’s constant, k= 1981x102 Je V= 14.0; O= 16.0; $=320; C1=35.53 Br = 80.0 Atomic Mantes: H | Use the following information to answer questions (1) and (2) : ; s [Ths docnaty of methane at 20°C and latm pressure is 1.09x10* poise; molar volume of gas is 22,400cm’; 83 ix ergs deg’’mole'; Nx = 6.02x10" molecules mol] ‘Calculate the mean free patly of methane at 20°C and Jatm pressure, a.394xt0%em b,7.88x10%m ¢.3.94x10%cm 4. T8RK1O%em e. 1.S8K104em ine the mean collision diameter of methane at 20°C and |atm pressure 88x107em b. 6.75x10"em ¢ 3.88xI0%em a. 5.07K10%em ©. 6.76x10%em 1 CK) fox the reaction —ANOup + Ongp Were determined = een See ie ane ® E ,32,98x10" c. 2.2x104 d, 2298x104 ’ : 4 ed as follows: sy a a mm the kinetic theory, the expression for the ideal gas pressure is déri nm? nme’ L nate Ds nme? ee <—dynesomr? \¢. P= Be Pe aneser scala ia 2 Br pe dae Orne = Taq nese” b. P= Coxygen and 0,08mole of nitrogen are placed in a vessel of Volume 14cm? at 11 0%C, What is the pressure of the mixt tm = 101, 300Nm*) a, 5.095x10°Nm b. 4.076x10°Nnv? c. 3.057x10°Nim? d. 2,038x10¢Nim? ¢. 1.019x10°Nm? ongentration plot is linear for a first order equation’ (A is one of the reactants) a, [A] versus time b, Square roc wstiime ¢ InA versus time {AF versus time 4 Tina) Celsius temperature required to change 10,0L of helium at 100k and 0.150 atm 10 30,01 at 200.atm. a. 40 BIPC 4.2840 6, 127°C ch of the following observations is incorrect about the order of a reaction? (Order of a reaction is always a whole numb Stoichiometric coefficient ofthe reaciauls doesn’t affect the order (¢) Order of reaction isthe sum of power to express Of reaction fo the concentration terms of the reactants (4) order can only be assessed experimentally comrect order indicated against the rate of reaction A+B —+-» ig @ Bewa o-B=raie) @- “4 =iaye) 2 qa). constant for a reaction at 20°C is half of the rate constant at 30°C. Caleulate the energy of activation of the reaction, tmol-'] a. 122.28Kcal/mol />,.1222.28Keal/mol 12.23Kealimol d. 1.22Keal/mol n 2A +B — 2C, with the rate equation: Ri [AFB] (a) the order with respect to A is | and the: order overall ex with respect 0 A ig 2 and the order overall is 2(¢) the onder wilh respect to A is 2 and the order overall ic 3, Vill respect to B is 2 and the order overall is 2 ee all a t4 i oe | |15, ‘The intermediate compound formation theory generally applies to (a) Homogeneous catatic reaction (b) Heterogencous catalytic reactions. (e) Aut catalytic reactions (¢) All ofthe aboye 16. Which of the following processes isan eximple of heterogeneous catalysis (a) Contact pfosess (b) Hydrogenation of vegetable All of the above (d) None of the above 17. The phenomenon of negati lysis is also known as (2) Auto catalysis (b) Selfcatalysis (c) Inhibition (a) Enzyme catalysis ii 18 A promoter ica substance which (a) Lowers the kinetic energy of reactants (owuowers Me activation energy of reaction (c) Enhances the astivity pf the catalyst (d) Enhances the. jon of the catalyst 19, Which is true (a)ivia Metal state offine subsdivision are more efficient catalysts than Fel iosscos Catalytic poisoning occurs due to blockage af free valence bonds on the surface (c) Aipromoter increase the Valence bond on the catalyst surface by changing the crystal lattice (d) All of the above 20. A catalyst; (a) Changes the free energy of a seaction (b) Is included in the balanced chemical equation for « reaction (¢) Changes the mechanism for a reaction (8) Slows down the rate ofa reaction all of these i emt A 21, Reaction rates can change with (a) Temperatire (b) the addition oF a catalyst ((¢) reactant concentrations (4) - 22) Reaction rates generally(a) Are constant throughout a reddtion\(b) Are smallest at the beginning and increase with time (c) Are greatest a the beginning of reaction and decrease with tiie (4) No such generalizations can be made } P 23. Consider the reaction, in which nitric oxide is oxidized to nitrogen dioxide, ; INO 4+ Oxy +t INOW» for which the rate"law i$ =k [NO]: [Os]. IFthis reaction takes place ina sealed vessel and the partial pressure of nitric oxide if doubled, what effect would this have om the rate of reaction?(a) The reaction rate would triple (b) [he reaction rate would double(e) The reaetion rate would ‘quadruple (@) there would be no effect on the reaction rate, ea 24, Which three factors affect the rate of a chemica Te re rent (@) Temperature, ‘concentration and container volume 25, For first-order reactions the rate constant, k, has the: unit(s) (a) |mol time mol |" 26, What are the units of the rate constant for aresetion in so (M is molarity, sis seconds. (a)Mta71 ()M1(c) 8" (@) Ms 27. The action A» B isa second-order process) When the Ini concentration ofA is 0.50 M, the halflife sa go minutes Whats the halite ifthe iat concentration of Ais 0.10 M7) 1.6 minutes (6) 8.0 minutes (©) 40.0 minutes (d) 16.0 minutes [ 28. ‘The quantity k in arate law expression(a) i independent of concentration (0) is called the Arrhenius "constant (c) Is dimensionless (d) is independent ofthe temperaturs — : 59 The first-order rte constant forthe decomposition of NsOs NOs aid.Oa at 70°C 18 682 »107s" Suppose we start with 0.300 mol of N2Osip in a 0.500.1. container. How many moles of NzOs will remain after 1.5 min? (a) 0,081 mol (b) 0.555 mol (¢) 0.325 mol (c) 0.162 ‘mol 40, As the temperature of a teaction is increased, the rate of the reaction increases beeanse the(a) Reactant molecules collide with greater energy. collide less frequently and with greeter energy (d) Activation energy is lowered 31. Ina series of reactions, Which is theFate-determining step?(a) The simplest reaction (oy The involving the major reactant(c) The slowest reaction (te fastest 6 alts 32. Beaker A contains a | gram piece of 2ing'aind beaker B contains ‘gram of powderec zine. If 1 0 of 0. M HCl is added to each of the ‘beakers, of reaction in beaker B2(a) The rate in A is greater Aisne sot grat are nope (©) Te 89 a = I a ution that has an overall reaction order of two? (b) Reactant moteeules collide less frequently (c) Reactant moleculesOPTION B 14. A thermos flask is an example of (a) isolated system (b) closed system (c) open system (d) heterogeneous system. 15. A closed system is one which cannot transfer matter but transfer ___ to and fro its surrounding (a) heat (b) radiation (c) work (d) all of these. 16. Bomb calorimeter measures? (a) AH. (b) AHr (c) AHu (4) Hm 17. The standard heat of combustion of liquid butanol is —472.40 keal at 25°C. Calculate its heat ‘of formation from the elements in their standard states at this temperature. (AH for CO2= _ 94,05 keal, H2O = - 68.32 kcal). (a) — 245.4 keal (b) — 245.4 cal (c) 245.4 kcal (d) 490.8 kcal. 18. The aspect of Chemistry that deals with the heat changes in chemical reactions is called? (a) Thermodynamics (b) Entropy (c) Chemicat kinetics (d) Thermochemistry (c) Electrochemistry, 19, If heat is evolved in a reaction, the reaction is called? (a) Spontaneous (b) Reversible (c) Endothermic (d) Exothermic (e) Enthalpy. 20, calculate the enthalpy of formation of Ca(OH)aq) from the following data (a) — 235.4 klcal (b) 235.4 keal (c) 470.8 keal (d) - 470.8 keal.— 21. Determine OH for the reaction CzHs+He Ni _CoHe Given that the bond enthalpies forOPTION D ADRENALINE TUTORIAL EMPIRE BSC, MSC AND PHD (CHM 223 ~ Physical Chemistry 11 (Chemicat tnermouynamresy Second Semester B.Sc. (HONS) Degree Examination ~ September 2023. ime Allowed: 2 hours. INSTRUCTIONS: 1, Shade the option of your paper on your OMR sheet 2. Indicate your Matriculation Number and Department clearly 3. Use the specified pencil 4, Attempt all questions: 1. Calculate AS when 28 g of N2 gas expands reversibly (@) 29.483 JK"! (B) 24.834 JK () 38.294 JK (d) 39.392 JK ym 2 Litres to 20 litres at 2. ‘The standard heat of formation of liquid water is -68.3 Keal at 20°C. Calculate the value at 95°C. The molar heat capacities at constant pressure in the given temperature range of H2 ip, O2 ) are 6,89, 6.97 and 18.0 Cal deg’ mot respectively. (a) 135.4 Keal (b) -67.7 Keal (d) 67.7 Keal 3. Which of the following Thermodynamic quantity is not Fundamental? (a) Mole (b) Mt (e)Time (d) Density 4, Which of the following processes is used to do maximum work done on the ideal gas that is compressed to half of its initial volume? (a) Isothermal (b), isochoric (c) isubarie (d)OPTION D 26. The entropy of a pure erystal is zero olute-zero. This is statement of (a) first law of thermodynamics (b) second law of thermodynamics (c) third law of thermodynamics (d) none of 1 2 ing process, is a maximum incre: {a) Dissolution of (b) Condensation of Water (c) (a) Melting of lee 2. Calculate the minimum work which must be done to compress 16g of oxygen at 300k from a vessure of | aim. 0.@ pressure of 100 atm. (R= 8.314 KJdeg"!mol!; O=16).(a) 10.74 KS (b) 5740 pm ‘J (e) 15.74 KI (a) 20740 29, Which of the following about an adiabatic proces (a) pav =-C.dT (d) none of the above is wrong? (a) dq = 0 (b) AE =-W 30, The enthalpy change for the reaction, AbClis) + GNa = 2Aly + 6NaCle is -300.0 Keal, The culate the heat of formation of solid AlzCls. hat of formation of solid NaCl is -98.2 Keal. C: (@) 332.4 Keal (@)-289.2 Keal (b) -332.4 Keal (c) 289.2ge Pe OPTION A i pl 33-'The decomposition of ethylene oxide'at 652 K (CH)30w > CHyy + CO ais first-order with K= 00120, a min “1. The activation energy of the rea kJ/mol: Caleulate the rate'constant ofthe reection at S98 KECa) TU» 16 Trin (5) 202 min (c) 8.7 « T° min! fd) 142 mint Here is second order reaction A+ P. Ifthe initial concentration of A 0.0818M goes down 30.0% in 3.15 minutes, what is the rate constant for the reaction? (aj 0.0078, moli='S (b) 1.71 mols“! (c) 9.1 Tmol"t s* " (4) 16 Timo} 51 a : , “3 (pprrteee??»-Eehaftstcorder reaction of the form A ifthe of A is 0.0013 M right now, hat is the best estimate ay ee of what it yesterday? (3) 0.0026 1 (BY'0.0065 M. pI ee 36. The rate law relates the rate of a chemical reaction tj (8)"The concentrations of reactants (b)the temperature (c) the activation energy (d) the y| mechanism, 37. Rate laws for chemical reactions are determined (a) By examining the coefficients in the balanced chemical ‘equation (b) From the equilibrium, constant (c) Fan the rates of the forward ani Teverse reactions of the system al equilibrium (4) By experiment =» - 2 38, Fora \ ‘a.graph of [A] versns time is found to be a straight line, What is the order ofthis reaction? ‘orden (b) first onder (6) second order (A) third onder “39. To study the rate of 2 reation, itis necessary to (a) Identify the reactants (b) Know the relative amounts of (0 ie reaction (d) All of the above are necessary lly as the temperature rises? 40. Why do most chemical reaction rates increase rap (a) The traction of the molecules with Kinetic energy greater than the activation energy increases rapidly with temperature (b) The average kinetic energy increases as temperature rises (c) The astivation energy ior (More ons ake place between particles so thatthe reaction can 18 1.00g Hs gas at 27.0°C is: $4 2.00% Vessel comaining 88.0g CO2 gas, also. the total pressure (in atni) when the gases are completely mixed (R= 0,082] Leatrn/mol+k] 820 atm c, 16.40 atm. d. 20,50 atm). 32:8 am e 7 a‘fernperature of 18°C and pressare of 755 tor. (S =” BOSH7L ¢.0914L 4.1371 mL € 143L gad pressure is derived as follows: ‘cylinder conins 0.4g helium, 1.6g of oxygen and 1.4g of nitrogen at ((328atm—c-OetShatm 4.0492 am _¢, 0.984 atm (0.421 moles of ethane and 0.116 moles of propane. If ial pressure of ethane. a. 0.0181 atm b. 0.0362 atm 46. Calculate the total pressure in a 10 titre IPC. [He = 40;0 = 16.0; N= 14.0] a. 0.246 arm 47. A sample of nataral ges contains 8.241 the total pressure ofthe gas is 1.37 atm, caloulate th ¢.0,0657 etm 4, 1.290atm ¢,0.1314atm- - \ es oomA P ~——- OPTION € ‘The average rate and instantaneous rate of a reaction are equal (2) atthe start (b) at the-end (c) in the middle (4) when two rate have @ time intorval equal to zero | What isthe energy of activation of a reaction whose reaction rate at 27°C gets doubled for 10°C rise in temperarure [R= 8.31418 ‘mot') a.535Ki/mol b, $35.98KY/mol c.536KU/mol d. $3.598KN/mol es it cadena dete ‘or a reaction A 1B — C, the experimental rate law is found to be R=k{A]'[B]'®. Find the rate of the reaction when [4] = {B] = 0.1 M and k=0.03. a) 4.74102 (Limol)"? 5-1() 5.3810? (L/mol)"@ 5 (¢) 5.748*107 (Limol)'? s+ (a) $6107 (L/mol)!? = | yw many grams of oxygen is contained in 10.5L of oxygen measured over water at 25°C and 740 torr [V.P. of H:O at 25°C i torr; R= 0.0821Latmimolk; O= 16.0) a.645¢ b.9.21g c.12.90g d I842g ©. 25.808 ; ‘ litces of hydrogen under 7.0atm pressure is contained in a eylinder which has a moveable piston, The piston is moved in the same mass of gas octupies 4.0L at the same temperature, Calculate the pressure in the cylinder. a. 18.0atm b. atm ©, 36.0atm d.45.0atm 6. $4.0atm nn a reaction: 2A + B —> Products, the active mass of B is kept constant and that of A is doubled. The rate of reaction will then two times (b) increase four times (c) docrease two times (d) decrease four times ‘ofa particular reaction becomes three times when the temperature is increased from 298K to 308K. Calculate the energ; ivation 2. 8.38KJ/mol . $38KJ/mol__¢. 83.85KI/mol _d. None of the above Lil Fore Nndorder reaction, what is the unit ofthe rte ofthe reaction? (a) s! (6) mol Ls (c) mot! L st @) mot? 12s! a The rate OF effusion of a particular gas was measured to be 24.0mL/min. Under the same conditions the rate of effusion of pun methane £6 OH, is 47.8 mL/min. Calculate the molar mass of the unknown gas. a. 37.6g/mol b.47.8g/mol c. 50.7g/mol i 63.7gmol "€. 76,3g/mol — Aa For the first order. decomposition of N2Os, the rate constant is 0.345minr". If the initial concentration of NOs is 1.20 mol dmx’, caleulat the tine required for the concentration to drop to 0.40 mol din*, (a) 4.14 min (b) 3.18 min (¢) 3.18min* (4) none A certain amount Of gas at 25°C and a pressure of 0.800atm is contained in a glass vessel. Suppose that the vessel can withstan; _— es gon ee can you increase the temperature of the gas without bursting the vessel? a. 247°C b. 427° ae te kineti nengy (in kilojoules) of a mole of COs at 177 (Boltzmann constant k= 1 384y30% We] 0.2.81 kia) doh eso Tel A. 8.43 kimot!—e. 11.22 kimol! ‘quantity K in arate law expression fora first order reaction a. Is independent of Concetta constant. Is dimensionless. Is independent of the temperature The rate constant of a reaction is 1.2 x 10sec“! at 303K. Calculate the rate constant at 313K if the activation energy for reaction is 44.12KJmol" a, 2.31x10" sec! b,2.31x107 see! ¢. 2.31K10" sec! d.23.1x10? sec? } ‘All the under listed equation is an expression of Arrhenius equation except = Ag RT c=, fa teen i ee Wlogh = sour tA Ul, asone as a. 1&Monly b.1& Ilonly c. Allofthe above d. None of the above | The racemization of pinene is a first order reaction. In the gas phase, the specific rate constant was found to be 2.2 x 10> min“) |, at 457.6°K and 3.07 x 10° at 510.1°K. From these data estimate the energy of activation. a. 43.64Kealmot! b, 53.64 Kealmot 4! © 63.64 Kealmot! d. 73.64 Kealmol! | For the first order reactions, the rate constant K, has the unit? a. mot! —b, time"! ¢. (mol/l timed. time mol! | A gas evolved during the fermentation of glucose has a volume of 0.78L when measured at 20.1°C and 1,00atm, Calculate the | volume of the gas at the fermentation temperature of 36.5°C and 1.00atm pressure, a. 0.28L b.0.82L ¢.280L d. 8.201 } © 28.00 £ Suppose the reaction 2NO2 + Fz —> 2NO.F occur by the mechanism: (i) NO2+F2—»NO:F + F — slow step. | ¥ (i) NO:+P:NOsF fast step el Overall reaction 2NO2+F:— 2NOF |: |The rate lay expression, molecalarity and order ofthe reaction mustbe Rate=___, A . f (@) k{A), 2 and 3 (b) KINO:} 2, & 3 (c)K[NOp]| F:],3&2(D)KINOJFIS&2 ° 4 suitable equation of state for real gases at high temperature and pressure which allows for the space occupied by the rrolecules by a volume factor, b, is aPV=RP+bT b,PY-RTibp c.PV-RT-b dPV=RT+b @PV=bRT4s 46, #2. | OPTION A i the deomposition of ethylene oxide at 652 K (CHL) sw —* CHa) + CO qs first-order with k= 0.0120 1. The activation energy of the reaction fs 21$ki/aol Calculate the rate eonstant ofthe reaction at Getad7 11 « 10%min 1h) 202 min! e) 8.7 « 14 min-\(d) —142 mint ‘ Here dg@second order reaction A— P. If the initial com .centration of A 0.0818M goss down 30.0% in oe . minutes, what is the rate constant for the reaction? (2) 0.6078 I mol “!s“! (b) 1.7 Lmols's“(€).9.{ Imol“"s a) 16 Emol i feist rer etion ofthe fom A ~»P, = Shouts: Ifthe concentration ofA 60.0013 M night now, hat is the best estimate of har it was the day before yesterday? (a) 0.0026 M (b) 0.0065 M (c) 0.0052 M. (40.08 Mt f 50, The rite ny relates the rate of a chemical reaction 10 (2) The concentrations of'renctants (b) te temperature (c) the activation energy (d) the reactioy mechanism ‘Rate laws for chemical reactions are determined (a) By examining the coefficients in the balanced chernical equation (6) From the equilibrium constant (¢) Fron the rates ofthe forward and reverse reactions of the 38 system at equilibria (d) By experiment 38. Fora reaction, A —> produets, a graph of [A] vers time is found to be straight line. What isthe order of thi reaction? (a) Zero order () ist order (¢)fecend order (3) third order 39, To study the rate of a reaction, itis necessary so (a) identify the reactants (b) Know the relative amounts of reactants wed (@) Know the overall chemical equafon fot the reaction (2) All of the abdve are necessary 40, Whiv do most chemical reaction rates increase rapifly as the temperature rises? {@) The iracton ofthe molecules with Kinetic enerfy greater than the activation energy inereases rapidly With temperature (b) The average kinetic energy irbreases as temperature rises (c) The astvation energy’ decreases as iemperature rises (d) Mere collisions lake place bebween particles so that te reaction can occur actly 10Umi. of oxygen is esected over watera23°C and 800 torr, Calelilate the siandard volume of the Sint (by 394ml. 46.) 94.SmL fa) 481 Bend (2) 188.0ML 4 dryloxygen. (WP. OF HO at 23°C A821 trrh (OAS: ‘A 100K. vessel coftsining 1.00 Hs as at27.0°C i eobnected to « 2,001 vessel containing 8.08 COs gas, also, at 27:09, Caleulte the coral pressure (in atm) when tip gases are completely mixed IR =0.0821 Leatm/mol] #4104 BAD a 6 160A 4 2050.m) «28 am oa 7 Calailate the yolunie occupied by 1.2168 of S02 gas tt.a temperature of 18°C and pressure of 755 torr. (S = 32050" 169;R=0081 Ledmfmolh}a04S7L HOSTL cODIL alamml. © LOL From the Kinetic theory, the expression for the ideal gas pressure is derived as follows: amc” 2 mmc* 2 ic aie at MO anc? pr 22 pen Pana \ nmv? | ir SE snccene | A suitable Squation of state for a real go at high sfmiperatues and pressures which allows for the space eupied ty Ae molecules by 2 volume factor, bis @ PV=bRT b.PV=R+b ©, PV=REd. PV=RE rope PY=RT—bp Calculate the folal pressure in a 10 Tite-cylinder conteins O-4z helium, 1 6g of oxygen and Lg of nitrogen at IC, [He= 40:0 - 160; N~14.0] a, 0.246'atm 6 O228atn c: 0.451 atm 0.492 atm €. 0.984 atm A sample of natural ges conttins 8.24 moles of methan}, 0.421 moles of ethane and 0.116 moles of propane. If the toa pressure of the gas is 1.37 atm, caleulat the ptel prosure of ethane, a, 0.0181 atm b.00362 atm ,0.0697 atm 4. 1,290-atm ¢.0.1314 atm Ss i ) yOPTION D sem that exchanges only energy with the surroundings is called” (a) Closed (b) Open (c) (d) Isolated Use the information below to answer questions 13 and 15. “Twenty (20) iires of nitrogen gas at 1 atm. and 25°C is allowed to expand reversibly and adiabatically to forty’ (40) litres (Given that CvCy = 1.4). 13. What is the final temperature? (a) 225.8 K (b) 326.9 K (c) 402.4 K (d) 607-8 K 14, What is the final pressure? (a) 7.01 atm, (b} 2.75 atm. (¢) 0.38 atm. (4) 1.38 atm. 15, In free expansion (a) T= 0 (b) V=0 (6) B= 0(d) q=0 16. Which of thee expressiontdfine the hee caps ofa substncosat constant volume. @2H Sof s 17, Which of the following about an irreversible process is wrong? (a) Pex (b) Wine < Wrev (©) Wore> Weee (d) none of them 18. What is the heat of formation of gascous ammonia from the thermochemical equation below? No(g) +3Ha(g) = 2NHs(g) AH" 18.00 Keal (a) 24000 cal (b) 48.00 Keal (c) — 48000 cal (@) 96.00 Keal 19, One-gram atomic weight of silver was heated from 0 °C to 30°C at constant pressure. The heat capacity ofthe metal at constant presse was 25.46 }dog-1 mol and was constant overPr nti OPTION C 50. st 2 33. 34. 5. a8 38, 3. 50. CCatenlate the root-mean-square velocity of molecular chlorine ia mis at 20°C (01-35-45 R<8314 Smolka 354m/s_ b. Spams c. 296m/s , 262m/5 «. 215m/s ‘The reaction NO: + CO— NO +/COs takes BNO NO NO aft GR=K NOP R= Ko NOI{CO] © : mn is 3.28 « 104 ¢?, Find the order of the reaction (a) Zero order (b) First 0 place in two stops. Find the rat a. R= ki [NOs] @ RK NOT der (€) Second order ‘The rate constant of a reaction (© Thied order : “The etfsion rate ofan unknove gas is mens 3 ‘Tsjon rite of Oss found 10 be 30.50mL/ain. Wi 5: NOs emperatre ll hydrogen rales have the Sts Yr est square speed a8 nitrogen molecules have AN ew auODK §-2000K c-44.0k 6. 33.0K 22 08 alee Calaite the molecular mass of « gas wtiose dENSHY 5 “soc and 758 mmble is 1.386 kg/m® [R ~ 00821410 a. FAsspinol b,26.Tée/mol e.35:70—/mol 4. 4.63e/m0l + Se ee cate ‘Thetate constant of zero-order reactions has the unit (©) ©! (&) mot Ls! © L?moF# 54d) L mol’ $ ‘ The rae oxquatin, wen the concentration of rast Unity ten ihe fale & equal to (2) specific rate constant (b) average y safoat (e) inslantangousrale constatt(d) Nane of the above ; ; inaseris jens, which ithe rate determining stops? a. The simplest reaction ’, The main reaction involving the major esctant e, ‘Theslowestreaction d._ The fastestrea The energy of activation fora reaction is 105KJmnol", Cateulate the specific rate The ee eet RES SII Imola 13x107ee! 10x10 see © Which ofthe following is untwolecular reaction? (a) 2H —+ He + (8) NOs N i identical experimental conditions the and found wo be 31.50mL/min. Under Mencal sPNCON "4G Coy th ofthe following isthe unknown e28? ot 38°C? [H= for the reaction at 300K if the frequency factor 33x 10% sect d.33.x 10? sec? 1104+ Yi Oo (c) Ha Cl > 2ACI (@) PCL + ch PCh or twvhih a substance react depends on ts (2) atomic weight (b) equivalent weight (e)molecular weight (4) active mass. MSs ine will 1.2162 0f S02 gas occupy at 18°C and 755 ton? (0 =160; S= 32.0}. 1.508L bISTIL GOL 4. O754L_¢. 0457. aoe ea isin aman ojnthesind Fnpeittogen apd hydrogen gases Nap ¢ 3a) = Ni How isthe ans e ermation oFammonia related tthe rate of consumption of hydrogen’? a The rate of formation ‘Oammontia is half Sag eta rae Shaumption of hydrogen b. The rate of formation of aminonia is too the fate oF consimpenn ‘of hydrogen ¢. The rate of oe cant of eon i equal othe rate of consiniption of hydrogen d. The rate of fomation of smenonis'S ‘two-thirds the rate ‘of consumption of hydrogen = S aereeriy of oxygen is 1 43g/L at STP, Determine the density of oxygen at 17%C and 800 torr. 1.428/1- Be LBgh c. 28igiL d.280gL 0.4.26 Given that the activation energy of a reaction was determined to be 98.6K)/ mol the reaction given that itis a first order reaction? [R= 8.3 14JK"Imoh'] a. 98.6K3 “Two isotopic forms af Uta ficrde, UF, are kon, One form contains uranim, of atomic donb svcight 235. What ae the relative rats of effusion ofthese eyo molecules2a, 0.96g 6.0.991 ©: 0.996 1009 A sample of ammonia (NF) gas is compl pressure is 666 mmbig, calculate the partial pressure of Ne. a. 217 anime When the concentration of reactant molecules is increased, tho rate of reaction inereasds, ‘The best explanation is: As the reactant concentration increases (a) the average (A) the activation energy increases. (¢) the ‘order of reaction increases kinetic energy of ‘molecules increases.(b) the frequency of molecular collisions increases, (c) the rate constant increases. aswer question 69.870 the value of A and Ea (activation energy) are 4.x 10!see “and 98:6 KY mot! ‘at 35¢C. What is the chonige in the enthalpy of b.96.04KI c. 121.69K3 d. 12428) ‘weight 238; aad the other of d. 1,004 ¢. \ctely déeomposed to nitrogen and hydrogen gases over heated iron WoOL If the ‘total mig. b.336 mmHg. ¢. 433 mmHg 4. $60 mmHg ¢. 650 respectively Ifthe reaction is first order, what would be the rate constant at = 10m {[S.Tunitof time is in seconds) 2. 11.55 x10" sec? b, 1155x109 ser" c. 1155x107 sec! 1, 115.5 see ‘Azaurne the halflife ofthe above reaction is 1Ominutes, at what reinperature will it get thers? R= 8314 Ti mot! b3N3K 313K d30b 1K inutes if that is assumed to be the half-life of the reaction a313K