Molality

1. Calculate the molality of a sulfuric acid solution that contains 24.9 g of acid.
sulfuric in 198 g of water.

Data: Solution:

24.9 g of solution Molar mass of H2SO4

198 liters of water = 0.198 kg H = 2*1 = 2

of the solvent S = 32 * 1 = 32
O= 16*4 = 64

98 g/mol

Moles of HNO3 Molality

ú
= = ( )

24.5 g 0.25
= = 0.198 kg
98

= 0,25 = 1,26

2. What is the molality of a solution that contains 7.78 g of urea (NH2)2CO in 203g
H2O?

Data: Solution:
7.78 g solution Molar mass (NH2)2CO

203 liters of water = 0.203 kg C = 12*1 = 12

of the solvent H = 4*1 = 4
N = 14 * 2 = 28
O= 16*1 = 16

60 g/mol

Moles of HNO3 Molality

ú
= = ( )

7.78 g 0.12
= = 0.203 kg
60

= 0,12 = 0,63
 3. Calculate the molality (m) of each of the following aqueous solutions.
a) Sodium chloride solution 2.5 M (density of the solution = 1.08 g/ml)

Data: Solution:
Molarity = 2.5 M = 2.5 moles of Molar mass of NaCl
solution
d = 1.08 g/ml = 1.08 kg of Na = 23*1 = 23
dissolution Cl = 35*1 = 35
58 g/mol

2.5 moles x 58 g/mol NaCl = 145 g NaCl

0.145 kg solute

kg solution = kg solute + kg solvent

kg solvent = 1.08 kg solution - 0.146 kg solute
kg solvent = 0.934 kg
Molality
ú
=
( )
2.5
= 0.934 kg

= 2,7

b) Dissolution of potassium bromide 48.2% by mass

Data: Solution:

KBr solution = 48.2% by mass Solution = solute + solvent

100 g = 48.2 g of KBr + solvent
solvent = 100 g - 48.2 g of KBr
51.8 g of H2O
1
48,2 | | = 4,05 10-1
119
1
51,8 2 | 3 | = 5,18 10-2 2
10
ú
=
( )
4,05 10-1
=
5,18 10-2
= 7,82
 c) Dissolution of sugar (C12H22O111.22 M (density of the solution = 1.12 g/ml)

Data: Solution:
Molarity = 1.22 M = 1.22 moles Molar mass C12H22O11
of the dissolved

d = 1.12 g/ml = 1.12 kg of C = 12*12 = 144

dissolution H = 1*22 = 22
O = 16*11 = 176
342 g/mol

1.22 moles x 342 g/mol C12H22O11= 373.68 g C12H22O11

0.373 kg solute

kg solution = kg solute + kg solvent

kg solvent = 1.12 kg solution - 0.373 kg solute
0.747 kg
Molality
ú
=
( )
1.22
= 0.747 kg

= 1,63

4. Calculate the molality of a solution of 95 grams of nitric acid (HNO3) in 2.5

liters of water.

Data: Solution:

95 g solution Molar mass of HNO3

2.5 liters of water = 2.5 kg H = 1*1 = 1

of the solvent N = 14*1 = 14
O = 16 * 3 = 48

63 g/mol

Moles of HNO3 Molality

ú
= = ( )

95 g 1.51
= = 2.5 kg
63

= 1,51 = 0,6
5. Calculate the grams of methanol (CH3OH) in a 15 m solution where the solvent is
50 grams of water.
Data:

Molality = 15 m
50 g = 0.05 kg of solvent

Solution:

Molar mass of CH3OH

C = 12*1= 12
H = 4*1 = 4
O = 16 * 1 = 16

32 g/mol
ú
= ( )
=

ú
15 = 0.05 kg
0,75 = 32 g/cm³

# = 15 0,05 = 0,75 32 /
# = 0,75 3 3 = 24

6. Calculate the molality of a solution containing 90 grams of glycerin (C3H8O3) in 200

grams of water.
Data: Solution:
90 g solution Molar mass C3H8O3
200 g of water = 0.2 kg of it C = 12*3 = 36
solvent H = 8*1 = 8
O = 16*3 = 48

92 g/mol

Moles of HNO3 Molality

ú
= = ( )

90 g 0.98
= = 0.2 kg
92

= 0,98 = 4,9
 200ml of H solution is mixed.2SO40.2 N with 300ml of an H solution2SO4
0.08M, then 500ml of distilled water is added. The question is:
a) How many Eq. H2SO4Was there in the first 200ml?
b) How many moles and how many Eq.g of acid were in the other 300ml of solution?
c) What is the normality and molarity of the resulting mixture?
Data:
c)#total moles=# ∑
V1200 ml
N = 0.2 = # /
=1 =
∗
=2
V2= 300 ml #

M= 0.08 1= 2
V3500 ml
Solution: = # /

1L
a)0.2 × |1000| × |200 K | 0.2
1 1=
2
= 0.04 2 4

1= 0.1

1L moles_totales# ∑
0.08 × |1000| × |300 |
1
moles_totales 1 +1 2 2
= 0.024 2 4
total moles of the solution= 0.1 ∗ 0.2 + 0.08 ∗ 0.3
− =# / 0.044
total moles of the solution= 1L
= # / = ∗ # /
2= 2∗ # / = 0.044 ∗2
2= 0.08 ∗2

2= 0.016 = 0.088
1L 300
0.16 × |1000 | × |0.024 |

=2

− =# /

98
− =
2

− = 49