PREROARD (2024-25) SEP IL CLASS = XI SUBIEC T= CHEMISTRY Dine: 3 Hours MM.:70 {Road the following instructions earetilly, There are § page Thore are 33 questions it this question paper with internal choice, [SECTION A consists of 16 multiple-choice questions carrying | mark each, |SECTION B consists of S very short answer questions earrying SECTION C consists of 7 short answer questions carrying 3 marks each, [SECTION D consists of 2 case= based questions carrying 4 marks each, SECTION ¥ consists of 3 long answer questions carrying 5 marks each JAI questions are compulsory, [Use of log table 2 muarks each, a nzymes are regarded a (a)Biocatalysts (Antibodies, Q2, Luca’s reagent is (a) Anhydrous CaCh and cone, HCL (b) Anhydrous ZnCl and cone, HCL () Anhydrous AICh and cone, HCL (4) Anhydrous PACI Q3. Tertiary alkyl halid (a) Steric hindrance (b) Induetive effect and cone, HCL I are practically inert to substitution by SN ? mechanism because of © ) Insolubility. ments — Assertion and Reason. Answer these questions select the b) Both A and Rare true, and B (c) A is true but R is false, (@) Ais false but Ris true, Q4. Assertion: Molecular n NOT the correct explanation of A, iss of benzoic acid when determined by colligative properties is high. Reason: Dimerization of benzoic acid. QS. Assertio D (+) - Glucose is dextrorotatory in nature. Reason: D’ represents its dextrorotatory nature, : Q6. Assert Reason: Rate constant of a zero-order reaction has the same unit as the rate of a reaction. shee ‘ ‘ate constant of a zero-order reaction does not | upon the concentration of the reactant. QT. Assertio H* is an intensive property. Reason: E° is constant for a particular electrode at a given temperature.QS. The name of the linkage isomer of [Co(NH;)sNOa|Chs will be (2) pentaamminotrocobalt (11) chloride {b) pentaaminenitrochloridecobaltate (I) (q) pentaamminenitritocobalt (111) chloride (4) pentanitrosoamminechtorocobaltate( Il) 99, The correct IUPAC name of the coordination compound KaFe(CN)sNO} is (a) Potassium pentacyanonitrosylferrate (11) (b) Pota (c) Potassium pentacyanonitroferrate (II) tritopentacyanoferrate (IV) (4) Potassium nitritopentacynanoiron (11) Q10. Among the following which are ambidentate ligands? () SCN" GiyNor— Gi)NOX (CON (=) @ and (iti) (©) (i) and (iv) (©) (ii) and (iii) @ Gi) and (iv) Q11. 1f2 gm of NaOH is present is 200 ml of its solution, its molarity will be Gs (a) 0.25 (0.5 ©@5 (@10 Q12. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows: (a) No deviation from Raoult’s Law. ; (b) Positive deviation from Raoult’s Law. (c) Negative deviation from Raoult’s Law. (d) ‘The solution is unsaturated. Q13. Which has highest freezing point: {a} 1 MC cose (b) 1 M NaCl (IM CaCl; @ IMAI Q14. The best way to prevent rusting of iron is by x (a) Putting it into saline water (b) Cathodic protection (©) Coating tin on it (@) Putting it in tap water O15. A toad storage battery is reel(@) The concentration of sulphuric acid decrea 16. Saturated solution of KNOs is used to make. 5 ke salt bridge beca Of K+ ion is gre: eens H ater than that of NO3- (b) Velocity of K+ ion is lesser than that of NO3- (©) Velocity of K+ and NOB- ions are equal (4) KNOs is highly soluble in water, SEC ay! Differentiate between following THON B 2 MARI } Globular protein and Fibrous protein (ii) Nucleotide and Nucleoside QIB. Give reasons: (® Aniline does not undergo Friedel Craft reaction, (ii) Aromatic diazonium salts are more stable than aliphatic diazonium salts OR (i) Although -NH2 group is o/p directing in electrophilic substitution reactions, yet aniline, on nitration gives good yield of m-nitroaniline. Gi)_pKb of methylamine is less than that of aniline. Q19. Give mechanism for the Dehydration of alcohol to form alkene. / 20. Although C1 is an electron withdrawing group yet it gives ortho and para product on electrophilic substitution reaction. Account for it. Q21. Describe the preparation of potassium dichromate. SECTION C (3 MARKS) Q22. Give Reasons: (i) Phenol is more a ic than Ethanol. (ii) Ortho = nitrophenol is more acidic than Ortho ~ methoxyphenol. (iii) The presence of electron withdrawing groups such as nitro group enhances theacidic strength of phenol. 023. (i) Write the chemical equation for the reaction involved in Cannizzaro reaction by taking a sultable example (ii) Draw the structure of the Semicarbazone of ethanal. (ili) Why pKa of F — CH2 ~ COOH is lower than that of Cl-CH2 -COOH? What information do we get when D-glucose reacts with following reagent, write thereaction also. a (a) Hydroxylamine (b) acetic anhydride (©)nitric acid Page 13Q25.Arrange in_ increasing order of boiling points (i) Bromomethane, Bromoform, chloromethane, Dibromo-methane i) 1-Chloropropane, Isopropyl chloride, 1-Chlorobutane. (ii) 1-Chloropropane, 1-Bromopropane, I-lodopropane OR Which compound will react faster in nucleophilic subst (i) CHsBrand CHI (Sy 2) Gil) (CH) sC-Cl oF CHYCI(Sx2) (iv) Propyl chloride and Allyl chloride(Sw!) Q26. Explain the following: (i) Law of mass action Gi) Half life period. (ii) Orientation factor. Q27. A first order reaction takes 10 minutes for 25% decomposition. Calculate t1/2 for the reaction. (Given:log 2 3010, log 3 = 0.4771, log 4 = 0.6021) Q28. (a) A solution contains 0.8960g of K2S04 in 500m| solution. Its osmotic pressure is found to be 0.690atm at 27°C. Caleulate the value of Van't Hoff factor. (K=39.0, S=32, O=16, R=0.082atm mot!K"!) (b) Which colligative property is most suitable to measure molecular mass of protein and why? SECTION D (CASE STUDY) (14142) 29. In amines the N atoms of the amino group are SP? hybridized. Aminés readily lose its electron pair and act as a base. In aliphatic amines, the alkyl group tends to increase the electron density on the nitrogen atom due to the +1 effect. In aromatic amines, the basic strengths are influenced by the presence of an electron withdrawing group at the O-, m- and p-position in the ring. (2) Lower inembers of aliphatic amine are soluble in water, why? (b) Out of (CHs)5N and (CHs);NH which one is more basic in aqueous solution, why? () Which isomer of CsH3N does not react with Hinsberg’s reagent. Give chemical equations of other two. OR (©) Give chemical test to distinguish between (i) Primary and Secondary aliphatic amine i) Aliphatic and Aromatic primary amine. 030 In coordination compounds, metals show two types of linkages, primary and secondary, Primary valencies ire ionizable and are satisfied by negatively charged ions, Secondary valencies are non-ionisable and are satisfied by neutral or negative ions having lone pair of electrons. ‘ary valencies are non-directional while secondary valencies decide the shape of the complexes. If PCl.2NHs does not react with AgNOs, what will be its formula? (@)What is the secondary valency of {Co(en)3]*? Can it show optical isomerism? (©) Whats the oxidation no, and coordination no, of Co in {Co(en)s}"2 (c) (1) Write the formula of Iron(IHl) hexacyanidoferrate({l (2) Write the IUPAC name of | [CoH sCICt Page | 4 °oR viour of [Ni(CN)4p> SECTION E (5 MARK: hhange for the following reaction at room temperature? i ie ‘action at roo s the reacti Sn(s) + 2Cu* (aq) Sn** (aq) + 2Cut (5) saataaiataraceres n?*/Sn and E°Cu*"/Cu are -0.14 V () The molar condu disso Q31. (a) What is the standard free energy el spontaneous? Given anil 40.34 V respectively ity of 0.025 mol L* ‘ation and dissociation constant. Given 4° methanoic acid is 46.1 S$ cm?mol (H+ )=349.6 Scm2mol-1 and ,%11COo OR Calculate its degree of '=54.6 Sem2mol-1 ” (a) Depiet the galvanic cell in which the followi ig reaction takes place Zn(s) + 2Ag+ > Zn 2+ +2Ag. {i) Which of the electrode is negatively charged? Gi ‘The carriers of the current in the cell are (ii) Write the reactions at each electrode, (b) A solution of Ni (NO): is electrolyzed between What mass of Ni is deposited at the cathode? (1 YQ32. (2) An organic compound “A” having molecular formula CsHigO gives negative Tollens'test, fo ‘n-pentane on Clemmensen reduction but doesn’t give iodoform test. Identify ‘A’ and give the renctiog >) involved / platinum electrodes using a current of S amperes for 20 minutes. i= 587 a) (©) Carry out the following conversions: @©repancie acid to 2-Bromopropancie acid ©) i) Benzoyl chloride to venntser@) 5 QO (©) How will you distinguish between benzaldehyde and acctaldehyd OR (a) Carry out the following conversions: (i) P-nitrotoluene to 2-bromobenzoie acii ii) Propanoic acid to acetic acid (b) An alkene with molecular formula CsHyo on ozonolysis gives a mixture of two compounds, B and C. Compound B gives positive Fehling test and also reacts with iodine and NaOH solution. Compound C does not give Fehling solution test but formsiodoform. Identify the compounds A, B and C. Q33. Assign reasons for the followin, (a) The enthalpies of atomization of transition elements are high, (b) The transition metals and many of their compounds act as good catalysts, (©) E°oa2eng values are not regular for first-row transition metals (3d series), (a) Although + + the highest Mn fluoride is Mn, whereas thehighest oxide is Mm2O7, ee soured. is more electronegative than (© Se is colourless in an aqueous sol ion whereas T?* is col Poge | 5