Atomic Structure 2
1. The letters s, p, d and f are used to represent
A) Orbit B) Sub-shells C) Shells D) Orbital
2. The value of magnetic quantum number is directly determined by the value of
A) Principal quantum number B) Azimuthal quantum number
C) Spin quantum number D) Both “A” and “B”
3. In which of the following Pauli’s exclusion principle is violated
A) B) C) D)
19
4. The order of energy level in K is?
A) 4s, 4p B) 3p, 4s C) 4s, 3d D) 3s, 3d
5. With increase in the value of principal quantum number ‘n’, the shape of the s-orbitals remain same
although their sizes
A) Decrease B) Increase
C) Remain the same D) May or may not remain the same
6. The number of completely filled orbitals in O-2 ion is
A) 2 B) 3 C) 4 D) 5
7. Which orbital correctly represents the last electron in the element of VII-A group and 3rd period
A) B) C) D)
8. The maximum number of electrons in an orbit can be calculated by the formula
A) 2(2 + 1) B) (2 + 1) C) 2n2 D) n2
9. Which one of the following ion has similar electronic configuration like Ar
A) Sc+2 B) Cr+2 C) Ti+4 D) Mn+6
10. How many electrons are present in the M shell of Cr-24
A) 18 B) 14 C) 12 D) 13
11. Which of following configuration is not correct according to Hund’s rule
A) B)
C) D)
12. In electronic configuration of Cu and Cr which of following is true
A) 3-d is full filled B) 7 electrons in s-orbitals
C) 3-d is half filled D) 8 electrons in s-orbitals
13. Which of the following violates Hund’s rule
A) B)
C) D)
14. Which of the following elements has least number of electrons in its ‘N’ shell
A) 25Mn B) 28Ni C) 20Ca D) 24Cr
15. The d-orbital which is bi-lobed with collar is represented as
A) dxy B) dz2 C) dyz D) dx2–y2
16. General electronic configuration of p-block elements are given, Which of the following element has
maximum first ionization energy
A) ns2, np2 B) ns2, np4 C) ns2, np3 D) ns2, np1
17. The charge on one proton is
A) 1.602×10–31C B) 1.602×10–19C C) 1.602×10–27C D) 1.602×10–11C
18. When = 3 , the number of possible orbitals in the sub–shell is
A) 1 B) 5 C) 3 D) 7
19. Which quantum number tells us about orientation of orbitals:
A) Principal quantum number B) Azimuthal quantum number
C) Spin quantum number D) Magnetic quantum number
20. The relative energies of 4s, 4p and 3d orbitals are in the order
A) 3d < 4p < 4s B) 4s < 3d < 4p C) 4p < 4s < 3d D) 4p < 3d < 4s
21. The atomic number of an element is 26. How many electrons are present in M-Shell of this element
in ground state
A) 11 B) 15 C) 14 D) 16
22. The correct electronic configuration of 29Cu is
A) B)
C) D)
23. Positive rays give flash on
A) AgNO3 plate B) ZnO C) AgCl plate D) ZnS
24. The number of unpaired electrons in the carbon atom in ground state
A) 4 B) 3 C) 2 D) 1
25. If = 1 then orbitals in which the value of m = +1, 0, –1 are
A) px, py, dxy, B) px, py, pz C) dxy, dyz, dxz D) dx2-y2, dz2
26. Which one of the following pairs has the same electronic configuration as possessed by neon (Ne-
10)
A) Na+, Cl– B) K+, Cl– C) Na+, Mg+ D) Na+, F–
27. A p-orbital has _____ energy than the s-orbital of same principal quantum number
A) Lower B) Equal C) Higher D) Variable orbit to orbit
28. When we distribute the electron in Ca-atom, the shape of valence orbital in which last electron is
present is
A) Spherical B) Dumb-bell C) Complicated D) Has no specific shape
29. Angular momentum of an electron
A) n2h/2 B) nh/4 C) nh2/2 D) nh/2
30. Planck’s equation is
A) E = mc2 B) E = h C) mvr = nh/2 D) = h/mv
31. When an atom absorbs energy the lines in the spectrum will appear which are
A) Brighter B) Colourless C) Darker D) Hard to locate
32. Identify the correct option associated with the shape of p-orbital:
B) C) D)
A)
33. The relationship between energy of a photon of light and its frequency is given by
A) de-Broglie dual nature of matter B) Planck’s Quantum theory
C) Bohr’s model D) Rutherford’s atomic model
34. A specie Z has following electronic configuration
What could Z be?
A) Ar B) S C) Cl– D) P3–
35. The total number of lobes in all the orbitals of a d-subshell are
A) 2 B) 4 C) 16 D) 18
36. “Two electrons in the same orbital should have opposite spins” according to
A) Aufbau’s principal B) Hund’s rule
C) Pauli’s exclusion rule D) None of these
37. Positive rays are produced
A) By burning of gas
B) By cooling of the gas
C) By the bombardment of cathode rays on gas molecules
D) From anode like cathode rays, produced from cathode
38. Quantum number values for 3p orbital are
A) n = 3, l = 0 B) n = 2, l = 1 C) n = 3, l = 1 D) n = 2, l = 3
39. Maximum number of electrons that can be accommodated in p-subshell
A) 2 B) 10 C) 6 D) 14
40. What will be the effect on proton when passed through the electric field
A) Deflection towards anode B) Deflection towards cathode
C) Deflection perpendicular to electric field D) Deflection downwards in electric field
