ATHANI COMPOSITE PU COLLEGE

VIDHVATH MEDICAL & IIT ACADEMY

Duration:3 hours 15 Minutes CLASS- II PU JEE TEST-14 HA 02 and 3 (10-08-2025) Max marks:360

PHYSICS PART:

1. If we observe the single slit Fraunhofer (c) Sound waves are mechanical waves
diffraction with wavelength  and slit (d) Sound waves are of longer
width e, the width of the central
wavelength
maxima is 2. On decreasing the slit
width for the same  6. Direction of the first secondary
maximum in the Fraunhofer diffraction
(a)  increases
pattern at a single slit is given by (a is
(b)  remains unchanged the width of the slit)
(c)  decreases (a) a sin  

(b) a cos 
3
(d)  increases or decreases depending 2 2
3
on the intensity of light (c) a sin   (d) a sin 
2
2. When light is incident on a diffraction
grating the zero order principal 7. A parallel monochromatic beam of
maximum will be light is incident normally on a narrow
slit. A diffraction pattern is formed on a
(a) One of the component colours
screen placed perpendicular to the
(b) Absent direction of incident beam. At the first
(c) Spectrum of the colours maximum of the diffraction pattern the
(d) White phase difference between the rays
coming from the edges of the slit is
3. A beam of light of wavelength 600 nm

from a distant source falls on a single (a) 0 (b)
2
slit 1 mm wide and the resulting
diffraction pattern is observed on a (c)  (d) 2
screen 2 m away. The distance 8. Diffraction and interference of light
between the first dark fringes on either suggest
side of the central bright fringe is (a) Nature of light is electro-magnetic
(a) 1.2 mm (b) 1.2 cm
(b) Wave nature
(c) 2.4 cm (d) 2.4 mm
(c) Nature is quantum
4. In order to see diffraction the thickness
(d) Nature of light is transverse
of the film is
(a) 100 Å (b) 10,000 Å 9. A light wave is incident normally over a
slit of width 24 10 5 cm . The angular
(c) 1 mm (d) 1 cm position of second dark fringe from the
5. Diffraction effects are easier to notice central maxima is 30o. What is the
in the case of sound waves than in the wavelength of light
case of light waves because (a) 6000 Å (b) 5000 Å
(a) Sound waves are longitudinal (c) 3000 Å (d) 1500 Å
(b) Sound is perceived by the ear
10. A parallel beam of monochromatic rotatory solution of concentration
light of wavelength 5000 Å is incident 60kgm–3 and specific rotation 0.01rad
normally on a single narrow slit of m2kg–1. The second tube contains laevo
width 0.001 mm. The light is focused rotatory solution of concentration
by a convex lens on a screen placed on 30kg/m3 and specific rotation 0.02
the focal plane. The first minimum will radm2kg–1. The net rotation produced
be formed for the angle of diffraction is
equal to (a) 15° (b) 0°
(a) 0o (b) 15o (c) 20° (d) 10°
o o
(c) 30 (d) 60 15. V o and VE represent the velocities,  o
11. A calcite crystal is placed over a dot on and  E the refractive indices of ordinary
a piece of paper and rotated, on seeing and extraordinary rays for a doubly
through the calcite one will be see refracting crystal. Then
(a) One dot (a) Vo  V E ,  o   E if the crystal is
(b) Two stationary dots calcite
(c) Two rotating dots (b) Vo  V E ,  o   E if the crystal is
(d) One dot rotating about the other quartz
12. A light has amplitude A and angle (c) Vo  VE , o   E if the crystal is calcite
between analyser and polariser is 60°. (d) Vo  V E ,  o   E if the crystal is
Light is reflected by analyser has
amplitude quartz
(a) A 2 (b) A / 2 16. Polarising angle for water is 53°4'. If
light is incident at this angle on the
(c) 3A / 2 (d) A / 2 surface of water and reflected, the
13. When light is incident on a doubly angle of refraction is
refracting crystal, two refracted rays- (a) 53°4' (b) 126°56'
ordinary ray (O-ray) and extra ordinary
(c) 36°56' (d) 30°4'
ray (E-ray) are produced. Then
(a) Both O-ray and E-ray are polarised 17. When a plane polarised light is passed
through an analyser and analyser is
perpendicular to the plane of
rotated through 90º, the intensity of
incidence the emerging light
(b) Both O-ray and E-ray are polarised (a) Varies between a maximum and
in the plane of incidence minimum
(c) E-ray is polarised perpendicular to (b) Becomes zero
the plane of incidence and O-ray in (c) Does not vary
the plane of incidence
(d) Varies between a maximum and
(d) E-ray is polarised in the plane of
zero
incidence and O-ray perpendicular
18. Consider the following statements A to
to the plane of incidence
B and identify the correct answer
14. Light passes successively through two A. Polarised light can be used to study
polarimeters tubes each of length
the helical surface of nucleic acids.
0.29m. The first tube contains dextro
 B. Optics axis is a direction and not any   5000Å and 50° per mm at   4000Å
particular line in the crystal . The value of constant a will be
50 50
(a) A and B are correct (a)  per mm (b)  per mm
9 9
(b) A and B are wrong 9 9
(c)  per mm (d)  per mm
(c) A is correct but B is wrong 50 50
(d) A is wrong but B is correct 23. When an unpolarized light of intensity
I 0 is incident on a polarizing sheet, the
intensity of the light which does not
get transmitted is
(a) Zero (b) I 0
19. Two Nicols are oriented with their
1 1
principal planes making an angle of (c) I0 (c) I0
2 4
60°. The percentage of incident
unpolarized light which passes through 24. Refractive index of material is equal to
the system is tangent of polarising angle. It is called
(a) 50% (b) 100% (a)Brewster’s law (b) Lambert’s law
(c) Malus’s law (d) Bragg’s law
(c) 12.5% (d) 37.5%
25. In case of linearly polarized light, the
20. Unpolarized light falls on two
magnitude of the electric field vector:
polarizing sheets placed one on top of
the other. What must be the angle (a)Does not change with time
between the characteristic directions (b)Varies periodically with time
of the sheets if the intensity of the final (c) Increases and decreases linearly
transmitted light is one-third the with time
maximum intensity of the first
(d)Is parallel to the direction of
transmitted beam
(a) 75° (b) 55° propagation

(c) 35° (d) 15° 26. When unpolarised light beam is

incident from air onto glass (n = 1.5) at
21. Unpolarized light of intensity 32Wm–2 the polarising angle
passes through three polarizers such
(a)Reflected beam is polarised 100
that transmission axes of the first and
percent
second polarizer makes and angle 30°
with each other and the transmission (b)Reflected and refracted beams are
axis of the last polarizer is crossed with partially polarised
that of the first. The intensity of final (c) The reason for (a) is that almost all
emerging light will be the light is reflected
(a) 32 Wm–2 (b) 3 Wm–2
–2 –2
(d)All of the above
(c) 8 Wm (d) 4 Wm
27. An optically active compound
22. In the visible region of the spectrum (a)Rotates the plane polarised light
the rotation of the place of polarization
b (b)Changing the direction of polarised
is given by   a  . The optical light
2
rotation produced by a particular (c) Do not allow plane polarised light to
material is found to be 30° per mm at pass through
 (d)None of the above the refracted ray inside the material is
28. When the angle of incidence on a (in ms–1)
material is 60°, the reflected light is  3 
(a) 3  108 (b)    10 8
completely polarized. The velocity of  2
(c) 3 108 (d) 0.5  108
29. Two polaroids are placed in the path of unpolarized beam of intensity I 0 such that no
light is emitted from the second polaroid. If a third polaroid whose polarization axis
makes an angle  with
the polarization axis of first polaroid, is placed between these polaroids then the intensity
of light emerging from the last polaroid will be
(a)  0  sin2 2 (b)  0  sin2 2 (c)  0  cos4 
I I I
(d) I 0 cos4 
8 4 2
30. For the study of the helical structure of nucleic acids, the property of electromagnetic
radiation generally used is
(a) Reflection (b) Interference (c)Diffraction (d)Polarization
CHEMISTRY PART

31.The correct order of acidic strength of carboxylic acids is

1) formic acid < benzoic acid < acetic acid 2) formic acid < acetic acid < benzoic acid
3) acetic acid < formic acid < benzoic acid 4) acetic acid < benzoic acid < formic acid
32.Which of the following acids has the smallest dissociation constant?
1)CH3CHFCOOH 2)FCH2CH2COOH 3)BrCH2CH2COOH 4)CH3CHBrCOOH
33.The correct order of increasing acid strength of the compounds
Me
CO 2H
(A) CH3CO2H (B) MeOCH2CO2H (C) CF3CO2H (D)Me

1) B < D < A < C 2) D < A < C < B 3) D < A < B < C 4) A < D < C < B
34.Among the following acids which has the lowest pKa value?
1) CH3COOH 2) HCOOH 3) (CH3)2CHCOOH 4) CH3CH2COOH
35.Consider the acidity of the carboxylic acids
(i) PhCOOH (ii) o-NO2C6H4COOH (iii) m-NO2C6H4COOH
Which of the following order is correct?
1) (i) > (ii) > (iii) > (iv) 2) (ii) > (iv) > (iii) > (i) 3) (ii) > (iv) > (i) > (iii) 4) (ii) > (iii) > (iv) >
(i)
3 
CH3CH2COOH   X  Y
Br2 NH alc

36. RedP
; Y in the above reactions is
1) lactic acid 2) ethylamine 3) propylamine 4) alanine
37. CH 3CH 2COOH 
Cl
Red P
 A 
2alc.KOH
 B ; What is B?
1) CH3CH2COCl 2) CH3CH2CHO 3) CH2 = CHCOOH 4) ClCH2CH2COOH
38.In a set of reactions propionic acid yielded a compound D.
CH 3CH 2COOH 
SOCl2
 B 
NH 3
 C 
KOH
Br2
D
The structure of D would be
1) CH3CH2CONH2 2) CH3CH2NHCH3 3) CH3CH2NH2 4) CH3CH2CH2NH2
39.Which of the following represents the correct order of the acidity in the given compounds?
1) FCH2COOH > CH3COOH > BrCH2COOH > ClCH2COOH
2) BrCH2COOH > ClCH2COOH > FCH2COOH > CH3COOH
 3) FCH2COOH > ClCH2COOH > BrCH2COOH > CH3COOH
4) CH3COOH > BrCH2COOH > ClCH2COOH > FCH2COOH
40.Acetophenone when reacted with a base, C2H5ONa, yields a stable compound which has
the structure.
CH CH C CH CH 2C

CH3 O CH3 O
1) 2)
CH3 CH3

C C CH CH

OH OH OH OH
3) 4)
41.The relative reactiveities of acyl compounds towards nucleophilic substitution are in the
order of:
1)Acyl chloride > Acid anhydride > Ester > Amide 2)Ester > Acyl chloride > Amide >
Anhydride
3)Acid anhydride > Amide >Ester >Acyl chloride 4)Acyl chloride >Ester >Acid anhydride
>Amide
42.Propionic acid with Br2|P yields a dibromo product. Its structure would be:
Br Br
H C CH2COOH H3C C COOH

1) Br 2) CH2Br – CH2 – COBr 3) Br 4)CH2Br–CHBr –

COOH

43.In a set of reaction, ethylbenzene yielded a product D.

CH 2CH 3 KMnO4

KOH
 B 
Br2
FeCl3
 C 
C2 H 5OH
H
D
Br
COOH COOC 2H 5

CH 2 CH COOC 2H5
Br
1) Br 2) CH 2COOC 2H5 3) OCH 2CH 3 4) Br

44.Following compounds are given:

CH 3  CHOH

a) CH3CH2OH b) CH3COCH3 c) CH 3 d) CH3OH

Which of the above compound(s), on being warmed with iodine solution and NaOH, will
give iodoform?
1) a and b 2) a, c and d 3) only b 4) a, b and c
45.Which of the following compounds will be most readily dehydrated?
OH
O O
CH3 O OH
H3C H3C H3C

1) O 2) OH 3) OH 4) H3C
46.The order of reactivity of phenyl magnesium bromide (PhMgBr) with the following
compounds
H3C H3C Ph
C O C O C O
H H3 C Ph
I   II   III 
1) III > II > I 2) II > I > III 3) I > III > II 4) I > II > III
47.Match the compounds given in List-I with List – II and select the suitable option using the
code given below:
List I List II
A) Benzaldehyde i) Phenolphthale in
 B) Phthallic anhydride ii) Benzoinc condensation
C) Phenyl benzoate iii) Oil of wintergreen
D) Methyl salicylate iv) Fries rearrangement
Code:
A B C D A B C D A B C D A B C D
1) (iv) (i) (iii) (ii) 2) (iv) (ii) (iii) (i) 3) (ii) (iii) (iv) (i) 4) (ii) (i) (iv) (iii)
48.An organic compound ‘A’ on treatment with NH3. Gives ‘B’ which on heating gives ‘C’, ‘C’
when treated with Br2 in the presence of KOH produces ethylamine. Compound ‘A’ is
CH 3  CHCOOH

1) CH3COOH 2) CH3CH2CH2COOH 3) CH 4) CH3CH2COOH 3

49.The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic
acid(A), acetic acid (C) and formic acid (D) is:
1) B > A > D > C 2) B > D > C > A 3) A > B > C > D 4) A > C > B > D
50.Consider the reaction: RCHO  NH 2 NH 2  RCH  N  NH 2 What sot of reaction is it?
1)Electrophilic addition – elimination reaction
2)Free radical addition–elimination reaction
3)Electrophilic substitution – elimination reaction
4)Nucleophilic addition–elimination reaction
51.Which of the following compounds will give a yellow precipitate with iodine and alkali?
1) Acetophenone 2) Methyl acetate 3) Acetamide 4)2-Hydroxypropane
52.The order of stability of the following tautomeric compounds is:
OH O O O O O
CH 2  C  CH 2  C  CH 3 CH 3  C  CH 2  C  CH 3 CH 3  C  CH  C  CH 3


1) III > II > I 2) II > I > III 3) II > III > I 4) I > II > III
53.Which of the following on treatment with 50% aqueous sodium hydroxide yields the
corresponding alcohol and acid?
O
1) CH 3  C  CH 3 2) C6H5CH2CHO 3) C6H5CHO 4) CH3CH2CH2CHO
54.A mixture of benzaldehyde and formaldehyde on
1) benzyl alcohol and sodium formate 2) sodium benzoate and methyl alcohol
3) sodium benzoate and sodium formate 4) benzyl alcohol and methyl alcohol
55.Butan-2-one can be converted to propanoic acid by which of the following
1) NaOH, NaI/H+ 2) Fehling’s solution 3) NaOH, I2/H+ 4)Tollen’s reagent
56.Compound (A) C5H10O forms a phenylhydrozone and gives negative Tollen’s and iodoform
test. Compound (A) on reduction gives n-pentane. Compound (A) is
1) Chloral 2) chloroform 3)chloromethane 4)chloroacetic acid
57.A carbonyl compounds react with hydrogen cyanide to form cyanohydrins which on
hydrolysis forms a racemic mixture of  -hydroxy acid. The carbonyl compound is
1) formaldehyde 2) acetaldehyde 3)acetone 4)diethyl ketone
58.The increasing order of the rate of HCN addition to compound, A – D is
A. HCHO B. CH3COCH3 C. PhCOCH3 D. PhCOPh
1) A < B < C < D 2) D < B < C < A 3) D < C < B < A 4) C < D < B < A
59.In the following sequence of reaction, end product is
  Ca  OH 
CaC2   A 
2
B   C   D   E
H 2O Hg / H 2 SO4 O 2 heat

1) acetaldehyde 2) formaldehyde 3) acetic acid 4) acetone

60. CH COOH  X 
3
LiAlH 4
Y  Z In the above reaction Z is
Cu
0
300 C
dilute

NaOH

1) Acetal 2) Butanol 3) Aldol 4) Ketol

 MATHEMATICS PART

61.If | ⃗| then | ⃗| lies in the interval

1) 2) 3) 4)
62.Which of the following vectors has the same direction as the vector i – 2j?
1) – i + 2j 2) – 2i + 4j 3) 3i – 6j 4) None of these
63.If i + j + 2k, 3i – j – k, 2i + j – k, 4i – j – 3k are the position vectors of the points A, B, C, D
then ⃗⃗⃗⃗⃗⃗⃗ + ⃗⃗⃗⃗⃗⃗ is
1) i – 2j + 2k 2) – 4i – 5k 3) 4i – k 4)
64.ABCD is a parallelogram ,⃗⃗⃗⃗⃗⃗⃗⃗ and ⃗⃗⃗⃗ represents the position vectors of the vertices, A, B &
D respectively. The position vector of the vertex C is
1) ⃗⃗⃗⃗ ⃗⃗⃗⃗ ⃗⃗⃗⃗ 2) ⃗⃗⃗⃗ ⃗⃗⃗⃗ ⃗⃗⃗⃗ 3) ⃗⃗⃗⃗ + ⃗⃗ - ⃗⃗⃗⃗ 4) ⃗⃗⃗⃗ + ⃗⃗⃗⃗ - ⃗⃗⃗⃗
65.If A , B , C are the vertices of a triangle whose position vectors are ⃗⃗⃗⃗, ⃗⃗⃗⃗, ⃗⃗⃗ and G is the
centroid of the ABC then ⃗⃗⃗⃗⃗⃗⃗ ⃗⃗⃗⃗⃗⃗⃗ ⃗⃗⃗⃗⃗⃗⃗ =
⃗⃗⃗⃗ ⃗⃗⃗⃗⃗ ⃗⃗⃗ ⃗⃗⃗⃗ ⃗⃗⃗⃗ ⃗⃗⃗
1) 2) 3) ⃗⃗⃗⃗ + ⃗⃗⃗⃗ + ⃗⃗⃗ 4) ⃗⃗
66. (⃗⃗ ⃗⃗) ⃗⃗ (⃗⃗ ⃗⃗) ⃗⃗
1) |⃗⃗| √ |⃗⃗| 2) |⃗⃗| |⃗⃗| 3) |⃗⃗| |⃗⃗| 4) |⃗⃗| |⃗⃗|
67.If ⃗⃗⃗⃗⃗⃗⃗ = ⃗⃗⃗⃗⃗⃗⃗⃗ = – and ⃗⃗⃗⃗⃗⃗⃗ = and cos( ̂ ) = 0 then
1) 2) 30 3) 35 4)
68.The position vectors of the points A,B,C are and
respectively, the greatest angle of the triangle ABC is
1) 2) 3) 4)
69.If ⃗⃗ ⃗⃗ ⃗ be 3 vectors such that
⃗⃗ (⃗⃗ ⃗) ⃗⃗ ( ⃗ ⃗⃗) ⃗ (⃗⃗ ⃗⃗) and |⃗⃗| |⃗⃗| | ⃗| then
|⃗⃗ ⃗⃗ ⃗|
1)13 2) 81 3) 9 4) 5
70.The vectors having initial and terminal points as ( ) ( ) respectively is
1) 2) 3) 4)
71.The position vector of the point which divides the join of points ⃗ ⃗⃗ and ⃗ ⃗⃗ in the
ratio 3 : 1 is
⃗⃗ ⃗⃗ ⃗⃗ ⃗⃗ ⃗⃗ ⃗⃗
1) 2) 3) 4)
72.Let ⃗⃗ ⃗⃗ The vector ⃗⃗ bisecting the angle AOB and C
being a point on the line AB is :
) ( ) 2) ( ) 3) 4)
73.The points with position vectors are collinear if
1) 2) 3) 4)
74.If |⃗⃗⃗⃗| = 11, |⃗⃗⃗⃗| |⃗⃗⃗⃗ ⃗⃗⃗⃗| = 30 then |⃗⃗⃗⃗ ⃗⃗⃗⃗| =
1) 10 2) 20 3) 15 4) 25
75.The sum of two unit vectors is a unit vector. The magnitude of their differences is
1) 2) √ 3) 4) √
76.If are perpendicular vectors, then the value of
1) 2) 3) 4)
77.The area of the parallelogram whose adjacent sides are 2i – 3k and 4j + 2k is
1) 2√ 2) 4√ 3) 16√ 4) √
78.The vectors from origin to the point A and B are, ⃗ ⃗⃗
respectively, then the area of triangle OAB is
1) 2) √ 3) √ 4) √
79.If | ⃗| | ⃗⃗| and | ⃗ ⃗⃗| then |⃗⃗⃗⃗ ⃗⃗|
1) 4 2) 2 3) 5 4) 6
80.If ⃗⃗ ⃗⃗ are two vectors such that
|⃗⃗ ⃗⃗| |⃗⃗ ⃗⃗| |⃗⃗| |⃗⃗| then
1) ⃗⃗ ⃗⃗ 2) ⃗⃗ ⃗⃗
3) ⃗⃗ ⃗⃗are any two non orthogonal vectors 4) ⃗⃗ ⃗⃗
81.If ⃗ ⃗⃗ ⃗ ⃗⃗ then the angle between ⃗ ⃗⃗
   
1) 2) 3) 4)
82.If ⃗ ⃗⃗ are unit vectors, then what is the angle between ⃗ and ⃗⃗ for √ ⃗ ⃗⃗ to be a
unit vector?
1) 2) 3) 4)
83.Which of the following is false?
1) | ⃗ ⃗⃗| | ⃗| | ⃗⃗| 2) ⃗ ⃗⃗ | ⃗| | ⃗⃗|
3) | ⃗| | ⃗⃗| ⃗ ⃗⃗ 4)
⃗⃗ be such that | ⃗| √
84.Let the vectors ⃗ | ⃗⃗| and ⃗ ⃗⃗ is a unit vector, then the
angle between ⃗ ⃗⃗
1) 2) 3) 4)
85.If ⃗ = (1, 2, 3), ⃗⃗ = (2, 3, 4) the direction cosines of 2 ⃗ – ⃗⃗ are
1) (0, 1, 2) 2) (1, 1, 1) 3) ( ) 4) ( )
√ √
86.Area of the rectangle having vertices, A,B,C and D with position vectors
respectively is
1) 2) 3) 4) 4
87.The projection of i + j – 2k on i + j + 4k is
1) √ 2) √ 3) √ 4) √
88.The unit vector perpendicular to the plane determined by P(1, -1,2) Q (2,0,1) and R(0,2,1)
is
( ) ( ) ( )
1) 2) 3) 4)
√ √ √
89.If ⃗⃗⃗⃗ = 3i + 2j – k, ⃗⃗⃗⃗ = i – k, ⃗⃗⃗= 2j – k,
⃗⃗⃗⃗= 3i + j – 2k then (⃗⃗⃗⃗ ⃗⃗⃗⃗). (⃗⃗⃗ ⃗⃗⃗⃗) is
1) 15 2) – 4 3) 0 4) 12
90.If direction cosines of a vector of magnitude 3 are and , then vector is:
1) ̂ ̂ ̂ 2) ̂ ̂ ̂ 3) ̂ ̂ ̂ 4) ̂ ̂ ̂