<br>

5T 12

Chapter1
fayr(Solution )

Easy Notes

Tr. Saurabh Mishra

M.Sc. (Chemistry)
<br>

CHAPTER

1 feIeTJoI (Solution)

TaeyT (Solitiom) -

fGRrÐr
fcIGtacer (Solste)
L

loogm
loo gyn

[1.1]
<br>

fatt (Solution)
Fosmudco
A B

A
T gce. = MA x loo
MA MA + mB
B DI Ce. = M8 xloo
MA+ MB

loo

NaCe Hao l66

An
x loo =0_x loo
|20

20 ml Lo0
= X
(20+ 160)m

[1.2]
<br>

HIYT fAlT (Chemistry)

1.

= ttM& =1

Nagt3 Halg) 2NH.s(g)

HT HT SHt : 0.2 3R 0.5 TI Aq|

He + 1
0.2
Ha ? 0.2 + O.5
=

0.5 D.3
caeioT
36 gm GGT
,46 g zoT
m.w.

H,0 18
36 gro
| 2
A 18 gm GH,OH 24 +
6+ 16
=46
46 gro 1 CH
OH 12 + 14 + 16=32
46
32 go = 1
32
= 4
=

1
H

[1.3]
<br>

faT (Solution)

nA
C, HO2

80
H,0 18

20
80
62 18
80

62 18
20% Wlw
T
20 CH,0, Loo T
fadg (H,0 ) 80

2(12) +6 +32 = 62
Golden point

H50

S8

mI= S0

nI =450 = 25
(8
[1.4]
<br>

HIYT fAlT (Chemistry)

Me = 58 1 = 01
S8
25
25t01
X2 =
26+0
2
Kit =|

Ha0 2+I6 = (8
CH,CoCHa (2t3+12+6+ 2
+3 =68

1
(ppr
Ppm

1: No gos lopp
lo mL No lomL

Co (HCo,, JreT Ha0

MA

(mA+ m6 MA

[1.5]
<br>

fdT (Solution)

mA

lo6 mA X lo6

lo6

PPb =

PPm = X lo6

PPmu = 88 X l0-3 X l06

l000

Molalitg / ereiar

1Lb

[1.6]
<br>

THYT fAl (Chemistry)

X-faoctos

TH,Soy2
+ 2+32+ G4 = 98
X- factos =

= 49
HC

1+ 36-5 366

X-faocos =1
1

= H DT IHeT
deT
HCL Sy
faee = H

lo
5T
Ha
l00
r
= H
5T HoHCT
l000

(HaSoy
[1.7]
<br>

fay (Solution)

X-factoS
98
+2
tery pT
GIN= 6Lt = 49

fieiy T GIGT (Lt)

49
= 1
= 0·02 N n
So

V= =

Wa
N=
EA
Xd W
X 1000

EA

d (gm/ml )
=

hT N

Et far
(2)

[1.8]
<br>

HIYT fAlT (Chemistry)

(HAH)

1
10 36.5 X
1

X 36.5
gm Anb.
3.65

36.5
1.
36.5

hcdT =

Solusion

CHsCooH

Ho

R44
[1.9]
<br>

fdT (Solution)

CH3CooH

|CHyCooH

(22
3UI

AGRaT ( Molaxity) I

(M)= X looo

OR =

6M (Malon)
6 Male
fae 1 ler facT A

Q 585

[1.10]
<br>

HIYT fAlT (Chemistry)

= o-4 mol /Lt

26

faae oo0

23+ 3S8 = 585

(Ha0)

(gm)
=
0:4m tns

HCL HCL
to3.65

= lb3.65
3.65 gn

i03.65 3.65

[1.11]
<br>

fd (Solution)

H
BT 31AR l+36.5
36.5

1ox 65 X 1ooo
3

36/5 i0o X loo

365
365
1 m

5M 5 male faoar
1 Itre (1o00 mD taeur
male
5m
5
faTI
. 3M Nal faoT

3 Male

3 Male Nal
3 X S8.5 NaCl
L45.5
(1 male
Nac 585 )
23 + 35.5 - 58.5

[1.12]
<br>

HIYT fAlT (Chemistry)

1.5

= 125
l00
x Lo00

= 1250

1250- 175.5
1074.5 gn
X 1000

(gm)
175.5 X
1000 m
Ans.
58.5 X 1044.S

NaCl t

25c male /tthe

[1.13]
<br>

fau (Solution)

Nacl

H,0

321420T te Nal KL

Nal

de- Chatlia Pricible

(Exatheme ) (EndotheHmic)
+ 4T, tact +
b

[1.14]
<br>

HINT fAH (Chemistry)

bakt
-atuft

narEI>LoI4HT
-at 4HT>back
|fadzidr
Rxn

stfusia

sT
[1.15]
<br>

fa (Solution)

Heny 's ka

(Absons -Stin

GIT
T HHG Efect of Temp

s HsfT ( Natne of Grases )

,
NH,
Gt- HCL
HCL HBr

+
NH > NHOH NH + OH

CO, + H,0 H, co Ht + HCO:

NH
NH40H
OH

[1.16]
<br>

HIYT fAlT (Chemistry)

fdeizes
GHas
s gtt ( Natine Of alvent)

Folsert (

- Hd, NH, T STT: H,0 fts gA-tter

ike dissole like Conekt

HHH
GIHT DT AG Efect o Temp

foowasodol

AHT - ( Effect Of Presue

t aty
JT

[1.17]
<br>

faT (Solution)

Co,

Gas

=
4T
m
kp

cbT

[1.18]
<br>

HINT fAH (Chemistry)

m oc

m kP

P= kH gas

t ts T
fadT ( Henky Conatants &
alubility )
P = KH X gos

KH

[1.19]
<br>

fdT (Solution)

2
KH V KHe
V

Practially -
Rome

KH

K gas

4.

ET 0.195 m .195 male faT io00 gm faGrds

m
STP Standad Termbnatie &
Bessune

1 bat
P = 1 bah
o.145
Loo0 55.5
18
o.195
kH P
0.195 + 55.5
ngas
gas
ngos + nH0
[1.20]
<br>

HIYT fAlT (Chemistry)

0.195
0.195 + 55.5

=
HIHT: T
feis He

N = 56.2 o
32.1

A I-eqjsqa VapewsO presswre at tq

Jlol lolol

Closedo ConTaine
[1.21]
<br>

faT (Solution)

|SqAq Vaopows poesswDe

Closedb Constaineso

zt faerT (Aiguid folatim )

aeqafter

Raoult's Law

qsqeiter
[1.22]
<br>

HIYT fAlT (Chemistry)

Ug 1

= Vwpouso psessuoe = Vapouso psessusoe o

o
Pusoe liq,1 Pusoe
liq2

faceT
+

1
2

Pi= P'x 1

Pe = P %2 2

Pr = P+ Pe

P = Pr'cit Pi%

Kit K2 =1
=
PT P° -%2) +Pa°%2
Pr= Pi°- P'oe t P2°2
[1.23]
<br>

fa (Solution)

Pr= Pe+Pao(-xi)
PT = Rx+ Pi-Pa x?

Pr= P+% (P-P°

KIth2 = 1
Pr =Pi+Pa

P %2= 1

%I=0
Xi=1
2= 1

STaf faOLT (Tdeal. faltiemn ) sFIGT fGHT (Non -Tdeal Falitien)

Agonda
P ,
>P= P

P,
2
P, > pi A<
0

HH (+)
[1.24]
<br>

, HIYT fAlT (Chemistry)

2. A-.A B-...8 = A--8

3.
B A,B 3.

AVtoT= 0

4. AH AOT
4:
+ n

+ egT

Postive devaionu toom Raoult's Law

1 Pr> P+P2

2 Av Ve

AH
A.. A
B--B A.B
Ve
A..A, B.B > A..B

CaHs OH
CaHsOH
H C
bondo CHa
CHg CHs C = O
CaHsOH CH3

CH3 C CHs CaHsOH

[1.25]
<br>

fa (Solution)

Pr>Pi+P2

Pr> Pi+P Rxample

ccly +
CCl4 + CH, OH
CHgOH + H,o

K2=0

Megalire deiation fuom Raout's Law

+
1: Pr< P
P

Av O Ve
AH Ve
Rxample
P° HNO3 t H,0
adtone + cHCIs
CHg
Pr< RtP2 CHg
CHCI t CHy COOH
HCI +t H,o

-
Bailing Point )
Ooo

H,0
[1.26]
<br>

HIYT fAlT (Chemistry)

qsE = 100c
2

> T 1
BP

faraitt (Azeotobe ) -
Loo mL
5ml H,0
95
m
Alcohal

(R3
5 o T8° C
(351K)
c
Alcohal 78.5° (351.5k)
k )
H,0 (373

78.5 C 78°c
Lo0°c
Alcohal

H,0

[1.27]
<br>

fa (Solution)

Loo
68 m HNO
ml
3
H,0
H NO, 68%
120.5° c
H,0
H,0 100 c
c
HNO 86

86°c 120.5c
L00 C
-HNO3

H,o

) ROT
G
34HT ( + y
)

ST 74Iaster fa

(Pune alent )

1
=
2
get
1 41RJCO
[1.28]
<br>

HIYT fAlT (Chemistry)

Taot T
+
(2LT)
P, + P

P P

P, = P

a
HlcT HNT

AP = ( P°

Pf

AP=
AP =

,+
P
,
(1-x,)
= 1
[1.29]
<br>

fdT (Solution)

1-1
=
1
AP

P =
P1

AP =
=
AP
1

1
P
P
1
- Pr
p°
1
n, <<
P - P faeT

faet

r
1

[1.30]
<br>

HIYT fAlT (Chemistry)

(Relatie doserisg dn Vapour Pegsare)

A sz c
facio B
arsq
Q.
25° CLA T ajsq G 143mm of H

65 ) 100 m CU4
TIT ( cu, T HT
1.58 /cc)
po = 143

grm
0.5
Me
Odds AR = 65

l00 X 1.58
158
M,
154
P
n1 (TaeRS )
m2
M

P1 M

[1.31]
<br>

fd (Solution)

143 - atP, 0.5

65
158
143 154
143 - P, o5 X
159

143 65 X 158
141.93 mm

Qtac5 A
T B qIsIG 0.80

( MP PMT 2000 )

0.80
0.6
0.80- 0.6
0.80
0.25 Ans.

in BP )

+ stt Taqafter
fagH

111111111

(Pune fabert ) (Saltion)

Fqy-is (Boiling Poit ) !

[1.32]
<br>

HIYT fAlT (Chemistry)

factt T

fder

< M
tererar
(( Malaity
)
AT, = Kb

X 0o0

J-r44 |-( Ele vati tn Boilig Po )

[1.33]
<br>

fdT (Solution)

T
33.5k ( 100c) 2
L.01% ban (1 aHse) at
aIsqIG 1.031 ba de Et
ats Trft
,
Fqu-i5

m=
T Ky =
( Ebullasapi Cmtart )

K kg 'mal-1 Ei]
= T OHH
MA
We =
Wa 1000
X
Wa
too0 x Kb

MA

[1.34]
<br>

HIYT fAlT (Chemistry)

Tb
T°

42 L00. 065° ca
Kh = 0.53 )
Lo0°c

Loo. 065°c
T
6-
l00.065 - 10o
O.065 Ans

4.18 gm
= K X 1000

0.065
OS3
2404

342 )
[1.35]
<br>

fdT (Solution)

1,1}
= K Tacu T HR X 1o00
AT

0.071 342 25 g
!-(Depsaistion An FAuybng Pait )
fast

fEids

feirs

c m
(netear )
AT; = Kf m

[1.36]
<br>

HIYT fAlT (Chemistry)

tf

k kg mal-1 Ž| 1
faa 5T HT )
( MA
(Wa =
X 1000
MA W8
1000 X K X WA

MA X Wg
at
.
L000 X X WA
MA k x
AT, Wg
3+.2 gm

342 T GT $T k = 1.86 k kg
273 k

Lo00

= 186 Loe
243-lt X X

X Leo0 X 10
34
[1.37]
<br>

fd (Solution)

273 - 0.186 k
-0.186
Grraph

RTaROT E
RAROT GTq-(Osmosis & Osmotic Paessene )

H,o

SPM

[1.38]
<br>

HIUT fAlT (Chemistry)

sTETRIUT
oet (Serni Peimeable Membyane ( SPM)D -

SPM

QlNOT (Omoi )

(2)

M
[1.39]
<br>

fd (Solution)

(a)HHH
CoCO

3103T

SIER

[1.40]
<br>

IUT f| (Chemistry)

4RIHROT 1
(Osmais PheSSure) i
pT HGIE SPM

5T t o7TI

RRoT
A= CRT (Oinastic

T1
(lo1)
(lo|)
(io)
M

AaCT = CRT 12

-
(1sotonic, Hyþotoni & Hybetonic poltims)

C
C1=
[1.41]
<br>

fdT (Solution)

V V2 1 2
241 W M,V
MV1

a
We faeT Htr M1 T M,
faat

seitr RrHROT (Revese Omoi )

[1.42]
<br>

HIYT fAlT (Chemistry)

Ue - a

(Nal)
H0
SPM

H,0 ( Nall )Ht

(Rase Watn) + T

P-PL = %e
P9

3 m
4 CRT
A=

Nac Yat t Ce

d= 4

2CH3 CooH 1(CH3CooH> 2

[1.43]
<br>

fdT (Solution)

Cosxectior
=
P°-P i02 AT# = i K m
PP
A = iCRT

2CH, COO H
(CHs CoOH)

t=0 1 0 0
t=

|+o+o |+0+0

loo/
i=|+
=1 |
t=0 1 0 0

L=
=
1
U= l+2
|i= I+2 loo!. TeTH
[1.44]
<br>

HIYT fAlT (Chemistry)

AL + 3 CL
ALCLy

t=0 1 0 0

i= I-tt 3

|+0+O

i=I+3| loo/. falc

An nA
t=0 1 O 0
t=
i=

b-l=n-)
=-1
n-1
1
t=0 11
2

i= 1

=
1 loo/. all 1
1 U=1-1

2 CH,
CooH(CH,CooH)
1

-
U-1 = t
i-t= (-4)
[1.45]
<br>

facut (Solution) INT fdsl (Chemistry) [1]

gg RT (Objective Type Questions)

Section (A) feey feTNO AY /HIGI YE

1. yh fdiy 320 UTH

Yt 33 MTH HYIRUT
T45 |
(1) 1000 TH fdJG

(1) 13.05 % (2) 9.09 %

(3) 1
âeR fdu (4) 22.4 ler fay
(3) 9.35% (4) 9.3 gm 13. HIE H,SO4 | 1.98 UTH A 3iN 4TRITHIR
g
2. 3.0 yfifra 80g fa fdetui 98% H, SO, §,
$H HGI
[2023] (1) 2 N (2) 19.8N
(1) 0.0625 mol kgl (2) 0.00625 mol kg (3) 39.6 N (4) 98 N
(3)0.625 mol kg1
1

(4) 6.25 mol kg

g
3. 10% GaH|T AfTRTG qIt gNI 200 fdYT À (1)
lteGI (2) H1 yH
[2023] (3) fdy T R yHI (4) HtRaI
(1) 5.0 g (2) 10.0 g
(3) 20.0 g (4) 40.0 g
15. 0.1 NHNO; HIT foy 10 Mot 10 N
HNO;

4. 180 TH sT [2023]
(1) 10 (2) 100
(1) 10 fA (2) 990 fA
(3) 18 (4) 1
(3) 1000 fAf (4) 1010 ff
5. [2023]
(1) T4dGT (2) GH|H 3T4GT HaRI [2008]
(3)
TtcI (4) HlRI (1) 0.074 (2)0.00133
(3) 0.008 (4) 0.0044
6. 90 UIH sli À 1.8 UTH
(1) 0.19 (2) 0.019 [2018] 17. H; PO, F IM fa â ÍHIG : [2006]
(3)0.0019 (4) 0.00019 (1) 0.5 N (2) 1
N

7. (3) 2 N (4) 3 N

(1) 1 (2) 1.8 [2021] 18. fr, 2M NaOH fAeiyt A

feY NaOH
5 fodi
(3) 18 (4) 0.018
[2006]
8. Na,CO, 0.2 M
fd 500 fAc fy 3TqYZG (1) 10 (2) 1

HI
[2022] (3) 5 (3) 2.5
(1) 1.53 YH (2) 3.066 UTH
19. AT (YG) yl HrGI [2010, 13, 14, 16, 17]
(3) 5.3 UTH (4) 10.6 TH (1) 55.56 H/er (2) 5.556 H/le
9. 5 AcÎ N HCI, 20 Ac N 2H, SO, 3N 30 Mil N/3 (3) 0.18 HlA/er (4) 81.00 H/fler
20. 36 UTH
sli 3r 46 yrH yferT oosÍ fAU
[2017]
(1) N/5 (2) N/ 10 (1) 0.667 (2) 0.538
(3) N/ 20 (4) N/40
(3) 0.462 (4) 0.333

forY
srf Ha NaOHfAyT 25 fcf STqYUHI
21. 5 fMHA NaCl
sfdlcr 3II [2019]
(1) 5 ppm (2) 50 ug mL:!
(3) 0.25 ug mL (4) 0.066 mol mL1
(1) 32 (2) 6 (3) 128 (4) 256
11. 2.0 M CH, OH I 150 fMci faot tur ar fey
22. 8 TH NaOH, 450 fMef fayT Hel fdey
[2019)
T
CH; OH Ò
fhct U4 fAGIÀ GIT?
(1) 9.6 x 103 (2) 4.3 x 102 (1) 0.444 M (2) 0.492 M
(3) 0.0286 M (4) 0.0392 M
(3) 9.6 (4) 2.4
<br>

a
fdT (Solution) HIYT fAIT (Chemistry) [2]
Section (B) qTYGT/ ZGT H
Section (C) freuai/ qH

(1) NH,CI (2) BaSO,

[2012] (3) KNO (4)CH,COONa

(1) PbSO4 (2) BaSO,

(3) CuS (4)Cu(NO,),

(1) KNO3 (2) NaNO3

(3) oI (4) CaO

cpGT?
(1) I4 (2) faea Hpft
(3) faeiyh âT 9pfa (4) fa qUi o 3HIOIR

3eTfRT ?
(1) (2) mee
(3) t (4) Re

(1) P, PAA (2) A H, mix #0

(4) f
(3) AV
#0

(1) AS
=0 (2) AH=0 (3) 18R IHA

(3) AV,ms =0

(1) AV u =+ ve
(2) AH = - ve
(3) A-B 3IGÉUT, A-A B-B 341hcu qG
(4) A-B 3TOSUT, A-A T
B-B 3A1HGU ygi
29. Ga A
TN B yo qt 14:
(4) GYR5 T
HIGÍ fay
y
38. HG tai (Gaseous soft drinks) JUST TET
hro

(1) rHUg Ig qRISR

EI?
(1) Oz (2) N2
(3) CO: (4) CO
<br>

fatu (Solution) HIYT faIH (Chemistry) [3)

:
Section (D) YIHYU Te 48. HHRT fdy àž, G
40. fferfy t- URA TOrÍ ? [2015] (2) 3ATG fay t
(1) yo HIq (2) QYITGT
(3) 34-1GÍ fagu
(4) 4oIÍRI6
I

(3) 4IHYU I HÍhAI (4) HH qgi5 TgG

[2016]
(2) Fqut faig (1) 3ATH T
(2) 34TH
MASI
TH
(3) TNISs fdeyT (4) ATH HG GIT
(4)oyifuH Gbe faaua| [2003]
42. 273 K
qr 3
H er HIGGI AI fd T (1) qRIHRU Iq (2) Hrctr HIGAI
(3) THIAM#
U (4) TI4
(1) 67.1 (2) 678.1
(3) 77.81 (4) 778.1
[2005]
(1) THIpftF (2) H4T4yi
(3) 3ftyRTT (4) HH9RIHÝ

52. T| YgcbY (3JUrHIR 342)

T 59%
fdci, yqei X ¢
(1)
fae 4Ug

(1) 68.4 (2) 171.2 [2013]

(3) 136.2 (4) 34.2
(4) $T
Section (E) JyF TUi/ aie B5 DqcR

[2014]
x
(1) x0.08205 x 273 (2) 0.1xlx 0.08205 273 (1) 1
M KCI (2) 1
M (NH);PO4
1

(3) 1
MBaClh (4) 1
MCGHi;06
0.1 273
(3) x0.08205x 273 (4)
0.1 1
9.08205 [2020]

[2013]
(2) fay
RI
(1) P= RT /C (2) P=CT /R
(3) P= RC/T (4) P/C= RT
(1) 2 % yrut (2) 1% NaCl
(3) 2% MgCl2 (4) 1% gT
[2004]
56.
-I TUT
y# 3ryri Tuí (colligative
property) TEi ? [2003, 19]
(2) fSH5 À 3q47
(3) 4RIRU Iq (4) yo Hq

47. [2015]
(1) YRIHRUT IG (2) qrq IG
(3) f3Hc5 (4) qqeH5
(1) HH4RIHEI
(2) 3rfyRTT [2015]
qR
(3) 3+eT: y
qq
(1) 4RIRUT IG (2) 34-47
(4)
4-TeY (4) 4co1fICA HÍDYI
<br>

fai (Solution) THRJT dlT (Chemistry) [4]

[2005]
(1) yo lq
(2) YRIIRUT GI
(3) 9o1fIG qufT (4) IGI

[2005]
(1) BaCl,> NaCl > oH
(2) NaCl > BaClh > ot
> BaCl, > NaCI
(3) eorH
(4) o > NaCl > BaCl;
69. Gl T Hld fHic frei 1.86°C/MI 0.1 M
= 60)
61. qfr (3rUTHTN
T 0.6% fduT foHo HH4RrH
[2003] (1) – 1.86°C (2) -0.186°C
(1) 0.1 M KCI (2) 0.1 M qoti (3) - 0.372°C (4) +0.372°C
(3) 0.6% ch faT (4) 0.6% KCI faYT 70. j
[2010]
(1) feHis farg a¢I
(2) Fqut fdty (2) fSH5 fag H I
(3) nfUH TNIgS (3) fHc5 farg yfrafa si I
(4) qqe yfrafta T

[2013]
(1) *qgatsi (2) facilyt fHIcG 3q-44 ufI lim
yftu
(3) gaot (4) r Hbe
64. (1) yo (2) r
(1) 0.1M NaCl HeT 01M Na, SO4 [2012, 20] (3) K,
(2) 0.1M yr qT 0.1M NaCI
(3) 0.1M Rr T
0.2M MgCl;
faH# ETT (K, =1.86K Hltef)
(4) 0.1M Ca(NO3)2 TeT 0.M Na, SO4
(1) 1.86°C (2)–0.93°C
(3) –0.093°C (4) 0.093°C

(1) P =P'n, (2) P, = Pn, :

HaT (K, =1.86L HclGI )
(3) P° = Pn, (4) P,=P (n, /n,)
(1) 88.71 UTH (2) 88.71 fAuT
(3) 82 UH (4) 82 YTH
(1) sI
TI4HIH HH

ArYHUSq sITI
H
(2)
yeffa T? [2004]
(1) 1% Hlui (2) 1% Tqoti
(4) GyRI
(3) 1% NaCl (4) 1% CaCl2

(1) 0.1 M BaCl2 (2) 0.1M al

(3) 0.2 M Hh (4)0.2 M MgSO4
(4) Gyth H
<br>

Tdy (Solution) HIYT fdIT (Chemistry) [5]

20% IITafa
K
=1.86 Ì HCF À 3q47 (1) nfsy4 Íbe (2) ifsUH deRISS
sTT: (3) fRT (4) fYH TeRIS
(1) 12°C (2) 0.22°C
82.
(3) 0.11°C (4) 0.12°C

(1) a i-1 (2) a= i-1

(2) AfryH TcÌNIgS
(r+y-1) (x+y+1)
(1)
fui
(3) refrA AHISS (4) Yfg4 HeoT (3) a = (r+y-1) (4) a=ty+1)
i-1 i-1

[2009, 20]
(1) ytfr HDC (1) 1 (2) 2 [2018]
(2) HISYH GNIS (3) 3 (4) 4
(3)
RI (4) ootui
[2019]
(2) fdery HRGIT
K,[Fe(CN),1*1 ŽI (3) HIetetGII
faeyT (4) fay# HGI
(1) NaCI (2) Naz SO4
(2) Al(S0)3 (4) Al(NO:):

80. Ca (NO3)2
(1) 1
T q|re aF uF
(2) 2
- (1) 0.015 M gol (2) 0.01 M MNO3
[2018, 19]

(3) 0.015 M yryT (4) 0.01 M NazSO4

(3)3 (4) 4

Subjective Type Questions

Section (A)fo fdyo fdTYT /HIT YG

e Tr4 NT (Long Answer Type Questions)
4T (Short Answer Type Questions)
Y
Sry

Id I gg
g
94. uf fbf sî 1.25 mL TT
Bt i?

[2017]

89. 100 yTH faNH À fa oI

10
[2017] [2018]

[2018]
[2015]

=
K=39, C= 12, O
l6. [2018] [2015]

= 60)
(K=39, C1 = 35.5) [2018] HR [2016, 17]
<br>

(Solution) THIYT fAIT (Chemistry) [6]

Section (B) q<Iq/ ISeC yH
g
BriRT YT (Short Answer Type Questions)
[2017]

100. yc5
frer 93% H,SO, faT (HTR/3[YT) HldcidT

[2017]

101. 96% HRYta HT (GaHIT/GHIT ) I 3TÝG 113. t Ga A q B HHT: 145°C TeT 190°C ye Gqdt ŽI
[2011]
[2018]
114. 3TG fdot fbt pE ?

[2018]

[2020]

104. aft 122 TH

TÉi ŽgraIT À 22 urH ¢-r gh té TtA HH Long Answer Type Questions)
[2021]

[2021]
Hafaa ?

[2022]

[2014]

= 60) [2022]
(fac4T rio =0.082 fi.-arg/fsfi/)
[2016]
[2023]
[2022]

Section (C) faeytt AyH

[2023] g Jrê4 4T (Short Answer Type Questions)

(i)
liiT
(i) levGT
124. 6.56 x 10 g qe
yei Yo ÍqT fàyT ye oT

110. f=feiferi qr feuut fera [2010, 18]

(i) Hl HI
(ii) rT
(iii) HtcidI
(iv) 4I
<br>

(Solution) HIYT fdT (Chemistry) [7)

t BT4 T
(Long Answer Type Questions)

CH;OH, CH;CN, HIGeItcrH|

4.27 x 10° mm Hg I 298 K qT 760 mm Hg GIG qR

[2005]

149. rafusi (macromolecules) t i nfa UjHrRT

150. Atc YRRY (reverse osmosis) T ?

ret sr4 T
(Long Answer Type Questions)

[2014]
136. fhgTfgT vld

[2016]

Section (D) YRIHROT IG

(i) 0.1 M
oH
(i) 0.1 M iIsUH GcilNIS |

AY BTRTY A
(Short Answer Type Questions)

[2018] [2023]

138. 0°C GI qR 0.45 UTH Tglgo|i o 250 H À

R=0.0821
139. 27°C yr ytRyT
er arg/fst/H| [2018, 20]
M/10 fd yIHYU qIS ld Section (E) 3ryG yuee/ qte ais bqer
figi (R =0.0821 ir ayK ) [2023]
Ag BrY T
(Short Answer Type Questions)

2.5
er i À go CaClh (i= 247) â HIaI YRofdd
(i) IM KCI
(ii) IM rr
141. 0.1 M ch fdT, 1% yfrT fiT TT 0.1 M

[2016]
[2016]

qqe
160. BY HlddI T HqT 2003, 14]
<br>

JAT (Solution) THRJT dT (Chemistry) [8]

162. IM yaoI fa4T 1M yR facyt fhHoT

I AIyú
179. qRIHrof TUjcs ?

[2014]

[2014]

[2015]
(t fey Kh= 0.52 K
kg mol")

+
167. Na,SO, i H7 RI ET? [2016]

fifoyI (R=0.082 f. arg/fsft ) [2017]

184. ya fro A o 0.816 UH fdery at 7.5 UTH
- À

I Hlci fEHÍG 3q47 ferrS 4.90 K kg mol! TeT

e GT HT (Long Answer Type Questions)
[2016]

[2016]

K
kgmolH Ž| fAyT I fBHiH IT rfYI
[2017]
ft fHio HTt fate (cryoscopic method) I HfAA qu
186. yo ytc 4.18 yTH Ì 240 TH v ti qr

[2016] [2017]

[2009]
187. 6 YTH yr (NH,CONH,) 200 UH Vd Hldt

[2010, 17]
1.86°C HIl [2017]
[2014]

[2017]

189, vs Vc 3qTyglt ycTt I 1.5 TH, 60 TH sli

34q-47 = 1.86°C)
freo [2017]
[2016]

[2018]
<br>

dUT (Solution) HIYT fdIT (Chemistry) [9)

= 342)
[2018]
196. 17.1 YTH
HH (3UPHTR
t 100 UTH
d À

192. yc5 ly
kg sii
fdT,
À
geT ,f 12.48
373.0832
WIH
K
qR
afNy GeNIS
GGciT afRuH
1.0

[2020]

(Kb = H, =
0.52 K-kg BaCl, 3TUd GHH
208.34 WTH
Hl) [2018]

193. 0.707 yH oÁM6 10 YTH yîc Hldt [2022]

198. 0.1 M yr TeT 0.1 M NaCi faNT À fo| yRIHRUT

TeT 3TUTfaco gT (km) = 16.7º. [2023]

frrics
[2018] 199. 27°C Tq qr yRar (ryR 60) 5% (w/v) Hety
= 0.0821
194. HleT 3Hq14T RRIG K, T EI ? 2.25 UTH fa yRINyT GIG SIG I (R
T.
)
qrgsT [2023]|

[2018]

195. 2.25 UTH Toqeot (yHrR = 180) 25 yTH

[2023]

[2020]

Answer Key
tg3 YYT (Objective Type Questions)

1. (3) 2. (1) 3. (3) 4. (1) 5. (3) 6. (2) 7. (4) 8. (4) 9. (4) 10. (3)

11. (3) 12. (3) 13. (3) 14. (4) 15. (2) 16. (1) 17. (4) 18. (1) 19. (1) 20. (1)
21. (1) 22. (1) 23. (4) 24. (1) 25. (2) 26. (4) 27. (1) 28. (2) 29. (2) 30. (4)

31. (2) 32. (4) 33. (4) 34. (4) 35. (1) 36. (2) 37. (4) 38. (2) 39. (4) 40. (3)

41. (1) 42. (1) 43. (2) 44. (1) 45. (4) 46. (2) 47. (1) 48. (2) 49. (2) 50. (2)
51. (4) 52. (1) 53. (2) 54. (3) 55. (3) 56. (4) 57. (1) 58. (4) 59. (2) 60. (1)

61. (2) 62. (4) 63. (4) 64. (4) 65. (1) 66. (2) 67. (1) 68. (1) 69. (3) 70. (1)

71. (3) 72. (3) 73. (1) 74. (3) 75. (1) 76. (2) 77. (1) 78. (1) 79. (4) 80. (3)
81. (1) 82. (1) 83. (3) 84. (2) 85. (4)