17-08-2025

1001CJA101016250019 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A ball is projected from a flat horizontal floor vertically with speed v. If the coefficient of
restitution for every collision between ball and floor be 'e', the ball would finally come to rest after a
time

(A)

(B)

(C)

(D)

2) Five identical balls each of mass m and radius r are strung like beads at random and are at rest
along a smooth, rigid horizontal thin rod of length L, mounted between immovable supports as
shown in the figure. Assume 10r < L and that the collision between balls or between balls and
supports are elastic. If one ball is struck horizontally so as to acquire a speed v, the average force

felt by the support is :

(A)

(B)

(C)

(D)

3) A disk is fixed at its centre O and rotating with constant angular velocity ω. There is a rod whose
one end is connected at A on the disc and can rotate with disc. The other end is connected with a
ring which can freely move along the fixed vertical smooth rod. At an instant when the rod is making
an angle 30° with the vertical the ring is found to have a velocity v in the upward direction. Find ω of
the disk. Given that the point A is R/2 distance vertically above point O and length of the rod AB is ℓ.
(A)

(B)

(C)

(D)

4) One end of an ideal spring is fixed at point O and other end is attached to a small disc of mass m
which is given an initial velocity v0 perpendicular to its length on a smooth horizontal surface. If the

0
maximum elongation in spring is and velocity at max elongation is v then (ℓ = natural length

and k = stiffness of spring)

(A)
,

(B)
,

(C)

(D)

SECTION-I (ii)

1) A bead slides on a fixed frictionless wire bent into a horizontal semicircle of radius R0 as shown in
figure. In addition to any normal forces exerted by the wire, the bead is subjected to an external
force that points directly away from origin and depends on distance r from the origin according to
the formula :-

(A) Given force is a central force.

(B) Given force is a conservative force.

(C)
Work done by external force as bead leaves the track is .

(D)
Speed of bead as it leaves the wire is .

2) A chain of mass 'm' and length 'ℓ' rests on a rough surface table so that one of its ends hangs over
the edge. The chain starts sliding off the table all by itself provided the overhanging part equals η
(<1) part of the chain length. If the total work performed by the friction forces acting on the chain
by the moment it slides completely of the table is W and the friction coefficient between table and
chain is μ, then :-

(A)

(B)

(C)
–

(D)
–

3) A cylinder and a wedge with a vertical face, touching each other are in equilibrium as shown in
figure. The masses of the cylinder & wedge are m1 & m2 respectively. All surfaces are frictionless

then :-

(A)

(B)

(C) N1 = m1g tan α

(D) m1 = m2

SECTION-I (iii)

1) Four rods of equal length l and mass m each form a square as shown in figure. Moment of inertia

about four axes 1, 2,3 and 4 are say I1, I2, I3 and I4.

List-I List-II

(P) I1 (1)

(Q) I2 (2)

(R) I3 (3)

(S) I4 (4)

(5) None of these

(A) P → 2;Q → 4;R → 2;S → 2
(B) P → 2;Q → 2;R → 4;S → 2
(C) P → 2;Q → 2;R → 2;S → 4
(D) P → 2;Q → 4;R → 3;S → 2

2) Two blocks of masses 3 kg and 6 kg are connected by an ideal spring and are placed on a
frictionless horizontal surface. The 3 kg block is imparted a speed of 2 m/s towards left. (In list–I &

list–II instantaneous conditions is given.)

List-I List-II

When the speed of 3 kg

(P) (1)
Velocity of centre of mass is m/s.
block is m/s

When the speed of 6 kg

Deformation of the spring may be
(Q) (2)
zero.
block is m/s

When the speed of 3 kg Deformation of the spring may be

(R) (3)
block is maximum maximum.
 When the speed of 6 kg Both the blocks may be at rest
(S) (4)
block is minimum with respect to each other.

Both the blocks are at rest with

(5)
respect to ground.
(A) P → 3,4;Q → 1,2;R → 1,3,4;S → 2,3
(B) P → 1,2,3,4;Q → 1,3,4;R → 1,2;S → 1,2
(C) P → 1,3,4;Q → 2,3;R → 1,2;S → 2,4
(D) P → 2,4;Q → 1,3;R → 3,4;S → 1,4

3) In list–I a situation is depicted each of which is in vertical plane. The surfaces are frictionless.
Match these with appropriate entries in list–II.

List-I List-II

Bead is threaded on a circular fixed wire and is

Normal force on the moving
(P) (1) body is zero at the top most
point of its trajectory
projected from the lowest point

Block loosely fits inside the fixed small tube and

is protected from the lowest point
Velocity of the moving body
(Q) (2) is zero at top most point of
it’s trajectory

Block is projected horizontally from the lowest

Acceleration of the moving

(R) (3) body is zero at the top most
point of it’s trajectory

point of a smooth fixed cylinder

Block is projected on a fixed hemisphere from

Normal force on the moving
body is radially outwards at
(S) (4)
the top most point of
trajectory
angular position θ

(5) None of these

(A) P → 1,3;Q → 2,4;R → 3,4;S → 1,4
(B) P → 1,2;Q → 3,4;R → 1;S → 2
(C) P → 2;Q → 2,3,4;R → 1;S → 3
(D) P → 2,4;Q → 1,2;R → 1;S → 2,3,4

4) In the given figures two balls are dropped from height h on a wedge which is placed on smooth
surface as shown in figure. If collisions are perfectly inelastic and collisions are occur
simultaneously. Then :-
 List-I List-II

Net impulse in horizontal

direction is towards right on
(P) (1)
the wedge.

Net impulse in horizontal

(Q) (2) direction is towards left on the
wedge.

Wedge will move towards

(R) (3)
right.

(S) (4) Wedge will move towards left.

(5) Wedge remains stationary.

(A) P → 2, 4;Q → 5;R → 2,4;S → 5
(B) P → 2,4;Q → 5;R → 1,4;S → 5
(C) P → 1,4;Q → 3,4;R → 2;S → 4,5
(D) P → 1,2;Q → 2,4;R → 3,4;S → 1,2

SECTION-II

1) Two blocks of equal mass 2 kg are placed on a rough horizontal surface as shown and a force is
applied on the upper block. The system is initially at rest. Find acceleration of the lower block in

m/s2.

2) A solid uniform cylinder of mass m = 6 kg and radius r = 0.1 m is kept in balance on a slope of
inclination α = 37° with the help of a thread fastened to its jacket. The cylinder does not slip on the
slope. The minimum required coefficient of friction to keep the cylinder in balance when the thread

is held vertically is given as μ. Find the value of 4μ.

3) A uniform metre scale of mass m is suspended by two vertical string attached to its two ends as
shown in figure. A body of mass m is placed on the 80 cm mark. The ratio of tension in the strings

is . Find the value of x. (Given : )

4) Two masses, 3m kg and m kg, start simultaneously from the intersection of two straight lines with
velocities 5 m/s and 15 m/s respectively. It is observed that the path of their centre of mass is a
straight line bisecting the angle between the given straight lines. Find the magnitude of the velocity

of centre of mass (in m/s). (here θ = 74° angle between the lines)

5) A closed circular tube of average radius 15 cm, whose inner walls are rough, is kept in vertical
plane. A block of mass 1 kg just fit inside the tube. The speed of block is 22 m/s, when it is
introduced at the top of tube. After completing five revolution, the block stops at the bottom region
of tube. The magnitude of work done by the tube on the block is ______ J. [Given g = 10 m/s2]

6) Power applied to a particle varies with time as P = (3t2 – 2t +1) watt, where t is in second. Find
the change in its kinetic energy between time t = 2 s and t = 4 s.

PART-2 : CHEMISTRY

SECTION-I (i)
1) The IUPAC name of is :-

(A) 3,4-Dimethylpentanoyl chloride

(B) 1-Chloro-2,3-dimethyl-1-oxopentane
(C) 3-Methylpentane-2-carbonyl chloride
(D) 2,3-Dimethylpentanoyl chloride

2) The IUPAC name of the following compound is

(A) 1-Bromo-4-chloro-3-ethenylbutane
(B) 4-Bromo-1-chloro-3-ethenylbutane
(C) 3-(Bromomethyl)-5-chloropent-1-ene
(D) 3-(Bromomethyl)-1-chloropent-4-ene

3) A sample of iron ore, weighing 0.700g, is dissolved in nitric acid. The solution is then diluted with
water, following with sufficient concentrated aqueous ammonia, to quantitative precipitation the
iron as Fe(OH)3. The precipitate is filtered, ignited and weighed as Fe2O3. If the mass of the ignited
and dried precipitate is 0.541 g, what is the mass percent of iron in the original iron ore sample (Fe
= 56)

(A) 27.0 %
(B) 48.1 %
(C) 54.1%
(D) 81.1%

4) Select the CORRECT statement

(A) Shape of orbital is determined by magnetic quantum number

In hydrogen atom, azimuthal quantum number does not play any role in determining the energy
(B)
order of subshells.
(n + ℓ) rule is responsible for differentiating the energy of various subshells in same energy
(C)
level in single electronic system.
According to Hund's rule, electrons are distributed among the orbitals of a subshell in such a
(D)
way as to give the maximum number of unpaired electron with opposite spin.

SECTION-I (ii)

1) Which of the following is/are incorrect IUPAC names?

(A) 2-Ethyl-3-methylpentane
(B) 1-Aminobutan-1-one
(C) 2-Methyl-3-ethylpentane
(D) 4-(1,1-Dimethylethyl)-2-methylpentane

2) Which of the following statements is/are correct :

(A) 0.2 moles of KMnO4 will oxidise one mole of ferrous ions to ferric ions in acidic medium.
1.5 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to ferric ion and carbon dioxide in
(B)
acidic medium in acidic medium.
0.6 moles of KMnO4 will oxidise 1 mole of ferrous oxalate to ferric ion and carbon dioxide in
(C)
acidic medium.
1 mole of K2Cr2O7 will oxidise 2 moles of ferrous oxalate to ferric ions and carbon dioxide in
(D)
acidic medium.

3) Select CORRECT statements?

(A) Lother Meyer's curve is made between atomic volume & atomic number of elements.
For HCl molecule shrinkage in bond length will be 8.1 pm.
(B)
[EN(H) = 2.1 & EN(Cℓ) = 3.0]
(C) It is easier to add an electron in Na⊕ as compared to Li⊕
(D) The incoming electron encounters greater repulsion for F atom than for Cℓ atom.

SECTION-I (iii)

1)

List-I List-II

(P) Only 2 primary carbon atoms (1) n-butane

(Q) Atleast 1 secondary carbon atom (2) Isobutane

(R) Atleast 1 tertiary carbon atom (3) n-pentane

(S) Atleast 1 quaternary carbon atom (4) Isopentane

(5) Neopentane
Match the code
(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 3;Q → 2;R → 5;S → 4
(C) P → 1;Q → 4;R → 2;S → 5
(D) P → 2;Q → 3;R → 4;S → 5

2) Match the pair of compounds given in List-I with possible isomerism given in List-II.

List -II
List -I
Possible
Pair of compounds
Isomerism
 (P) (1) Stereoisomers

,
(Q) (2) Position Isomers

Functional
(R) (3)
Isomers

(S) (4) Chain Isomers

(5) Metamers

(A) P → 1;Q → 3;R → 2;S → 4

(B) P → 5;Q → 2;R → 4;S → 1
(C) P → 1;Q → 5;R → 2;S → 4
(D) P → 2;Q → 3;R → 1;S → 4

3)

List – I List - II

A gaseous organic compound

containing C = 52.17%, H = One mole of compound
(P) 13.04% & O = 34.78% (by (1) contains 4NA atoms of
weight) having molar mass 46 Hydrogen.
g/mol.
 0.3 g of an organic compound
containing C, H and O on The empirical formula of the
(Q) combustion yields 0.44 g of (2) compound is same as its
CO2 and 0.18 g of H2O, with molecule formula.
two O atoms per molecule.

A hydrocarbon containing C = Combustion products of one

42.857% and H = 57.143% (by mole of compound contains
(R) (3)
mole) containing 3C atoms per larger number of moles of
molecule. CO2 than that of H2O.

A hydrocarbon containing 10.5 CO2 gas produced by the

g carbon per gram of combustion of 0.25 mole of
(S) (4)
hydrogen having vapour compound occupies a volume
density 46. of 11.2 L at 1 atm and 273 K.

Combustion products of one

mole of compound contains
(5)
equal number of moles of
CO2 and that of H2O.
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 2;Q → 4;R → 1;S → 1
(D) P → 2;Q → 3;R → 1;S → 1

4)

Match the list :

List-I List-II
(Molecular species) (Structural properties)

d-orbitals with zero nodal plane used in

(P) (1)
hybridisation

(Q) (2) Non axial d-orbital is used in hybridisation

(R) IOF3 (3) Planar species

(S) (4) Nonplanar species

(5) Any bond angle ≤ 109°28'

The CORRECT option is
(A) P → 1,2,3,5;Q → 4,5;R → 1,4,5;S → 3,5
(B) P → 1,4,5;Q → 2,4,5;R → 2,4;S → 3,5
(C) P → 1,3,5;Q → 3,5;R → 1,2,4;S → 2,3,5
(D) P → 1,2,3,5;Q → 1,4,5;R → 1,3,5;S → 3,5

SECTION-II

1) Calculate total number of ester structures possible having molecular formula C5H10O2
2) If relative density of a gaseous mixture of CO2(g) and H2O(g) at 125°C and 1 atm pressure with
respect to He(g) under similar condition is 7.1, then mole % of CO2 gas in the mixture will be-

3) A hydrate of magnesium iodide has a formula MgI2 . xH2O. A 3.376 g sample is heated to a
constant weight of 2.224 g. What is the value of 10 × x ? (Mg = 24, I = 127)

4) If a mixture of Na2CO3 and NaOH in equimolar quantities when reacts with 0.1 M HCl consumes
30 ml of the acid. What will be the volume (in mL) of 0.15 M H2SO4 used in the separate titration of
same mixture ?

5) Find number of "ous" acids which have M–O–M type of linkage. [M = central atom]
H2S2O7 , H2S2O5 , , H4P2O5 , (HPO3)4 , H6P4O13 , (HNO)2 , H2S2O4

6) Among the following, total number of planar species with all equal bond lengths ?
(i) SF4 (ii) BrF3 (iii) XeF2
(iv) IF5 (v) (vi)
(vii) (viii) (ix)

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let α, β and γ be the length of sides of a triangle ΔPQR. The possible value of

is equal to (where [.] represent greatest integer function)

(A) 2
(B) 5
(C) 4
(D) 1

2) Let x, y, z are unequal even numbers then minimum value of

is

(A) 64
(B) 128
(C) 256
(D) 512

3) The value of α for which the system of equations

αx – 3y + z = 0
x + αy + 3z = 1
3x + y + 5z = 2
does not have unique solutions are

(A)

(B)

(C)

(D)

4) Suppose 'a' and 'b' are integers and b ≠ –1. If the quadratic equation x2 + ax + b + 1 = 0 has a
positive integral root, then which of the following is/are true -

(A) the other root is also a positive integer

(B) the other root is an integer
(C) a2 + b2 is a prime number
(D) None of these

SECTION-I (ii)

1) Let x, y, z are real numbers such that x, y, z ∈ and x > y > z. If x + y + z = , tanx +
tany + tanz = 5 and tanx tany tanz = 1, then

(A)

(B)

(C)

(D)

2) Consider a sequence {an} with a1 = 2 and (for all n ≥ 3, terms of the sequence being
distinct). Given that a2 and a5 are positive integers and a5 ≤ 162 then the possible value(s) of a5 can
be

(A) 2
(B) 32
(C) 64
(D) 162
3) If , |x + 1|, |x – 1| are the first three terms of an arithmetic progression then

(A) Sum of first 50 terms of the AP can be 970

(B) 50th term of the AP can be 40
(C) Sum of first 50 terms of an AP can be 2400
(D) 50th terms of the AP can be 97

SECTION-I (iii)

1) Answer the following by appropriately matching the lists based on the information given
in the paragraph
α1, α2, α3, α4 and α5 are all roots of x5 – 4x3 – 3x2 + 2x – 2 = 0.
There are some expression given in List-I whose values are given in List-II below :

List-I List-II

(P) α12 + α22 + α32 + α42 + α52 (1) 1

(Q) |(1 – α12)(1 – α22)....(1 – α52)| (2) 8

(R) |(α13 – 4α1 – 3) (α23 – 4α2 – 3)...(α53 – 4α5 – 3)| (3) 12

(S) (4) 24

(5) 48
(A) P → 4;Q → 2;R → 5;S → 1
(B) P → 2;Q → 4;R → 5;S → 1
(C) P → 2;Q → 4;R → 1;S → 5
(D) P → 2;Q → 5;R → 4;S → 1

2) Consider the set A = {x : |a2x + 1| + a2|x – a| – a3 = 1 & x ∈ R} & let n be the number of integers
in set A.
In List-I : conditions on 'n' are given.
In List-II : set of all possible values of 'a' are given corresponding to the value(s) of 'n'.

List-I List-II

(P) n≥2 (1)

(Q) n≥4 (2)

(R) n≤8 (3)

(S) n≤6 (4)

 (5)

(A) P → 1;Q → 2;R → 3;S → 4

(B) P → 1;Q → 3;R → 4;S → 2
(C) P → 1;Q → 2;R → 5;S → 4
(D) P → 1;Q → 3;R → 2;S → 5

3) Let a, b, c are sides of a triangle and a3, b3, c3 are roots of x3 – px2 + qx - r = 0 . Then, match
the following List–I with List–II

List-I List-II

(P) sin3 A + sin3 B + sin3 C + 3sinAsinBsinC = 8Δ3 (1) p = 14, q = 5, r = 8

(Q) asin2 A + bsin2 B + csin2 C = 14Δ2 (2) p = 36, q = 7, r = 27

(R) sinAsinBsinC = 2Δ3 (3) p = 9, q = 7, r = 8

(S) acos2A + bcos2B + ccos2C = 2(s – Δ2) (4)

p= , q = 5, r = 27

(5) p = 1, q = 8, r = 8
(A) P → 1,2;Q → 1,4;R → 1,3,5;S → 5
(B) P → 1,3;Q → 1,2;R → 3,4;S → 4
(C) P → 1,5;Q → 2,5;R → 3,5;S → 1,3
(D) P → 5;Q → 1,3,5;R → 1,4;S → 1,2

4) Match the following List-I with List-II

List-I List-II

If angles A, B of ΔABC are roots of equation

(P) , (1)

then C can be equal to

(Q) If where A is a angle of ΔABC then A (2)

cannot be

In a ΔABC if sin A cos B + cos A sin B sin C = 1,

(R) (3)
then angle C can be

If 16cos4x + k2 – 2k = 8cos2 x – 2 then possible

(S) (4)
values of is (where k ∈ R, x ∈ R)

(5)

(A) P → 1;Q → 2;R → 3;S → 4

(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 4;Q → 3;R → 2;S → 1

SECTION-II

1) Suppose the quadratic equation ax2 + bx + c = 0 has equal roots and 4a – 2b + c = 0, then value

of is

2) Let a, b, c be three real numbers such that and c ∈ R. If

& , then value of is

equal to

3) Let the sum of all the solutions of the equation is S, then the value
of 2S, is

4) In a triangle ABC(with usual notations), a = 5, b = 4 and then the value of

c2 is

5) Let a, b, c are positive real numbers such that a + b + c = 1, then the minimum value of

is

6) Sum of all the integral roots of , is λ then λ2 is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A B C A

SECTION-I (ii)

Q. 5 6 7
A. A,B,C B,C A,B,C,D

SECTION-I (iii)

Q. 8 9 10 11
A. A B D A

SECTION-II

Q. 12 13 14 15 16 17
A. 5 3 7 6 245 46

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. D C C B

SECTION-I (ii)

Q. 22 23 24
A. A,B,C,D A,B,C,D B,D

SECTION-I (iii)

Q. 25 26 27 28
A. C D A A

SECTION-II

Q. 29 30 31 32 33 34
A. 9 40 80 10 1 2

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. A C A B

SECTION-I (ii)

Q. 39 40 41
A. A,B,D B,D A,C,D

SECTION-I (iii)

Q. 42 43 44 45
A. B C A B

SECTION-II

Q. 46 47 48 49 50 51
A. 8 3 90 36 27 36
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct Answer (A)

2)

3)

4)

Applying conservation of angular momentum

0 0 0
mv ℓ = mv × ℓ

.... (i)

5) is a central force, because direction of force is always away from the fix

point origin & work done by this force is zero in any close loop force is
conservative
Work done by the force on bead = =

6)
fr = μN = μ (1 − x) g

7)
N2cos α = m1g N3 cos α = m2g

N2 = N3 =
also N1 = N2 sin α also N1 = N3 sin α

N1 = and N2 sin α = N3 sin a

N1 = m1g tan α N2 = N3

m1 = m2

8)

Correct Answer (A)

9)
(A)

(B)

(C)

(D)

10)

Correct Answer is (D)

11)

Correct Answer is (A)

12)

N1 = 30, fmax1 = 18
N2 = 50, fmax2 = 5

amax of lower block is = 6.5 m/s2

F – 5 = 4 (6.5)
F = 31 N since we applied 25 N

∴ block move together; a = = 5 m/s2

13) Fr – fr = 0
mg sinα – F sinα – f = 0

F=f=
F cosα + N – mg cosα = 0

N= cosα; N = ;

fmax = μN; =
μ = tanα = 0.75

14) For translational equilibrium T1 + T2 = 2mg

For rotatory equilibrium
Take torque about extreme left point = mg[0.5 + 0.8] = T2 × 1
T2 = mg × 1.3 ∴ T1 = 2mg –T2 = 0.7 mg

∴ Ratio

15)

Correct Answer is (6)

16)

ravg = 15 cm
 wf + wg = ΔKE

wf + 10 × 0.3 = × 484
wf = –245 J

17)

Wnet =
Also wnet = ΔKE

ΔKE

= [43 – 42 + 4] – [23 – 22 + 2]
ΔKE = 46J

PART-2 : CHEMISTRY

18)
2-Ethyl-3-methylbutanoyl chloride

19)

20)

Moles of Fe(OH)3 = mol

Moles of Fe =

Mass of Fe = 2 × × 56 gram
Mass % 'Fe' in original sample

=2× = 54.1%.
21)

(A) Shape of orbitals is determined by azimuthal quantum number

(B) H :- Single electronic system
(C) (n + ℓ) rule is for multielectronic system
(D) electrons are distributed with parallel spin

22)

(A) Wrong main chain

(B) It is amide
(C) Alphabetical order
(D) Wrong main chain

23) MnO4– + 5e– + 8H+ → Mn2+ + 4H2O

1 mole of MnO4– accepts 5 mole of e–
1/5 mole of MnO4– accepts 1 mole of e–
0.6 mole of MnO4– accepts 3 mole of e–
Fe2+ → Fe3+ + e–
1 mole of Fe2+ will liberate 1 mole of e–
Cr2O72– + 6e– + 14H+ → 2Cr+3 + 7H2O
1 mole of FeCr2O72– will accept 6 moles of e–
1 mole of FeC2O4 → Fe3+ + CO2 + 3e–
1 moles of ferrous oxalate gives 3 moles of e–

24) (A) Lother Meyer curve :- between atomic volume and atomic mass
(B) Shringkage in bond length :- 9(ΔEN) = 9 × 0.9 = 8.1 pm
(C) EA :- Li⊕ > Na⊕
(D) Incoming electronic goes in 2p of F & in 3p of Cl.

25)

(P) – 13; (Q) – 134; (R) – 24; (S) – 5

26)

P–2, Q–3, R–1, S–4

27)

(A) C:H:O = : : = 4 : 12 : 2 or 2 : 6 : 1
Empirical formula = C2H6O & molar mass = 46 g/mol
Molecular formula = C2H6O
C2H6O + 3O2 2CO2 + 3H2O
1 mole 44.8 L at NTP
0.25 mole (11.2 L at NTP)
(B) Mass of C in organic compound = mass of C in CO2 = × 12 = 0.12 g

Mass of H in organic compound = Mass of H in H2O = × 2 = 0.02 g

∴ Mass of O in organic compound = 0.3 – (0.12 + 0.02) = 0.16 g

∴ C:H:O = : : = 0.01 : 0.02 : 0.01 = 1 : 2 : 1

∴ Empirical formula = CH2O, but it contains 2 O atom per molecule
∴ Molecular formula = C2H4O2
1 mole of C2H4O2 contains 4 NA hydrogen atoms.
C2H4O2 + 2O2 2CO2 + 2H2O
1 mole 44.8 L
0.25 mole 11.2 L

(C) C : H = 42.857 : 57.143

= 3:x (given)
On solving, x = 4 ∴ molecular formula = C3H4
1 mole of C3 H4 contains 4NA hydrogen atoms.
Empirical formula is same as molecular formula
C3H4 + 4O2 3CO2 + 2H2O
>

(D) C: H = : = : 1 = 7 : 8 Empirical formula = C7H8

Mol wt. = 2 × VD = 2 × 46 = 92
Mol formula = Empirical formula = C7H8
C7H8 + 9O2 7CO2 + 4H2O
>

28) :- sp3d3 , pentagonal planar shape.

:- sp3 , tetrahedral
IOF3 :- sp3d , see-saw
:- sp3 , bent shape

29)

4+2+1+2=9

30)

28.40 = ⇒ x = 40%

31)
Assuming 'a' moles of MgI2.xH2O
 278 + 18x = 422
x=8

32)

m. eq. HCl = m. eq. H2SO4

30 × 0.1 = V × 0.15 × 2
∴ V = 10 ml.

33) "ous" acids :- H2S2O5 , H4P2O5 contain P-O-P linkage , (HNO)2

34) XeF2 ,

PART-3 : MATHEMATICS

35) α + β > γ, β + γ > α, γ + α + β

Also, we hence, (α + β + γ)

...(1)
using A.M. ≥ H.M.

...(2)
from (1) and (2)

36)
= (x – y)2(y – z)2(z – x)2 = 256 (Min. value)
x, y, z are unequal even numbers
|x – y| = 2, |y – z| = 2, |z – x| = 4

37)
∴ 5α2 – 6α – 11 = 0

38) x2 + ax + b + 1 = 0
α + β = –a αβ = b + 1
If one root is integer then other root is also integer.
a2 + b2 = (α + β)2 + ((αβ) – 1)2
= α2 + β2 + α2β2 + 1
a2 + b2 = (1 + α2)(1 + β2)
Thus a2 + b2 has a factor other than 1 and itself.

39) Given t1 + t2 + t3 = 5
t1t2t3 = 1

and x+y+z=

⇒ 5 – 1 = Σt1t2 – 1
⇒ Σt1t2 = 5

40) a1, a2, a3, a4, ..... are in G.P.

Let a2 = x ⇒

⇒ with common ratio

common ratio

Given ⇒x≤6

and x and are only in x, must be even and then only will be an integer
⇒

41)
C-1 x≥1

2x + 2 = –1
x = –6 (rejected)
C-2 x ∈ [–1, 1]

2x + 2 = +1–x

⇒ ⇒

S50 = 970

C-3 x ∈ (–∞, –1]

–2x – 2 = +1–x

–2x – 2 = +1

⇒ ⇒ x = –2
–1, 1, 3 ..... A.P.
T50 = –1 + 49(2) = 97

42) Let ƒ(x) = x5– 4x3 – 3x2 + 2x – 2

Σα1 = 0, Σα1α2 = –4, Σα1α2α3 = 3
Σα1α2α3α4 = 2, α1α2α3α4α5 = 2
Σα12 = (Σα1)2 – 2Σα1α2 = 8
(1 – α12) (1 – α22)...(1 – α52) = –f(1) ƒ(–1)
= –(–6)(–4) = –24
(α13 – 4α1 – 3)...(α53 – 4α5 – 3)
43) |a2x + 1| + a2|x – a| = 1 + a3
⇒ a2x + 1 ≥ 0 & x – a ≤0
For a = 0, x ∈ R

a≠0 x≥ and x ≤ a

For n ≥ 2 ; a ∈

For n ≥ 4 ; a ∈

For n ≤ 6 ; a ∈

For n ≤ 8 ; a ∈

44) a3 + b3 + c3 = p
a3b3 + b3c3 + c3a3 = q
a3b3c3 = r

(P)

(Q)

(R)

(S) a + b + c – 2 (asin2A+bsin2B+csin2C) = 2 (s – Δ2)

45) (P)

(Q) Clearly from figure , tanβ > tanα, if

(R) sin A cos B + cos A sin B sin C ≤ sin A cos B + cos A sin B

⇒ or

(S)

46) ƒ(–2) = 0 and both roots are equal so root is –2.

So SOR = –4, POR = 4

i.e. and

47) Each term independently zero

⇒ ⇒

48)
⇒
⇒ x = 9, 27
or |x – 3| = 1 ⇒ x = 2, 4
or |x – 3| = 0 ⇒ x = 3
Sum of solutions = 3 + 2 + 4 + 9 + 27 = 45

49)
⇒ ⇒ ⇒

⇒ c2 = 36

50)

Also ⇒

⇒ hence

51)
Let log5x = t
t2 + t3 + 1 – t = 1 + t
t3 + t2 – 2t = 0
t = 0, t2 + t – 2 = 0
t = 1, t = –2
log5x = 0, log5x = 1, log5x = –2

x=1 x=5
sum = 6