03/11/2023 A

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MM : 438 Thermodynamics-02201 Time : 100 Min.

Chemistry

1. The entropy change for the conversion of 36 6. The following two reactions are known
g of water to vapour at 100°C (Normal N2 (g) + 2O2 (g) → 2NO2 (g), ΔH = –Z kJ
boiling point) is (ΔHvap for H2 O = 40.63 2NO(g) + O2 (g) → 2NO2 (g), ΔH = – Y kJ
kJ/mole) The value of ΔH for the given reaction in kJ
(1) 217.8 kJK–1 is
N2 (g) + O2 (g) → 2NO(g) is
(2) 108.9 kJK–1
(1) Y–Z
(3) 217.8 JK–1
(2) –Z – Y
(4) 108.9 JK–1 (3) 2Z + Y
(4) Z+ Y
2. 1 mol of an ideal gas undergoes a change of
state from (2 atm, 3 L) to (4 atm, 10 L) with
7. 2 moles of an ideal gas is expanded
change in enthalpy (ΔH) of 40 L-atm then
reversibly from 10 atm to 5 atm at 300 K.
change in internal energy (ΔU) (in L-atm) is
Change in internal energy of the process is
(1) 6 (1) Zero
(2) 16 (2) –3.458 kJ
(3) 74 (3) +3.458 kJ
(4) 18 (4) –6.2 kJ

3. Which of the following is correct expression 8. For which of the following ΔfH° is zero?
for 1st law of thermodynamics under
(1) H2 (s)
isothermal condition?
(1) ΔU = q – w (2) C(Diamond)
(2) ΔU = w (3) S(rhombic)
(3) q = –w (4) O2 (l)
(4) q = w
9. The amount of heat required to raise the
4. If the heat of combustion of C (graphite) is – temperature of 10 g of iron from 30°C to
400 kJ/mol, then the heat released upon the 100°C is (The specific heat of iron is 0.45 J
formation of 88 g of CO2 from C (graphite) is g–1 K–1 )
(1) 800 kJ (1) 290 J
(2) 300 kJ (2) 200 J
(3) 600 kJ (3) 315 J
(4) 1500 kJ (4) 410 J

5. The amount of heat released when 0.1 M, 10. Which of the following is incorrect regarding
100 ml HCl is mixed with 0.2 M, 200 ml isothermal expansion of an ideal gas?
NaOH is (1) ΔH =0
[Given: H+ + OH − → H2 O, (2) q = 0
−1
[ΔH = −57 .1 kJ mol ] (3) ΔU = 0
(1) 0.571 kJ (4) ΔT = 0
(2) 5.71 kJ
(3) 571 kJ
(4) 0.0571 kJ
11. The change in internal energy and 18. For the combustion of solid benzoic acid at
temperature for 2 mole of ideal gas is +300 J 27°C, ΔH and ΔE are related as (ΔE and ΔE
and +5 K respectively. The molar heat are in kcal/mol)
capacity (in JK–1 mol–1 ) at constant volume (1) ΔE = ΔH + 0.3
will be (2) ΔH = ΔE + 0.3
(1) 20 (3) ΔE = ΔH – 0.6
(2) 30 (4) ΔH = ΔE + 0.6
(3) 40
(4) 60 19. If the equilibrium constant of a reaction is 2 ×
103 at 25°C then the standard Gibbs free
12. Necessary condition for a process to be energy change for the reaction will be
isochoric is (1) – 2.5R × 298
(1) ΔU = 0 (2) – 7.6R × 298
(2) ΔH = 0 (3) – 7.6R
(3) ΔV = 0 (4) – 5.1R × 298
(4) ΔT = 0
20. A process is always non spontaneous if
13. When 5 g of formic acid is burnt at 25°C, the (1) ΔH > 0 and ΔS < 0
amount of heat evolved is x kJ. Then, the ΔH
(2) ΔH > 0 and ΔS > 0
for combustion (in kJ) of formic acid is
(3) ΔH < 0 and ΔS > 0
(1) –18.4x
(4) ΔH < 0 and ΔS < 0
(2) –2.3x
(3) –9.2x
(4) –4.6x 21. Among the following, choose the one which
is not an intensive property
(1) Volume
14. What is the order of γ (=CP/CV) for the
(2) Pressure
following gases He, N2 , O3 ?
(3) Density
(1) He > N2 > O3
(4) Temperature
(2) N2 > O3 > He
(3) He < N2 < O3 22. If calorific value of CH4 is x kJ/g then the
(4) He = N2 = O3 heat of combustion of CH4 (in kJ/mol) is
(1) x
/16

15. In which of the following (2) 16x

reactions, ΔH ≠ ΔU?
(3) x
(1) C(s) + O2 (g) → CO2 (g)
(4) 16
(2) H2 (g) + I2 (g) → 2HI(g) x

(3) FeO(s) + CO(g) → Fe(s) + CO2 (g)

(4) CaCO3 (s) → CaO(s) + CO2 (g)
23. The heat of formation of AB is – 50 kJ mol–1 .
If the bond dissociation energy of A2 and B2
are 10 and 20 kJ mol–1 respectively then the
16. If for the given reaction, bond dissociation enthalpy of AB is (in kJ
2X(g) + Y(g) ⇌ X2 Y(g), at 300 K mol–1 ) is
ΔS° = 8.0 JK−1 mol−1 and ΔG° = 60 kJ mol−1 (1) 50
then ΔH° will be
(2) 20
(1) 2460 J mol–1
(3) 80
(2) 62.4 kJ mol–1 (4) 65
(3) 57.6 kJ mol–1
(4) 6.24 kJ mol–1 24. If the enthalpy of formation of N2 O(g),
N2 O4 (g), CO(g) and CO2 (g) is 800, 15, –
100, and –400 kJ/mol respectively, then ΔrH
17. In which of the following processes entropy
decreases? for the given reaction is
N2 O4 (g) + 3 CO(g) → N2 O(g) + 3 CO2 (g)
(1) Boiling of egg
(1) +90 kJ/mol
(2) stretching of rubber
(2) –115 kJ/mol
(3) Melting of ice
(3) +115 kJ/mol
(4) Thermal decomposition of CaCO3
(4) –500 kJ/mol
25. If enthalpy change for the reaction OCl2 (g) 32. A process is performed from A to B through
→ O(g) + 2Cl(g), is 420 kJ mol–1 then different paths 1, 2, 3 and 4 as shown in
average bond energy of ‘O-Cl’ bond (in figure. The maximum work is involve in
kJ/mol) will be
(1) 420
(2) 210
(3) 170
(4) 398

26. Which of the following is incorrect for a cyclic

process?
(1) ΔH = 0
(2) ΔS = 0
(3) ΔU = 0
(1) Path 1
(4) W = 0
(2) Path 2
(3) Path 4
27. 2 moles of a gas is expanded isothermally
and reversibly from 10 lit. to 50 lit at 300 K (4) Path 3
temperature. Work done during the process
is (Given log10 5 = 0.7) 33. The heat evolved by the combustion of 1.6 g
(1) – 8.04 kJ methane gas is (ΔHoC of methane is –x kJ
(2) + 12.5 kJ mol–1 )
(3) – 4.01 kJ (1) 10 x kJ
(4) + 6.2 kJ (2) x kJ
100

(3) x
kJ
28. The dissociation energy of CH4 (g) is 360 10

kcal mol–1 and that of C2 H6 (g) is 620 (4) 100 x kJ

kcal/mol. The C–C bond energy is
(1) 260 kcal/mol 34. Maximum heat will be released in which of
the following acid-base neutralisation
(2) 180 kcal/mol
reactions?
(3) 130 kcal/mol
(1) CH3 COOH + NH4 OH
(4) 80 kcal/mol
(2) HF + NaOH
(3) HCl + NH4 OH
29. In an adiabatic free expansion
(4) HCl + NaOH
(1) Q = 0
(2) W = 0
(3) ΔU = 0 35. A fixed mass `m' of a gas is subjected to
transformation of states from A to B to C to D
(4) All of these and back to A as shown in the figure.

30. What is the molar heat capacities of

isothermal and adiabatic process
respectively?
(1) ∞, 0
(2) 0, 0
(3) ∞,1
(4) 0, ∞

31. Which of the following has non-zero

enthalpy of formation? The succeeding operations that enable this
(1) Graphite transformation of states are
(2) White phosphorus (1) Cooling, heating, heating, cooling
(3) Br2 (l) (2) Heating, cooling, cooling, heating
(4) Ozone (3) Cooling, heating, cooling, heating
(4) Heating, cooling, heating, cooling
36. Standard entropy of X2 , Y2 and XY4 are 30, 42. For a sample of perfect gas when its
60 and 110 JK–1 mol–1 respectively for the pressure is changed isothermally from pi to
reaction pf, the entropy change is given by
1
X2 + 2Y2 → X Y4 ; ΔH = −40 kJ (1) p
f

2 ΔS = nR ln( )
pi
To be at equilibrium, the temperature will be
(1) 800 K (2) p
f

ΔS = nRT ln( )
pi
(2) 1600 K
(3) pi
(3) 750 K ΔS = RT ln(
pf
)

(4) 1800 K
(4) pi
ΔS = nR ln( )
pf

37. If 100 ml of 0.2 M H2 SO4 is mixed with 200

ml 0.1 M NaOH then amount of heat 43. If a reaction has ΔH = – 40 kJ and ΔS = – 62
released in above process is J/K, then this reaction would be
(1) 27.4 cal (1) Spontaneous above a certain
(2) 274 cal temperature only
(3) 13.7 cal (2) Spontaneous below a certain
(4) 137 cal temperature only
(3) Non-spontaneous at all temperatures
38. Entropy is (4) Spontaneous at all temperatures
(1) Extensive property and state function
(2) Intensive property and state function 44. The amount of heat required to raise the
temperature of 21 g of aluminium from 250 K
(3) Extensive property and path function
to 350 K is (Specific heat of aluminium is 0.9
(4) Intensive property and path function
J (°C)–1 g–1 )
(1) 1590 J
39. The enthalpy change for the reaction (2) 2010 J
13
C4 H10 (g) + (
2
) O2 (g) → 4CO2 (g) (3) 1890 J
(4) 2400 J
+ 5H2 O(g)

is 45. Which among the following is a correct

(Given: bond energy of C – C, C – H, C = O, relation for
O = O, and H – O bonds are x1 , x2 , x3 , x4
and x5 kJ/mol respectively)
(1) 3x1 + 10x2 – 6.5x4
(2) 3x1 + 10x2 – 8x3 + 6.5x4 – 10x5
(3) 3x1 + 6.5x2 + 8x3 – 10x4
(4) 3x1 + 10x2 + 8x3 – 6.5x4 + 10x5

40. Given below are the two statements.

Statement I: H – TS is a state function.
Statement II: State functions depend on the
(1) 1–b=d–c
path followed by the system.
Choose the correct answer from the given (2) a+b=d–c
options. (3) b+c=a+d
(1) Both statements I and II are correct (4) a–d==b+c
(2) Both statements I and II are incorrect
(3) Statement I is correct but statement II is 46. A : If a refrigerator's door is kept open, then
incorrect room will get heated.
(4) Statement I is incorrect but statement II R : Heat transfer from a colder body to Hotter
is correct body is a spontaneous process.
(1) Both Assertion & Reason are true and
the reason is the correct explanation of
41. For monoatomic ideal gas the value of the the assertion
ratio of CP and CV is
(2) Both Assertion & Reason are true but
(1) 5
the reason is not the correct
3
explanation of the assertion
(2) 5

2 (3) Assertion is true statement but Reason

(3) 4 is false
3
(4) Both Assertion and Reason are false
(4) 7
statements
5
47. The third law of thermodynamics deals with 53. A : Enthalpy of combustion of graphite is non
(1) Absolute entropy zero.
R : More is the calorific value, better will be
(2) Enthalpy
the fuel.
(3) Free energy
(1) Both Assertion & Reason are true and
(4) Entropy change the reason is the correct explanation of
the assertion
48. One mole of an ideal gas is allowed to (2) Both Assertion & Reason are true but
expand reversibly and adiabatically from a the reason is not the correct
temperature of 27°C. If the work done by the explanation of the assertion
gas in the process is 3 kJ, then the final (3) Assertion is true statement but Reason
temperature will be equal to (CV = 20 J/K is false
mol) (4) Both Assertion and Reason are false
(1) 100 K statements
(2) 450 K
(3) 150 K 54. Heat release during the mixing of 200 ml 0.1
(4) 400 K M H3 PO3 with 100 ml 0.1 M NaOH is
[enthalpy of neutralization of strong acid and
strong base is 13.7 kcal eq–1 and assume,
49. A reaction is spontaneous at all temperature
H3 PO3 is acting as strong acid]
when
(1) ΔH > 0 and ΔS > 0 (1) 13.7 kcal
(2) ΔH > 0 and ΔS < 0 (2) 137 cal
(3) ΔH < 0 and ΔS < 0 (3) 137 kcal
(4) ΔH < 0 and ΔS > 0 (4) 13.7 cal

50. Conversion of A to E is carried out by 55. For the reaction

following path C6 H5 COOH(s) +
15
O2 ( g) → 7CO2 ( g)
2
A ⟶B ⟶C ⟶D ⟶E
Entropy change of step B → C, is + 3H2 O(l)
(given: ΔSA → B = x, ΔSA → E = y, ΔSD → E =
z and ΔSD → C = t). . The difference between enthalpy change
and internal energy change at temperature T
(1) y+t+x–z
(K) is
(2) y+t–x+z (1) +RT
(3) y+t–x–z (2) –RT
(4) y–t+x–z (3) 3 RT
2

51. Bomb calorimeter is used to calculate (4) −

RT

(1) ΔU
(2) ΔH 56. For the reaction, A ⇌ B + C Equilibrium
(3) ΔS concentrations of A, B and C are 0.001 M,
(4) ΔV 0.15 M and 0.05 M respectively. The ΔG° for
reaction at 25°C is (log 7.5 = 0.875)
52. A : Enthalpy change when 1 mole of a (1) –11.23 kJ mol–1
substance dissolved in excess of solvent is (2) –34.61 kJ mol–1
known as hydration enthalpy.
R : Enthalpy of solvation is always positive. (3) –4.99 kJ mol–1
(1) Both Assertion & Reason are true and (4) –17.31 kJ mol–1
the reason is the correct explanation of
the assertion
57. Universe is an example of
(2) Both Assertion & Reason are true but
the reason is not the correct (1) Open system
explanation of the assertion (2) Close system
(3) Assertion is true statement but Reason (3) Isolated system
is false (4) Closed isothermal system
(4) Both Assertion and Reason are false
statements
58. Enthalpy of neutralisation of four acids A, B, 64. Calculate ΔEo for the reaction,
C and D with NaOH are –10.5, –13.7, – 5.9 CaC2 (s) + 2H2 O(l) → Ca (OH) (s)
and –12.7 kcal eq–1 respectively. Out of A, B,
2

C and D strongest acid is + C2 H2 (g)

(1) C if ΔHof(CaC = – 62. 0 kJ / mol

2)

(2) A ΔH
o
= – 286. 0 kJ / mol
f(H2 O)
(3) D ΔH
o
= – 986. 0 kJ / mol
f[Ca (OH) ]
(4) B o
2

ΔH = + 227. 0 kJ / mol
f(C2 H2 )

(1) +122.52 kJ/mol

59. In an isothermal process, entropy change for
1 mol of substance is expressed as (2) –122.52 kJ/mol
(1) ΔS = q rev
(3) +127.48 kJ/mol
2
T
(4) –127.48 kJ/mol
(2) ΔS = 2R ln
V1

V2

(3) P1 65. Assuming ideal gas Cv, m will be

ΔS = nRT ln ( )
P2 temperature independent for
(4) V2 (1) O3
ΔS = R ln ( )
V1
(2) N2
(3) CO2
60. 4 mole of an ideal gas at 17°C is expanded
(4) He
isothermally and reversibly from 5 litre to 20
litre. The entropy change in the process is
(R = 8.314 J K
−1
mol
−1
) 66. Which of the following statements is
incorrect about entropy of the gaseous
(1) 20.25 JK–1
system?
(2) 46.11 JK–1 (1) When heat is added to the system, it
(3) 15.25 JK–1 will decrease
(2) A system at higher temperature has
(4) 61.15 JK–1
greater randomness than at lower
temperature
61. A : Standard enthalpy of formation of (3) With increase in volume at constant
graphite is lower than that of diamond. temperature, its value will increase
R : Generally, standard enthalpy of most (4) Heat added to a system at lower
stable allotropic form of an element is taken temperature causes greater
to be zero arbitrarily. randomness than when the same
(1) Both Assertion & Reason are true and quantity of heat is added at higher
the reason is the correct explanation of temperature
the assertion
(2) Both Assertion & Reason are true but 67. When an ideal gas expands adiabatically
the reason is not the correct against a constant pressure, then its
explanation of the assertion
(1) Temperature always increases
(3) Assertion is true statement but Reason
is false (2) Entropy remains constant
(4) Both Assertion and Reason are false (3) Internal energy increases
statements (4) Internal energy decreases

62. Which among the following is a path 68. For which of the given reactions, the value of
function? ΔH ≠ ΔU at 25°C?
(1) U (i) H2 (g) + I2 (g) ⟶ 2HI(g)
(ii) N2 (g) + 3H2 (g) ⟶ 2NH3 (g)
(2) U+PV
(iii) 2HCl(g) ⟶ H2 (g) + Cl2 (g)
(3) H – TS
(1) (i) and (ii) only
(4) W
(2) (ii) only
(3) (i) and (iii) only
63. For the reaction, N2 H4 + H2 → 2 NH3 ,
bond energies are given as : B.E. (N – N) = (4) (i), (ii) and (iii)
x, B.E.(H – H) = y, BE (N – H) = z, then ΔH°f
(NH3 ) is
(1) x – 2z – y
y
(2) x
− −z
2 2
y
(3) z −
x
+
2 2

(4) Cannot be calculated

69. Calculate the heat produced when 56 dm3 75. Heat of neutralisation of a weak dibasic acid
of water gas (mixture of equal volumes of is found to be –25.2 kcal mol–1 . The
CO and H2 ) undergoes combustion at NTP. enthalpy of ionisation of weak acid will be
Given (1) 2.2 kcal mol–1
1
H2 (g) + O2 (g) ⟶ H2 O(g), ΔH =
2 (2) 13.3 kcal mol–1
−242kJ (3) 6.2 kcal mol–1
1
CO(g) + O2 (g) ⟶ CO2 (g), ΔH =
2 (4) 1.5 kcal mol–1
−280kJ

(1) 522 kJ
76. If a gas expands adiabatically such that
(2) 652.5 kJ
TV1/4 = constant, then the value of
(3) 1305 kJ C
p, m

(4) –1305 kJ ( ) of the gas will be

C
v, m

(1) 3

70. Find out the incorrect statement. 2

(1) At absolute zero temperature, entropy (2) 5

2
of all substances is zero
(3) 5

(2) When an egg is boiled, entropy 4

increases (4) 4

(3) One gram equivalent of all strong acids 3

give the same number of H+ ions

(4) In any natural process, the entropy of 77. A : During isothermal expansion of an ideal
universe tends towards maximum gas, w = – q.
R : Internal energy of one mole of an ideal
gas depends on temperature.
71. Select the correct statement in the following (1) Both Assertion & Reason are true and
(1) If ΔGsystem < 0, then process is non- the reason is the correct explanation of
spontaneous the assertion
(2) If ΔSsystem > 0, then process must be (2) Both Assertion & Reason are true but
spontaneous the reason is not the correct
explanation of the assertion
(3) If ΔStotal > 0, then process must be
spontaneous (3) Assertion is true statement but Reason
is false
(4) If ΔHsystem > 0, then process must be
(4) Both Assertion and Reason are false
spontaneous
statements

72. If the amount of heat required to raise

78. Standard entropies of X2 , Y2 and XY2 are
temperature of 2 mole monoatomic ideal gas
by 1°C at constant pressure is 10 cal, then 60, 40 and 50 J K–1 mol–1 respectively. If the
change in internal energy of gas is (R = 2 reaction
cal/K-mol) 1
X2 (g) + Y2 (g) → X Y2 (g) ⋅ ΔH = −20kJ
2
(1) 6 cal to be at equilibrium, the temperature should
(2) 12 cal be
(3) 9 cal (1) 500 K
(4) 3 cal (2) 650 K
(3) 800 K
73. The work done in an open vessel at 400 K, (4) 1000 K
when 0.56 g iron reacts with dilute HCl is
(1) 8 cal 79. The heat of neutralisation of NaOH and
(2) 12 cal CH3 COOH at 25°C is –54.1 kJ mol–1 . The
(3) 16 cal heat of ionisation of CH3 COOH will be
(4) 4 cal (1) 3 kJ
(2) 11.2 kJ
74. The enthalpies of solution for copper (3) 57.1 kJ
sulphate pentahydrate and anhydrous (4) 5 kJ
copper sulphate are respectively –x and –y
kJ mol–1 . The hydration enthalpy of
anhydrous copper sulphate (in kJ mol–1 ) is
(1) (x–y)
(2) (y–x)
(3) –x–y
(4) (x + y)
80. 1 mol ideal monoatomic gas at 27°C and at 84. Rajat was studying the effect of pressure on
1 atm pressure expanded adiabatically volume of a fixed mass of gas at a constant
against 3 atm pressure then select the temperature. Following were his
correct option for this process. observation. The observation which is odd
(1) Q ≠ 0 one as per Boyle’s law is?
(2) Δ U = 0 (1) 5 L, 3 atm
(3) Δ H = 0 (2) 2.5 L, 6 atm
(4) Final temperature becomes 540 K (3) 3 L, 5 atm
(4) 3.5 L, 6.5 atm
81. The entropy change for the conversion of 36
g water to vapour at its boiling point at 1 atm 85. The heat liberated when 1.5 g benzoic acid
is is burnt in bomb calorimeter at 25°C
(Enthalpy of vaporization for water is 40.63 increases the temperature of 17.27 kg of
kJ mol–1 ) water by 0.55°C. The heat of combustion of
(1) 218 JK–1 benzoic acid is
(Specific heat of water at 25°C is 0.998 cal
(2) 319 JK–1 g–1 deg–1 )
(3) 619 JK–1 (1) 670 kcal/mol
(4) 602 JK–1 (2) 981 kcal/mol
(3) 840 kcal/mol
(4) 771 kcal/mol
82. N2 (g) + 2O2 (g) →2NO2 (g) + X kJ
2NO(g) + O2 (g) → 2NO2 (g) + Y kJ
Enthalpy of formation of NO (in kJ mol–1 ) is 86. From the following bond energies
(1) (X−Y) H–H bond energy : x kJ mol–1
2 C­­=C bond energy : y kJ mol–1
(2) 2X – 2Y C–C bond energy : z kJ mol–1
(3) X+Y C–H bond energy : u kJ mol–1
2
Enthalpy for the reaction (in kJ mol–1 )
(4) 1
(Y − X) CH3 –CH=CH2 + H2 → CH3 –CH2 –CH3 , will
2

be
(1) 2y + x – z
83. The curve which most likely represents
reversible adiabatic and reversible (2) y + x – 2u – z
isothermal expansion are (3) y + x + 2u+ z
(1) (4) 2y + x – 3u + z

87. If the enthalpy of hydrogenation of

cyclohexene is – x kJmol–1 and resonance
energy of benzene is – y kJmol–1 then
enthalpy of hydrogenation of benzene in
(2) kJmol–1 will be
(1) (– x – y)
(2) (– 3x – y)
(3) (– 3x + y)
(4) (x + y)

(3) 88. If the heat of combustion of carbon (graphite)

is – 400 kJ/mol, then the heat released upon
the formation of 22 g of CO2 from carbon
(graphite) and oxygen is
(1) 100 kJ
(2) 200 kJ
(3) 400 kJ
(4) (4) 800 kJ
89. If the enthalpy of fusion of a compound is 49 95. Heat of combustion of carbon is –x kJ mole–
kJ mol–1 at 77°C then the molar entropy 1
, heat of formation of water is –y kJ mole–1
change for the melting of the compound is and heat of combustion of propane is –z kJ
(Melting point of compound = 77°C) mole–1 . The heat of formation of propane
(1) 75 J mol–1 K–1 per mole will be
(2) 140 J mol–1 K–1 (1) (z – 3x – 4y)kJ
(3) 80 J mol–1 K–1 (2) (3x + 4y – 2z)kJ
(3) (–x –y + 2)kJ
(4) 120 J mol–1 K–1
(4) (z – x – 2y)kJ

90. In which process, entropy increases?

96. Human body is an example of
(1) Sublimation
(1) Open system
(2) Condensation
(2) Closed system
(3) Polymerisation
(3) Isolated system
(4) Crystallisation
(4) Closed isothermal system

91. If enthalpies of combustion of glucose, C(s)

and H2 (g) are –x kJ, –y kJ and –z kJ 97. If ΔH°fus of a substance is ‘a’ and ΔH°sub is
respectively then enthalpy of formation of ‘b’, then ΔH°vap will be
glucose is (1) a + b
(1) x – 6y – 6z (2) 2(a + b)
(2) –6z – 6y – x (3) 2a – b
(3) x + 6y – 6z (4) b – a
(4) x + 6y + 6z
98. A : CP – CV = R (where R = gas constant)
92. Which of the following statement(s) is/are R : CP = SP × Formula mass(where SP
correct? =Specific heat capacity at constant pressure)
(1) Entropy for a spontaneous process (1) Both Assertion & Reason are true and
increase till it reaches maximum. the reason is the correct explanation of
(2) At equilibrium the change in entropy is the assertion
zero (2) Both Assertion & Reason are true but
(3) Free energy change of a chemical the reason is not the correct
reaction allows predication of the explanation of the assertion
spontaneity of the chemical reaction. (3) Assertion is true statement but Reason
(4) All of these is false
(4) Both Assertion and Reason are false
statements
93. A : ΔU (= q + w) depends only on initial and
final state.
R : Both q and w are state function. 99. Enthalpy change of which reaction,
(1) Both Assertion & Reason are true and represents enthalpy of formation?
the reason is the correct explanation of (1) H2 (g) → 2H(g)
the assertion
(2) H2 (g) + Cl2 (g) → 2HCl(g)
(2) Both Assertion & Reason are true but
the reason is not the correct (3) H2 (g) + l2 (s) → 2Hl(g)

explanation of the assertion (4) C(graphite) + O2 (g) → CO2 (g)

(3) Assertion is true statement but Reason
is false
100. If for a process ΔH and ΔS respectively are –
(4) Both Assertion and Reason are false
20 kJ/mol and 200 J/K-mol then at what
statements
temperature reaction will be spontaneous?
(1) 100 K
94. In which of the following process entropy (2) 120 K
decreases?
(3) 90 K
(1) Vapourization of water
(4) All of these
(2) Melting of ice
(3) Crystallization of potash alum from
solution
(4) Boiling of egg
101. Enthalpy change of combustion of toluene 106. A : Heat of neutralisation of a strong acid by
(C7 H8 (l)) at 300 K is –3910 kJ mol–1 . The a strong base is a constant value.
value of ΔU for the combustion of one mole R : When 1 mole of H2 SO4 is mixed with 2
of toluene at 300 K is moles of NaOH, heat produced will be –57.3
kJ.
(1) –7810 kJ
(1) Both Assertion & Reason are true and
(2) –3905 kJ
the reason is the correct explanation of
(3) –1950 kJ the assertion
(4) –975 kJ (2) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
102. Out of the following, choose an extensive
property. (3) Assertion is true statement but Reason
(1) Boiling point is false
(2) E.M.F of cell (4) Both Assertion and Reason are false
statements
(3) pH of the solution
(4) Entropy
107. A : Ice cubes in thermos flask is an example
of an isolated system.
103. A : For adiabatic irreversible process R : A system is said to be open if it can
ΔSsystem = 0. exchange energy as well as matter with the
R : Adiabatic irreversible process is an surrounding.
isoentropic process. (1) Both Assertion & Reason are true and
(1) Both Assertion & Reason are true and the reason is the correct explanation of
the reason is the correct explanation of the assertion
the assertion (2) Both Assertion & Reason are true but
(2) Both Assertion & Reason are true but the reason is not the correct
the reason is not the correct explanation of the assertion
explanation of the assertion (3) Assertion is true statement but Reason
(3) Assertion is true statement but Reason is false
is false (4) Both Assertion and Reason are false
(4) Both Assertion and Reason are false statements
statements
108. A : Heat of neutralisation of HF when
104. A : The ionization of NH4 OH is suppressed neutralised with strong base is –13.7 kcal
on addition of NH4 Cl. eq–1 .
R : A mixture of NH4 Cl and NH4 OH acts as a R : HF is very strong acid.
buffer around pH 9.25. (1) Both Assertion & Reason are true and
(1) Both Assertion & Reason are true and the reason is the correct explanation of
the reason is the correct explanation of the assertion
the assertion (2) Both Assertion & Reason are true but
(2) Both Assertion & Reason are true but the reason is not the correct
the reason is not the correct explanation of the assertion
explanation of the assertion (3) Assertion is true statement but Reason
(3) Assertion is true statement but Reason is false
is false (4) Both Assertion and Reason are false
(4) Both Assertion and Reason are false statements
statements
109. A : Temperature of the system remains
105. A : Energy released during neutralisation of constant during adiabatic expansion.
HF with one mole of NaOH is greater than R : Temperature and volume are intensive
57.1 kJ. properties.
R : F– has higher hydration energy due to its (1) Both Assertion & Reason are true and
small size. the reason is the correct explanation of
the assertion
(1) Both Assertion & Reason are true and
the reason is the correct explanation of (2) Both Assertion & Reason are true but
the assertion the reason is not the correct
explanation of the assertion
(2) Both Assertion & Reason are true but
the reason is not the correct (3) Assertion is true statement but Reason
explanation of the assertion is false
(3) Assertion is true statement but Reason (4) Both Assertion and Reason are false
is false statements
(4) Both Assertion and Reason are false
statements
110. A : All naturally occurring processes i.e.
spontaneous proceed spontaneously in a
direction which leads to decrease of Gibbs
energy.
R : ΔG for melting of ice at –18°C is zero.
(1) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion
(2) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
(3) Assertion is true statement but Reason
is false
(4) Both Assertion and Reason are false
statements

111. A : Work and heat appear only during a

change in state
R : Work and heat are state functions
(1) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion
(2) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
(3) Assertion is true statement but Reason
is false
(4) Both Assertion and Reason are false
statements