Date 01/02/2022

SAFETY DATA SHEET

Version01

ENAEX PERU
NCh 2245 - 2021

IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND THE COMPANY

SECTION I:
THE COMPANY
TRADE NAME OF Rapid expansion metallic mix: PLASMA BULK, PLASMA 600D,
PRODUCT PLASMA1000D, PLASMA LARGER DIAMETER.
INTERNAL CODE HDS-PLASMA-01
RECOMMENDED USE Fracturing rock, for applications in Civil Works, Open Pit Mining and
Subterranean.
SUPPLIER NAME ENAEX Servicios S.A.
DIRECCIÓN DEL PROVEEDOR Enaex Punta Teatinos s/n, Km 484 La Serena.
PHONE NUMBER OF +56228377400
SUPPLIER
E-mail enaex@[Link]
EMERGENCY PHONE NUMBERS +56 2 2837 7700

SECTION 2: IDENTIFICATION OF THE HAZARD OR HAZARDS

SGA Pictogram
The Globally Harmonized System of Classification and Labeling of Chemicals - GHS (its acronym in English
GHS (Global Harmonized System) is a comprehensive international risk communication system.
whose compliance becomes mandatory in the workplace.

Classification according to SGA.

Specific toxicity in target organs; lungs, kidneys, liver (repeated exposure)
Classification
Category 2.
Ocular irritation, Category 2A.
Specific toxicity in certain organs – repeated exposures, Category 2.
Aquatic toxicity, long term, Category 1, chronic 1
ATTENTION
Word of H228: Flammable solid category 1.
warning H319 Causes serious eye irritation.
Indications of H302: Harmful if swallowed.
danger H373: May cause damage to the kidney with prolonged or repeated exposure in case of
ingestion.

H410: Very toxic to aquatic life with long lasting effects.

P260: Do not breathe dusts or mists.

Page 1 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

Wash hands and face carefully after handling.

P270: Do not eat, drink or smoke while handling this product.
Advice from Do not disperse in the environment.
prudence Use eye/face protection equipment.
P301+P312+P330 IN CASE OF INGESTION: Call a CENTER OF
TOXICOLOGY/doctor if the person is feeling unwell. Rinse the mouth.
P305+P351+P338 IN CASE OF CONTACT WITH EYES: Rinse with water
cuidadosamente durante varios minutos. Quitar las lentes de contacto cuando estén
presents and can be done easily. Proceed with the washing.
P337+P313 If irritation persists, consult a doctor.
P391 Collect the spills.
P501 Dispose of the contents/container in accordance with D.L 1278 Decree
Legislature approves the Comprehensive Solid Waste Management Law

Description of Causes severe eye irritation (conjunctivitis), harmful if ingested, generates irritation to
dangers the mucous parts. Toxic to aquatic organisms with lasting harmful effects.

Efectos cancerígenos: No disponible. Efectos mutágenos: No disponible. EFECTOS

TERATOGENIC: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is
Description of
toxic to the lungs. Repeated or prolonged exposure to the substance can cause
specific dangers
target organs. Repeated exposure to a highly toxic product can cause deterioration
general health due to accumulation in one or several human organs.

SECTION 3: Composition / Information on the Components

Systematic Chemical Name Not applicable

(IUPAC)
Common or generic name Rapid expansion metal alloy "PLASMA"
Number NU 3089
IN CASE OF MIXTURE
Hazardous components of the mixture Sodium Nitrate, Ferric Oxide, Aluminum, Magnesium, Copper Oxide
Component 1 Component 2 Component 3 Component 4 Component 5
Denomination
Sodium nitrate Al Mg CuO
Chemistry
Common name Powder of Scale of
Nitrate of
aluminum metals Magnesium Oxide of
sodium
metallic ferrous copper

Page 2 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

Range of
20%-40% 5%-30% 20%-40% 1%-30% 1%-30%
Concentration
CAS Number 7631-99-4 7429-90-5 65996-74-9 7439-95-4 1317-38-0
Number NU 1498 1309 ---------- 1418 3077

SECTION 4: FIRST AID

Remove it from the exhibition, move it immediately to a ventilated area and get
Inhalation
medical attention.
Wash the skin with plenty of water for at least 15 minutes and remove all clothing.
Contact with the skin and contaminated shoes. If necessary, call a doctor. Wash and dry
meticulously the contaminated clothes and shoes before using them again.
Rinse the eyes with plenty of water for at least 15 minutes. Call a
Eye contact doctor immediately.
Ingestion Rinse the oral and nasal cavity several times with water, call the doctor immediately.
Do not induce vomiting.

Symptoms/effects more Effects of chronic overexposure (long term). Medical conditions that
important will be aggravated by exposure to the product "There is no information
available.
Expected lagging effects, Causes serious eye irritation. Harmful if ingested.
symptoms/effects more
important

Protection of those who provide Gloves, personal protective glasses, in case of ingestion, evaluate the onset of
first aid, notes therapy irritating product in contact with pathways and mucous membranes.
specific for the doctor Do not induce vomiting.
dealer

SECTION 5: FIRE FIGHTING MEASURES

Multi-purpose dry chemical powder (ABC), carbon dioxide or
Extinction agents
Arena.
Extinction agents Water.
inappropriate
Products that are formed in the
combustion and degradation There isn't.
thermal
Specific dangers associated About a temperature of 150°C spontaneous generation of thermal energy, reaction
thermochemistry.

Page 3 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

Specific methods of The standards in firefighting work.

extinction
Precautions for personnel Avoid inhalation of material or products derived from combustion Oxide of
in case of emergency and/or the reduction, N2. The combustion that occurs is a chemical reaction of
firefighters reduction-oxidation, in which a large amount of energy is generally released
energy, in the form of heat and light, manifesting visually as fire.

SECTION 6: MEASURES TO BE TAKEN IN CASE OF SPILL

ACCIDENTAL
Avoid the following cases:
Personal precautions
Direct contact with the substance (Use of personal protective equipment)
Protective suit, polyethylene gloves, safety shoes,
I use a half mask with a P-100 filter for fine dust only. in case
of direct contact with the substance.
Protective equipment and
Clean the area in a way that does not disperse dust into the air.
emergency procedures
Introduce the substance in a closed and dry environment. In case the material
be humid, let dry in a ventilated place and then introduce into a
closed and dry container.
Precauciones Collect the waste in a dry form. Never pour the product down drains or
environmental sanitary systems. This must be removed according to Section 13.
Methods and materials of Contain with sand walls or another mechanical system. Collect the product with
containment, confinement and/or a shovel and confine in a closed and dry container.
depression
Methods and materials of Collect manually. Do not rinse with water or aqueous cleaning agents. No
cleaning I used the vacuum cleaner. The dust deposits on the shelves, flat surfaces and
Recovery Overhead beams that cannot be avoided should be cleaned regularly. Do not allow
Neutralization let the dust accumulate.
Final disposition
Additional measures of No information available.
disaster prevention

Page 4 of 10
 Fecha01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

SECTION 7: MANIPULATION AND STORAGE

Precautions for the Carry out the appropriate handling to ensure that the containers do NOT break.
safe handling they contain the mixture. Avoid the formation of dust clouds. Avoid the formation of
dust. Dust deposits on shelves, flat surfaces, and overhead beams
that cannot be avoided, must be removed regularly. Do not allow the
deposits accumulate. Use appropriate protective clothing. Handle away from
incompatible materials, such as oxidizing agents, acids, alkalis, water.

Operational measures and Store in a cool, dry, and ventilated area. Protect against damage from impacts.
techniques for prevention of friction. Do not expose to flame, heat, sparks and do not handle in the presence of
exhibition thunderstorms.

Other precautions
Prevention of contact with Store separately from strong oxidizers, metal oxides, strong bases, and acids.
incompatible substances strong.
Storage of the mixture in its transport boxes, a warehouse or container,
always protecting from environmental conditions (humidity, heat, and radiation
Conditions for the solar).
secure storage Store in a dry place and not outdoors, the product is flame-sensitive.
friction, impacts with ferrous materials, electrical storms or electric sparks.

Substances and mixtures Store away from incompatible materials, such as oxidizing agents,
incompatibles acids, alkalis, water.

Packaging and wrapping materials Without limitations, that are solid and stable
recommended

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Maximum concentration Aluminum AL Nitrate of Scales of Producto terminado
permissible sodium NaN03 metals plasma
Ferrous
Aluminum Al 5 mg/m3 OSHA TWA (respirable fraction)
15 mg/m3 OSHA TWA (total dust)
5 mg/m3 OSHA TWA (pyrotechnic dusts)
10 mg/m3 ACGIH TWA (metallic particles)
Sodium nitrate NaNO3 DS. 594: 8 mg/m3 (total dust); 2.4 mg/m3 (respirable dust) Substance no
specified
Iron Metal Scales TWA: 0.2 (mg / m3) from ACGIH [1995] Consult the responsible parties
places of acceptable exposure limits.
TWA: 5 (mg (Al) / m) of ACGIH (TLV) [United States] Inhalation (pyro dusts,
welding fumes) TWA: 10 (mg (Al) / m) from ACGIH (TLV) [United States]

Page 5 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

Finished product Plasma Inhalation (metal dust) Consult local authorities about the limits
of acceptable exposure.
Personal protective elements
Half-face mask with P-100 filter for fine dust only in case of
Respiratory protection
direct contact with the substance, for example, when transferring, spills, etc. For
the handling of packaged loads does not require an element of
personal respiratory protection
Hand protection Use gloves.
Eye protection Hermetic lenses
Skin and sun protection Jumpsuit or regular work clothes
body
Engineering measures Not applicable.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical state Solid
Appearance, color, smell Gray powder without odor
Concentration Not applicable

pH 6.5–7.5 * sample: H2O = 5 (v/v)

Combustion temperature Without spontaneous combustion below 150 °C
spontaneous
Flash point: No focus occurred below 93ºC (method of
Flash point quick balance
Burning time: < 5 minutes at 20ºC (UN TDG test and criteria
Test N1)
Burning time/Test Burning time: <5 minutes at 20°C, * Wet area: approved
of speed
Flammability limits 680 °c
Vapor pressure Not applicable because it is a solid

Density of vapor Not applicable as it is a solid

Minimum density 0.6 g/cm³
Solubility in water Insoluble at 20°C without danger of reaction with water at 20°C, Gas emission rate:
0 L/kg.h

Page 6 of 10
 Fecha01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

SECTION 10: STABILITY AND REACTIVITY

Chemical stability Stable solid under normal conditions of use, storage, and transport, in
abnormal conditions can intensify the fire.
Dangerous reactions Does not polymerize.
Conditions that must be Avoid environments saturated with humidity, direct sunlight, heat, flames, and sparks.
avoid Avoid inhalation of steam, mist, or dust.
Materials / substances Fuels, strong oxidizing agents, strong acids.
incompatibles
Hazardous products of the Nitrogen oxides
decomposition
If the Plasma mixture comes out of its cartridge container and comes into contact with water,
Hazardous products of the undergoes very slow oxidation with the possibility of generating flammable hydrogen gas.
combustion

Intended use and misuse Do not apply high voltages, sparks, friction or blows with ferrous material and flames.

Security measures when Whenever it is necessary to discover a load without starting with mechanized equipment
discharge plasma loads without (shovel, backhoe, etc.) the area must be delineated and access restricted to
start people in a safety radius of 50 meters.

Security measures during During the extraction of fractured material with mechanized equipment (shovel,
the extraction of the material backhoe, etc.) There should be no people within a radius of less than 50 meters.
fractured Do not pierce, cut, or impact the cartridges without starting with some material.
electric, drill or pneumatic rock pick, drill, etc.

SECTION 11: TOXICOLOGICAL INFORMATION

Acute toxicity (LD50, LC50): Oral rat LD50: >2,000 mg/kg *from US NLM/ECHA
Rabbit skin LD50: no information available
Inhalation rat LC50: no information available.
Skin irritation / corrosion Slightly hazardous on contact with skin (Irritant)
Severe eye injuries / eye irritation Severe eye irritation.
Respiratory or cutaneous sensitization It irritates the mucous membranes of the respiratory system.
Mutagenicity of reproductive cells / in No relevant data available.
in vitro
Carcinogenicity No relevant data available.
Reproductive toxicity, specific to organs No relevant data available.
particulars, unique exposure, repeated
Danger by inhalation Chronic exposure to dust can cause coughing disease
chronic obstructive pulmonary disease, pneumoconiosis.

Page 7 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Versión01

ENAEX PERU
NCh 2245 - 2021

SECTION 12: ECOTOXICOLOGICAL INFORMATION

No relevant data is available.
Ecotoxicity (EC, IC, and LC)
Persistence and degradability The degradation products are less dangerous than the same product.
Potential bioaccumulation It can be toxic to sensitive aquatic species.
Mobility on land No relevant data available.

SECTION 13: INFORMATION RELATING TO THE REMOVAL OF SUBSTANCE OR

MIXTURE
Waste For being a critical controlled chemical substance regulated by the Regulation
Complementary No. 83 of Law No. 17.798, on Control of Arms and Elements
Similar, these waste products must be disposed of as stipulated by the Authority.
Inspector of the DGMN, Article 261 Regulation No. 83.
Packaging and wrapping There is no special treatment. Due to being a controlled chemical substance by the
contaminated Complementary Regulation No. 83 of Law No. 17,798 on Arms Control
Similar Elements, these waste materials must be disposed of as stipulated by the
Oversight Authority of the DGMN
Contaminated material There is no special treatment. Because it is a chemical substance controlled by the
Complementary Regulation No. 83 of Law No. 17,798 on Arms Control
Similar elements, these residues must be eliminated as stipulated by the
Oversight Authority of the DGMN
Prohibition of discharge into waters No information.
residual

SECTION 14: INFORMATION RELATING TO TRANSPORT

Modalidad de Transporte
Terrestrial Maritime Air
Regulations NCh 2190 NCh 2190 NCh 2190
N° NU 3089 3089 3089
Official designation of Flammable Metal Powder Flammable Metal Powder Flammable Metal Powder
transport N.E.P N.E.P N.E.P
Danger classification 4 4 4
primary NU
Hazard classification 4.1 4.1 4.1
secondary NU
Packaging/Container Group II II II
Environmental hazards Toxic to aquatic organisms with long-lasting harmful effects.

Page 8 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

Identification badge of
danger according to NCh2190

Environmental hazards - Yes -

Bulk transport (MARPOL - International Maritime Organization. MARPOL: Articles, protocols, annexes,
972 73/78- Annex II-; IBC unified interpretations of the International Convention for the Prevention of
Code) Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto,
consolidated edition. IMO, London, 2006.
International Maritime Organization. IBC code: International code for the
construction and equipment of shipping carrying dangerous chemicals in bulk: With
Standards and guidelines relevant to the code. IMO, London, 2007.

SECTION 15: INFORMATION ABOUT REGULATIONS

Law 17.798; DS No. 83, DS No. 298 and its amendments from the MTT, D.S No. 594 and
National regulations its modifications by the MINSAL; D.S 40, Exempt Resolution 3048 of the DGMN,
NCh 2190, 382, 2245, 1411/4
United Nations. Recommendations on the Transportation of Goods
Dangerous, eighteenth edition.
International Regulations United Nations. Manual of Tests and Criteria, fifth edition.
United Nations. Globally Harmonized System of Classification and Labeling
of Chemical Products (SGA).

Page 9 of 10
 Date 01/02/2022
SAFETY DATA SHEET
Version01

ENAEX PERU
NCh 2245 - 2021

SECTION 16: OTHER INFORMATION

La información relacionada con este producto puede no ser válida si éste es usado en combinación con otros
materials.

Abreviaturas y acrónimos; LPP: Límite permisible ponderado; LPT: Límite permisible temporal; LD: Dosis letal; LC:
Lethal concentration. GHS: Globally Harmonized System of Classification and Labeling of Products
Chemicals.
References
The information provided on this sheet is the currently known information on the subject. It should be followed
faithfully the safety recommendations for handling, transportation, and storage.

Safety signal
(NCh1411/4)

Creation date JANUARY 2022 Next review date DECEMBER 2023

Change control Creation and drafting of the HDS according to NCh2245–2021

The data provided in this information sheet was obtained from reliable sources. The opinions expressed
this form is for trained professionals. The information provided in it is currently
known about the subject.
Considering that the use of this information and the products is beyond the control of the supplier, the Company does not
assume any responsibility for this concept. Determining the safe usage conditions of the product is
user's obligation.

Page 10 of 10