I couldn't find answer to this question so I tested myself.
I think it's worth noting:
<?php
use ExistingNamespace\NonExsistingClass;
use ExistingNamespace\NonExsistingClass as whatever;
use NonExistingNamespace\NonExsistingClass;
use NonExistingNamespace\NonExsistingClass as whatever;
?>
None of above will actually cause errors unless you actually try to use class you tried to import.
<?php
// And this code will issue standard PHP error for non existing class.
use ExistingNamespace\NonExsistingClass as whatever;
$whatever = new whatever();
?>