If you need convert function arguments without default default values and references, you can try this code:

<?php
    $func_args = '$node, $op, $a3 = NULL, $form = array(), $a4 = NULL'
    $call_arg = preg_match_all('@(?<func_arg>\$[^,= ]+)@i', $func_args, $matches);
    $call_arg = implode(',', $matches['func_arg']);
?>
Result: string = "$node,$op,$a3,$form,$a4"