PERANCANGAN CONDENSER PARTIAL :

Downtherm Q in

T1 = 80 oC

Downtherm out
Gas input kondenser:

Komponen
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
Total:
Kondisi Operasi :
Pin
=
Th1
=
Th2
=
tc1
=
tc2
=

Kg/jam
14.69620252
5.545736801
5049.267108
2679.285174
1133.780379
8882.5746
3
45
-10
-30
0

atm
oC
oC
oC
oC

Kmol/jam (Fi)
0.291013911
0.078108969
59.5432442
22.42079643
7.362210252
89.69537376

318.15
263.15
243.15
273.15

xi
0.00324447
0.000870825
0.66383852
0.249966029
0.082080156
1

BM
50.5
71
85
119.5
154

K
K
K
K

Type condenser :
Shell and Tube
(Acuan, kern hal 285)
coba HE 1 - 4 PASS
Shell side:
Tube Side:
ID=
23.1/4 (in)
23.25
Number
352 (for 4 passes)
Baddle space=
12 in
length
16 ft
Passes=
1
OD=
0.75 in
BWG:
16
PITCH:
1 in tri
passes
(n) :
4
Heat Balance:
Gas in :

Qd m cp (Tin Tout )

m=
Cp gas=
Tin=

massa campuran gas masuk =

0 KJ.Kmol/K
318.15 K

0.025579 kmol/s

92.0847 kmol/jam

Tout=

263.15 K

Qd =
0 KJ
=
Mencari entalpi untuk gas dan steam:
Entalpi Gas :

0 Btu/jam

T2 = 26.99 oC

BM
50.5
71
85
119.5
154

BM Mean
0.163845713
0.061828571
56.42627423
29.87094051
12.64034399
99.16323301

18

Kondensor CD-01

Tugas :
Jenis :
Dasar Perencanaan :
rate uap
Suhu gas masuk (dew point)
Gas keluar
tekanan operasi 1 atm

Mengembunkan gas hasil keluar absorber

Shell and tube HE

Campuran gas masuk kondensor:

8882.5746 kg/jam
Gin =
45 oC
Tin (dew point) =
0.220553156 atm
Pin =
Fasa :

2.467381833

Keseluruhan arus dalam fasa gas

Komponen

Kg/jam

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
Total:

14.6962
5.5457
5049.2671
2679.2852
1133.7804
92.3242
8882.5746

Kesetimbangan komponen - komponen pada condenser :

Kondisi Operasi =
P=
3.13055 atm
T=
-35
oC =
238.15
238.15

Komponen

Kg/jam

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
Total:

14.6962
5.5457
5049.2671
2679.2852
1133.7804
92.3242
8882.5746

Kmol/jam (Fi)
0.2910
0.0781
59.5432
22.4208
7.3622
2.5294
89.6954

wi
0.0017
0.0006
0.5684
0.3016
0.1276
0.0104
1

Flowrate input condenser

8882.5746

kg/jam =

Suhu keluar kondenser pada T boiling point, dimana:

Ki xi 1

T boiling point=
45

-40 oC

233

T h,in
T c,out

30
Neraca Panas disekitar condenser:

Qc L0 H L D H D V HV
T referensi =

273.15

Coolant in

Lo

Perhitungan entalpi :

Komponen
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl

Komponen
CH3Cl

hout, kJ/Kmol
-1.0990E+05
-2.2092E+04
-1.3031E+05
-1.4007E+05
-1.3506E+05
-537432.0390

Lo (Kmol./jam)
0.2910

D
2.9101E-06

hin, kJ/Kmol
-1.0134E+05
-1.4554E+04
-1.2007E+05
-1.2924E+05
-1.2278E+05
-487983.8990

V
5.6886E-07

Lo.h
1905.5591

Cl2
0.0781
CH2Cl2
59.5432
CHCl3
22.4208
CCl4
7.3622
HCl
2.5294
Total :
92.2248
Sehingga beban kondenser dapat dihitung :

7.8109E-07
3.8703E+01
5.6052E+00
5.1535E-01
7.5832E-02

6.5234E-09
1.5807E+00
1.0144E-04
1.4372E-02
#VALUE!
#VALUE!

4.4899E+01

500.3661
274018.0098
213894.3979
18663.2030
5053.7999
514035.3357
514035.3357

Qc =

D.h +V.Hv -Lo.h

Sehingga didapatkan beban kondenser sebesar:

#VALUE!

Qc =

kJ/Jam

Pada kondenser pendingin yang digunakan adalah propana :

Suhu awal =
-40
oC

-40

Suhu akhir =

86

30

oC

Hot Fluid (oF)

Komponen

Cold Fluid (oF)

113
86
27

high temperature
lower temperature
different

-31
-40
CH2Cl2

Menghitung nilai ta :
ta

ta

T2 + t1
2

-35.5 oF

Menghitung nilai Tv :
Tv

Tv

T1 + t2
2

99.5 oF

Menghitung jumlah propana yang dibutuhkan :

Qc m p C p (Tcout Tcin )
dimana,

Qc
mp
Cp
Tcout
Tcin

=
=
=
=
=

Beban kondenser kJ/jam

massa pendingin yang dibutuhkan , kg/jam
kapasitas panas gas

Suhu coolant keluar, oF

Suhu coolant masuk, oF

Dari perhitungan menggunakan program aspen plus didapatkan Cp propana pada Tin = 40 oC, sebesar:

Cp.propana

0.348 Btu/lb.oF

Sehingga massa pendingin yang dibutuhkan dapat dihitung:

mp

mp

Qc
Cp (Tcout - Tcin)

0.348
mp

x
#VALUE!

#VALUE!
86

lb/jam

Mentrial nilai UD awal :

Untuk light organics dengan light organics UD = 40 - 75

Sehingga diambil nilai UD :

DTLMTD

DTLMTD

70

(Thin tcout ) (Thout tcin )

(T t )
ln hin cout
(Thout tcin )

16.38430608 oF

Luas transfer panas :

Q
U D DTLMTD

#VALUE!

ft2

Trial nilai L awal :

L
=
OD
at

Menghitung nilai Nt:

12 ft
3.657599883 m
=
=
=

0.75 in
0.1963 ft2/ft
2.3556 ft2

Nt

A
p L OD

Nt

#VALUE!

buah

Dari tabel 9 dan 10 Kern didapatkan data - data sebagai berikut:

Jenis:
HE 1-4
3/4 in OD tube on 1 - in square pitch
Shell (propana)
39
12
1
1049
Horizontal tube

ID,in:
L,ft:
pass:
Nt:

Tube (Gas Umpan)

0.75
0.302
15/16 (tringular)
0.1963
0.62
4

OD,in:
at',in2:
Pt, in:
a/lin:
ID,in
pass:

Diketahui dari data sebelumnya:

Wt
=
#VALUE!
lb/jam
Ws
=
8882.5746 lb/jam
A
=
#VALUE!
ft2
Menghitung nilai Ud :
Ud

Qc
A.DTLMTD .Ft

Ft = faktor koreksi
sehingga didapatkan nilai Ud:
Ud

#VALUE!

Btu/ft2.oF

Dari penggunaan program aspen , didapatkan data densitas sebagai berikut:

. Propana
=
36.2126537 lb/ft3
. Kondensat
=
0.04206906 gm/cc
Menghitung heat flux :
Q/A
=

Asumsi ho =

#VALUE!

Btu/ft2.jam

HOT FLUID : Shell side, propana

300 Btu/hr.ft2.oF

COLD FLUID :
Flow area :

tw =
tf =
G"=
sf =
f =
kf =

-12.3129771
43.59351145
7.169804141
7.2524E-05
6.50E-03
8.86E-03

oF
oF
=

0.855507292

cp
Btu/h.ft.oF

Dari grafik 12.9 Kern didapatkan nilai:

ho =
120 Btu/hr.ft2.oF
Fig. 25 Kern:
hi
hio

hio . ho
hio ho

Uc

gas

Uc

Rd
Rd

99.38931298

Uc U D
U c .U D

#VALUE!

Dari tabel .12 Kern didapatkan nilai Rd.avg =

Rd hitung < dari Rd .avg sehingga digunakan over design Rd = 0.005
Rd avg = Rd di shell + Rd di tube
Rd avg = Rd di shell + Rd di tube
=
#VALUE!
sudah mendekati nilai Rd avg standar

0.005

Menghitung Pressure Drop:

Hot Fluid : Shell side, propana
B
C'
Pt
as

:
:
:
=

19.5 in
0.25 in
1 in
ID x C'B/144 Pt

1.624999175

Gs
De

=
=
=

(at Tin)

Re

N+1
S

=
=

1.3203125 ft2
6727.630467 lb/ft2.jam
0.7209561 in

0.060079644

6.50E-03 cp

1.57E-02

7.12E+06

(turbulen)

12 L/ B
=
4.20206E-05

88.61542963

=
=
=

89.6954
45 oC
-35 oC

=
=

kg/s

yi
0.0032
0.0009
0.6638
0.2500
0.0821
0.0282
1.0282

BM
50.50
71.00
85.00
119.50
154.00
36.50

BM Mean
0.1638
0.0618
56.4263
29.8709
12.6403
1.0293
100.1925

yi (komposisi mol gas)

0.0032
0.0009
0.6633
0.2504
0.0822
0.0282
1

BM
50.50
71.00
85.00
119.50
154.00
36.50

Kmol/jam
0.2910
0.0781
59.4031
22.4208
7.3622
2.5294
89.5553

19582.72489 lb/jam =

5.43965 lb/s

K
-35
T h,out
T c,in

-40

V
vapour

liquid
D

Coolant out
Hv, kJ/kmol
2.2166E+04
2.0343E+04
3.2381E+04
3.4467E+04
3.3117E+04
12978.74458

D.h
1.9056E-02

V.Hv
1.2609E-02

(H)

h.kJ/Kmol
6.5480E+03
6.4060E+03
4.6020E+03
9.5400E+03
2.5350E+03
1998

5.0037E-03
1.7811E+05
5.3474E+04
1.3064E+03
1.5151E+02
2.3304E+05
2.33E+05
233040

1.3271E-04
5.1184E+04
3.4964E+00
4.7595E+02
#VALUE!
#VALUE!
1.32E+05
132400

#VALUE!

oF
oF

Different
144
126
18

Btu/jam

E!
-

-40
#VALUE!

)
kg/jam

Btu/jam.ft2.F

9.102392266 oC

0.062499968 ft

as Umpan)
0.75
0.302
15/16 (tringular)
0.1963
0.62

Mencari data - data:

Gas in condenser:
0.002626286 lb/ft3

COLD FLUID : tube side , gas umpan

Komponen

Kg/jam

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
Propana

14.69620252
5.545736801
5049.267108
2679.285174
1133.780379
#VALUE!

8882.5746
at=

#VALUE!

ft2

Gt=
Gt=

wt/at
#VALUE!

lb/hrft2

v=
v=

Gt/(3600*)
#VALUE!

ft/s

ta=

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
Propana

-1.374
-3.571
-20.372
-4.392
-7.745
-5.462

Komponen

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
Propana

-0.00185
-0.00194
-0.00122
-0.00019
-0.0007
-0.00869

-35.5 oF

=
=

700 Btu/h.ft.oF
578.6666667 Btu/h.ft.oF

=
=

1.10E-02 cp
2.66E-02 lb/ft.hr

1.06E+00

(for fuel oil)

Komponen

Menghitung nilai mean:

Cp mean
=
mean
=
k mean
=
mean
=
BM.mean
=

0.2673164
1.10E-04
7.71E-03
2.7526033
100.19254

Cp pendingin
pendingin
k pendingin
pendingin
BM.pendingin

0.348
6.50E-05
1.53E-02
36.212654
44

=
=
=
=
=

ft

ft
lb/ft.jam

kmol/jam
113 oF
-31 oF

Pi (atm)
9.7160
8.0688
1.1979
0.5776
0.3406
11609114.0605

Pi (atm)
0.61
0.03
0.02
0.00
0.00
#VALUE!

Ki = yi/xi
xi = yi/Ki
Y1+Y2+Y3+Y4+Y5+Y6=1
X1+X2+X3+X4+X5+X6 = 1
Ki (Pi/P)
1/Ki
0.1955
5.1158
0.0084
119.7364
0.0077
130.3926
0.0000
68650.7329
0.0015
671.4311
#VALUE!
#VALUE!

A (SURFACE TENSION)
24.8377
26.9785
39.5857
34.7304
33.8748
15.3265

Kg/jam
14.69620252
5.545736801
5049.267108
2679.285174
1133.780379
#VALUE!

Kmol/jam (Fi)
0.291013911
0.078108969
59.5432442
22.42079643
7.362210252
89.69537376

xi
0.00324447
0.000870825
0.66383852
0.249966029
0.082080156
1

8882.5746
A

-1.374
-3.571
-20.372
-4.392
-7.745
-5.462

3.86E-01
4.87E-01
4.37E-01
3.73E-01
3.95E-01
3.27E-01

-4.87E-05
-8.53E-05
-7.75E-05
-5.17E-05
-1.12E-04
-1.07E-04

-0.00185
-0.00194
-0.00122
-0.00019
-0.0007
-0.00869

2.03E-05
3.83E-05
1.84E-05
2.23E-05
2.21E-05
6.64E-05

7.32E-08
-6.35E-09
3.54E-08
1.23E-09
6.79E-09
7.88E-08

Gas in
Btu/lb.R
poise
W/m.K
lb/ft3
g/mol

=
=
=
=
=

0.481165611
7.38E-06
4.46E-03
2.752603321
100.1925411

Btu/lb.K
lb/ft.sec
Btu/h.ft.oF
lb/ft3
lb/lbmol

Propana in
Btu/lb.R
poise
W/m.K
lb/ft3
lb/lbmol

=
=
=
=
=

0.626394989
4.37E-06
8.86E-03
36.2126537
44

Btu/lb.K
lb/ft.sec
Btu/h.ft.oF
lb/ft3
lb/lbmol

56711.6467

xi
0.0000
0.0000
0.6500
0.2500
0.0700
0.0300
1

yi
1.95E-06
8.35E-08
2.65E-02
4.52E-06
1.95E-03
#VALUE!
#VALUE!

xi
00324447
00870825
66383852
49966029
82080156
1

Cp (Btu/lb.R))
0.49
0.298
0.303
0.226
0.203
0.348

rho (lb/cuft)
1.346
1.894
2.257
3.153
4.036
0.144

miu
1.346
1.894
2.257
3.153
4.036
0.144

4.87E-05
8.53E-05
7.75E-05
5.17E-05
1.12E-04
1.07E-04

7.32E-08
6.35E-09
3.54E-08
1.23E-09
6.79E-09
7.88E-08

Tmin
230
200
273
250
280
1.93E+02

Tmax
700
1000
993
700
800
7.50E+02

ngas @25oC
109.47
134.03
103.16
102.25
100.06
82.61

Tmin
213
200
250
273
255
2.33E+02

Tmax
750
1000
500
573
556
7.73E+02

kgas @25oC
0.01071
0.00891
0.00742
0.00656
0.00648
0.01811

lb/jam

%massa
0.001654498
0.000624339
0.56844635
0.30163385
0.127640963
1

ngas@ Tmin

nas@ Tmax

84.9
90.41
93.27
85.65
94.06
53.72

1.346
398.09
337.55
231.44
236.74
179.92

kgas@ Tmin

kas@ Tmax

0.0058
0.00547
0.0056
0.00598
0.00587
0.01106

0.05457
0.03001
0.01685
0.01297
0.01367
0.08971

T, K
318.15
318.15
318.15
318.15
318.15
233.15

MIU (mikropoise)
Miu (poise)
1.17E+02
1.17E-04
1.43E+02
1.43E-04
1.11E+02
1.11E-04
1.09E+02
1.09E-04
1.07E+02
1.07E-04
6.50E+01
6.50E-05

318.15
318.15
318.15
318.15
318.15
273.15

k.gas (W/mK)
1.20E-02
9.60E-03
8.23E-03
7.02E-03
7.01E-03
1.53E-02

T, K

3 atm

45 C

318.15 K

Densitas (g/ml)
Komponen
#REF!
#REF!
#REF!
#REF!
#REF!
#REF!

A
0.35821
0.45965
0.49807
0.58807
0.44134
0.566

B
0.26109
0.25678
0.25274
0.27663
0.26957
0.27315

n
0.2869
0.29012
0.28766
0.29
0.3187
0.2883

Tc
416.25
510
536.4
556.35
324.65
417.15

Rho (kg/m3)

0.869735172
1.279516076
1.440357109
1.606271607
1.1739
1.333848423
1.283938065

Konstanta Kapasitas Panas Fungsi Suhu pada Fase Gas

Komponen
CH3CL
CH2CL2
CHCL3
CCL4
Cl2
HCl

A
2.74E+01
2.67E+01
2.25E+01
1.98E+01
2.72E+01
2.92E+01

B
2.60E-02
8.40E-02
1.98E-01
3.33E-01
3.04E-02
-1.26E-03

H2O
33.933
-8.42E-05
Viskositas Fase Gas
Komponen
A
B
CH3Cl
-1.374
0.3863
CH2Cl2
-20.372
0.4375
Cl2
-3.571
0.4870
HCl
-9.118
0.5550
CHCl3
-4.392
0.3731
CCl4
-7.745
0.3948
H2O
-10.2158
1.79E+03
Konduktifitas Panas Gas
Komponen
A
B
CH3Cl
-0.00185 2.0296E-05
CH2Cl2
-0.00122 1.8440E-05
Cl2
-0.00194 3.8300E-05
HCl
-0.00119 4.4775E-05
CHCl3
-0.00019 2.2269E-05
CCl4
-0.0007 2.2065E-05

C
1.03E-04
8.97E-06
-2.17E-04
-5.05E-04
-3.34E-05
1.12E-06

E
3.16E-11
1.87E-11
-2.46E-11
-8.42E-11
-2.70E-12
-2.50E-12

2.99E-05 -1.78E-08

3.69E-12

C
Tb,K
BM (kg/kgmol)
-4.8650E-05 248.93
50.49
-7.7549E-05 312.90
84.93
-8.5300E-05 239.12
70.90
-1.1100E-04 188.15
36.46
-5.1696E-05 334.33
119.38
-1.1150E-04 349.79
153.82
1.77E-02
-1.26E-05
18
C
yi
7.3234E-08 0.00316
3.5385E-08 0.645092
-6.3523E-09 0.000848
2.0997E-10 0.027469
1.2257E-09 0.24348
6.7913E-09 0.07995
0

Konstanta Kapasitas Panas Fungsi Suhu Pada fasa liquid

Komponen
CH3CL
CH2CL2
CHCL3
CCL4

A
-7.35E+00
-5.10E+00
-4.78E+00
-6.46E+00

B
8.54E+02
6.87E+02
6.99E+02
1.04E+03

273.15

D
-1.09E-07
-5.09E-08
1.16E-07
3.41E-07
1.60E-08
4.97E-09

C
1.95E-02
1.25E-02
1.09E-02
1.40E-02

D
-2.35E-05
-1.45E-05
-1.22E-05
-1.41E-05

Cp(J.mol/K)

1.49E+03
2.12E+03
3.33E+03
4.90E+03
1.57E+03
1.33E+03
1.56E+03
yi
0.003160285
0.64509241
0.00084823
0.027468516
0.243480143
0.079950416

ki (W/m.K)
9.9580E-01
9.9722E-01
9.9554E-01
9.9726E-01
9.9956E-01
9.9839E-01

a
1.1616E-02
2.8235E+00
3.4901E-03
9.0726E-02
1.1964E+00
4.2697E-01

T=
Cp(J.mol/K)

2.34E+05
1.88E+05
1.91E+05
2.84E+05

Cl2
HCl

-7.68E-01
-1.52E+00

1.51E+02
1.95E+02

H2O

-10.2158

1.79E+03

-8.07E-04
3.07E-03

4.08E-07
-1.38E-05

1.77E-02 -1.26E-05

4.13E+04
5.31E+04
4.91E+05

Komponen
Sifat fisis gas:
BMgas
Cpgas
kgas
rhogas
miugas

CH3Cl
97.46351555
Cl2
0.0000 KJ.Kmol/K CH2Cl2
0.3488 kg.m/s3.K CHCl3
11.200515 kg/m3
CCl4
7.93385E-05 cp
HCl
Total

BM gas
rho gas
BM gas selain HCL

Cp(J.mol/K)

4.70E+00
1.37E+03
8.11E+02
3.92E+02
1.33E+00
3.64E+01

miu(cp)
4.0901E-02
4.0244E-21
2.5316E-04
7.0539E-10
3.9149E-05
1.6625E-08
11.45867342

1 cp
1 poise
1 g/cm.s

a
0.00091847
2.39252E-20
1.80813E-06
1.16997E-10
0.000104149
1.64852E-08
0.001024444

b
a/b = ki camp (kg.m/s3.K)
0.159562794
7.2801E-02
54.78769839
5.1536E-02
0.060139478
5.8033E-02
1.001502102
9.0590E-02
29.06665945
4.1162E-02
12.297973
3.4719E-02
0.3488
273.15

Fraksi Mol

0.003160285
0.00084823
0.64509241
0.243480143
0.079950416
0.027468516
1

b
0.011665
2.831387
0.003506
0.090975
1.196966
0.427657
0

a/b = miu camp (cp)

miu gas
0.078735649
7.7266E-02
8.44999E-21
1.6029E+20
0.000515763
3.3506E+00
1.28604E-09
3.8941E+07
8.70108E-05
6.2192E+03
3.85477E-08
4.8090E+06
0.079338463
1.6029E+20
0.000793385 poise
7.93385E-05
kg/m.s

F, kg/jam
14.69620252
5.545736801
5049.267108
2679.285174
1133.780379
92.3242
8974.8988

kg/s
0.004082
0.00154
1.402574
0.744246
0.314939
0.025646
2.493027

kmol/s
8.08372E-05
2.16969E-05
0.016500873
0.006227999
0.002045058
0.000702619
0.025579084

97.46351555 kg/kmol
11.200515 kg/m3
2.467381833 0.024876 99.18539021
0.01 poise
1 g/cm.s
0.1 kg/m.s

6.2385E-28 kg/m.s
g/cm.s

Mencari nilai Pas masing - masing komponen:

-35 oC =
Tout=
Persamaan antoine :

Komponen
A
B
CH3Cl
25.7264
Cl2
28.6659
CH2Cl2
32.5609
CHCl3
56.6178
CCl4
31.9407
HCl
43.6356
H2O
29.8605
Mencari surface tension:
Persamaan:
Komponen
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl

Tin=
Komponen
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

C
-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

Tc
68.594
67.56
88.57
69.264
66.75
85.2

TMIN

0.452
0.401
0.41
0.375
0.241
0.647
0.321

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

TMAX
175.43
172.12
178.01
209.63
250.33
158.97

318.15 K
D
-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

n
416.25
417.15
510
536.4
556.35
324.65
647.13

E
-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

1.1966
1.085
1.28
1.1761
1.214
1.297

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

Tc
32.534
28.56
41.91
42.953
37.89
30.54
52.053

D
-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

416.25
417.15
510
536.4
556.35
324.65

45 oC =
B
25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

Enthalpy of vaporization :
Komponen :
A
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

238.15 K

416.25
417.15
510
536.4
556.35
324.65

E
-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

HVAP
KMOL/JAM
16.62351491
23.18760396
15.78797129
12.6712
27.83554079
55.07869412
30.45294608
2.0222
30.7626849
0.0578
1.35423687
0
41.73296274
0

93.01749808

57158.694

Tmin

Tmax

P (mmHg)

175.43
172.12
178.01
209.63
250.33
158.97
273.16

416.25
417.15
510.00
536.40
556.35
324.65
647.13

P (atm)

465.07
19.87
18.25
0.03
3.54
#VALUE!
0.23

0.61
0.03
0.02
0.00
0.00
#VALUE!
0.00

g/cm2/s2 = dyne
Sigma(dynes/cm, T-K)
24.83769466
26.97851809
39.58570383
34.73040894
33.8747968
15.32652518

Tmin

10

Tmax

P (mmHg)

175.43
172.12
178.01
209.63
250.33
158.97
273.16
T=
MOL/JAM
0
0
55078.69412
2022.2
57.8
0
0

416.25
417.15
510.00
536.40
556.35
324.65
647.13
322.02 K
m.Hvap
0
0
1533145.237
61581.94756
1778.083187
0
0

7384.14
6132.30
910.41
438.95
258.87
8822926685.96
71.98

P (atm)
9.72
8.07
1.20
0.58
0.34
11609114.06
0.09

Q=

1596505.267 kjoule/jam
57158.69412

Enthalpy Of Vaporization :

T=
-35 oC =
238.15 K
Komponen A
Tc
n
TMIN
TMAX
Tb
Hvap@Tb Hvap (kJ./mol)
CH3CL
32.534
416.25
0.452
175.43
416.25
248.93
21.55 22.16610747
CL2
28.56
417.15
0.401
172.12
417.15
239.12
20.29 20.34300365
CH2CL2
41.91
510
0.41
178.01
510
312.9
28.38 32.38090011
CHCL3
42.953
536.4
0.375
209.63
536.4
334.33
29.79
34.4669523
CCL4
37.89
556.35
0.241
250.33
556.35
249.79
29.84 33.11665451
HCL
30.54
324.65
0.647
158.97
324.65
188.15
17.43 12.97874458
Entalpy campuran
Komponen h (kJ/mol) kJ/Kmol
CH3CL
6.548
6548
CL2
6.406
6406
CH2CL2
4.602
4602
CHCL3
9.54
9540
CCL4
2.535
2535
HCL
1.998
1998

Hv (KJ/Kmol)
22166.10747
20343.00365
32380.90011
34466.9523
33116.65451
12978.74458

Fungsi

Mengembunkan sebagian gas yang keluar dari absorber

Type

Kondenser parsial

Pengembunan berlangsung dari suhu 146,88 C - 112,2 C

I. Penentuan suhu Bubble Point dan Dew Point

Tin =
353 K
n

Td
322.02
322.02
322.02
322.02
322.02
322.02
322.02
49.02

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O
Dew point
Tout =
n

Fm
(Kg /j)

(K)

1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
506.92

Tb

(K)
233.92
233.92
233.92
233.92
233.92
233.92
233.92
-39.08

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O
BP

7046.81
4932.2431
(Kg
/j)

1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000

7046.806
Delta :
13.2525
22.02375899
II. Perhitungan Point to Point Composition
Kondenser dibagi menjadi beberapa bagian ( range suhu ) :
Range :
49.02 - 26.99 C
T=
26.99
oC =
n

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O
Suhu
Range

(K)
299.99
299.99
299.99
299.99
299.99
299.99
299.99
26.99

26.99 - 4.97 oC

Yi
( Kg/J)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
7046.80574

T=

4.97

Suhu

Yi

(K)

( Kg/J)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
7046.80574

255.95
255.95
255.95
255.95
255.95
255.95
255.95
-17.05

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O
Suhu

28.71
-17.06 -( - 39.08)
-39.08

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O
Suhu
T
=
Menghitung CPv dan CPl
Komponen

CH3Cl
Cl2
CH2Cl2

( Kg/J)
1170.9740
899.6552
4681.689
241.6529
8.9012
43.93344
0
7046.80574

4.97 - 17.06
-17.05 oC =

Range :
T=

Yi

(K)
277.97
277.97
277.97
277.97
277.97
277.97
277.97
4.97

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

Range
T=

oC =

oC =
Yi

(K)

( Kg/J)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
7046.80574

233.92
233.92
233.92
233.92
233.92
233.92
233.92
-39.08
353.00

K=
(R =

B
2.74E+01
2.72E+01
2.67E+01

2.60E-02
3.04E-02
8.40E-02

CHCl3
CCl4
HCl
H2O

2.25E+01
1.98E+01
2.92E+01

1.98E-01
3.33E-01
-1.26E-03

33.933

-8.42E-05

-38.48042673
391.4804267
T
=
299.99
K
Menghitung CPv dan CPl
(R =
A
Komponen

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

2.60E-02
3.04E-02
8.40E-02
1.98E-01
3.33E-01
-1.26E-03

33.933

-8.42E-05

K
(R =
B

2.74E+01
2.72E+01
2.67E+01
2.25E+01
1.98E+01
2.92E+01
3.39E+01

T
=
255.95
Menghitung CPv dan CPl
Komponen
A

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

2.74E+01
2.72E+01
2.67E+01
2.25E+01
1.98E+01
2.92E+01

T
=
277.97
Menghitung CPv dan CPl
Komponen
A

CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl
H2O

429.9608535

2.60E-02
3.04E-02
8.40E-02
1.98E-01
3.33E-01
-1.26E-03
-8.42E-05
K
(R =

2.74E+01
2.72E+01
2.67E+01
2.25E+01
1.98E+01
2.92E+01
3.39E+01

IV. Menentukan Heat Load for the Entire Range

2.60E-02
3.04E-02
8.40E-02
1.98E-01
3.33E-01
-1.26E-03
-8.42E-05

Tvap
K
353.0
300.0
277.97
255.95

H
kJ/jam
2.60E+05
1.33E+04
-1.55E+05
-3.44E+05

P.Downterm Q =
Cp Downterm Q =
Downterm Q in =
Downterm Q out =
Kebutuhan Downterm Q =
Sigma U.A
Weighted t

Q
kJ/jam
1.843E+06
1.681E+05
1.891E+05
1.597E+06
1
0.362
-10
30

atm
Btu/lb.F
C
C
26351.790
11952.985
39633.713
40.281
72.507

=
=

HEAT EXCHANGER
Tipe Alat
Shell and Tube Condenser
Luas Transfer
Hot Fluid
Cold Fluid
Range Ud
Ud dipilih

Panas
=
=
=
=

Light Organics
dowtherm
100 s/d 200
100
2044.175
19.389
208.697

Luas transfer panas =

Penentuan Jumlah Pipa ( Tabel 10 Kern )
OD
=
0.5 in
BWG
=
12
ID
=
0.402 in
Jml pipa =
199.291 buah
Lay Out Condenser
Jenis HE =
HE 1 - 4
Shell_side
ID Shell =
19.25
Pass
=
1
Bs
=
9.625

Luas transfer panas terkoreksi

Ud terkoreksi

in
in

213.629
19.847
= 97.692
1996.986

V. Menentukan Cp rata-rata
Komponen
CH3CL
CH2CL2
CHCL3
CCL4
Cl2
HCl

H2O

B
2.74E+01
2.67E+01
2.25E+01
1.98E+01
2.72E+01
2.92E+01

2.60E-02
8.40E-02
1.98E-01
3.33E-01
3.04E-02
-1.26E-03

33.933

-8.42E-05

Condensate sensible heat load =

Submergence
=

322674.96
20.21

Shell Side, Hot Fluid

Unsubmerged tubes
Nt'

162.77

G"

204 buah
15521.599 lb/jam
65.083 lb/jam ft

Asumsi ho=
t avg

90 Btu/j.ft2.F

277.8 K
40.7 F

Tv,K

304.47 88.65

tw,K

287.58 58.25

tf,K

296.03 73.45

Pada tf
u
=

1.956 Lb / ( ft*j)

0.2000 Btu/j.ft.F

sg

1.1570

Dari Fig.12.9 Kern

ho

500

Btu/jam ft2 F

Clean Overall Coefficient

Uc kondensasi

118.5768

Clean Surface Required for Condensation

Ac, kondensasi

16.351

Clean Surface Required for Subcooling

As, subcooling

35.568

Total Surface Required

Ac
Uc overall

211.546
=

4033.290
Rd

0.0044

Rd > Rd min sehingga HE bisa digunakan

Shell Side
as

Gs

0.322 ft2
48253.349 lb/jam ft2
1.956 lb/jam ft

Dari Fig.28 Kern

De

0.990 in
0.083 ft

Res

2035.221

Dari Fig.29 Kern

f

N+1
rho
s

0.0036 ft2/in2
=

=
=

9.974
36.342 lb/ft3
0.582

Ds

1.604 ft

dPs

0.027 psi

275
Uc
Ud
Rd calc.
Rd req.
0.3345
2.0

CONDENSER PARTIAL (CD-01)

uar dari absorber

dari suhu 146,88 C - 112,2 C

P=

2 atm

2.196672
0.101616811

1520

162.12 kpa
1520 mmhg

BM

Yi
( kmol/j )

50.50
71.00
85.00
119.50
154.00
36.50
18.00

23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000

yi
0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

94.221

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

Antoine

57.1587
BM

Yi
( kmol/j )

50.50
71.00
85.00
119.50
154.00
36.50
18.00

23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000

xi
0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

94.2212
T1

T2

T3

26.99

299.99
Yi
( Kmol/j)
23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000
94.221

4.97

Antoine

close enough
T4
-17.05
-39.08

K
BM

yi

50.50
71.00
85.00
119.50
154.00
36.50
18.00

0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

Antoine
A

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

277.97

Yi

BM

( Kmol/j)
23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000
94.221

yi

50.50
71.00
85.00
119.50
154.00
36.50
18.00

0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

Antoine

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

255.945 K
Yi

BM

( Kmol/j)
23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000
94.221

50.50
71.00
85.00
119.50
154.00
36.50
18.00

233.92

0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

Antoine

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

Yi

BM

( Kmol/j)
23.1876
12.6712
55.0787
2.0222
0.0578
1.2037
0.0000
94.221

8.31433
C

yi

yi

50.50
71.00
85.00
119.50
154.00
36.50
18.00

80.00 oC
kJ/kmol/K)
D
1.03E-04
-3.34E-05
8.97E-06

-1.09E-07
1.60E-08
-5.09E-08

0.2461
0.1345
0.5846
0.0215
0.0006
0.0128
0.0000
1

E
3.16E-11
-2.70E-12
1.87E-11

Antoine
A

25.7264
28.6659
32.5609
56.6178
31.9407
43.6356
29.8605

Cpv
kJ/kmol/K
45.138
34.457
55.509

-1.75E+03
-1.67E+03
-2.52E+03
-3.25E+03
-2.66E+03
-1.63E-03
-3.15E+03

Hvap
kJ/kmol
2482.580
1895.158
3052.996

-2.17E-04
-5.05E-04
1.12E-06

1.16E-07
3.41E-07
4.97E-09

-2.46E-11
-8.42E-11
-2.50E-12

2.99E-05

-1.78E-08

3.69E-12

468.4412802
26.99
8.31433
kJ/kmol/K)
C
D

1.03E-04
-3.34E-05
8.97E-06
-2.17E-04
-5.05E-04
1.12E-06

-1.09E-07
1.60E-08
-5.09E-08
1.16E-07
3.41E-07
4.97E-09

3.16E-11
-2.70E-12
1.87E-11
-2.46E-11
-8.42E-11
-2.50E-12

2.99E-05

-1.78E-08

3.69E-12

70.189
88.135
29.118
36.903

3860.395
4847.428
1601.497
2029.672
17740.053

Cpv
kJ/kmol/K
41.800
33.748
51.473
65.390
82.801
29.080
36.148

Hvap
kJ/kmol
83.307
67.259
102.584
130.321
165.022
57.957
72.042

Cpv
kJ/kmol/K
40.447
33.420
49.750
63.193
80.194
29.072
35.860

Hvap
kJ/kmol
-810.180
-669.430
-996.535
-1265.805
-1606.343
-582.330
-718.295

Cpv
kJ/kmol/K
39.120
33.072
48.004
60.869
77.334
29.067
35.588

Hvap
kJ/kmol
-1645.159
-1390.807
-2018.767
-2559.822
-3252.238
-1222.405
-1496.617

4.97
8.31433
C

kJ/kmol/K)
D

1.03E-04
-3.34E-05
8.97E-06
-2.17E-04
-5.05E-04
1.12E-06
2.99E-05

-1.09E-07
1.60E-08
-5.09E-08
1.16E-07
3.41E-07
4.97E-09
-1.78E-08

3.16E-11
-2.70E-12
1.87E-11
-2.46E-11
-8.42E-11
-2.50E-12
3.69E-12

-17.05
8.31433
C

kJ/kmol/K)
D

1.03E-04
-3.34E-05
8.97E-06
-2.17E-04
-5.05E-04
1.12E-06
2.99E-05

-1.09E-07
1.60E-08
-5.09E-08
1.16E-07
3.41E-07
4.97E-09
-1.78E-08

3.16E-11
-2.70E-12
1.87E-11
-2.46E-11
-8.42E-11
-2.50E-12
3.69E-12

dtb
46.18
4.21
4.74
55.12

tb

dtav

Q/dt

303
256.82
252.61
247.88

46.50
33.48
15.10

3.9634E+04
5.0211E+03
1.2523E+04
3.9634E+04

1.515 kJ/kg.K
263 K
303 K

Panas laten : Q = m.
Q.latent =

Downtherm Q :
range suhu :
Oil dan gas chemical processing h

kg/j
lb/j
1lb =

1596505.267
2.2 kg

K
F

11952.985

Btu/jam ft2 F
Btu/jam ft2 F
kJ/jam/m2/K
m^2
ft2
a't
a''t
L

=
=
=

(Kern,1950.p.840)

1 in =
1 cm =

(bisa pake shell and tube)

0.127
0.131
8

in2
ft2/ft
ft

Tube_side
OD
BWG
ID
Pt
L
Nt
Pass

=
=
=
=
=
=
=

0.75
12
0.402
1
8
204
4

ft^2
m^2
Btu / ( jam.ft2.F )
(kJ/(j.m^2.K )
337.722

in
in
in square pitch (1)
ft
buah

2.54
0.3937

Tavg=

326.496
C
1.03E-04
8.97E-06
-2.17E-04
-5.05E-04
-3.34E-05
1.12E-06

D
-1.09E-07
-5.09E-08
1.16E-07
3.41E-07
1.60E-08
4.97E-09

2.99E-05

-1.78E-08

K=

53.496 oC
E
3.16E-11
1.87E-11
-2.46E-11
-8.42E-11
-2.70E-12
-2.50E-12

Cp(J/mol.K)

-1.03E+04
-1.27E+04
-1.67E+04
-2.22E+04
-1.03E+04
-9.55E+03
3.69E-12
-1.12E+04
Cpgas =

Cp(J/mol.K)

-2.54E+03
-7.44E+03
-3.58E+02
-1.36E+01
-1.39E+03
-1.22E+02
0.00E+00
-1.19E+04

kJ/jam
%

Tube Side, Cold Fluid

buah

a't

0.1270 in2

at

0.0450 ft2

Gt

265744.919 lb/( jam .ft2 )

ta avg. =
v

50 F
1.189 ft / s
0.0335 ft

Dari fig. 25 Kern

F

hi

290 Btu/j.ft2.F

hio

155 Btu/j.ft2.F

F
0.809

cP

0.024191402

coulson n richarson
Btu/jam ft2 F

2423.918 kJ/jam/m^2/K

Rd tube =
Rd shell =

m2

175.979 ft2

ft2
ft2
kJ/j.m2.K

19.653 m2
197.307 Btu/jam ft2 F

Pressure Drop
Tube Side

Ret

21.926 Lb/(j.ft)
0.034 ft
406.020

Dari Fig.26 Kern

f
dPt

=
=

0.001
1.680 psi

Dari Fig.27 Kern

h outside

V^2/2.g' =

1.000

dPr

6.944 psi

dPT

8.624 psi

52
33.83
31.73
0.0020
0.0015

Calc. P
Allow. P

8.6244
10.0

mmhg

Antoine
C

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

Antoine

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

5.25

Antoine
C

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

Antoine
C

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

Antoine

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

-6.72E+00
-8.52E+00
-8.80E+00
-1.87E+01
-8.58E+00
-1.52E+01
-7.30E+00

Yi
( kmol/j )
23.188
12.671
55.079

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

-1.30E-09
5.38E-03
1.29E-10
9.52E-03
-6.71E-10
1.38E-02
2.42E-09

H1
kJ/jam
57565.075
24013.923
168155.031

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

4.43E-06
-7.79E-13
3.32E-06
1.16E-12
2.97E-06
-1.50E-11
1.81E-06

2.022
0.058
1.204
0.000
94.221

7806.490
280.181
1927.651
0.000
259748.351

CP liq
A

b
1.14E+01
1.28E+02
3.89E+01
2.83E+01
9.67E+00
7.40E+01

6.23E-01
-6.02E-01
4.90E-01
6.59E-01
9.34E-01
-1.29E-01

c
-2.44E-03
1.58E-03
-1.62E-03
-2.04E-03
-2.68E-03
-7.90E-05

92.053

-4.00E-02

-2.11E-04

d
3.83E-06
-5.31E-07
2.31E-06
2.59E-06
3.04E-08
2.64E-06

5.35E-07

CP liq
A

1.14E+01
1.28E+02
3.89E+01
2.83E+01
9.67E+00
7.40E+01
9.21E+01

6.23E-01
-6.02E-01
4.90E-01
6.59E-01
9.34E-01
-1.29E-01
-4.00E-02

-2.44E-03
1.58E-03
-1.62E-03
-2.04E-03
-2.68E-03
-7.90E-05
-2.11E-04

3.83E-06
-5.31E-07
2.31E-06
2.59E-06
3.04E-08
2.64E-06
5.35E-07

CP liq
A

1.14E+01
1.28E+02
3.89E+01
2.83E+01
9.67E+00
7.40E+01
9.21E+01

6.23E-01
-6.02E-01
4.90E-01
6.59E-01
9.34E-01
-1.29E-01
-4.00E-02

-2.44E-03
1.58E-03
-1.62E-03
-2.04E-03
-2.68E-03
-7.90E-05
-2.11E-04

3.83E-06
-5.31E-07
2.31E-06
2.59E-06
3.04E-08
2.64E-06
5.35E-07

laten : Q = m.

1596505.267 kj/jam

-33 hingga 330

oC
gas chemical processing heat recovery

cm =
in

0.025

Cp (kJ/kmol.K)
-2.54E+03
-7.44E+03
-3.58E+02
-1.36E+01
-1.39E+03
-1.22E+02
0.00E+00
-1.19E+04

Properties larutan pada suhu Ta (YAWS):

Cp = A + BT + CT2 + DT3

Data kapasitas panas:

Senyawa

2.739E+01

2.604E-02

Cl2

2.721E+01

3.043E-02

CH2CL2

2.669E+01

8.398E-02

CHCL3

2.249E+01

1.982E-01

CCL4

1.982E+01

3.331E-01

H2O
CH2CL2

Komponen
CH3CL
cl2
ch2cl2
chcl3
ccl4
HCl
0.002
0.002

CH3CL

HCl

coulson n richarson

H2O

total :

2.924E+01

-1.262E-03

3.393E+01

-8.419E-05

5049.2671
Massa (kg/jam)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
37859.6463

xi
0.0552
0.0481
0.8420
0.0526
0.0021
0.0000
0.0000
1.0000

0.002

log Miu = A + B/T + CT + DT2

Data viskositas:
Senyawa
CH3Cl
Cl2

A
-7.3473
-0.7681

B
853.9500
151.4000

CH2Cl2
CHCl3
CCl4
HCl

H2O
Total:

Komponen
CH3Cl
Cl2
CH2Cl2
CHCl3
CCl4
HCl

H2O

Total:

-5.1043
-4.7831
-6.4564
-1.5150
-10.2158

Massa (kg/jam)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
37859.6463

686.5300
699.0200
1037.9000
194.6000
1792.5000

xi
0.0552
0.0481
0.8420
0.0526
0.0021
0.0000
0.0000
1.0000

rho = A*B^-(1-T/Tc)^n

Data densitas:
Senyawa

CH3Cl

0.35821

0.26109

Cl2
#REF!
#REF!
#REF!
#REF!

0.566
0.45965
0.49807
0.58807
0.44134
0.3471

0.27315
0.25678
0.25274
0.27663
0.26957
0.274

Massa (kg/jam)
1170.9740
899.6552
4681.6890
241.6529
8.9012
43.9334
0.0000
37859.6463

xi

H2O

Komponen
CH3Cl
Cl2
#REF!
#REF!
#REF!
#REF!

H2O

Total :

0.055
0.048
0.842
0.053
0.002
0.000
0.000

1.0000

Properties Air pada suhu ta (YAWS):

Cp =

36.4731 kJ/kmol.K

=
=

2.0263 kJ/kg.K
0.4840 BTU/lbm.F

log miu =
miu =
=

0.9573
9.0638 Cp
21.9262 lb/ft.hr

(1-T/Tc)^n =
Rho =
=
=

0.6549
0.8104 kg/L
845.0020 kg/m3
52.7518 lb/ft3

H2O in =

448.9737 kg/jam

H2O masuk kondenser =

CL2 UMPAN =
CL2 IN COND =

Po

mmhg

8530.5005
899.6552

Pt
1520
1520
1520
1520
1520
1520
1520

8130.2960
6712.9774
1038.1727
505.3823
299.1572
8300177416.3475
87.5711

Po

mmhg

378.5012
378.0613
13.5521
4.6201
2.5599
65568636189.7270
0.1517

Po

(
mmhg)
4538.6995
3880.3871
465.3816
213.4696
123.6763
12123507377.3547
26.5245

K
( Po /Pt)
5.3489
4.4164
0.6830
0.3325
0.1968
5460643.0371
0.0576

mmhg

Pt

mmhg
1520
1520
1520
1520
1520
1520
1520

Pt
(mmhg)
1520
1520
1520
1520
1520
1520
1520

K
( Po /Pt)
0.2490
0.2487
0.0089
0.0030
0.0017
43137260.6511
0.0001

Ki

(
Po /Pt)
2.9860
2.5529
0.3062
0.1404
0.0814
7975991.6956
0.0175

Po

mmhg)
2293.962
2043.344
178.773
76.150
43.206
19225461531.114
6.456

Po

(
mmhg)
1017.0728
952.8033
56.1944
21.7567
12.1385
33553193131.4087
1.1877

Po

mmhg)
378.5012
378.0613
13.5521
4.6201
2.5599
65568636189.7270
0.1517

Pt
(mmhg)
1520
1520
1520
1520
1520
1520
1520

Ki

Pt
(mmhg)
1216
1216
1216
1216
1216
1216
1216

Ki

Pt
(mmhg)
1216
1216
1216
1216
1216
1216
1216

Ki

Po /Pt)
1.5092
1.3443
0.1176
0.0501
0.0284
12648329.9547
0.0042

Po /Pt)
0.8364
0.7836
0.0462
0.0179
0.0100
27593086.4568
0.0010

Po /Pt)
0.3113
0.3109
0.0111
0.0038
0.0021
53921575.8139
0.0001

Cpl
kJ/kmol/K
82.686
74.602
102.234
112.742
49.674
99.347
75.511

Hliq
kJ/kmol
164.791
148.680
203.751
224.692
99.000
197.998
150.493

L
(Kmol / j )
4.120
2.556
37.352
1.661
0.051
0.000
0.000
45.741

V
(Kmol / j )
19.068
10.115
17.726
0.362
0.006
1.204
0.000
48.481

Cpl
kJ/kmol/K
78.797
70.714
99.358
109.838
63.017
88.625
76.126

Hliq
kJ/kmol
-1578.355
-1416.448
-1990.208
-2200.136
-1262.277
-1775.234
-1524.856

L
(Kmol / j )
13.215
7.578
52.020
1.973
0.057
0.000
0.000

V
(Kmol / j )
9.972
5.093
3.059
0.049
0.001
1.204
0.000

Cpl
kJ/kmol/K
75.646
67.926
96.773
107.055
73.787
79.963
76.968

Hliq
kJ/kmol
-3181.252
-2856.602
-4069.747
-4502.135
-3103.097
-3362.811
-3236.850

L
(Kmol / j )
22.814
12.480
55.029
2.021
0.058
0.000
0.000

V
(Kmol / j )
0.374
0.192
0.050
0.001
0.000
1.204
0.000

= A + BT + CT2 + DT3

...J/mol.K

BM (kg/kmol)

1.032E-04

-1.089E-07

50.50

-3.335E-05

1.596E-08

71.00

8.971E-06

-5.092E-08

119.50

-2.168E-04

1.164E-07

154.00

-5.051E-04

3.406E-07

85.00

1.121E-06

4.968E-09

36.50

2.991E-05

-1.783E-08

18.00

Cp (kJ/kmol.K)
43.0976
34.1471
53.2984
68.1516
86.5839
29.1245
36.4731

Miu = A + B/T + CT + DT2

C
1.9485E-02
-8.0650E-04

Cp (kJ/kg.K)
0.8534
0.4809
0.4460
0.4425
1.0186
0.7979
2.0263

xi/Cpi

D
-2.3484E-05
4.0750E-07

miu

Cp pd ta (J/mol.K)
43.0976
34.1471
53.2984
68.1516
86.5839
29.1245
36.4731
cp.cam.gas =
cp

0.0471
0.0231
0.3755
0.0233
0.0021
0.0000
0.0000
1.1506

0.654587391
0.589279406
0.255578402
0.999458085
0.213326068
0.204824232
0.672863296

...Cp

-9.17E-01
3.47E-01

yi.miu
-2.69E-01
7.61E-02

1.2459E-02
1.0929E-02
1.4021E-02
3.0670E-03
1.7730E-02

-1.4540E-05
-1.2244E-05
-1.4107E-05
-1.3760E-05
-1.2631E-05

log miu

miu (Cp)
0.1211
2.2232
2.6636
3.5500
8.3286
1.1746
9.0638

-0.9167
0.3470
0.4255
0.5502
0.9206
0.0699
0.9573

4.25E-01
5.50E-01
9.21E-01
6.99E-02
9.57E-01

xi/miu-i

1.96E-01
7.26E-03
2.80E-04
9.37E-04
0.00E+00
0.0108
miu

0.4554
0.0216
0.3161
0.0148
0.0003
0.0000
0.0000

0.2190
0.3776
0.7970
1.8506
1.7923
1.9406
0.1425

0.8083

...gr/mL .(K)

= A*B^-(1-T/Tc)^n
n

Tc

0.2869

416.25

0.2883
0.29012
0.28766
0.29
0.3187
0.28571

417.15
510
536.4
556.35
324.65
647.13

(1-T/Tc)^n
0.7003
1.0000
0.9989
0.9999
0.9994
1.0000
0.6549

Rho (kg/L)

Rho camp =
=
ok

0.9173
2.0721
1.7873
1.9704
2.1242
1.6372
0.8104

xi/rho-i
0.0601
0.0232
0.4711
0.0267
0.0010
0.0000
0.0000
0.6408

rholb/ft3
3.7547
1.4500
29.4081
1.6674
0.0616
0.0000
0.0000
36.3419

1.0000 kJ/kg.K
0.2388 BTU/lbm.F

1.0000 cp
2.4191 lb/ft.hr

1.0000 kg/m3
0.0624 lb/ft3

47.35027371 kg/jam
KG/JAM
KG/JAM

xi
0.046
0.030
0.856
0.065
0.003
0.000
0.000
1.000
yi
0.0613
0.0334
0.0052
0.0001
0.0000
0.90000
0.0000
1.000

xi

V/L trial

0.0000
0.0000
1.9093
0.1528
0.0075
0.0000
0.0000
2.0696

1.5500
1.5500
1.5500
1.5500
1.5500
1.5500
1.5500

Li = Yi / (1+Ki. V/L)
( Kmol/j ) ( Kg/j )
( Kmol/j)
4.6283
4.120
208.052
19.068
3.9570
2.556
181.493
10.115
0.4746
37.352
3174.959
17.726
0.2177
1.661
198.453
0.362
0.1261
0.051
7.904
0.006
12,362,787.1282
0.000
0.000
1.204
0.0270
0.000
0.000
0.000
45.741
3770.861
48.481
0.86875239
V/L hitung =
Delta
=
Ki . V/L

Vi

fD

V/L trial

0.1631
0.1000
4.9702
0.4284
0.0216
0.0000
0.0000
5.4202

0.5000
0.5000
0.5000
0.5000
0.5000
0.5000
0.5000

L'
( Kmol/j ) ( Kg/j )
0.7546
13.2154
667.3765
0.6722
7.5778
538.0222
0.0588
52.0196
4421.6640
0.0250
1.9728
235.7476
0.0142
0.0570
8.7765
6,324,164.9773
0.0000
0.0000
0.0021
0.0000
0.0000
74.843
5871.587
Ki . V/L

( Kmol/j)
9.9722
5.0934
3.0591
0.0494
0.0008
1.2037
0.0000
19.379

Yi/V

v/l hitung
delta

fD

V/L trial

Ki . V/L

0.2942
0.1716
12.6496
1.1995
0.0615
0.0000
0.0000
13.911

0.0196
0.0196
0.0196
0.0196
0.0196
0.0196
0.0196

0.0164
0.0154
0.0009
0.0004
0.0002
540,620.6422
0.0000

L'
( Kmol/j ) ( Kg/j )
22.8137
1152.0941
12.4796
886.0526
55.0289
4677.4539
2.0215
241.5682
0.0578
8.8995
0.0000
0.0001
0.0000
0.0000
92.4015
6966.0684

( Kmol/j)
0.3739
0.1916
0.0498
0.0007
0.0000
1.2037
0.0000
1.8196

Yi

v/l hitung
delta
fD

V/L trial

Ki . V/L

0.7906
0.4326
52.4521
5.6488
0.2914
0.0000
0.0000
58.392

0.0147
0.0147
0.0147
0.0147
0.0147
0.0147
0.0147

0.0046
0.0046
0.0002
0.0001
0.0000
793,941.9504
0.0000

L'
( Kmol/j ) ( Kg/j )
23.0818
1165.6318
12.6135
895.5555
55.0697
4680.9209
2.0221
241.6394
0.0578
8.9009
0.0000
0.0001
0.0000
0.0000
92.8448
6992.6486

( Kmol/j)
0.1058
0.0577
0.0090
0.0001
0.0000
1.2037
0.0000
1.3763
v/l hitung
eror

Yi

Hl
kJ/J
678.914
380.062
7610.614
373.146
5.081
0.000
0.000

Hv
kJ/J
1588.480
680.324
1818.436
47.112
1.068
69.760
0.000

H2
kJ/j
2267.393
1060.386
9429.050
420.257
6.150
69.760
0.000
13252.997

Hl
kJ/j
-20858.561
-10733.525
-103529.798
-4340.391
-71.937
0.000
0.000

Hv
kJ/j
-8079.300
-3409.691
-3048.518
-62.552
-1.301
-700.924
0.000

H3
kJ/j
-28937.861
-14143.216
-106578.316
-4402.943
-73.238
-700.925
0.000
-154836.499

Hl
kJ/j
-72576.269
-35649.296
-223953.550
-9101.027
-179.324
-0.007
0.000

Hv
kJ/j
-615.057
-266.459
-100.584
-1.814
-0.037
-1471.352
0.000

H4
kJ/j
-73191.325
-35915.755
-224054.134
-9102.841
-179.361
-1471.360
0.000
-343914.775

k
Cp . Yi
12.6680
7.4858
24.5139
0.8987
0.0263
0.3906
0.0000
45.9834

KOMPONEN

HCl

-1.85E-03
-1.94E-03
-1.22E-03
-1.90E-04
-7.00E-04
-1.19E-03

H2O

5.30E-04

CH3CL
Cl2
CH2CL2
CHCL3
CCL4

Cp camp =
ok

10^(A+(B*(1-(T/C))^(2/7)))

0.8691
0.2076

0.246
0.134
0.585

0.021
0.001

miu camp =
ok

0.013

0.8083 Cp
1.9560 lb/ft.hr

0.000
1.000

1.5605 kg/L
1560.5454 kg/m3
97.4217 lb/ft3

sg

0.6889

1.0000
0.0624

Vi
( Kg/j )
962.9221
718.1624
1506.7300
43.1998
0.9969
43.9334
0.0000
3275.945
1.0599
-0.4901

yi

xi
0.294
0.219
0.460
0.013
0.000
0.013
0.000
1.000

0.055173571
0.048130342
0.841971876
0.052628051
0.00209616
9.42406E-10
0
1

Yi/V
( Kg/j )
503.5975
361.6330
260.0250
5.9053
0.1247
43.9334
0.0000
1175.219

Lci
( Kmol / j )
4.1198
2.5562
37.3525
1.6607
0.0513
0.0000
0.0000
45.741

L akhir
(Kmol/j)
9.0955
5.0215
14.6671
0.3121
0.0057
0.0000
0.0000
29.102

Lci
( Kmol / j )
17.3352
10.1340
89.3720
3.6335
0.1083
0.0000
0.0000
120.5831

L akhir
(Kmol/j)
-5.4785
-2.3456
34.3432
1.6120
0.0505
0.0000
0.0000
28.1816

Lci
( Kmol / j )
40.1490
22.6136
144.4009
5.6550
0.1661
0.0000
0.0000
212.9846

L akhir
(Kmol/j)
17.0671
10.0002
89.3312
3.6329
0.1083
0.0000
0.0000
120.1398

0.2589
-0.2411

Yi

( Kg/j )
18.8799
13.6026
4.2351
0.0847
0.0017
43.9334
0.0000
80.7373
0.0197
0.0001

Yi

( Kg/j )
5.3422
4.0997
0.7681
0.0135
0.0003
43.9334
0.0000
54.1572
0.0148
0.0001

yi

xi
0.0032
0.0008
0.645
0.2434
0.0799
0.0275
0.0002

0.0006
0.0002
0.8617
0.6445
0.3524
0.0000
0.0022

10^(A+(B*(1-(T/C))^(2/7)))

2.03E-05
3.83E-05
1.84E-05
2.23E-05
2.21E-05
4.48E-05

7.32E-08
-6.35E-09
3.54E-08
1.23E-09
6.79E-09
2.10E-10

4.71E-05

4.96E-08

326.496

k pd Ta

t=

k pd Ta (W/mK)

k (Btu/j.ft.oF)

yi

#NUM!

#NUM!

2.94E-01

#VALUE!

#VALUE!

2.19E-01

#NUM!

#NUM!

4.60E-01

#NUM!

#NUM!

1.32E-02

#NUM!

#NUM!

3.04E-04

#NUM!

#NUM!

1.34E-02

#NUM!

#NUM!

0.00E+00

ki.yi
#NUM!
#VALUE!
#NUM!
#NUM!
#NUM!
#NUM!
#NUM!
0.20

komponen kmol/jam kg/jam

ch3cl
24.6207
1243.34535
cl2
57.5721
4087.6191
ch2cl2
7.8945
671.0325
HCL
8.8084
321.5066
CHCL3
0.2826
34.0533
CCL4
0.1162
17.8948
total
99.2945
6375.45165
ch3cl
cl2

4511.71
8979.474

Komponen Umpan Masuk:

umpan CH3CL
KG/JAM
CH3CL
6387.81
CH2CL2
320.9954774
UMPAN CL2
KG/JAM
8530.500504
CL2
H2O
448.9737108

wi
0.195021
0.64115
0.105253
0.050429
0.005341
0.002807
1

Master
ch3cl
cl2
ch2cl2
hcl
chcl3
ccl4
total

kg/jam
6187.5
918.699
214.494
38.278
17.303
1.818
7378.092

kg/jam
2225.431
961.785
5050.973
3827.778
2249.134
440.567
14755.67

kmol/jam
44.06794
13.54627
59.42321
104.8706
18.66501
2.860825
243.4339

wi
0.150819
0.065181
0.342307
0.259411
0.152425
0.029857
1

kmol/jam
122.5248
12.93942
2.523459
1.048712
0.143593
0.011805