MOLECULAR WEIGHT FORMULA WHERE MOLECULAR WEIGHTS ARE - BUTANE - 58.120 NH3 = 17.032 vom - 62.50 PROPANE - 44.094 PROPYLENE - 58.088 METRIC TONNES VAPOUR = VOL. X MW. X_ To X Po +P 22818 ToT Po T= TEMP To= STD. TEMP P = PRESSURE Po = STD. PRESSURE STD. PRESSURE MM= 760) M KGICM2 = 1,033 TO CALCULATE FACTOR 013.3 BARS= 1.0133 PSC= 14.698 inHg =29.021 MOLECULAR WEIGHT FACTOR = __ MW. X_273 Wat4 1033 7 FORK.G. =] MW. x_273 P asia F033 M.T. VAPOUR = VAPOUR FACTOR X M3 J P| : Dye xe TO VAPOUR FACTOR = MW.FACTOR X 1 Pe ( Mw ox + cua? 273+ T wedla pea — Mw. FACTOR BARS ks BUTANE = . 6986036 685281 PROPANE = 53011 519903 NH3- = 204725 2008208, VoM = 751251 736824 PROPYLENE = .505778 496133, BUTADIENE = 698604 6849035 bpm. fees > ! ht ‘ ns fry KS 7 foes bedDRAFT, FORD. AFT TRIM LIST. [ANKNO | GRADE [rancno TT anenoz [anenos [_vanenow LiQuID Temp. DEG C. VAPOUR TEMP DEG C [VAPOUR PRESSURE BARG RUE DENSITY @ 15 DEG C (in Vacuum) JCONSTANT VALUE (0.0011) o- sue Tobe se 0.0011 0.0011 2.0014 0.001 JAPPARENT DENSITY @ 15 DEG C (In Ai) MOLECULAR WEIGHT JOBSERVED SOUNDING. DENSITY CORRECTION [TAPE CORRECTION [TRIM CORRECTION List CORRECTION [CORRECTED SOUNDING Lau VOLUME @ 20 DEG & [THERMAL CORRECTION istsagoi FACTOR LIQUID VOL. @ ORS. TEMP. [VF or VRF TO 15 DEG C (TABLE 54) Liquio VOLUME @ 15 DEG C JAPPARENT DENSITY @ 15 DEG C (InAir) [WEIGHT OF LIQUID IN MT. [TANK VOL. (109%) @ 20 DEGC 17490 558 20389.905, 20382.356 20235.738 [roTAL LIQUID vou. [VAPOUR VOL @ 20 066 ¢ [THERMAL CORRECTION FACTOR VAPOUR VOL @ O85, TEMP. [TRUE VAPOUR DENSITY @ OBS. TEMP. [CONSTANT VALUE (0.0011) or see 70156 0.0011 090011, 0.0014 9.0011 JAPP_VAP DENSITY @ OBS TEMP. MASS OF VAPOUR IN MT, [WEIGHT OF LIQUID IN MT. [OTAL WEIGHT IN MAT. GRADE PROPANE BUTANE, UNIT cum | mr. ut] ees [cum 7 mr. ut e618 [TOTAL ON BOARD ON ARRIVAL [TOTAL ON BOARD ON DEP. [TOTAL LOADED / DISH. |SHORE FIGURES. [SURVEYORS FIGURES DENSITY OF VAPOUR AT OBS'D TEMP = 288 x (1.013 + Py)_x MOLECULAR WEIGHT (Pv = Vapour Press. - Guage) Get x 1013 x 23645 (Tv= Vapour Tema. Deg CiLaws of Physics for gas ‘When the weight of any gass equal to its molecular weight, its volume is equal to 22.414 firs Provided that its temperature is 273 degs kelvin (0 degs C) and its pressure is 1 Atmosphere Boyle's Law states that if temperature of gas is kept constant, its Volume is inversely propotionel to its Pressure 1e.P;V, =P2V; or Constant Charles law states that if pressure of gas is kept constant Volume of gas is directly propotional to its temperature he. VslTy BV 2/12 OF VM 2 = T/T Now since Volume in 1 atmospeher at 273 degs K (or 0 degs C)is equal to 22.414 irs Therefore Volume in 1 atmosphere at 273 + 15 degs K (or 15 degs C) is equal to Var ViKTaIT, = 22.414 x(273 + 15)/273 = 23.645 ts Pressure law states that f Volume of gas is kept constant , Pressure of gas s directly propotional to its temperature 1e.P,/T, =P,/T; = Constant The above three laws may be combined into P.ViIT, = PVT, = Constant ‘where Py= 1 atmosphere, Vi = Volume in ts a 15 dogs C and T; = 18 dege C in kevin where P: = Observed pressure in atmospheres, = Volume in ts at observed temperature and T; = observed temperature in kelvin Therefore Vz = Py x Vy x Tol (Ty x P3) V2 = atmosphere x Volume in irs at 18 dags C x Observed Temp. in K/ (Temp. in K at 15 degs C x Observed pressure in atmospheres) ‘r using Universal Ideal Gas Constant PV/T = (Mim) xR \heteP is absolte pressure in pascals Nim’, Vf incubic metres, Ti n degrees Kelvin, Mis mass of gas in Kgs, mis the molecular weight and Ris the Universal Gas Constant = 8.314 Kikg mol K Using above formula V2 = P1 x V1xT2/(T1 x P2) we get volume of gas of a mass of molecular weight Now Mass / Volume = Density ‘Therefore Vapour Density at Obs. Temp. = Molecular weight / Volume \Vap. Density at Observed Temp = MoLWt. x T J Sh 1 atmosphere x Volume ints at 15 degs C x Observed temperature in K Since Pressure readings obtained in bars or kg/cm? all pressures to be converted to bars of kg/em? depending con the unit of the pressure gauge, 1 atmosphere = 1.013 bars = 1.033 kg/m? Therefore Vapour density at Observed Temp = MolWt.x (273+ 15) x (1.013 + Vapour Press 1,013 x 23.645 x (273 + Observed temperature in C) ‘Shore Terminals supply Liquid density information at 15 degs C or 60 degs F in vacuum. To convert this to density in air for LPG liquids, use thumb rule Density in air= density in vacuum - 0.0011 fr find and apply the factor for converting Weight in Vacuum to Weight in Air from ASTM Table 56 Thermal correction factor tor iquid and for vapour can be found from Tank Tables. Density correction, Tape ‘correction, Trim correction and List correction also can be found in Tank Tables. VRF or VCF to 15 degs C ‘can be found in ASTM Table 4, From Cargo Calculation Sheet it can be seen that Liquid Volume at 20 deg C is multiplied by Thermal correction factor to obtain Liquid Volume at Obs. Temp. andis then muliplied by VRF or VCF fo 15 dags C to obtain Liquid Volume at 15 degs Candis then multiplied by Density in Air to obtain Weight of Liquid in Air. Hence if we muitily Thermal correction factor for iquid by VRF or VCF to 15 degs C and then by Density to Air we can get a factor to convert Liquid Volume at 20 degs C to Weight of Liquid in Air or Vice varsa by muliplying this factor by Liquid Volume at 20 degs C or dividing Weight of Liquid in Air by this factor respectively. we have to load 2 gases in 1 tank (mixture) We can get the approx. weight and densities of both gases for the message from shore With the above info we can calculate the approx. Volumes of the 2 gases Vi = Wy, ; V2 = WalD2 (Note: shore supplies these densities usualy at 15 deg Cia vacuum hence approx volumes area 1S degs C) Therefore approx. Wuyx = Ws + W2 & APPFOX. Vauxiia tts deg¢ = Vs + Vo Therefore Approx. Density x ssegc = WMIK / apprOX. VMIX cca 18Tre 2pPrOX density L1G mix x angc We Can ook up Tom the ax table and get approx density LIQ mix Tepe nth observed ego tank sounding, we can get densty corecton. We can then get tape eorecans by looking at vapour Tee at Oe tim and hee correction from vs present itm & heel and apph these sonestone eres eee ‘sounding ier the frst gas i loaded we can calculate the volume of quid, volume of vapour and density of the vapour as done normally {for single cargo. We can then calculate as follows Yaa X Denstya iors dog¢ = Waa (Densitva ic ssngc SUpped by terminal) Va var x Densttya vas = Ws vie (Density, vap calculated on board) Wrrera, Now Wa tora. ! Density, aw isaepe Va rorAs a1 ag c(Stcealbutane vapour wil eondense as son a propane loaded.) NOW Ve aes degc = VMIX 1c at 8 dogs c = Va rorat at 18 deg Denstyrwcseissesc = _(Varorac aap X DENSI ua ass up c+ Vests. ic X Density uo at 15 dag c) Varorauatsseg¢ * Veatts cog Now we can calculate the Molecular weight as follows; We x MM, = We = x MWg ’ Wat Wex MWe = 2 +b Therefore MWyx = ath Wa* We Now with MW we can calculate Vapour Density sox a sees eng We can then calculate Vapour Weight and then total cargo,