Piezoelectric Nanogenerators For Self-Powered Nanodevices
Piezoelectric Nanogenerators For Self-Powered Nanodevices
www.computer.org/pervasive
Piezoelectric Nanogenerators
for Self-Powered Nanodevices
Zhong Lin Wang, Xudong Wang, Jinhui Song, Jin Liu, and Yifan Gao
Vol. 7, No. 1
JanuaryMarch 2008
2008 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or
for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be
obtained from the IEEE.
For more information, please see www.ieee.org/web/publications/rights/index.html.
I M PL ANTA B L E E L E CTR O N I C S
Piezoelectric
Nanogenerators
for Self-Powered
Nanodevices
A novel approach converts nanoscale mechanical energy into electric
energy for self-powering nanodevices.
fy
1
1
0 + E
(1)
1
a
P ER VA SI V E computing
49
IMPLANTABLE ELECTRONICS
Maximum 0.405
Maximum 0.268
0.4
0.25
0.20
0.15
0.05
0
0.05
0.15
0.20
0.25
Minimum 0.268
0.2
Potential (V)
Potential (V)
0.3
0.1
0
0.1
0.2
0.3
Minimum 0.398
(a)
(b)
3
4( 0 + )
(2)
a3
l3
vmax
50
P ER VA SI V E computing
www.computer.org/pervasive
z
VT
VC
>0
=0
<0
y
(a)
(b)
(c)
Vm
Vm
I0
VT
RL
VT
VC
VC
ZnO
Ag
(a)
(b)
An innovative design
Although the AFM-based approach
has been useful in exploring the principle
of the nanogenerator and its potential for
20 m
Figure 4. Scanning Electron Microscopy images of a ZnO wire with one end affixed by silver paste onto a silicon substrate and the
other end free.
JANUARYMARCH 2008
P ER VA SI V E computing
51
IMPLANTABLE ELECTRONICS
Topography
V(mV)
Output voltage
R
0
4
0
30
60
30
60
(b)
V(mV)
(a)
0
4
0
Figure 5. In-situ observation of converting mechanical energy into electric energy by a piezoelectric ZnO wire, shown via
two characteristic snapshots and the corresponding topography and output voltage images. (a) The AFM tip pushes the wire
toward the right side but doesnt go above and across its width, which the topography image indicates. We didnt detect any
output voltage. (b) The AFM tip pushes the wire toward the right side and goes above and across its width, as the peak in the
topography image indicates. The output voltage image showed a sharp negative peak. There is a delay in the output voltage
peak in reference to the normal force image (the peak in the topography image). Y represents the relative position of the
scanning tip perpendicular to the wire.
52
P ER VA SI V E computing
www.computer.org/pervasive
Zigzag electrode
ZnO nanowires
Conductive
substrate
JANUARYMARCH 2008
V+
V+
I
Ultasonic wave
II
III
IV
Sonic or
mechanical waves
(a)
Advantages
and potential applications
The piezoelectric nanogenerator
could potentially convert the following
into electric energy for self-powering
nanodevices and nanosystems:
mechanical-movement energy, such
as body or muscle movement or
blood pressure;
vibration energy, from acoustic or
ultrasonic waves; and
hydraulic energy, such as from the
flow of body fluids or blood, the contraction of blood vessels, or dynamic
fluid in nature.
The microelectromechanical systems
microgenerator, which is mostly built
on a piezoelectric thin-film cantilever,11
can also convert such energy into electric energy. However, the ZnO NW-
(b)
P ER VA SI V E computing
53
IMPLANTABLE ELECTRONICS
NG II
I sc(nA)
1.0
0.7 nA
1 nA
0.5
0
5
10
15
Time (s)
NG I
(a)
20
(b)
10
15
Time (s)
NG II
0.5.
10
(c)
2.0
10
15
Time (s)
20
1.0
I sc(nA)
1.5
1.8 nA
0.5
0
4 nA
2.5
I sc(nA)
20
NG II
0.5
I sc(nA)
1.5
NG III
NG I
1.0
I sc(nA)
8
7 NG III
6
5
4
3
2
1
0
1
5
2.0
NG I
1.5
10
15
Time (s)
(d)
5.9 nA
20
(e)
10
15
Time (s)
20
Figure 7. A short-circuit current (ISC) measured from an integrated nanogenerators system. We measured the current signal
from three individual nanogenerators: (a) NG I, (b) NG II, and (c) NG III. (d) The current signal we measured from connecting NG
I and II in parallel. (e) The current signal we measured from connecting NG I, II, and III in parallel. (Insets show the connection
configuration.)
54
P ER VA SI V E computing
www.computer.org/pervasive
the AUTHORS
ACKNOWLEDGMENTS
The National Science Foundation, US Defense
Advanced Research Projects Agency, Department of Energy, National Institute of Health, and
National Aeronautics and Space Administration
sponsored this research.
REFERENCES
1. Y. Huang et al., Logic Gates and Computation from Assembled Nanowire Building Blocks, Science, vol. 294, no. 5545,
2001, pp. 13131317.
2. A. Bachtold et al., Logic Circuits with
Carbon Nanotube Transistors, Science,
vol. 294, no. 5545, 2001, pp. 13171320.
3. J. Chen et al., Bright Infrared Emission
from Electrically Induced Excitons in
Carbon Nanotubes, Science, vol. 310,
no. 5751, 2005, pp. 11711174.
4. B. Tian et al., Coaxial Silicon Nanowires
as Solar Cells and Nanoelectronic Power
Sources, Nature, vol. 449, 18 Oct. 2007,
pp. 885890.
5. Z.L. Wang and J.H. Song, Piezoelectric
Nanogenerators Based on Zinc Oxide
Nanowire Arrays, Science, vol. 312, no.
5771, 2006, pp. 242246.
6. P. X. Gao et al., Nanowire Piezoelectric
Nanogenerators on Plastic Substrates as
Flexible Power Sources for Nanodevices,
Advanced Materials, vol. 19, no. 1, 2007,
pp. 6772.
7. J.H. Song, J. Zhou, and Z.L. Wang,
Piezoelectric and Semiconducting
Coupled Power Generating Process of a
Single ZnO Belt/Wire. A Technology for
Harvesting Electricity from the Environment, Nano Letters, vol. 6, no. 8, 2006,
pp. 16561662.
8. Y.F. Gao and Z.L. Wang, Electrostatic
Potential in a Bent Piezoelectric Nanowire.
The Fundamental Theory of Nanogenerator and Nanopiezotronics, Nano Letters,
vol. 7, no. 8, 2007, pp. 24992505.
9. X.D. Wang et al., Direct-Current Nanogenerator Driven by Ultrasonic Waves,
Science, vol. 316, no. 5821, 2007, pp.
102105.
10. X.D. Wang et al., Integrated Nanogen-
JANUARYMARCH 2008
Zhong Lin Wang is a Regents Professor and College of Engineering Distinguished Professor at Georgia Institute of Technology. His research interests
include the science and application of nanoparticles, nanowires and nanobelts; functional oxide and smart materials for sensing and actuating; and
nanomaterials for biomedical applications and nanodevices. He received his
PhD in physics from Arizona State University. Hes a fellow of the American
Physical Society and the American Association for the Advancement of Science. Contact him at the School of Materials Science and Eng., 771 Ferst Dr.
NW, Georgia Inst. of Technology, Atlanta, GA 30332-0245; zhong.wang@mse.
gatech.edu; www.nanoscience.gatech.edu/zlwang.
Xudong Wang is a research scientist in the school of Materials Science
and Engineering at Georgia Institute of Technology. His research includes
designing, assembling, and testing piezoelectric-nanowire-based devices.
He received his PhD in materials science engineering from Georgia Institute
of Technology. Contact him at the School of Materials Science and Eng., 771
Ferst Dr. NW, Georgia Inst. of Technology, Atlanta, GA 30332; xdwang@
gatech.edu; www.nanoscience.gatech.edu/zlwang/group/xw.htm.
Jinhui Song is a PhD candidate in the school of Material Science and Engineering, Georgia Institute of Technology. His research interests include synthesizing and characterizing large-scale 1D aligned nanowires, investigating
nanostructure properties using AFM, and fabricating nano devices based on
nanowires. He received his MS in physics from Georgia Institute of Technology.
Contact him at the School of Materials Science and Eng., 771 Ferst Dr. NW,
Georgia Inst. of Technology, Atlanta, GA 30332; [email protected].
Jin Liu is a PhD candidate in the School of Electric and Computer Engineering
at Georgia Institute of Technology. His research mainly focuses on fabricating
piezoelectric nanowire-based devices and developing novel processes for the
integration of top-down and bottom-up approaches in nanoscale devices. He
received his MS in electric and computer engineering from Georgia Institute
of Technology. Contact him at the School of Materials Science and Eng., 771
Ferst Dr. NW, Georgia Inst. of Technology, Atlanta, GA 30332; gt1687c@mail.
gatech.edu
Yifan Gao is a graduate research assistant at Georgia Institute of Technology.
His research interests include packaging of nanogenerators and theoretical
calculations of piezoelectric nanosystems. He received his BS in physics from
Peking University of China. Contact him at 771 Ferst Drive, J. Erskine Love
Bldg., Atlanta, Georgia 30332-0245; [email protected].
12. Z.L. Wang, The New Field of Nanopiezotronics, Materials Today, vol. 10, no. 5,
2007, pp. 2028.
For more information on this or any other computing topic, please visit our Digital Library at
www.computer.org/csdl.
P ER VA SI V E computing
55