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4541t1 Kimia Kertas 1 Sept 2009 1 ' / aj a m

JA B A T A NPELAJARAN NEGERI JOHOR P E P E R IKSAAN PERCUBAAN SPM

KIM IA Kertas 1 S a tujam iim abelas minit

JA N GA NB U K A K E R T AS SOALANINISEHINGGA DIBERITAHU 1. 2. 3. Kertas soalanini adalahdalamdwibahasa. yang sepadan Soalan dalambahasa lnggeris mendahului soalan dalambahasaMelayu. Calondikehendaki membaca maklumat halamanbelakanqkeftas di soalanini.

ini K e rta s a l an r r r engandungi halam an cetak so 42 ber

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SULIT

454yr

Whichof the following represents arrangement particles water? the of in Antaraberikut,yang manakahmewakilisusunan zarah bagi air?
Affi\

)#
ffi

aY-nl

dlfr
B
Xn-rWrvrr
\_./ L

nW-X

-AJ

"I 0
D

VY

a-P

ffi
gas contains 1 moleof oxygen 6.02x 1023 molecules 1 mol gas oksigenmengandungi 6.A2x 1A?3 molekul 1 moleof sulphur atomcontains 6.02x 1023 atoms 1 mol atom sulfurmengandungi 6.02x 1023 atom 1 moleof a gas occupies dm3 roomcondition 24 at 1 molgas menempati dm3padakeadaan 24 bilik 1 mole of a gas occupies dm3 standard 24 at temperature pressure and 1 mol gasmenempati24 dm3 paclasuhu dan tekananpiawai

Whichof the following statement not truefor one moleof a substance? is Antarayang berikut, yang manakahtidak benarbagi satumol bahan? A B

c
D

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SULIT

454U1

of Diagram showsthe symbol fluorine 1 atom. Rajah 1 menunjukkan simbolbagi atom fluorin

Diagram 1 Rajah 1 Whichof the following true basedon the symbol Diagram is 1. in Antara berikutyang manakahbenarberdasarkan simboldalam Rajah 1 Proton number A B Nu c le o n u mb e r n Nombornukleon Numberof electron Bilanaan elektron

c
D

10

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SULIT 4 which of the following comparison correct is aboutioniccompounds and covalent compounds?

4541tl

Anlara perbandingan berikut, yang manakahbetutmengenai sebatian ionik dan sebatiankovalen? loni c c o mp o u n d s Sebatian ionik Havelow melting and boiling points Mempunyaitakatlebur dan didih yang rendah. E xista s s o lid t ro o m a temperature. Co v a le n tc o mp o u n d s Sebafian kovalen Ha v eh ig hme lt in g n d b o ili n g a p o t n ls . Mempttnyaitakatlebur dan didih yang tinggi. Ma ye x is ta s s o lid , u id r g a s liq o at roomtemperature.

Wujudsebagaipepejatpada suhu Baleh wujudsebagatpepejal, bitik cecairatatt gas pada suhu bilik. Conduct electricity aqueous in s o lu t io n r mo lt e n t a t e . o s Mengkondu ksi kan elektrik dalamlarutanakueusatau

Do notconduct electricity. Tidak mengkonduksikan elektrik,

Usually is s o lv e o rg a n ic d in solvents. Biasanyalarut dalantpelarut organik.

Usually dissolve water in Biasanya larutdalam air.

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SULIT

4541tr

Whichof the following wili circuit cause bulbto lightup? the Antaralitar berikut.yang manakahakanmenyalakan mentol'r
I I

F-----------1

Am m onia solution Lartttan ammonia

ill

Glucose solution Larutanglukosa

IV

F-___-l

Ethanol Etanol I and ll only I dan ll sahaja I and lll only I dan lll sahaja D lll a n d lV o n ly lll dan lV sahaja ll a n d lll o n ly ll dan lll sahaja

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SULIT

451Ur

Whichof the following not a chemical property an alkali? is of Antarapernyataanberikutyang manakahbukan sifatkimia suatu alkali? A B C D Alkali+ acid + Alkali+ asid ) Alkali + salt+ water garam + air salt + water insoluble metalhydroxide g s a lt + wa t e r + a mmo n ia a s garam + air + gas ammonia

metal +

A lkali + loga m )g a ra m+ a ir Alkali+ metalion ) Alkali + ion logam ) Hidroksidalogam yang tidak larut A lkali+ ammo n iu ma lt ) s Alkali + garam ammonium t

Whichof the following is insoluble water? salt in Manakahdi antarayang berikutmerupakan garamtak terlarutkan dalamair? di A B C D Silvernitrate Argentumnitrat Calcium chlorid e Kalsium klarida A mmonium sulp h a t e Ammoniumsulfat Lead(ll) carbonate Plumbum(ll) karbonat

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4541t1 Diagram showsthe flowchartof Contact 2 Process manufacture to sulphuric acid. Raiah2 menunjukkan carta alir prosesSenluhuntukpembuatan asidsutfurik S ulphur S u lp h ud io x id e r Sulfurdioksida
bul0nurtnoxrde i
,l

.l

t, Sulfur _i

----------|l

Sutfur trioksida

W
Diagram 2 Rajah 2
Whatis X ? Apakah X? A B C D Oleum abum A mmonia Ammania Nitric Acid AsidNitrik S ulphur monoxi d e Sulfurmonoksida

{- [i]

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SULIT which of the following statement explains decrease rateof best the in peroxide time? decomposition hydrogen of with Antara berikut,yang manakahpenerangan terbaikuntukmenerangkan pengurangankadar penguraian peroksida dengan masa? hidrogen A B Decrease quantity products in of Pengurangan kunatitih ast I Decrease volume hydrogen in peroxide of Pengurangan isipadu hidrogenperoksida C D Decrease temperature hydrogen in peroxide of Pengurangan peroksida suhu hidrogen Decrease concentration hydrogen in peroxide of Pengurangan kepekatan peroksida hidrogen

{541i1

10 Margarine madeby hydrogenationthe unsaturated is of vegetable oil suchas sunfloweo ilo r p a lmo rl. r Margerindihasilkan melaluipenghidrogenan minyaksayuran tak tepu seperli minyakbungamatahari atauminvaksawit.

Basedon the information above whatis the catalyst, temperature pre$sure and needed the reaction takeplace? for to Berdasarkan maklumatyang diberi.apakahmangkin,suhu dan tekanan yang diperlukan untuktindakbalastersebut berlaku?

Catalyst

Temperature(oC)

A B

Wkt,
tron
lron Nickel Nbk;

i
I

srhrf c)_
goo 20a

Pressure(atmosphere) Tekanan(atmosfera)

c
D

_i
4

I
I

* --t

I
I

200

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SULIT

4541tt D i a g ra m sh o w sa se t- up appar atus a r edox eaction. 3 of of r Rajah3 menunjukkanset radas untuk tindakbalas redok.

11

l ro n(l l )su l p h a te (ll) Ferum sulfat

Acidified Potassium manganate$/lsolution l) Kaliummangganat(Vll) berasid

S u lp h u ric c id a Asidsulfurik

Diagr am 3 Rajah3 Whichof the following correct? is Manakahantarapernyataan berikut adalahbenar? l ro n (l l )o n ,F e 't is r educed i lon Ferum(ll), penurunan Fe2*mengalami Electrons flowfromelectrode to Q P Elektronmengalirdari elektrodP ke Q T h e p u rp l e l our solution co gr of becomes een Warnaungu larutanmenjadihijau Ma n g a n a te (V ion,MnO+- acts the r educing ll) as agent l o n ma n g a n a t(Vll) , MnO+- tindak ber sebagai agenpenur unan

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SULIT 12 rs Whichof the following an endothermic reaction? Manakahantaraberikutadalahtindak balasendotermik? A B C D pellets distilled Dissolving sodium hydroxide in water butirannatriumhidroksida Melarutkan aalam air (ll) Addingzincpowder copper sulphate to solution Tambahkan serbukzink kepadalarutankuprum(ll) sulfat Dissolvingmmo n iu mh lo rid s o lidin d is t ille wa t e r a c e d pepejalantmonium Melarutkan kloridadalam air suling The combustion ethanol excess of in oxygen Pembakaran etanoidalamoksiqenberlebihan

154u1

13

food.Whichof thefollowing a thickener? Thickeners usedto thicken are is untukmemekatkan Agenpemekatdigunakan makanan. Yangmanakah antara satuagenpemekat? berikutmerupakan A B C Vinegar Cuka Lecithin Lesitin Gelatine Gelatin D Aspartame Aspaftam

t0
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SULIT
14 Diagram belowshowsan atomic 4 model Rajah4 menunjukkan suatumodelatom.

454u1

r'c\r ,!\
\\

?-o:'
lr t A
A \-,

V ., //

Dia g ra m 4 Raiah 4 Whichof the following not true? is Antarapenyataanberikutyang manakahtidak benar? A B C P roposed J.J. T h o ms o n . by Dicadangkan oleh J.J. Thomson positively*charged The nucleus particles contains calledprotons. positifyang dipanggil Nukleus mengandungi proton. zarahbercas The electrons movein a space thatis larger thanthe spaceoccupied by the nucleus. Electronbergerakdalamruangyang lebih besardaripadaruangyang ditempati oleh n ukleus. D The positive charge and mostof the massof the atomare conceritrated in the nucleus. jisimatom terTumpu pada nukleus. Cas poslfifdan kebanyakan

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SULIT 15

.154 t/r
Thefollowing equation shows reaction the gas between hydrogen and iodine gas icdide. to formhydrogen Persamaanberikut menunjukkan tindak balasantara gashidrogendan gasrodrn untuk membentukhidraqeniodida. H, (g ) + lz (9 ) ) 2 Ht (g )

Whichof the following statement not true? is Antarapernyataan benkutyangmanakah tidak benar? atomic mas s ,H = 1 , | = 1 2 7] I Relative H I JisimAtom Relatif, = 1, | = 127] at and I Molarvolumeof gas = 24 dm3mol"r roomtemperature pressure] suhu dan tekananbilikl flsipadumolar gas = 24 dm3mofl pacla A 2 molecules hydrogen of produced react with2 molecules iodine of 2 molecule hydrogen of iodide 2 malekulhrdragen bertindakbalasbertindakbalasdengan2 molekul iodin menghasilkan molekulhidrogeniodida 2 B '1 2 mol of hydrogen iodide produced the reaction is by between molof ga g hydrogen s a n d 1 mo lo f io d in e a s 2 mo! hidrogen iadidadihasilkan olehtindakbalasantara1 mol qas hidrogendan 1 mol gasiodin C 48 dm3of hydrogen iodide produced the reaction is by between molof 1 ga g hydrogen s a n d I mo lo f io d in e a s 48 dm3hidrogenioclicia clihasilkan tindak balascltantara mol gas oleh 1 hydrogendan 1 mol gas rodin D g 1 mol iodine a sa n d 1 mo lh y d ro g eg a s a re re q u ire do p ro d u c e m o l n t 2 gas cf hydr"ogen iodide 1 mol iodirtdan 1 mol gashtdrogen diperlukan untukmenghasilkan mol 2 gas htrogeniodida

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4541t1

16 Diagram showsthe position element in the Periodic 5 of X Tableof Element. Whichof the following not true aboutthe element? is Rajah5 menunjukkan kedudukan unsurXdalamJadual Berkala lJnsur.Antara berikut,yang manakahtidak benar tentangunsuritu?

Dia g ra m 5 Rajah5

It doesnotconduct heat la tidakmengkonduksi haba poin t It has highmelting ta mempttnyai takatleburyang tinggi

It canformcoloured comp o u n d s la boleh membentuksebatian yang benuarna It showsdifferent oxidation numbers itscompounds in la menunjukkan nomborpengoksidaan yang berlainandalam sebatiannya

-l J

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SULIT 17

154u1

gas Magnesium reacts withchlorine to produce magnesium chloride. Whichof the following true aboutmagnesium is chloride? Magnesium bertindak balas dengan gas klorin untuk menghasilkanmagnesium klorida" Yangmanakahadalahbenar tentangmagnesium klarida? Molecular Formu la Formula molekul MgCle
MgCl2

Bond lkatan lo n ic !onik Covalent Kovalen lo n ic ionik

Type Of Particles Jenis Zarah lo n ion Molecule Molekul ton lon Mo le c u le Molekul

MgCl

Co v a le n t Kovalen

T4
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SULIT 18 Diagram showsthe set-upof apparatus a chemical 6 of cell Whichof the following true of a chemicat are cell? Rajah 6 menunjukkansusunanradassuarusel kimia. Antaraberikutyang manakah benarmengenaisetkimia?

'l54lll

Electrodes Elektrod L iq u id A CecairA Dragram 6 Rajah 6 The electrodes of the samemetal. are Elektrod-elektrod adalahlogamyang sama. ll ill The electrodes of different are metals Elektrad-elektrod adalahlogamyang berlainan Liquid is an electrolyte. A CecairA ialah sejenis elektrolit. Liquid is an o rg a n ic o lv e n t . A s CecairA ialahpelarut organik. A I and lV only I dan lV sahaja ll and lll only ll dan lll sahaja ll and lV only ll dan lV sahaja D l, lll and lV only l, lll dan lV sahaja

lv.

ll

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SULIT 19

154u1 22.0cm3of hvdroxide solution, NaOHis needed neutralize to 25.0cm3of sodlum of hydroclrloric HCl.Whatis the molarity the sodium acid, 0.10moldm-3 NaOHsolution? hydroxide, 22.A NaOHcliperlukan untukmeneutralkan 25.Acm3 larutannatriumhidroksida, HCl. cmu0.10 mol dm'3Asidhidroktorik, NaOH? BerapakahkemolaranlarutanNatriumhidroksida, A B C D mol O.0BB dm-3 0.078mol d m-3 0.077mold m-3 0.08mol dm-3

reaction? equation Whichof the following chemical represents neutralisation a satutindakbalas kimiaberikut yangmanakah mewakili Antarapersamaan , peneutralan ? l. ll. lll. lV P bO + Mg + 2HC l + 2HN O 3 ) HzSO4+ P b O lz + Hz O Hz O Hz 2HCl

CH3COOH + BaClz +

KOH )

CH3 CO O K+

M9 (NO 3 )2 * BaSOo +

I and ll only I dan Il sahaja ll and lll only ll dan lll sahaja ll and lV only ll dan lV sahaja l, lll and lV on ly l,ll dan lV sahaja

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SUT,IT 21

454u1

Whichof the following composite materials correctly are matched withtheiruses? Antarabahankomposit yangmanakah berikut dipadankan denganbetul?

Composite materiai tsahanKomposit FibreOptic Fiber Optik gla Fibre s s Fiber kaca S uperco n d u c t o rs Superkonduktor Reinforced Concrete Konkrit y ang diteguhkan and ll only dan ll sahaja and lll only dan lll sahaja ll and lV only ll dan lV sahaja ll,llland lV only
ll il, lll ril ^^r drru t\/ rv -^L^;^ )d|dJd

i i^^^ tJ >CJ

Kegunaan phones Usedin mobile Diqunakandalam telefonmudahalih To makewaterstorage tanks Untukmembuattangkisimpanan air

I L

To makeoptical lenses Untukntembuat kantaontik To buildoil platforms IJntuk nembtnapelantar minyak

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SULIT

4541t1 Diagram showsa graphof the volume carbon 7 of gas produced dioxide against timefor the reaction between calcium carbonate sulphurrc ano acid. Raiah7 menunlukkan graf isipadu gaskarbon dioksida terhasitmelawan masa untuk tindakbalas antarakalsiumkarbonatdan asidsulfurik. Volumeof CO, gas/ cmu lsipadugas CO2/ cm"

Dia g ra m 7 Rajah 7 The gradient the graphdecreases timebecause of with Kecerunangraf berkurangan dengan masakerana Catalyst not used is Mangkin tidak digunakan Voiumeof mixture decreases i sipaducampLtran berkurangan Temperature reaction of decreases lsipadutindak balasberkurangan Concentration sulphuric decreases of acid Kepekatanasidsulfuik berkurangan

Time/ second Masa/ saat

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SULIT 23

4541t1 A carbon compound, caH6undergoes foilowing the chemicar reactions except sebatiankarbon,coH6 menjatanitindak balas kimia berikutkecuati A Combustion reaction Tindak balas Pembakaran B C D Substitution reaction Tindak balas pe nukargantian Halogenation reaction TindakbalasPenghalogenan Hydrogenation reaction Tindak balaspenghidrogenan

24

Whichof the following shows correct the oxidation numbers eachparticle? for Manakahantara berikutmenunjukkan nombor pengoksidaan yang betul bagi sellap zarah?

Ns'
A

Hzo

l9

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SULIT 25 Thefollowing showsa thermochemical equation Berikutadalahsuatupersamaantermokimra.

I
I

1511t1

I t

Nr(g) + 2o z (9 ) -)

2 NO : (g )

AH= +180.6 J k

Basedon the equation above, can be concluded it that persamaandi atas,bolehdisimpulkan Berdasarkan bahaw,a A Energy content nitrogen oxygen hrgher of and is thanenergy content c{ nitrogen dioxide. Kandungan tenaganitrogen dan okstgen aclalah lebihtinggidaripada kandungantenaganitrogendioksida. B C D Heatis released overcome bo'rctng nrtrogen oxygen. to the of and Tenagadibebaskan untukmengatasi tkatan nitrogen dan oksigen. 180.6kJ energy absorbed is during formatron nitrogen the of dioxide. 180.6kJ tenagadiserap penbentukan sernasa nitrogen dioksida. Temperature the surroundings of increases during reaction the Suhupersekitaran bertambah se/7iasa tindakbalasberlaku.

26

Azo andtriphenyl compounds commonly are usedin food industries. Statewhy azo and triphenyl compounds added are foods. Sebafianazo dan trifenilkerap dtgunakan clalant industrimakanan. Nyatakan mengapasebatian dan trifenik azo ditambahke dalam makanan A B C D To restore colour food the in Untttkmengembaltkan warnadalammakanan To stabilise dispersion oil in warer, the of penyebaran Untukmenstabilkan minyakdalamair. To enhance tasteandflavour food. the of Untukmeningkatkan rasadan kelazatan makanan To prevent foodfrombeingoxidised air. the by Untukmenghalang makanan dioksidakan oleh udara.

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SULIT

1541t1

27

Diagram showsthe electron 8 arrangement sodium of atom Rajah B menunjukkan susunanelektronatontnatrium.

Dia g ra m B RajahI Whichis the correct standard representation the atom?[Nucleon for number: 23] Yangmanakahmenunjukkan penwakilan piawaiyangbetul bagi atom tersebut? INombor Nukleon: 23 ] A lllr^ c

2 jtvQ
B

;; tva

2 -t rr

??wo

)ir,,o

28

The number atomsin one moleof carbon of dioxide equalto the number is of atomsin Bilanganatom didalam satumol karbondioksidaadalahbersamaan dengan bilanganatom didalam A B C D 1 molechlorine s ga 1 mol gas klorin 3/4 moleammonia 3/4 mol ammonia 112 malealuminium 1/2 mol aluminium 2/3 molesulphur dioxide U3 mol sulfur dioksida

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SULIT

4s4lt1
Table'1showsthe proton number elements X, y andZ. for W, Jadual1 menunjukkan protonbagiW,X,y dan Z. nombor

29

B T a b le1 Jaclual1 which of the following statement true about elements is the w,X,y andz Antarapernyataanberikut,yang manakahbenar tentangunsur-unsur X, w, dan Z? Element andY are metals W Unsur W dan Y adalahlogam Element willforman amphoteric X oxide UnsurX akan membentuk oksidaamfoterik ill E lement is a ls ok n o wn s n o b le a s Z g a UnsurZ juga dikenalisebagaigas adi All the elements W,X,Y andZ are in period three Semua unsur W, X, Y dan Z beradadalamkala tiga A I and ll only I dan ll sahaja ll and lll only ll dan lll sahaja

IV

c
D

ll , lll and lV on ly ll, lll dan lV sah a ja l, ll , lll and lV l, ll, lll dan lV s a h a ja

/.1

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SULIT

4541/l Diagram showsthe electron 9 arrangement a compounciformed of between atomsX and Y. Raiah 9 menuniukkansusunan elekktronbagi sebatian yang terbentukantara atom X dan Y.

30

Dia g ra m 9 Rajah9 Whichof the following statement trueabout compound? is the Antarapernyataanberikutyang manakahbenartentang sebatian ini? A B C D The compound a h ig hb o ilin g o in t . has p Sebatianini mempunyaitakat yang tinggi dictih The compound doesnotconduct electricity. Sebatianini tidakmengkonduksikan elektrik. The compound formed electron is by transfer, Sebatianini terbentuk melatuipemindahan elektron. The compound exists solidat roomtemperature. as Sebalianiniwujud sebagaipepejal padasuhu bilik.

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31

of 10 the of for Diagram shows set-up apparatus theelectrolysiscopper(ll) Y in nitrate solution beaker ustng in solution beaker andsodium X sulphate electrodes. carbon proseselektrolisis radas susunan menjalankan untuk Rajah10menunjukkan nitratdi dalam larutan Kuprum(ll) sulfatdi dalambikarX danlarutanNatrium elektrod karbon. bikar Y denganmenggunakan

Coppe(ll) sulphate solution Larutan kuprum(ll) sulfat Beaker X BikarX

Diagram 10 Rajah10 Y Beaker Bikar Y

nitrate Sodium solution natrium Larutan nitrat

are at Whichof the following produced the anodesof beakerX and beakerY? Manakah antara berikut hasilyang akan diperolehidi anod pada bikar X dan bikar Y?

Beaker X Bikar X
A Oxygen Oksigen Oxygen Oksigen

Beaker Y Bikar Y -Oxygen Oksigen Nrtrogen Qksigen

Oxygen aksigen S o d iu m Natrium

c
D

Sulphur Sulfur Copper Kuprum

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32

A farmer discovered his vegetables that werenotgrowing well because soil the was acidic. Whichof the following substances be usedto overcome can the problem? Seorangpetani mendapatitanantan sayurannya ticiaktumbuhdengansubur keranatanahnyaberasid.Antarabahanberikut, yang manakahboleh digunakan untukmengatasimasalah tersebut? A B C D Zincoxide Zink oksida Calcium oxide Kalsium oksida S odium hydroxide Natrium hidroksida Magnesium hydro x id e Maqnesiumhidroksida

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S ULIT

4 5 4 ti 1

33 A seriesof iesis were carried on a solution sattX Table2 showsthe results out of of the tests. Safu srri ujian telah dijalankan ke atas larutan qarant X Jadual 2 ntenunjukkan keputusanuiian tersebut. i
I

Test Ujian A dd lead(ll) nitrate solu t io n . Tambahkan larulan plumbum(l nitrat t)

heated

O b s e rv a t io n Pemerhatian Whitepre-iprtate Oisscives ,,,/ater il. when

Mendakan putih, larut dalant atr apaotla
.t;^^,^^^t,^^ vluotlaa^dt !

A dd dilute sulphuric id . ac Tambahkan asid sulfurikcair

No c h a n g e

Addaodlum hydroxrde soluiifi-u;tiln Whiteprecipitate formed is

I t is in s o lu b le e x c e s s o d iu m y d r o x i d e rn s h s o lu t io n . Tambahkan iaruta natrrumhidroksicta n sehingga Derlebihart. Mendakan putih terhentuk. ia tidaklarut daiamiarutannatilum excess.

berlebihan. i hidroksida ionffiilLnxcess F\nIe p;ecibiijie is'roim;A

l
I

Tantbahkan larutanakueusantmonia I sehingga berlebihan. putih terbentux 1Menclakan la tidaklarut dalantlarutanakueus anmoniaberlebihan. T a b le 2 JaCual 2 Basedon the results the experiment. X is of salt Berdasarkan keptiiusaneksperimen, garamX talaii A B C Zinccnioride Zinc klorida Calcium carb o n a t e Kalsiumkarbonat A luminiunru rlp h a t e s Aluminium sulfat D Magnesiumh lo rrd e c Magnesiunt klorida

I t is rn s o lu b le e x c e s s mmo n ia ol u t i o n in a s

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34

Thefollowing information shows properties glassX. the of Maklumatberikutmenunjukkan ciri-c:iri baqi kaca*. Low melting point Takatlebur rendah Easily shaped Mudah dibentuk Highchemical durability Daya tahanyang tinggiterhadap bahankimia Highthermal expansion coefficient Pemalarpengembangan termatinggi Whatis glassX? ApakahkacaX? Fusedglass Kaca silica telakur S oda-lime glass Kaca soda kapur Borosilicate glass Kaca borosilikat Leadcrystal glass Kaca Plumbum

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.t5+ t,,l

35

I and il to studythe rateof in obtained Experiments Table3 showsthe result reaction yangdiperolehi I dalameKsperimendan i! keputusan Jadual3 menunjukkan untukmengkajikadar tindakbalas. I i i 1 . . i -. E xperiment1 Z in c me t a l(5 9 ) .
i i I
I

i il
i i-'

Eksperimen Logamzink(S9) ] . .VoluT" I ., (cm') IstP duu lsiPadu (url l

,

Hy d ro c h lo ric a c id Asidhidroklorik Co n c e n t ra t i o n I

-! '

/mnr .r*.3\ - !mo!{ni)-----:

'

kepe*atan

l)u r'Butirani"
I

l - d lul^ ^Jl^ ^i.,1 c

A,l l

l" t

lf i L_,-_---__

,,
_ ,

P ow der
>C T D U K
,

nc 13

e ) eL

T a b le3 J a d u a3 l graphs represent two experiments? the Whichof the foilowing itu? yang manakah eksperimen graf berikut, mewakilikedua-clua Antara A B Volumeof Hrr'cm3 H2/cm3 lstpaou

Volumeof H2/cm3 lsipaduH2/cm3

+l i
j./

i, ..,'
ji

_---*

rl

l. t iiTimels Masa/ Volumeof H2lcm3

-----***,-*.1"

Timeis Masa/ Volurre cf Hr,cm3 /s/pac.,n. anl'

1l ''-*"--v**

I Iil tC/>

Time/s
!VId Jd !

tvtdJCl/

28
Pelajaran Negeri Johor pta 454 I I | @ 20A9H akci .labatan

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454y1

I1

i I I
r r llf\-t 1 |-l

IJ I I I

I]-

c
I I I LI I1

r '_ a \
L _ -\ _ I I

(-L
i

tr rr

I
It

I I
II

LI

Whatis the namefor the structural formula shownabove? Apakahnama untukformulastruktur yang ditunjukkan atas ? di

Pent-2-ene Pent-Z-ena

3-methylbut-2-ene 3-metilbut-2-ena

2-methylbut-2-ene 2-metilbut-2-ene

2-methylpent-2-ene 2-metilpent-2-ena

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.t54li1

37

whichof thefollowing not true? is 11 In Diagram below, tidak benar? Dalam Rajah11 di bawah,yangmanakah

X plate PlatX

Y p la t e Plat Y
F l ani r nl r i to

Elekrrolit Dia g ra m 1 1 Rajah11 MetalXIY Logam X/Y Metalthat will be reduced Logam yang mengalami penurunan lro n Eesi
f'-nnnor

Besi/Kuprum
/S A luminium t a n u m Aluminium/Timah MagnesiumCo p p e r / Kuprum Magnesium/

Kuprum

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454U1

Table4 showsthe fuelvalues somecommon of fuels. Jadual4 menunjukkan nilai bahanapi untukbeberapabahan api yang biasa.

Fuel Bahanbakar
Coal Arangbatu Charcoa l Arang Kerosene Minyak Tanah

F u e lv a lu e(k J g ' ' ) Nilaibahan baker (kJg')

l
i
I i

g N a tu ra las
i Gas asli Table4 Jadual4 W hich fuelhas a highfue lv a lu eb u tis n o te c o n o mic an o te a s ily v a ila b le n d l, a a non-renewable. Bahan api yang manakahmempunyai nitaibahanapi yang tinggi,tetapitidak ekonomi,sukardiperolehi dan tidakbolehdrperbaharui. A B C D Coal Arangbatu Charcoal Arang Kerosene Minyak Tanah Natural Gas Gas as/i
i

JI

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SULIT 39

454ltr withsoap? will scumwhen it reacts substance produce Whichof the following kekat apabilabertindak Manakahantarabahan berikutakan menghasilkan dengansabun? A B C c S odium h lo rid e Natrium klorida s Calcium u lp h a t e Kalsium sulfat c Magnesiu mh lo rid e Magnesiumklorida D nitrate Potassium Kalium nitrat

40

A Table5 showsthe massof elements and O in a metaloxide,and theirrelative atomicmasses. A Jadual 5 menunjukkanjisim unsur-unsur dan a dalam suatu oksida logam seriajisimatom relatifmasing-masing.

M a s s/ g Jisim /g mass atomic Relative Jisim atom relatif

11 428

Table5 Jadual5 o fl Whatis the empi ric a o rmu la f t h e c o mp o u n d ? itu? Apakahformulaempiriksebatiari A B ArO

c
D

Aro.
A,OU

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4541tl In the Pedodic Tableof Elements, element is in Group2 andelementy is in X Group17.The letters and Y are notthe actual X symbol the elements. of Which of the followingchemicalequationis true for the reactionbetween element and element X Y? Dalam JadualBerkalalJnsur,unsurX berada dalamKumpulan2 dan unsur y beradadalam Kumpulan17. Huruf- huruf X dan Y yang diguna4an bukansimbol sebenar unsuritu. Antarapersamaankimia berikut, yang manakahbenar bagi tindak balas antara unsurX dan unsurY? X + Y) B XY

2X +Y +X 2Y X + Y 2+X Y 2 2X +Y r)2X Y

c
D

JJ

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4541lr
?

rra n g e me n t in io n s WX , , dalamionW , X* elektron

,,*
i

andZ-2+ oan L

/+

,/fi-.\
\ 10n /

(z
\20nl

/,-\

1 Dia g ra m 2 Raiah12 of number the ion? nucleon the shows correct Whichof the foliowing ion nukleon yangbetul? nontbor yang manakah menuniukkan berikut, Antara

Nu c le o nn u mb er Nombor nukleon

A B

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454111

A student wantsto electroplate ironkeywith silver. an Whichof the following pairs of electrodes electrolyte suitable be usedin thisexperiment? and are to Seorangpelajar ingin menyadurkunci besidengan argentum.Pasanganelektroci
dan elektrolit Vanq manakah sesLt

Cathode A B

ElectroivG

- -- __l

Elektrolit S ilv e r u lp h a t e s Argentumsulfat S ilv e r h lo rid e c Argentumklonda tron Sesi

I
I K trhnn

c
D

Ca rb o n

Silvernitrate I, Argentumnitrat S ilv e r y d ro x id e h Argentumhidroksida

44

Hydrochloric reacts acid withsubstance and produces gas as one of the Y a y? products. Whichof the following not substance is Asidhidroklorik bertindak balas denganbahany dan menghasilkan suatu gas sebagai salah satuhasiltindak balas,Manakah antaraberikutbukan bahany? A B C D Zincgranule Kepinganzink Zincoxide Zink oksida S odium thiosulp h a t e Natrium tiosulfat Magnesium carb o n a t e Magnesiumkarbonat

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45

454111 acid hydrochloric and between belowshowsthe reaction equation Chemical sodiumcarbonate Powder. persamaan tindak balasdi antara asidhidroklorik kimia berikutmenunjukkan natriumkarbonat. dan serbuk 2HCl + NazCO: ) 2NaCi + H2C + CO,

when25 cm3of gas dioxide released the Calculate volumeof carbon sodium with completely excess reacts acid hydrochloric of 0.2 moldm-3 carbonate Powder. at 24 ] [ 1 mol of gas occupies dm3 roomtemperature apabila25 cm3 asid yang ctibebaskan gas karb^on dioksida Hitung isipadu balaslengkapdenganserbuknatrium 0.2 nidroktorik mot dm'3berlindak karbonatyang berlebihan.^ [ 1 mol gasmenepati24dm'pada suhu bilik] A B C D 60 cm3 0.6 dm3 50 cm3 dm3 0.'12

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SULIT 46

45tyl The following information showsthe effectof a particular factoron the rateof reaction. Maklumatberikutmenunjukkankesansuatufaktoryang mempengaruhi kadar tindakbalas. Particles havehigher kinetic energy Zarah mempunyaitenaga kinetikyang tinggi Frequency collision particles of between Increases pelanggaran Frekuensi antarazarahbertambah Frequency effective of collision increases Frekuensipelanggaran berkesanbertambah

Whichof the following can causethe aboveeffect? Manakahantaraberikutakan memberikankesan di atas? A B C D Addinga catalyst. Menambah mangkin lncreasing temperature reactants of Menaikkansuhu bahantindak balas Increasing concentration reacranrs. the of Menambah kepekatan bahantindakbalas Increasing surface total areaof reactants. jumlah luaspermukaan Menambah bahantindak balas

)l

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SULIT 47

4541t1 acid '13 of the Diagram is a flow chartshowing conversion alkeneto carboxylic and alkane. dan cafta atirperubahanalkenakepada asid karboksilik Rajah13 menunjukkan alkana.
I
.!-

i-;u'*-l{-Atkana
I I

---------|

I^ I
t{

l"

I i
1 Dia g ra m 3 Rajah13

acid I Carboxylic nsia Karboksilik !

1,2 Whatarereactions and3? '1, balas 2 dan3? tindak Apakah

Hydrogenation Penghidrogenan Hydrogenation Penghidrogenan Oxidation Pengoksidaan

Hydration Penghidratan
Oxidation Pengoksidaan Hydration Penghidratan Hydrogenation Penghidrogenan

Oxidation Pengoksidaan Dehydration Pendehidratan

Dehydration Pendehidratan
Oxidation Pengoksidaan

Hydration Penghidratan

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4511tl P, Q and R are metals. Basedon the ionicequations below, whichof the following is statement true? P, Q dan R merupakanlogam.Berdasarkan persamaan di bawah,penyataan ian yang manakahbenar ? 1 Reaction Tindakbalas 1 Reaction 2 Tindakbalas2 :R +P2+ + R2 * + p

P and Q are oxidised P dan Q teroksida P is moreelectropositive R. than P adalah lebih elel<tropositif daripadaR Q can displace fromitssaltsolution. P P Q boieh menyesarkan daripadalarutangaramnya Q is lowerthan R in the electrochemical series. Q adalahdi bawah R dalamsirielektrokimia.

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SULIT 49 fuels' of Table6 showsthe heatof combustion threecommon untuktiga bahanapi habapembakaran 6 Jactuat menunjukkan Fuel Bahanapi Methane Metana Ethanol Etanal Propane Propana Table6 Jadual6 is statement true? Whichof the following pernyataanberikut,yang manakah benar? Antara A -13 7 6 of Fleat combustion/ kJmol' / HabaPembakaran kJmoll -890

4541i1

-2234

than0'1 mol of propane' produces moreheatenergy 0.1 mol of methane lebih 0.1 mal metanamenghasitkan banyakhaba berbanding0'1 mol prapana. atomsper molecule, of number carbon has Propane the lowest P opana me mp u n y a ib i|a n g a n a t o mk a rb o n p e rmo |e k u l y a n g p a | i n g rendah

of on depends the number oxygenatomsin the The heatof combustion molecule, atom kepadabilangan bergantung sesuafubahanapi Haba pembakaran oksigen dalammolekul'

is when0.05mol of ethanol burntin excess is 6g.g kJ of energy released oxygen. apabilaa.05 mol etanal terbakar lengkap 68.8 kJ tenaga dibebaskan dafam oksigenberlebihan.

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151y1:

50

The production soapcan be represented the equation of by below. Pembentukan sabunboleh diwakilidengan persamaan berikut. Fats/ Oils + Sodium hydroxide Soap + Glycerol ) Lemaldminyak + Natriumhidroksida ) Sabun + Gliserol Whichof the foilowing true? is Yangmanakahpenyataanyang benar? I ll lll lV A B C D Glycerol a typeof alcohol is Gliserol merupakan sey'enr'skohot al The reaction knownas Saponification is Tindakbalasdikenatisebagaisaponifikasi Sodiumhydroxide usedas catalyst is Natriumhidraksida beftindaksebagaimangkin Animalfatsor vegetable arecommonly oils used Lentakhaiwandan minyaksayuranbiasanyadigunakan I and ll only I dan ll sahaja ll and lV only ll dan lV sahaja I and lV only I dan lV sahaja l, li anOlV only l, il dan lV sahaia

E NDO F Q UE S T I O N A P E R P KERTAS SOALANTAMAT

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.t5"11/l

INFORMATION CANDIDATES FOR MATLUMATUNTUKCALON p 1 . T h i sq u e sti o n a perconsists 50 qilestions. of Kertas soalanini mengandungi soalan. 5A 2 . A n sw e r l l q u e stions. a Jawabsemua soalan, 3 , E a ch q u e sti o ns followed fouralter native i by answer s, B, C and D. F or A, nnlv Rlr nkan \/^uranswer th e q u e sti o n , oose e a ch ch one answer on objective answersheetprovided. jawapan,iaituA, B, C dan D. Bagi Tiapliap soalandiikutiolehempatpilihan jawapanandapada setiap soalan,pilih satujawapan sahaja. Hitamkan jawapan objektif yang disediakan. kerlas youranswerer ase blackened kthatyou hav e 4 . l f yo uw i shto ch a nge , mar the ma d e . h e nb l a cken space the newanswer . T the for jawapan,padamkan Jika anda hendakmenukar tandayang telahdibuat. jawapanyang baru, Kemudian hrtamkan pr 5 . T h e d i a g ra msn thequestions ovided e notdr awnto scaleunles s tated. i ar s yang mengiringi Raiah soalan tidakdilukismengikutskalakecualidinyatakan 6 . Y o u ma y u sea n on- pr ogr amm able scientific calculator . Anda drbenarkan menggunakan kalkulator yang tidakbaleh saintifik diprogram.

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2OO9 JU L ANG JOHOR CHEMISTRY PAPER1 ANSWER Q U E S T ION 1 ANSWER

QUESTION

2 3
4 5 6 7 I I

D
A

B A B
D

26 27 28 29 30
31 32

ANSWER A

c
A

B B B B D B D
C

A
D D

33 34
35

10
11

12
13

c c
A A
A

14
15

36 37 38 39
40 41

D
D

16
17 18 19

A C

42
43
44

D
A B A

2A 21 22

B A A
U

23
24 25

D B

45 46 47 48 49 50

B
A

D D
D

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JABATANPELAJARAN NEGERI JOHOR

PEPERIKSAAN PERCUBAAN SPM 2OO9 CHEM IST RY Kertas2 September 2% jam Du aja m tiga puluh minit JANGANBUKA KERTAS SOALANINI SEHINGGA DIBER]TAHU 1. Tuliskan nama dan tingkatanpada yang disediakan. ruang 2. Kertassoalan adalahdalam ini dwibahasa. 3. Soa/an dalam bahasa lnggeris mendahului soalanyang sepadan dalambahasaMelayu. 4. Calondibenarkan menjawab kesel uruhanatau sebahagian soalansarnaada dalambahasa lnggerisatau bahasa Melayu. 5. Calondikehendaki membaca maklumat halamanbelakana di kerfassoalan ini.

4541t2

UntukKegunaanPemeriksu Bahagian Soat3n i ^ I renun

I Markah

Markah Diperoleh

?
3
5
o
D T

r0 I
l0 t0 i
t0 i0 20 2A 20 20

7
8 9

l0
J u mla h

Kertas soalan mengandungi halaman ini 36 bercetak

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PERCUBAAN JOHOR 2009

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2 SectionA BahagianA [60 marks] markah) 16O Answer questions thissection. all in Jawabsemua soalan dalambahagianini

Diagram,1 shows arrangement 1 the of atoms substanceandY. in X Rajah di bawah menunjukkan susunan 1.1 atom-atom untuk bahan danY X

X Substance BahanX
(a)

Diagram1.1 Rajah 1 1

Y Substance BahanY

questions: 1.1,answer following Basedon Diagram the BerdasarkanRajah 1.1, jawab soa/an-soa berikut'. lan (i) ldentifywhico f t h e s u b s t a n cin Dia g ra m . ' 1 a p u reme t a lo ra ll o y h e 1 is Tentukan bahanyangmanakah dalam Rajah1.1adalahlogamtulen

ataualoi. Puremetal
Logam Tulen A lloy: Aloi [1 mark] [1 markah] [1 mark] [1 markah]

(ii)

youranswers (a) (i) in Explain jawapan anda dalam(a) (i), Terangkan

[2 marks] [2 markahJ
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SULIT (iii)

3 Whichsubstance harder, or Y? is X Give a reasonfor youranswer. Di antarabahanX dan Y, yang manakahlebih keras? Berikansafu sebabbagijawapananda.

[2 marks] [2 markah]
(b)

Diagram below 1.2 shows structural the formula a polymer. of Rajah1.2di bawah menunjukkan formula struktur bagisuatupotimer.

HH

lil
C-C-C

-cI
Diagram1.2 Rajah1.2

HH il
C-C

tll
H C IH

li

CI HCI

Basedon Diagram questions: 1.2,answer following the BerdasarkanRajah 1.2,jawab soa/an-soa berikut: lan (i) Statethe meaning polymer of Nyatakanmaksud polimer.

[1 mark] [1 markah]

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SULIT (ii)

of formula its monomer. Draw and namethe structural dan namakanformulastrukturbagi monomernya Lukiskan

[2 marks] [2 markah] (iii) 1 in Stateone useof the polymer Diagram 2 in our dailylife pada Raiah1.2dalamkehidupan polimer satukegunaan Nyatakan kita. seharian [1 mark] [1 markah]

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Diagram2.1 showsthe heating curveof solidnaphthalene, C,oHu. Rajah2.1 menunjukkan pepejalnaftalena,C,rH, lengkungpemanasan

T imeI s Diagram 2.'1 Rajah 2.1 (a) (i) Namethe process involved thisexperiment. in Namakanproses yang terlibatdalam eksperimenini"

(ii) State typeof particle present naphthalene, the in CroHe.

markl 11 markah 11 l

jeniszarah yangterdapat Nyatakan dalam naftalena, CtoHa .

markl 11 markah) 11
(b) Explain why thereis no change temperature in fromB to C Terangkan mengapatiadaperubahan suhu dari B ke C

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particles (c) Statehow the movement naphthalene from C to D during of changes heating. Nyatakan bagaimana pergerakan zarah-zarah naftalena berubah se/??asa pemanasan dariC ke D.

t1 mark] 11markahl
(d)

Diagram showsthe atomic modelproposed NeilsBohr. 2.2 by Rajah 2.2 menunjukkan madel atomyang dicadangkan oleh Neif Bohr. s

Diagram2.2 2.2 Raiah

i\ tJ

Name X a n dY.

kan X dan Y. Nama X

[1 mark] 11narkahj ii) particles involved a chemical Whichsubatomic are in reaction? Zarah-zarah sub-atomyang manakahterlibatdalam tindak balaskimia?

[1 mark] [1 markah]

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(e) Table2 showsthe numberof protons and neutrons four different of atoms. protondan neutronbagi empat atom yang Jadual2 menunjukkan bilangan berlainan.

A.tom W
X

Number protons of Bilanganproton

to

Number neutrons of Bilanganneutron

17 to

19 Table2 Jadual2 Whichatomsare isotopes? Atom-atom yang manakahadalahisotop?

20

[1 mark] l1 markah) ii)

Givea reason your for answer (e)(i). in Berikan safusebab bagijawapan andadi (e) (i)

[2 marks] [2 markah]

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SULIT Table3 showspH values different of concentration hydrochloric of acid,HCI solutions. pH Jadual3 menuniukkan nilai-nilai bagi larutan asidhidroklorik, HCI yang berbeza kepekatan.

Typeof sduilon Jenislarutan

Concentration Kepekatan

Solution I LarutanI

Solutionll Larutanll
0.0'1mol dm 3

So/sfion//i Larutanlll
0 001 mol dm-3

0.1 mol dm'3

pH value pH Nilai
T a b le3 Jadual3 (a) (i) Whichof the solutions Table3 hasthe hiqhest in concentration of hydrogen ions? Larutanyang manakahdalamJadual3 mempunyaikepekatanion hidrogen yang paling tinggi? l1 markl [1 markah] (ii) Calculate number hydrogen the of t ionsin 25 cm3of Solutionl = Constant 6 x 1023mol-1 [Avogadro ] Hitungkanbilanganion hidrogen dalam25 cm3Larutan ll. Avogadro= 6 x 1a23 mol-' ] fNombor

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SULIT (iii) can of Namean indicatorthat be usedto measure pH values the the l, solutions ll and lll. Namakan satupenunjukyang bolehdigunakanuntukmengukurnilaipH larutan-larutan ll dan lll. l,

[1 mark] markah] [1 (b) Solutionis used neutralise cma 0.1moldm-3 sodium I 25 hydroxide, of to of NaOH solution.
LarutanI digunakanuntukmeneutralkan cm3larutannatrium hidroksida. 25 NaQH0.1moldm'3. (i) of NaOHin the the hvdroxide. Calculate number molesof sodium solution. Hitungkanbilanganmol natriumhidroksida, NaOH dalamlarutan.

[1 mark] [1 markah] (ii) I of sodiumhvdroxide, Calculate volume Solution usedto neutralise the NaOHsolution cm 3 . in HitungkanisipaduLarutanI yang digunakan larutan untukmeneutralkan natriumhidroksida, NaOH dalamcm".

[3 marks] [3 markah]

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IO (iii) Drawan apparatus set-up the titratron sodiumhydroxrde for of solution withsolution I Lukts susunanradas untukpentitratan larutannairiumhiciroxsida denganLarutanI

[2 marks] {2 narkahl

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II

of of 4 to the Diagram showsthe set-up apparatus investigate eiectrolysis sodium chloride solution with carbon eiectrodes. radas untukmengkajielektrolisis larutannatrium Rajah4 menunjukkansusunan elektrod-elektrod kloridadenganmenggunakan karbon.

Testtube TabungUji

Electrolytic C
Se/ Elekfrolisis

0 , 0 0 1mo ld m-3 o d ium s chloride solution larutannatium klarida 0.AU mol clms

Electrode P ElektrodP

Electrode Q Elektrod Q

Dia g ra m 4 Rajah4 (a) in Whatis the energy change the electrolgic above? cell Apakahperubahan tenagadalamsel elektralisis afas? di

11markl [1 narkah]
(b)

Writethe formulae all ronsoresent sodium of in solution. chloride Tuliskanformulabagi semuaion yang hadtr dalamlarutannatriumklorida.

markl 11 markahl 11

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SULIT (c) (i)

l2 at P. Namethe gas collected electrode pada eleWrod P Namakangas yang terkumpul

[1 mark] markah] [1 (ii) Howdo you identify gas collected (c)(D? the in gas andamengesahkan yang terkumpuldi (c)(i)? Bagaimanakah

i2 narksl [2 markahi
(d)

(i)

formed electrode if the experiment repeated at P is Whatis the product s c e using2.0 moldm " 3 o d iu m h lo rid s o lu t io n ? ini Apakah hasilyang akan terbentuk elektrodP jika eksperimen di di larutan natrium klorida2.a mot dm3? ulangidenganmenggunakan

(ii)

your in Explain answer (dXi). jawapan andadi (d)(i). Terangkan

11mark) {1 markahl

12marksl [2 narkah]
(iii) Writethe halfequation the reaction electrode P. for at Tuliskanpersamaan setengahbagitindak balasdi elektrodP

11marl<l narkahl {1

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SULIT (e)

tr-1

Suggest one metalthatcan replace carbon the electrodes thisexperiment in to obtainthe sameresultas above. cadangkan satulogam yang boleh menggantikanelefirod karbon dalam eksperimentersebutuntukmendapatkan yang sama seperti keputusan di afas.

11narkl markah] [1

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SULIT

14

potnts points somealkanes of and boiling Table5 showsthe melting takatleburdan takatdidihbagi beberapaalkata Jadual5 menunlukkan

Alkanes Alkana

Me lt in g Number carbon of p o in t atomspermolecule Takatlebur Bilanganatom (c) karbonper molekul

Pni ,rnn uv r l i ,'y

nn Pv

nt r I

Takat didih
/o /r \

Ethane Etana

Table5 ladual5 questions (a) Basedon the datain Table5, answer following the lan Berdasarkan data dalamJadual5, iawab soa/an-soa berikttt.

(i)

Plot a graph of boilingpoint againstnumber of carbon atoms per molecule. Plotkangraf takat didihmelawanbilanganatom karbonper molekul. [3 marks] [3 markah]

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l5

il*--*"-

i-,f,
I

t.---i i

|a, t i
i* * - ' * ' " * "

*j, -'-1i**-J ;f:;:"i",,-i

i . . ,.'., $ .,.::
" i ^ - . - ^ ".' { "".- *".*

-i ,.." , ,: |
- i" "- " "' - ' "".J.

-*,j ,*:*;,."j: ,*:*-"i-"--"-- i; i . , i ll' ' ! . i ' i-*,1 ;, . i.

',

-. .. -.,'"i .

ii l. . , , . . , i,.r ,i .

, |t , i, , i. i1i, l

***r-";. "^^i """--.f,"-^.,-,."*",, -{--^.:**--j-"---"-".*-*-*"i*-".*^-*,"*i*,*,*""

i1i,;:
l ''r,"'.:l t.,''', .i , , , : f , . , t .! : r , . r, , r i
t

).,
i i ..l
I

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SULIT (ii)

lo

as Explainwhy the boilingpoint of alkanesincreases the numberof molecules increases. carbonatomsin alkanes atom apabilabtlangan mengapatakatdidihalkanabertambah Terangkan per molekulalkanabertambah. karbon

[1 mark] [1 markah] (iii) Givethe physical at stateof hexane roomtemperature Eerikeadaanfizik heksanapada suhu btlik.

[ 1 mar k t markah] [1 formulae isomersfor alkanesJ and name the of (b) Draw all of the structural system. isomers usingIUPACnomenclature Lukiskansemua formulastrukturisomerJ dan namakanisomernya mengikut sisfemIUPAC.

[4 marks] [4 markah]

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SULIT

l7

A pupilcarried an experimentto out investigateredoxreaction. a Diagram 6.1 showsthe set-upof apparatus usedin the experiment. seorangpelajarmenjalankansatueksperimen untukmengkajitindak balas redoks. Rajah6.1 menunjukkan susunanradasyang digunakandidalam eksperimen ini.

Carbon electrode X Elektrod karbon X Bromine water Air Eromin U Tube TiubU
Dia g ra m . 1 6 Ra ja h . 1 0

Ca rb o n le c t ro dY e e Elektrodkarbon Y lro n(ll) s u lp h a t e o lu t io n s (ll) sulfat Larutanferum S u lp h u ric c id A Acid Sulfurik

(a) Nameone substance canreplace that bromine waterin this experiment Namakansatubahanyangbolehmenggantikan bromindalam air eksperimen ini,

[ 1 ma rk ] ntarkah] [1 (b) lf the experiment repeated is usingcooking to replace oil sulphuric acid the galvanometer nots h o wa n y re a d in gE x p la in y . does . wh Jika eksperimen diulangidenganmenggunakan ini minyak masak menggantikan asid sulfurik,galvanometer tidakmenunjukkanbacaan. Terangkan mengapa.

[ 1 ma rk ] markah] [1

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i8

Y (c) The halfequation the reaction electrode is as below at of pada elektrodY adalah yangberlaku tindakbalas setengah Persamaan sepertidi bawah. Fe2*+Fe3' + e (i) in solution this reaction change iron(ll) sulphate of Statethe colour Nyatakanperubahanwarnalarutanferum (ll) sulfat di dalamtindak ini. balas [ 1 ma r k ] [1 markah] Wh (ii) Thisreaction a n o x id a t iore a c t io n . a tis me a n tb y o x id a t io n n is transfer? reaction termsof electron in pengaksidaan. Apakahyang Tindakbalasini adalahtindakbalas dari segi dengantindak balaspengoksidaan dimaksudkan elektron? nemindahan

[1 mark] [1 markah] Y. at (iii) Namea reagent identify to Fet*ion produced electrode yang terhasil ion Fe3. Namakansatureagenuntukmengenalpasti pada elektrodY.

[1 mark] markah] [1

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SUL IT
( d)

l9

Zincpowder Serbuk zink

Glassrod Rodkaca

C o p p e(l l )su l p h a te r so l u ti o n (ll) Larutan Kuprum sulfat

Dia g ra m . 2 6 Rajah6.2 ln another experiment, excess zincpowder addedto 25 cm3of 0.2 mol is dm -3of copper sulpha t e o lu t io a s s h o wn Dia g ra m . 2 .T h e s o lu t io n (ll) s n in 6 is stirred untilthereis no colour in change the solution. solution The is filtered and the filtrate, is poured M intoanother beaker. yang lain, serbukzink berlebihan tambahke dalam25 Dalam eksperimen di cm' larutankupurm(ll) sulfat0.2 moldm'3 seperti ditunjukkan dalam Rajah 6.2. Larutanitu dikacausehinggatidakada perubahanwarnapada larutan itu. Larutanitu dituras dan hasrl turasan, dituanqkan dalamsebuah M ke bikaryang lain. (i) Namethe filtrate M. Namakanhasilturasan M.

[ 1 ma rk ] [1 markah] (ii) Writea balanced chemical equation this reaction. for Tuliskansatupersamaan kimiayang seimbang bagi tindakbalas ini,

[ 1 ma rk ] [1 markah]

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SULIT (iii)

20 in of number copper thisreaction. in Statethe change the oxidation kupruntdalamtindak pengoksidaan nombor perubahan Nyatakan balasini. [1 mark] [1 narkah] (iv) in (ll) of the Calculate number molesof copper sulphate the solutton Hitungkanbilanganntol larutankuprum(ll) sulfat clalamlarutan.

[1 mark] [1 markah] (v) produced. the Calculate massof zincsulphate ma a t o mic s s : Z n= 6 5 ,S = 3 2 ,O = 1 6 ] [Relativ e yang dihasilkan. Hitungkaniisimzink sulfat = 65, S = 32, O = 16] [Jisim atom relatif:Zn

[1mark] markah] [1

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2l SectionB Bahagian B l2Qmarks] [20 markah] Answerany one question fromthis section, Jawab mana-mana satu soalandaripadabahauianini.

(a) Diagram showsan apparatus 7.1 set-up determine empiricalformula to the of magnesium oxide. Rajah7.1 menunjukkansusunanradasuntukmenentukan formulaempirik maanesiumoksida.

Magnesium ribbon Pita magnesium

Dipanaskan Dia g ra mT . 1 Rajah7 1

(i)

During experiment, need raise lid a littleat intervals. the we to the Whv? Ketikaeksperimen penutup sekalisekala. dijalankan, perlumembuka kita Mengapa?
[2 marks] [2 markah]

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LL

tne to for (ii) Table7 showsthe results the experiment determine empirical o of formuia m a g n e s iu mx id e rimenuntuk bagisafuekspe keputusan Jadual7 ntenuniukkan oksicla bagimagnesittnt empirik farmula menentukan

+ i *ur. of crucible lid l,Lisimmangkuk pijar+ penutup

+ rib Massof c ru c ib le lid+ ma g n e s iu m b o n I Jislmmangkukpiiar+ penutup+ pitamagnesLtm + o t Massof cru c ib le lid + ma g n e s iu mx io e oxrde pijar + penutup+ magnestLtnt i Jisimmangkuk T a b le7 Jadual7

28.2ag

322a9

of formula the in Basedon the results Table7, determine empirical oxide. magnesium ma a t o mic s s : Mg = 2 4 , O = 1 6 ] IRelative dalamJadual 7, tentukanformulaempirikbagi keputusan Berdasarkan magnesiumaksida. = = IJisim atornrelatif: Mg 24 , O 16]

,*[5 p marKanJ

marks]

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13

(b) Diagram showsan apparatus 7.2 sefup to determine empirical the formula of copperoxide. Rajah7.2 menunjukkan susunanradasuntukmenentukan formulaempirik kuprum oksida.

gas Hydrogen Gashidrogen

Copper oxide Kuprum oksida

i----l*li
ti VAI
,,/A IAl I
I

Heat Dipanaskan

PartB Bahagian B

PartA BahagianA

Dia g ra m . 2 7 Rajah7.2

(i)

comparethe method usedin experiment Diagram withDiagram 1 in 7.2 7 Bandingkan kaedahmelakukan eksperimen dalam Rajah7.2 dengan kaedahdalam Raiah7.1. [4 marks] [4 markah]

(ii)

Statethe reactants produce gas to hydrogen in PartA. Nyatakanbahan-bahan untukmenqhasilkan hidrogendi Bahagian gas A. [2 marks] [2 markah]

(iii) Writethe chemical equation the reaction PartA. for in Tuliskanpersamaan kimiauntuktindak balasdi BahaqianA

[1m ar k ] 11markahl

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)A

SULIT

that (iv) Statethreeprecautions mustbe takenin PartB youranswer. Explain B. dalamBahagian yang mesticliambil tiga langkahberiaga-iaga Nyatakan anda. Terangkan iawaPan [6 marks] [6 markah]

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SULIT I (a)

l>

Saltscan be classified soluble into and insoluble salt. Garamboleh dikelaskan kepadagaramterlarutkan dan garam tak terlarutkan. (i) Nameone example an insoluble of chloride salt. Namakansatu contohgaramkloridatak terlarutkan. [1 mark] [1 markah] (ii) Namethe chemicals needed prepare in (a) (i) and namethe reaction. to salt Namakan bahan kimia yang diperlukanuntuk menyediakangaram di (a) (i) dan namakantindak balasitu. [3 marks] [3 markah]

(b)

Diagram showsa flowchartof the qualitative I anaiysis substance of X. Rajah 8 menunjukkan cartaalir analtsis kualitatif bagi sebatian X.

Blackpowder X SerbukhitamX Add hydrochloric acid,HCIsolution Tambahlarutan asid hidraklorik.HCI

Blue solution Y Larutan biru Y Solution + Sodium Y hvdro> NaOH solution Larutan + larutan Y natrium hidroksida. NaOH
Solution + Silver Y nitrate, A g N0 3s o lu t io n Larutan Y + Larutanargentum nitrat,AgNO,

Whiteprecipitate putih Mendakan

Diagram 8 Rajah I

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SULIT (i)

26 the B, Basedon diagram identifY raiah B kenal Pasti Berdasarkan X Blackpowder X Serbukhitam Y Bluesolutron Larutanbiru Y Cationand anion of Y solution Kationdan anionlarutanY [4 marks] ll rnarkahl salt' for an insoluble an out is An experiment carried to construct ionicequation (Vl) lead(ll) chromate . Pb(NO3)'? (ll) nitrate, of A fixedvolume 5.00cm3of 1.0moldm'3lead soiutio n is p la c e o in t o e a c h o f t n e E t e s t t u b e s o f t h e s a me s i z e ' soiutton (Vl),KrCrO+ chromate potassium of votume 1.0moldm'3 . Different is addedto eachtesttube rTheheight o f t h e y e llo wp re c ip it a t e , le a d (ll)c h ro ma t e (V l ) f o r m e d i n t o in and recorded plotted Graph8' eachtesttubeis measured,

garanttaK t membtnalsersarttaaiotl ttrttuk ttntttk rimen dtialankan Safuekspe pl terlarukan, umbum(l!) kromat(Vl)' . . t P1(NO'), nttrat 1.0 S.A0cm3 moldm4lartianplttnnum(ll) lslpadutetap s;l uit ke diisikan dalamsefiapB tabttng yang s/rrd (Vll Xalium'kroitat KzCrOu1 0 mol dm-3 larutan yang berbeza lsipadu ke diiambahkan dalamsetiaptabunguii datam yang terbentuk plumburr(il; krontat1V|) kuning Tinggimenctakan sefiapt a b L ln g u jic liu k u t ' c lt re k o d c la rlc lip |o t c la |a rn Gr a f B ,

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SULIT

27

of Height lead(ll) chromate precipitate cm / ffl) Tinggimendakanplumbum (ll) kromat(Vl) / cm

l234
-*;
't

.l;ll

I
I

.l
j

i- - i1

rri l

chromate Volumeof potassiunr (V l)s o lu t io nK z CrO/qc m 3 , lsipadularutankalium / KrCrO" cm3 kromat(Vl).

Graph8 GrafI

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SULIT Basedon Graph8 Graf I Eerdasarkan (i) Calculate Hitungkan .

28

of The number molesof lead(ll) ionsused' (ll) molion ptumbum yang digunakan Bilangan (Vl) chromate thathas reacted of of The number moles potassium 5.00cm3of lead(ll) nitrate with completely balasseiengkapnya mol Bilangan kaliumkromat(vt) yang bertindak (ll) plumbum nitrat' dengan5.00cm3 [4 marks] [4 markah]

(ii)

for an in Basedon the answer (c)(i),construct ionicequation the formation (Vl). of lead(ll) chromate ian Berdasarkan iawapan anda di (c) (i), binapersamaart untuk plumbum(ll) kromat(Vl)' pembentukan [2 marks] [2 markah]

wh (iii) E xplain y mengaPa Terangkan constant and increases thenremaln formed of The height precipitate ntenjadimalar' dan kemudian Tinggimendakanbertambah abovethe precipitate in change the solution The colour di larutan bahagtanatasmendakan' warna Perttbahan The eighttesttubesusedare of the samesize' sama. adalahbersaiz tabunguiiyang digunakan Kelapin-lapan [6 marks] [6 markah]

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SULIT

Ir.)

SectionC Bahagian C 120marks) [20 markah] fromthissection. Answeranyone question soalandaripada Jawabmana-mana satu bahagianini 9 structure threeelements Y and Z. of X, Diagram showsthe atomic Rajah9 menunjukkan strukturatom bagi tiga unsur X, Y dan Z.

XY Dia g ra m 9 Rajah 9 Basedon Diagram two typesof compounds be formed. 9, can Explain differences between two compounds the formedin termsof the . Typesof chemical bonds, and . p B oiling and me lt in g o in t s . BerdasarkanRajah9, duajenis sebatianboleh terbentuk. perbezaandt antaradua sebatian Terangkan tersebutdari segi t jenisikatankimiayang terbentuk, dan . takat lebur dan takatdidihnva. [4 marks] [4 markah] (b) X of formedbetween and Y Drawthe electron arrangement the compound and explain formation the compound the of susunan elektron untukpembentukan sebatian antaraX dan Y, di Lukiskan pembentukan sebatiantersebuf, dan terangkan [6 marks] [6 markah] [Lihat sebelah
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SULIT (c)

30
P substances' and Q of two samples clremical You are gtven and compound Q is an ionic whitesolids P is a covalent Bothof themare comP ound. of conductivity P the to experlmenl investigate electrical a Describe laboratory in the and Q. lnclude observations youranswer' Q P eaih substance and substance for example Suggesta suiiaLte bahankimia,P dan Q' Andadiberidua sampet kovalendan Q adalah putih.P adalahsebatian nerwLrna Kedua-duanya ion. sebatian arus elektrik rimenmakmaluntukmengkajikekonduksian Huraikansafu ekspe dalamlawapan yang diperolehi pemerhattan P sebatian ctanQ. Serfakan anda. Cadangxansatu c o n t o h y a n g s e s u a ib a g is e t ia p b a h a n P d a n b ah a n Q , [10 marks] markahl 110

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SULIT

fl

.)l

10

(a)

in usedas a fueland is the maincomponent Methane, CHois commonly gas. natural liquified is The heatof combustion methane -898kJ mol-' of Writethe chemical equation the complete for combustion methane. of g of methane completely of heatreleased Calculate amount the when1 is burntin air. H= atomrc masso f C= 1 2 , ' l, O = 1 6 [Relative ] Metana,CH+adalahbahan api yang biasadigunakandan ianya adalah kompanenutamayang terdapatdalam gas as/i cecair. Haba pembakaranmetanaadalah -898kJ mof', persamaankimiabagi pembakaran lengkapmetana.Hitungkan Tuliskan jumlah haba yang dibebaskan apabila1 gram metanaterbakardengan lengkapdalam udaraberlebihan. : H=1,O=16 lJisimatomrelatif C=12, l 14marksl [4 markah]

(b)

I of Diagram 0.1 and diagram 10.2showtwo energy leveldiagrams reactions Rajah10.1dan 10.2menunjukkan gambarrajah arastenagatindakbals dua kimia.

Energy Tenaga

C+ D

Dia g ra m 0 . ' 1 1 Rajah14 1

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SULTT

aa )L

Energy Tenaga

R+ S

10.2 Diagr am 10.2 Raiah

of 10,1and 10.2in termsof changes energy Diagram compareand contrast changefor the reactions temperature heat changeand i-he content, B andingkanda n b e z a k a n Ra ja h l0 . ld a n la ' 2 d a ris e g ip e rubalas b a h an dalam p")irauiin habadanperubahansuhutindak tenaga, kandungan tindak balasini

[6 marks] i6 markahl

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SULIT (c)

JJ

of Table10 showsthe heatof combustion fourtypesof alcohol. bagi empat jenis alcohal habapembakaran Jadual 10 di atasmenunjukkan Relative molecular mass Jisim atom realtif
JZ

Nameof alcohol Nama Alkohol

Molecular formula Formula Molekul

Heatof combustion Haba Pembakaran / kJ mol'1 - 725 1 376 2 015 -2 6 7 6

Methanol Metanol Ethanol Etanol Propanol Propanol B utan-1-ol Butan-1-ol

CH30H

C2H5OH

4+O

caHToH
c4HeoH T a b le1 0 Jadual10

OU

74

UsedatafromTable10,drawthe graphof magnitudeof heatof combustion number carbon of atoms. against Basedon the datafromTable10 andthe graphplotted, (i) for in statethe change the heatof combustion the givenalcohols. youra n s we in (c )(i). (ii) r explain datadariJadual10, lukisgraf magnitudhaba Denganmenggunakan pembakaranmelawanbilanganatom karbon. data dari Jadual 1Adan graf yang di plotkan, Berdasarkan perubahan (i) bagialcoholyang habapembakaran nyatakan diberikan. jawapan anda dalam(c)(i) (ii) terangkan

[10marks] [10m ar kah]

E N DO F Q UE S T I O N A P E R P KERTAS SOALA,VTAMAT

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34

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SULIT
, 't)'

35

c!-

i6

(9

L-

e! - i*& E el s
3 r.* 6r
,5 r
@IL6H

i-

.t; -.1 ) <. ;s"

o 0 6 X

F: E:

5 rr;R

r=

l*

:l;e

L:-e,

u
a

Fo - l1\ - v?m 60

s fiEsis
E

sa$:l

9l

={ij
o E i t,I r . o * >-o' :i 9Z, . 1nri'o ' I' -=-----*+-

S< o

*\Ji- n Sc
I

*E:silEin
F i

$t o 6r

ir, iih L b , E*-a F i E n

u .--*----1'-''-I

'N-.

a
0)

:r t 5r

Ff;'eh f f i n i
*: l*c0 E: P <qr
E

9lm

i9

r r'| =i

E
CI

* . i ' r ! n

1*__-+|-j

i-a[; r-5 n l

(\

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LU

o tu
J

xzla

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sd+p

16

tr

a o
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tsvxos-D_ ^E

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fLihat sebelah

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STJLIT N a ma

Kelas

JA B A T A N E L A J ARAN P NEGERI JOHOR

PEPERIKSAAN PERCUBAANSPM 2OO9 C H EM ISTR Y Kertas 3 S e p te m b e r ":'/z1am S a t u ja m ti ga p u luh minit

1s4u3

JANGAN BUKA KERTASSOALA]\ INI SEHINGGA DTBEII.ITAHLI 1 Tttliskarr pada nama dan tingkatan ruangyang disediakan.

2. Kerfassoa/ariini adalahdalant dwibahasa. 3 rlalam bahasalnggeris Sc;alan rnenclahttlui soalanyang sepadan dalam bahasa Melayu.

4. Calon dikehendakimembaca maklumatdi halaman belakang kertas soalanini.

Kertassoalan mengandirnciI halarnan ini 1 bercetak

1 5 4 1 / 3 O J abat ar r e l u i a l a n e s e l i J o h o r P \{

I L ih a f s e b e la h S UL I T

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SULIT Jawabsemua saalan. '1 1 Thealkali metals Group of thePeriodic in Tabte Elements react of can withoxygen gaswithdifferent reactivity. Table shows experiment observation Lithium, Sodium, and 1 the and when Li, Na Potassium,react K withOxygen, gas. 02 LogamalkalidalamKumpulan JaduatBerkala 1 lJnsur bolehbertindak balasdengan gas oksEendengankereaktifan berbeza. Jadual1 menunjukkan eksperimen pemerhatian dan Litium, Li, Natrium,Na apabila danKalium, bertindak K balas gas dengan oksigen. Experiment
Eksperimen Observation Pemerhatian Lithium burnsslowlywith a red flame. Whitefume rs released. Whitesolrdis produced. Litium terbakarperlahan-lahandenean nyalaanmerah.

Ga sj a r Balanggas gas Oxygen Gasoksigen L i th i u m Litium

putihdi Wasap bebaskan. putihterhasil. Pepejal Sodium burns vigorously a yellow with flame White fumeis released. White solid produced. is Natrium terbakar cergasdengannyalaan kuning. putihterbebas Wasap putihterhasil. Pepejal Potassium burns veryvigorously a with reddish-purple flame. White fumeis released. White solid produced. is Kaliumterbakar sangatcergasdengan nyal n ungu-kemerah n. aa a putihterbebas. Wasap putihterhasil. Pepejal

-_-JL TItTl__1,
ttr+-

Ga sj a r Balanggas

l)^'tilI ll+|

Oxygen gas Sodium Natrium

Ga sj a r Balanggas Oxygen gas Gasoksigen Potassium Kalium

Table1 Jadual 1

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SULIT

.)

in (a) State inference the observationsTable1. for the dalam inferens Nyatakan bagipemerhatian-pemerhatian Jadual1
i ' :t

[3 marks] 13markahl
(b)

Based the experiment above: on di Berdasarkan eksperimen atas: (i) the the to State method manipulate variable. pembolehubah kaedahuntukmenanipulasi Nyatakan

variable. the State responding ak Nvatakanpentbol hubah bertind balas. e

(iri)

variable. State controlled the pembolehubah alarkan dim Nyatakan [3 marks] 13markahl
I

r:t--

I
I

for (c) State hypothesis the experiment. the tersebttt tlyatakanhpolesis bagi eksperimen [3 marks] 13narkahl
(d)

gtvet h e withoxygen, metals alkali between By refering the reaction to metals. of forthe reactivity alkali definition operational berikan Merujuk kepadatindak balasantaralogamalkalidenganoksigen, alkali. logam-logam bagi kereadifan definisi secaraoperasi [3 marks] 13markah)

l(d)

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SULIT

4 AlkalimetalX ignites spontaneously air with a reddish-violet in flame.White fumesand a whitesolidarealsooroduced. LogamX juga adalahmerupakan Kumpulan1. ahli LogamalkaliX terbakar secaraspontandi udaradengannyalaanungukemerahan. Wasapputihdan pepejalputihjuga terbentuk. (i) Predict whichperiod, metal is located the Periodic in the X in Tableof Element. Ramalkan Kala,loqamX diletakkandalamJadualBerkala lJnsur. [ 3 mar k s i 13makaa", (ii) Based the observationsTable1 and (e)(i) , arrange on in lithium, potassium metal in ascending sodium, and X orderof reactivity of metals towards oxygen.

r--=
I irl

1(eXi)

1 ( e Xi i ) I I l tt* r---lrl

Berdasarkan pemerhatian dalamJadual1 dan (e) (i) , susun litium, natrium, kaliumdan logamalkaliX mengtkut tertibmenaik kereaktifan logam terhadapoksige n. [ 3 ma r r s i f3 markan'

(0

0.2g of sodium willt a k e 8 s e c o n d s t o u rnc o mp le t e in o x y g e n a s . 1 g b ly 0.5g of sodium take45 seconds burncompletely oxygen will gas. to in State relationship the between massof sodium the andthetimetakenforthe metaltoburncompleteiy oxygen gas. in 0.2 g natrium mengambil masa18 saatuntukterbakar lengkap dalamokstgen gas. 0.5 g natriummengambilmasa45 saatuntukterbakarlengkapdalamokstgert
rYz a

jisim ittyatakan hubLtngan antara yang diambil natriumdan masa untuk logan itu terbakar bertindakbalaslengkapdalamoksigengas. l(0 I I tt-{ r--t t3 l

[3 marks] 13markahl

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SULIT
Ex amtncr

Whenthereaction Table1 is completed10 cm'of wateris poured thegas in into , jar.A pH meter dipped thesolution is into formed. Table shows pH meterreading. 2 the
Apabila tindak balas dalam Jadual 7 selesai, 10 cm?air dituang ke dalam balang gas Meter pH drcelupke dalam larutan yang terbentuk.

[,s E

ph. iadual 2 n.enunjukkan bacaan nteter

I _

10.554

G a sja r ll gas Balang ll Water Air

G a sja r lll gas lll Balang Water Air

Reading: . . Bacaan T a b le 2

Reading Bacaan

Jadual 2 (g) Record pH meterreading onedecimal place Table in the to 2. perpuluhan Rekod meterpH dengansatutempat dalamJadual2. bacaan [3 marks] 13markahl

1(e)

t-;I 3 l I

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For Examiner's [,sc

SULIT (h) Writetheobservations bluelitmus when paper paper dipped andrecj litmus are intothesolution forme d G a sJ a rI , G a sJ a rll a n dG a sJ a r lll. in
Tuliskanpemerhatian apabtla kertaslitmus biru clanmerah clicelupke dalam larutan yang terbentuk dalam Balang Gas 7, Balang Gas /l clan Balang Gas il/
'-T-

S olutions Larutan-larutan GasJar I BalangGasI GasJarll BalangGas l/

Gas Jar lll Balang Gas ///

Redlitmus paper Kertas litmusmerah

I :

Btuelitmus paper Kertaslitmusbiru

[3 marks 13markah':
(i)

Write balanced the chemical equations thereaction: for Tulispersamaan kimiayang seintbang untuktindakbalas (i) Between alkali metal andoxygen (choose gas onlyonefromTable1): Di antaralogamalkalidangas oksigen(pilih satuctaripada Jadual1).

(ii) Between product the formed from(i)(i)andwater Di antarahasilyangterbentuk (i) claripada (i) tlan air [ 3 ma rk s l 13markahl

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STJLIT

U)

Classify following the alkaline solutions strong into alkali weakalkali. and Kelaskan larutan-larutan alkailberikut kepacla alkalikuatdan atkalilemah. Sooium hydroxide, NaOH Natri hidroksida, um NaOH Potassrum hydroxide, KOH Kali hidroksida, urn KOH A mmo n iao lu iio n , s NH. Larutan ammonia, NH3 Ca lc iu m y d ro x id e , (O H)r h Ca Ka!sium hidroksida, Ca(a Fl),

!:riirt rrt;,'

[3 marks] 13rnarkaltl

45{l/J

e Je hma nl ) elir jir r ' : \ eper ' i J olr or rn

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SLTI,TT
li.roniiner's [,,.se

Reaction| ! 'findak balasI j Reaction between sodiumthiosulphate, NazSzO:, and dtlutesulphuric soiution acic, FJ2SC4 produce will sociir.lni sLrlphate NazSOrsulphur, sulphur S, dioxide i -l-he t-lzC. chemical equation is. I SO, and water', Tindak balas antara larutannafriumtiosutfat,fuazs:o: clan asiclsulfurikcair H2SO1 akan menghastlkan natriumsu/fal Na:Sao suifur, S, sulfur drbksrda SO dan air, H20. Persarnaan kimia adalah.
N a rS 2 O3 + H rS Oq ) N arS O, * S + S O, + 1-1rg
t-

Reaction I Tindakbalasll ll
t- ^ , I I

I R"**;

n"tr"*n f,VO..nf aciO. CmnO f-f o* tr.-Z- *lmro,f l,." rr..nr"=

gas, Hr.The chemicar and hycrogen eqJatrons I ZnCl2

I
I

gas H2. Persamaan ktmia aclalal'r I klorida,7-nCl.tdan hydrogen,

I I Tindak balas antara asid hidroklorik, HCl dan zink, Zn akart rnenghastlkan zirli<

+ zHCt zn ) Znct,+ 2,

By using information Reaction Reactron planan experrment the of I or ll to tnvestigate effect temperature therateof reaction the of on Yourplannrng shoulc include:
Denganmenggunakan maklumatTindakbalasI atau Tlndak balas ll, rancang sa:,., eksperimenuntukmengkajikesansuhu ke atas kadartrncJak balas.Perancangan anda hendakl rnengandungi: ah (i) Problem statement Pernyataanmasalah All the variables Semuapembolehubah

(ii)

(iii) Hypothesis Hipofesis (iv) Listof material and apparatus Senaraibahan dan alat radas (v) Procedure Prosedur

Total )

(vi) Tabulation data of Penjadualandata 117marksl 117markah) END OF QUESTION PAPER

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-:s!
@

*:
FE*

to statethe
Sample answer:

Ru b ric correctly

::

(of withoxygen) The reactivity alkali increase from metals lithium potassi u m. // to Lithium, sodium andp o t a s s iu m lk a li t a ls h o ws imila r /a me s chemical theirreactions oxygen. in with Able to statethe inferencelesscorrectlv.
D a m p l e a n s w e [. Sample answer

The reactivity increase // All metals whitefumeandwhitesolid// burnsproduced GoingdowngroupI the reactivity increase. Able to stateany idea of inference. S ample answer: Lithium, an sodium d potassium showdifferent reactivity // lit P otassium,odium, h iu m S lncrease tVoresponseor wrongresponse

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Ablets state the$ee variabl@rectl y: 1. Method t&anipa-b!.evdfnble. -,

'*:

2 Theresffiding tffianrc.

3. The con{reltedvariable. answer: S ample (i) Use different 1) typesof (alkali)/(groupmetals // (ii) Reactivity metals with oxygen of gJ and between metals Vigorousness the reaction il oxygen. gas/7size/ mass"of metal (iii) Oxygen correctly: Able to stateany two variables correctly Able to stateany one variable No responseor wrongresponse

l0

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'::

.:i:l1i:-:l1Ei

1 ffi,:-

between correffily | nArcfo sfafetherdiffionship

+ I Sampleanswer: -,:. down/up) of the I (fne lower/higher positron metalin)/(Going with is reactive the metalin reaction I Group1, the more/less // oxygen. in of the The lower/higher position metals group1, the is lower/higherthe reactivity. / whichis lo,iter upperin Group1 is more/less The metal // oxygen. in reacttve reactionvvtth I the The lower/higher metalin Group1 the more/less with the reactive reactton oxygen. betweenthe manipulated Abteto statefhe relationship variable. variableand the responding answer: Sample metals alkali between for increases the reaction Reactivity to whengoingdownGroup1i fromiithium oxygen and potassium. // down/up) of the (Thelower/higher position metalin)/(Going // reactive. Group1. the more/less in whichis lower/upper Group1 is more/less The metal reactive// the The lower/higher metalin Group1 the more/less // the reaction. reactive of the the the The morereactive reaction, lower position the metalin Group1 Able to statethe idea of hypothesis. Answer: Sample // withoxygen. in Metals Group1 can react reactivity. havedifferent Alkalimetals or No response wrongresponse

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dEtrI

(d) :_

definition s6su@ly by

vigorously/ more vigorous/ reactivet-with oxygen more/ highlyreactive

S amole answer: An alkali metal thatreacts morevigorously oxygen a with is morereactive metal.
;

Ableto gtv;Th; op
any two of the information above. Sample answer: The metalthatreacts morevigorously oxygen a more with is reactive metal. /i The alkali metal thatreacts morevigorously a more is reactive metal. // The higher/lower alkali the metalsthe more/less reactive metal Able to give the operational definition correctlyby stating any one of the information above. Sample answer: Alkalimetals can reactwithoxygen. // Metals can react vigorously oxygen. with No responseor wrongresponse

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of n1teto make a prediction the positionof metalX in Group 7 /ess accurately. answer: Sample potassium l/ /under Below Lowerthan potassium of Able to make any precliction the positionof metalX in

1. Group answer: Sample Li/ thanLi/Na/Kll Lowei'than Na 1 In group // Upper

or No response wrongresponse

I I

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#.J
lg-

iGE

(eXii)

1#r
,EiG*'

the ,Ahleto arrd.gjie me reactiW their =

Sampleanswer: X P S Lithium, odium, ot a s s iu m,ll L i,Na ,K , X Able to arrangeany threeof the metalsin ascending order based on theirreactivitv. Samole answer: X , Li, Na, K ll NaLi,K ,X 7 Li , K , Na .X ll Na, K . L i, X ll K , L i, Na ,X t l L i X Na , K

Able to arrangeany two of the metalsin ascending order or based on theirreactivity arrangein descending order. answer: S ample X ,K Li,Na ll X L i. Na . K / / K. X, Na, Li ll X, Na. K, L-i ll X K ,Na Li ll K . X , Na , L i Na ,K , L i , X

I No responseor wrongresponse

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the Able to sfafeffie relationshiiffietween and the \ilnsffien foffiie metalt6'burn

n Y\/r \o n
.

of sodium
tn

n2q

ff

+ ..-. the higherthe mass/ the biggerthe the longerthe time taken burn completely

Sample answer: the the of the,nrass metals, longer timetakento The higher burncompletel[// the the of the-stze metals, longer timetakento The bigger burncompletely. betweenthe mass of sodium Able to statethe relationship in for the metalto burn completely and the time taken gas. oxygen answer: S ample the the the The higher massof metals longer timetaken i/ // Moremassmoretimeto burncompletely betweenfhe mass of sodium Abte to statethe relationship in and the time takenfor the metalto burn completely oxygengas. answer: Sample // massburnslonger. Bigger time // needslonger The metals Moremassmoretimeto burn. ] No responseor wrongresponse

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1 (g)
=i

with rd allthe reaCings or@ecimal

Able to recordany two readingswith one decimalplace accuratelv. answer: S ample 2

1 0 1 ,1 0 .61 O.8 i l 101,105,1g_/ ,

10.0, 19i- l- 0.9 I

,-

Able to recordat leastone readingwith one decimalplace accurately. answer: S ample 101// 106 il 109 or No response wrongresponse

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fo sfa@servations for blueandffi litmus

vvttvvLt)t.

nnrrar,flrt

.ffi .G

.='

=:'

':::

Sample answer: S olutions GasJar I GasJar ll GasJar lll paper Redlitmus Tur n sb lu e Tur n sb lu e Turn s lu e b p B lu elit mu s a p e r No c h a n q e No c h a n q e
No chanqe

Able to stateany one of the litmuspaper observat'rons

S olutions

Re dlit mu s

B lu elit mu s

GasJar lll

i Turn sb lu e

GasJar ll GasJar lll

re , Turn s d Turn sre d I

Able to give an idea on litmuspaper obseruations. Samole answer: S olutions GasJar ll GasJar lll Redlitmus paper No c h a n g e B lu elit mu s T u rn sb lu e

Tur ns blue
T u rn sb lu e

No response wrongresponse or

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fr .:ll -a .g
a

'=

1 (i) .:--

Able to writetwo chemicalequations withcorrectchemical formulanutnot balanced Anv one of the two balanced // chemiC-aequations'for the re ac't n accu ratey. t io I Samole answer: Na
ii.
C -2 )

Na 2 O a n d
)

Na2O + HzO 02)

NaOH 2 Na rO 2 Na O H

ll ll

ii.

NarO + HzO )

Able to give at least one chemicalformulae the of subsfances correct// Able to writeany one of the two chemical withcorrect equations chemicalformulae not but balanced . Sample answer: i. Na ll Oz ll
Na2O NaOH NazO NaOH ll and

ii. NazO ll H2O ll i. Na 't" Oz )

ii. Na2O + HzO )

No responseor wrongresponse

l0

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'=
5

1 (i)

Able to@ssify all alk

soiufions

aliffirectly.
Sample answer: / : hydroxideNaOH, Strong alkali Sodium hydroxideKOH / Potassium Ca Calc iu m y d ro x id/e (O H), h NHs s Weakalkali : A mm o n ia o lu t io n , any two of strongalkaliand one weak alkali Able ta c/63slfy correctly.Sample **"r, h Na : S trong alkali S odiu m y d ro x id/e O H, / Potassium hydroxideKOH s n W eakaikali : A mm o n ia o lu t io / NH: any one of strongalkaliand weakalkail Able to classify correctly. answer: Sample / . hydroxideNaOH// Strong alkali Sodium hydroxide IKOH ll Potassium ll Calcium hydroxideCa(OH)z I s n W eakalkali : A mmo n ia o lu t io / NHo No responseor wrongresponse

ll

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vc thc statemenf of

se is in questionform. Sample answer: Doesthe temperature sodium of thiosulphate solution affect the rateof reactron? ll Howdoesthe temperature sodium of thiosulphate solution affectthe rate of reaclion? ll Howdoesthe high/ low temperat[re f s o d iu mh io s u lp h a t e o t solution affect rateof reaction? the Able to give the statement the problem lessaccurately. of Responsein questionform. S amole answer: Doesthe increase decrease temperature / in increase/decrease rateof reaction? ihe // Howdoesthe increase/decrease in temperature affect the rateof reaction? Able to give an idea of statement the problem of S ample answer Doestemperature affect rateof reaction? the The increase/decrease in temperature increase will /decrease rateof reaction. ihe // The higher lowerin temperature increase / will /decrease the rateof reactionl/ To investrgate effect temperature the of reaction. tVoresponseor wrongresponse rateof

T2

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:4=!E

Able Sa

ate the three variables

variab le : Manipulated solution thiosulphate of Temperature sodium // Rateof reaction Timetakenfor mark 'X' to become /disappea r invisible variable : Constant sulphuric of andconcentration sodiumthiosulphate/ Volume flask acid/ sizeof conical correctly \ Able 1osfafeany two variables correctly \ Able to stateany one variables se i No respon ar wrongresponse

13

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.: -re._ -re : ' :

]:#. .G{E

ii#,,:

?,,(i1i)

fo sfafe fied v

between'the
variablewith
i-: jG

g.4F-

: Sbmple answer: The higher/lower temperature sodium the of thiosulphate solution, higher/lower rateof reaction. the the // The higher/lower temperature sodium the of thiosulphate solution, shorter/longer timetakenfor mark,X,to the the disappear fromsighVview i/ ; The increase/decrease in temperature sodium of thiosulphate solution increaseEecrease rateof will the reEetion. /i Whenthe temperature sodium of thiosulphate solution increase /decrease, rateof reaction the will increase/decrease. Able to state rentronsn'tp the Oetween man'trulated the variableand the responding variablewith direction S amole answer: The higher/lower temperature, higher/lower rate the the the of reaction. // The higher/lower temperature, shorter/longer the the the timetakenfor mark'X' to disappear ll The increases/decreases in temperature increase will /decrease rateof reaction. the // Able to statethe idea of hypothesis. Sample arlswer; Different temperature, different reactivity. // Temperature changes, timetakenis different the No responseor wrongresponse

:i-

t4

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2 (iv)
-E!-

grve
==

Iistof

s and apparatus

Dampte answer
,,

Mat-erials
S odium thiosulphase lu t io n ,u lp h u ricc id . to s a Apparatus. Conicalflask, b ,buns e n u rn e r, a s u rinc y lin d e(i0 ml), me g r measuring (50 cylinder ml),stop-watch, /white filter /cardBoard paper. Able-togive completelistof materAlsand four apparatus as following. Answer: Materials: S odium thiosulphase lu t io n .u lp h u ricc id to s a Apparatus : Conical flask thermo me t eb u n s e n u rn e r. ilt e r wh it e r. b f / /cardboard paper. Able to giveat leastone substances at teastone ana apparatus

No responseor wrongresponse

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-#.

#
*ffi

to listallfhesfepscWactly
pleAnswer: 1. 'X 'markis drawnori a pieceof white/filter/ cardboard paper 2 50 cm3of sod iu mh io s u p h a tse lu t io n(O0 1 -1 . 0 ) t o t moldm 3lis measured witha (50cm3 measuring ) cylinder is p o u re d t oa c o n ic aflla s k . and in The solution slowly is heated until30 "C. 5 cm3of hydro c h lo ric idt (0 . 1 2 . 0 )mo ld m-3is ac 1 measured a (1O*rn")measuring with cylinder is and added the conical to flask.A stop-watch started is immediately 5 The conical flaskis swirled and is olaced a on white/filter/cardboard witha mark'X' paper The 'X' markis observed vertically fromthetop through s o lu t io n . the The stop-watch stopped is immediately whenthe 'X' markcannot seen.Timeis recorded. be The experiment repeated usingthe sodium is by thiosuphate lu t io n t 4 0 " C, 5 0 o C,O 0o Ca n d7 0 " C so a respectrvely Able to listdown sfeps 2, 4, 5, 7, I Ableto givean tdeato step4 No responseor wrongresponse
fla

l+

tz
l I

16

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=+ "#

to tabulate'th'e data
-g

==. titles withunits

Completelistof temperdfilTes Sample answer Temperature T ime (s)

("c)
30 40

50
60 70

Able to contructa table. 1. At least1 titles correct without units 2. lncomplete of tempereatures list S ample answer: Temperature

No responseor wrongresponse

t7

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+
@

_re

ff!! ffil

.::,.. .: r#E ,*
Lry:

:+'-]]+

,]Effi

.:-tr,ZnCl2 -1

-j:=_ l-E, =re:-:: -E{R:

ubr ic 2 (i)
Ablffi1 give th6'stateme Response in questroi is S ample answer: Doesthe temperature hydrochloric solution of acid the affect rateof reaction? li Howdoesthetemperature hydrochloric solution of acid affectthe rate of reactron? ll * Howdoesthe high/ lowtemperature solution of affecttlre ratehydrochloric of reaction? acid Able to give the statement the problernlessaccurately. of Response questton in form. S ample answer: Doesthe increase decrease temperature / in increase/decrease rateof reaction? the l Howdoesthe increase/decrease in temoerature affect the
I r a te n f r o a n fin n ?

the problemacc

.G rlilFi'F-

:-.

t"'""
I

n,- l- - , - of Able to give an idea of statement the problem

--

S ample answer, Doestemperature affect rateof reaction? the The increase/decrease in temperature increase will /decrease rateof reaction. the // The higher lowerin temperature increase / will /decrease the rateof reaction. // To investigate effectof temperature the rateof the to reaction. No re

t8

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;SEIGE

to
" -:= Sampf.answer,

s correctly

ry

Manipulated variab le : Temperature hydrochloric of acid Responding variable : Rateof reaction Volume gas perunittime // of Constant variable. Wiass/size zincll of lumeand concentration hydrochloric of acid Able to stateany two variailes correcily Able to stateany one variables correctly No responseor wrongresponse

t9

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:
&,
G
@

iiiiH

; =
a-

2 (iii

S ample answer: The higher/lower temperature hydrochloric the the of acid, higher/lower rateof reaction. the // The higher/lower temperature hydrochloric the the of acid, higher/lower volume the hydrogen release the of gas per unittime i/ : The increase/decrease:in temperature hydrochloric of will increase/decreasdlh-e of-ieaction rate // Whenthe temperature hydrochloric of acid increasesidecreases,rateof reaction the will increase/decrease. Able to statethe relationship betweentne maniputateA variableand the responding vartable with clirection. S ample answer: The higher/lower temperature, higher/lower.the the the rate of reactron. // The higher/lower temperature. higher/lower the the the volume the hydrogen released unittime. i/ of gas per The increase/decrease in temperature will increase/decrease rateof reactions. the // Able to statethe idea of hvpofhesis Sample answer; Differe temperatu diffe nt re, rentreactivity. // Temperature changes, timetakenis different the No responseor wrongresponse

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' Sample answer:

:: '

Materials: Zinc,hydrochlori c id ac Apparatus: Conical flask, thermometer burner, stop-watch , bunsen measuring (50 cylinder ml),delivery tubeand stopper, burette. basin. Able to give all materialsandfive apparatus following. as Answer: Materials: Zinc,hydrochloric acid Apparatus : Conical flask, thermometer. bunsen burner, delivery tube, burette Ableto giveat leastone substance at leastone and apparatus.

No responseor wrongresponse

2l

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uueffiffiNo.'

tcsre

Answer: ;sampte ffi

=- l

AbE&list all the Ws e

correcflv

E +, I

_f

is 1. Burette nffeO water inverted a basin I with and into co n ta i n i ng water . I 2 The burette clamped is vertically usingretort stand.
Initial reading burette recorded. of is dm-'lis measured a (50ml) measuring with cylinder and is poured intoa conical flask. The solution slowlv is heated until3O"C.n g of zincis weighed, is put intothe[onical 2 and flask. '-7 The conicalflask closed is immediatelyWith a stopper whichis joined the delivery to tubeand the stoowatch started. is reading recorded interval 30 is L The burette at of untilthe reaction completed. is seconds 9 The experiment repeated usrng is by the hydrochlo ric ida t 4 0 " C, 5 0 " C, 6 0 " C a n d ac 70 "C respectively. Able to listdownsfeps 7, 4 6, 8, I Ableto givean ideato step6.
a

4 t20-501 o f h y d ro c h lo ric id [ (0 . 0 1 -1 . 0 ) l cm3 mo ac

response tVo response wrong or

22

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-4..+4+ *.-:t

-i!gr!

L
E

Fr

to tabalate

Ru b ric with followingaspecfs :=

1. Correcttitleswith units 2. Completelistof temperatures Sample answer: Temperature T ime (s)

("c)
40 50
OU

70

Able to contructa table. 1. At least1 titles withoutunits correct list 2. lncomplete of tempereatures answer. S ample

No responseor wrongresponse

S E NDOF MA RK I NG CHE ME

23