P3-oxysan ZS

REVISION DATE: 26-09-2005

SAFETY DATA SHEET P3-oxysan ZS

PRODUCT NAME: APPLICATION: SUPPLIER:

P3-oxysan ZS Disinfectant for industrial use Ecolab Ltd. Duke Avenue Stanley Green Cheadle Hulme Cheshire SK8 6RB England 0161 485 6166

TELEPHONE:

EMERGENCY TELEPHONES: 0161 485 6166

2. COMPOSITION / INFORMATION ON INGREDIENTS:

INGREDIENT NAME Acetic acid Peracetic acid Hydrogen peroxide Caprylic acid

EINECS NO. 200-580-7 201-186-8 231-765-0 204-677-5

CONTENTS > 30.0% 5.0 - 15.0% 5.0 - 15.0% < 5.0%

CLASSIFICATION C;R10 R35 R10 O;R7 Xn;R20/21/22 C;R35 N;R50 R5 O;R8 C;R35 Xn;R20/22 C;R34

The full text for all R-Phrases is displayed in section 16.

3. HAZARDS IDENTIFICATION: HUMAN BEINGS: Serious risk of tissue corrosion after contact with skin or eyes. Contact rapidly causes itching and stinging pain. Serious risk of permanent damage to sight.

ENVIRONMENT:

See section 12.

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P3-oxysan ZS

REVISION DATE: 26-09-2005

4. FIRST AID MEASURES: EYE CONTAMINATION: Without delay, rinse affected eye(s) with water for at least 15 minutes. Do not attempt to remove contact lenses, at least for first two minutes of rinsing, which should continue up to and during transport to hospital. Seek urgent medical attention. Rinse affected area with plenty of water. Remove and wash contaminated clothing. Seek urgent medical attention. Remove to fresh air and rest. If breathing distress persists, seek medical attention. Rinse mouth immediately with water. Give water to drink if subject is conscious. Do not encourage vomiting, but if it happens or appears imminent, keep affected person lying on side with head low to avoid inhalation of stomach contents. Seek urgent medical attention.

SKIN CONTAMINATION: INHALATION: INGESTION:

This document should accompany transportation to clinic/hospital and be at hand if a doctor is being contacted.

5. FIRE FIGHTING MEASURES: EXTINGUISHING MEDIA: The product is compatible with all commonly used extinguishing media.

SPECIAL FIRE FIGHTING PROCEDURES:

Remove the product if possible; otherwise, keep it cooled with water.

6. ACCIDENTAL RELEASE MEASURES: Limit leakage into sewers or local environment by damming, or by taking liquid up with adsorbent, non-combustible material (e.g. dry earth or sand). Rinse copiously with water. Dispose of spillage residues according to local procedures, e.g. delivery to a designated station for disposal of chemical waste. See also sections 8 and 13.

7. HANDLING AND STORAGE: HANDLING: To be handled with caution. Must not be used in fully closed systems: these must first be provided with pressure-release valves or similar safety device. Avoid accidental or deliberate mixing of the product with alkaline substances or those containing chlorine. To be stored at cool temperature in closed, original container and kept separate from foodstuffs, medicinal products, animal feeds, and suchlike. Also keep product well away from alkaline products or those containing chlorine, to avoid risk of mixing unless the reactivity of the product (see section 10) otherwise have been taken into account. Possibility to control leaks e.g. by use of sumps or retaining dams should be in place.

STORAGE:

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REVISION DATE: 26-09-2005

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION: INGREDIENT NAME Hydrogen peroxide EINECS NO. 231-765-0 LT EXP. (8 hrs) WEL : 1.4 mg/m ST EXP. (15 min) WEL : 2.8 mg/m

Specific monitoring procedures are not needed when used as intended. Use suitable protective gloves of plastic or rubber e.g. Nitrile or Neoprene (Class 2, breakthrough time over 30 minutes; EN 374). Also wear splash-proof goggles or full-face shield (EN 166) and an acid-proof apron (EN 463; type 6). Apply moisturising cream/lotion regularly to prevent skin drying out. There must be access to eye-irrigation facilities and a plentiful source of water.

9. PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: COLOUR: DENSITY/SPECIFIC GRAVITY: pH VALUE (CONCENTRATED): pH VALUE (1% SOLUTION): Clear liquid Colourless 1.08 1 FLASH POINT: 79 deg C

10. STABILITY AND REACTIVITY: The product is not itself flammable, but it will sustain fire. It reacts violently with organic compounds and with alkaline-reacting substances. Risk of excessive pressure developing. Contact with chlorine-containing compounds generates toxic gases.

11. TOXICOLOGICAL INFORMATION: EYE CONTAMINATION: SKIN CONTAMINATION: INHALATION: INGESTION: Causes tissue corrosion. Risk of serious risk of damage to cornea and loss of sight. Causes tissue corrosion. Splashes have immediate blanching effect on skin (white blotches that disappear spontaneously after some time). Inhalation of aerosols can irritate and corrode respiratory tract lining. Risk of lung damage at high doses. Corrosive; causes vomiting and distress.

12. ECOLOGICAL INFORMATION: The organic compounds in the product are ultimately easily degradable, and do not need to be classified in respect of their environmental toxicity.

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REVISION DATE: 26-09-2005

13. DISPOSAL CONSIDERATIONS: Disposal according to Local Authority regulations, e.g. delivery to designated station for disposal of chemical waste. Verify that procedure complies with local regulations.

14. TRANSPORT INFORMATION: DANGER CLASS (ADR/RID): PROPER SHIPPING NAME: UN-No.: PACKAGING GROUP: HAZCHEM CODE: MARINE POLLUTANT: Class 5.2 Organic peroxide, type F, liquid (contains peracetic acid) 3109 II 2R No

15. REGULATORY INFORMATION: LABEL FOR SUPPLY:

Oxidizing (O) CONTAINS: R-PHRASES:

Corrosive (C)

Peracetic acid, hydrogen peroxide and acetic acid R7: May cause fire. R35: Causes severe burns. S2: Keep out of the reach of children. S3: Keep in a cool place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Health & Safety at Work Act. The Control of Substances Hazardous to Health. The Chemicals (Hazard Information and Packaging for Supply) Regulations. Requirements for special training: None specified. However, this product should only be handled by persons who have been instructed about its hazardous properties.

S-PHRASES:

REGULATORY INFORMATION:

COMMENTS:

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REVISION DATE: 26-09-2005

16. OTHER INFORMATION: USER NOTES: DECLARATION ACCORDING TO REGULATION (EC) No.648/2004: Oxygenbased bleaching agents 15.0 - 30.0%, Phosphonates < 5.0%,

LIMITATIONS OF USE: R-PHRASES (SECTION 2):

Must not be used by persons under 18 years of age, except when adult supervision is available. R5: Heating may cause an explosion. R7: May cause fire. R8: Contact with combustible material may cause fire. R10: Flammable. R20/22: Harmful by inhalation and if swallowed. R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R34: Causes burns. R35: Causes severe burns. R50: Very toxic to aquatic organisms.

ISSUED BY: REVISION DATE: REPLACES: CHANGES IN: DISCLAIMER:

C.T.Wright 26-09-2005 14-02-2003 8, 16 This information relates only to the specific material designated and may not be valid for such a material used in conjuction with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made as to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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