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Distillation Column (D-203) Stream 20: in in Out Out 1 5 3 6 2 4

Distillation Column D-203 separates a stream containing ethanol, ethyl acetate, and water into two outlet streams. Stream 19 contains 105.13 kg/hr of ethyl acetate at 65.37°C and 1.01 atm. This stream is separated in the distillation column to produce Stream 20 containing only ethyl acetate, and Stream 21 containing ethanol and water. Heat calculations are provided for the temperature changes of each component as they enter and exit the distillation column. The overall heat duty of the distillation column is calculated to be 36.0934333 MJ based on the heat of transfer for each component.

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IzhamGhazi
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42 views3 pages

Distillation Column (D-203) Stream 20: in in Out Out 1 5 3 6 2 4

Distillation Column D-203 separates a stream containing ethanol, ethyl acetate, and water into two outlet streams. Stream 19 contains 105.13 kg/hr of ethyl acetate at 65.37°C and 1.01 atm. This stream is separated in the distillation column to produce Stream 20 containing only ethyl acetate, and Stream 21 containing ethanol and water. Heat calculations are provided for the temperature changes of each component as they enter and exit the distillation column. The overall heat duty of the distillation column is calculated to be 36.0934333 MJ based on the heat of transfer for each component.

Uploaded by

IzhamGhazi
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Distillation Column (D-203)

Stream 20

Ethyl acetate (l) = 105.13 kg/hr


T = 65.37 C
P = 1.01 atm

Distillation Column
(D-203)

Stream 19
Ethanol (l) = 1064.28 kg/hr
Ethyl acetate (l) = 105.13 kg/hr
Water (l) = 48.63 kg/hr

Stream 21
Ethanol (l) = 1064.28 kg/hr
Water (l) = 48.63 kg/hr

Components
Ethanol
Water
Ethyl acetate

Inlet
nin (kmol)
23.1021
2.6993
1.1931

Hin (kJ/mol)
H1 = 4.5375
H3 = 0.1689
H2 = 6.8386

H1
Ethanol (25C, l)

Ethanol (65.37C, l)

H1 = CpdT
= 0.1224 kJ/molC (65.37 25) C
= 4.5375 kJ/mol
H2
Ethyl acetate (25C, l)
H = CpdT

Ethyl acetate (65.37C, l)

Outlet
nout (kmol)
Hout (kJ/day)
23.1021
H5 = 5.9909
2.6993
H6 = 0.2230
1.1931
H4 = 8.8257

= 0.1694 kJ/molC (65.37 25) C


= 6.8386 kJ/mol
H3
Water (25C, l)

Water (65.37C, l)

H = CpdT
= 0.004184 kJ/molC (65.37 25) C
= 0.1689 kJ/mol
H4
Ethyl acetate (25C, l)

Ethyl acetate (77.10C, l)

H = CpdT
= 0.1694 kJ/molC (77.10 25) C
= 8.8257 kJ/mol
H5
Ethanol (25C, l)

Ethanol (78.3C, l)

H = CpdT
= 0.1224 kJ/molC (78.3 25) C
= 5.9909 kJ/mol
H6
Water (25C, l)

Water (78.3C, l)

H = CpdT
= 0.004184 kJ/molC (78.3 25) C
= 0.2230 kJ/mol
*All Cp values are taken from National Institute & Standards Technology (NIST)

Q = =


out

= [(1.1931 kmol 8.8257 kJ/mol) + (23.1021 kmol 5.9909 kJ/mol) + (2.6993 kmol
0.2230 kJ/mol)] [(23.1021 kmol 4.5375 kJ/mol) + (1.1931 kmol 6.8386 kJ/mol) + (2.6993
kmol 0.1689 kJ/mol)]
= 36.0934333 MJ

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