STP Lec
STP Lec
ENGINEERING
SEWAGE TREATMENT: PLANNING & DESIGN
POLLUTION
Wastewater collected from municipalities and communities must ultimately
be returned to receiving waters or to the land.
Pollution may be defined as the introduction of a substance to the
environment at levels leading to lost beneficial use of a resource or
degradation of the health of humans, wildlife, or ecosystems.
CONTAMINATION
The presence of infectious or non-infectious agent in an inanimate article or
substance.
Water Pollution
DAO 34 (DENR Administrative Order No. 34 Series of 1990) Revised Water
Usage and Classification
Water Usage and Classification for the purpose of maintaining the
quality of Philippine waters in a safe and satisfactory condition, all waters
are classified according to beneficial usages (i.e. Class AA, A, B, C, D,
SA, SB, SC and SD.
POINT AND NON-POINT SOURCES
Point sources of pollution occur when harmful substances are emitted
directly into a body of water from a pipeline or sewer.
Non-Point sources pollution occurs as water moves across the land or
through the ground and picks up natural and human-made pollutants.
These are characterized by multiple discharge points.
EXISTING WATER RESOURCES (NWRB)
Marine Waters
- cover an area of about 226,000 sq. km, including bays and gulfs
- coastline stretches to about 17,460 km
- 64 or 79 provinces are in coastal areas
Groundwater
Inland Waters
- Lakers 99
o Major (minimum area of 4 km2) - 16
o Minor (minimum area less than 4 km2) 83
- Status of our Rivers
o 180 of 421 rivers are polluted
o 50 are biologically dead
o 4 rivers are from Metro Manila
INTRODUCTION 1
SEWAGE TREATMENT: PLANNING & DESIGN
SEWAGE TREATMENT
Sewage treatment is the process of removing contaminants from wastewater,
primarily from household sewage.
It includes physical, chemical, and biological processes to remove theses
contaminants and produce environmentally safer treated wastewater (or
treated effluent).
By-product of sewage treatment: semi-solid waste or slurry, called sewage
sludge and effluent.
WASTEWATER ENGINEERING
Wastewater engineering is the branch of environmental engineering in which
basic principles of science and engineering are applied to the problems of
water-pollution control that is issues associated with the treatment and reuse
of wastewater.
The ultimate goal is the protection of the environment in a manner
commensurate with economic, social, and political concerns.
Specific objectives:
To reduce the pollution loading i.e. carbonaceous removal, nutrients
removal, heavy metals removal, etc.
Compliance with the government standards mandated by DENR
and/or LLDA (Laguna Lake Development Authority)
Sustainable development
you sit down outside, you shall dig with it and shall turn to cover up
your excrement. (Deuteronomy 23: 12-13)
Cathole or cat hole (sometimes called pighole) is a pit for human feces.
During ancient times, aside from a place for disposing bowel
movements, it was also used for disposing spent water from kitchen.
Also used by hikers and other individuals engaged in outdoor
recreation.
Pit Privies (also known as out houses and earth closets)
Have been used for thousands of years, in urban settings such as
ancient English church, American rural settings, and some cities of
developed countries.
Chamber pots
Chamber pots were typically emptied into community latrines when
large number of people lived in close proximity, or private ones
elsewhere.
Chamber pots evolved eventually into a more intricate design and
INTRODUCTION 2
SEWAGE TREATMENT: PLANNING & DESIGN
INTRODUCTION 3
SEWAGE TREATMENT: PLANNING & DESIGN
SEWAGE
It is the liquid (spent water) conveyed by a sewer. It may consist of any one or
a mixture of the following depending on the type of collection system used
and may include:
Domestic Sewage also known as sanitary sewage, is the on that
originates in the sanitary convencies of a dwelling, residences,
commercial, institutional and similar facilities.
Industrial wastewater wastewater in which industrial wastes
predominate (i.e. waste from industrial process such as brewing,
dyeing, etc.)
Storm sewage liquid flowing in sewers during or following a period of
rainfall and resulting from precipitation runoff.
Infiltration is the groundwater entering sewers and building
connections through defective joints and broken or cracked pipe and
manholes.
Inflow is water discharged into sewer pipes or service pipe
connections from sources such as roof leaders, etc.
Composition of Sewage
ORGANIC
COMPOSITION
Carbohydrates
(30-50%)
SOLID
COMPOSITION
SEWAGE Proteins
COMPOSITION Organic (40-60%)
0.10% Solids
Inorganic Fats & Oil
Sewage (10%)
-sand, grit &
99.9% Water metal chips
Nutrients
INTRODUCTION 4
SEWAGE TREATMENT: PLANNING & DESIGN
Population Projection
1. Arithmetic Method the rate of growth is always constant.
= +
4. Logistics Method the logistic curve used in modeling population trends has an
S shape. The hypothesis of logistic growth may be tested by plotting recorded
population data on logistic paper.
=
+ ( + )
INTRODUCTION 5
SEWAGE TREATMENT: PLANNING & DESIGN
CHARACTERISTICS OF WASTEWATER
Physical
Chemical
Biological
Radioactive
Physical Characteristics
1. Total Solids
2. Taste and odor
3. Temperature
4. Color
1. TOTAL SOLIDS
defined as all the matter that remains as residue upon evaporation at
103 to 105 OC.
=
Solids Determination:
Ignition at 103 OC
Total Solids
Organic
(Volatile Solids)
Ignition at 550 OC
Sample
Inorganic
(Fixed Solids)
Imhoff Cone
Suspended
Solids
INTRODUCTION 6
SEWAGE TREATMENT: PLANNING & DESIGN
SETTLEABLE SOLIDS
Suspended solids that will settle to the bottom of a cone-shaped
container (Imhoff cone) in one-hour.
are approximate measure of the quantity of solids that will
be removed by sedimentation in clarifiers or ponds
approximately 75% organic
COLLOIDAL SOLIDS
not truly dissolved yet and do not settle readily.
are particulate matter with an approximate diameter
range from 1 millimicron to 1 micron
important factor in treatment and disposal of wastewater
VOLATILE SOLIDS
are determined by igniting the residue on evaporation, or the
filtered solids at 550 OC in an electric muffle furnace.
dried solids are burned for 15 to 20 min.
indicator of the organic content of wastewater since the
organic fraction will oxidize and will be driven off gas at 550
OC
FIXED SOLIDS
are inorganic fraction that remains behind as ash after ignition. It
is the rough measure of the mineral content of wastewater.
However, many inorganic salts volatilize during ignition
CaCO3 Calcium Carbonate, the major component of the
inorganic salts, is stable up to a 825 OC
INTRODUCTION 7
SEWAGE TREATMENT: PLANNING & DESIGN
TS - Total Solids TS
2. ODORS
Caused by gases produced by the decomposition of organic matter.
The most characteristic odor of stale or septic wastewater is H 2S, which is
produced by anaerobic microorganisms that reduce sulfates to sulfides.
Offensive odors can cause poor appetite for food, lowered water
consumption, impaired respiration, nausea and vomiting and mental
perturbation.
3. TEMPERATURE
The temperature of wastewater is commonly higher than water supply.
Mean annual wastewater temperature: 10 to 21.1OC
Representative value: 15.6 OC
Impacts:
Effect on aquatic life
Chemical reactions and reaction rates (serious depletions in
dissolved oxygen, DO concentrations, in the summer months
Suitability of the water for beneficial use
Abnormally high temperatures can foster the growth of
undesirable water plants and wastewater fungus.
Standards: Class C Inland Water it should be ambient not to raise 3
OC above river
INTRODUCTION 8
SEWAGE TREATMENT: PLANNING & DESIGN
4. COLOR
Fresh wastewater: Gray
Septic/Stale: Black
Anthropogenic sources:
Paper mills
Textile mills
Food processing
Chemical compounds: humic acid (yellow); iron oxides (red) and
Manganese oxides (brown)
Impact:
Aesthetic displeasing and unacceptable
May be an indication of toxicity
May stain textiles and fixtures
Types of Color:
Apparent Color due to suspended solids
True Color due to dissolved solids that remain after suspended solids
Measurement: Colorimetric (Visual Comparison Method)
Unit Measurement of Color:
1. True Color Unit (TCU)
2. Platinum Cobalt Unit (PCU)
o Standard color solutions: Potassium Chloroplatinate
(K2PtCl6) tinted with small amounts of cobalt chloride.
o Color produced by 1 mg/L of Pt plus mg/L of Cobalt = 1
standard color unit
o Comparison tubes: Nessler tubes
Chemical Characteristics
1. pH
2. FOG (Fats, Oil and Grease) and other organic matter
3. BOD5
4. COD
5. Nutrients
6. Heavy Metals
1. pH
is negative logarithm of hydrogen ion concentration.
pH = -log [H+] or pH = log 1/[H+]; [H+] = antilog pH
pH + pOH = 14
low or high pH is undesirable in wastewater
pH range 6.5 to 9.0 (standards)
Acid Base
0 7 14
2. ALKALINITY
Is the ability of water to neutralize acids.
CO32- H2BO3-
HCO3- HPO4-
OH - NH3
HSiO3-
These compounds result from the dissolution of mineral substances in the
soil and atmosphere.
INTRODUCTION 9
SEWAGE TREATMENT: PLANNING & DESIGN
3. HARDNESS
Is caused by divalent or multivalent cations or positively charged
metallic ions principally Ca+2 and Mg+2, others include Iron, Strontium,
Manganese and Barium.
Anions are bicarbonates, chlorides and sulfates.
Like alkalinity, it is expressed in terms of mg/L of CaCO3
Cations Anions
Ca2+ HCO3
Mg 2+ SO42-
Sr 2+ Cl-
Fe2+ NO3-
Classification of hardness:
Nature of water Range of hardness
Soft 75 mg/L as CaCO3
Moderately hard 75-150 mg/L as CaCO3
Hard 150-300 mg/L as CaCO3
Very hard >300 mg/L as CaCO3
5. ORGANIC MATTER
These solids are derived from both the animal and plant kingdoms and
the activities of man as related to the synthesis of organic compounds.
Are normally composed of a combination of carbon, hydrogen, and
oxygen, and nitrogen in some cases.
Proteins are the principal constituents of the animal organism.
They are complex in chemical structure and unstable, being
subject to many forms of decomposition. When present in large
quantities, extremely foul odors are apt to be produced by their
decomposition.
Carbohydrates include sugars, starches, cellulose and wood
fiber.
Surfactants are large organic molecules that are slightly soluble
in water and cause foaming in wastewater-treatment plants and
in the surface waters into which the waste effluent is discharged.
INTRODUCTION 10
SEWAGE TREATMENT: PLANNING & DESIGN
BOD Exerted
If you determine the BOD after 5 days, this is called the 5-
day BOD (BOD5). If you determine the BOD after 20 days,
this is called the 20 day BOD (BOD20). These are really
BOD exerted values.
Ultimate BOD
It is the amount of oxygen required to decompose all of
the organic material after infinite time. This is usually
simply calculated form the 5 or 20 day data.
Mathematically,
INTRODUCTION 11
SEWAGE TREATMENT: PLANNING & DESIGN
Integrating,
ln =
=
BOD exerted,
=
= (1 )
where:
Yt = BOD exerted @ time t
Lo = ultimate BOD, mg/L
Lt = BOD remaining @ time t
k = reaction constant (per day)
INTRODUCTION 12
SEWAGE TREATMENT: PLANNING & DESIGN
=
- Varies from 0.4 to 0.8 for domestic wastewaters
- BOD5/COD > 0.6 = waste is fairly biodegradable
- 0.3>BOD5/COD> 0.6 = seeding required to treat biologically
- BOD5/COD < 0.3 = cannot be treated biologically
Nitrogen
Is a constituent of proteins, chlorophyll and many other
biological compounds.
Proteins that are converted to amino acids and further
reduced to ammonia (NH3)
Sources: Proteins, Amines, Amino Acids, Urea
Objectionable: promotes Eutrophication
Total Kjeldahl Nitrogen (TKN) is a measure of the total
organic and ammonia nitrogen in the wastewater.
TKN gives a measure of the availability of nitrogen for
building cells.
INTRODUCTION 13
SEWAGE TREATMENT: PLANNING & DESIGN
Nitrogen Cycle
Protein
Atmosphe Organic
re Nitrogen
N2 gas NO2
NO3
Phosporus
Source: Detergents, Fertilize,
Form: Phosphate (PO43-)
Measurement: Colorimetric
Important in bacterial propagation
Promotes eutrophication or algal bloom
6. HEAVY METALS
Non-toxic Metals
Sodium Iron
Manganese Aluminum
Copper Zinc
Toxic Metal
Arsenic Barium
Cadmium Chromium
Lead Mercury
Silver
Standards are set in DAO No. 35
Treatment by precipitation, coagulation, ion exchange, reverse osmosis
Biological Characteristics
Domestic wastewater contains enormous quantities of microorganisms.
Depending on sewage age and the quantity of dilution of water,
bacterial counts in raw sewage may be expected to range from 500,000
to 5,000,000 per mL.
Algae Protozoa Crustaceans
Fungi Rotifers
INTRODUCTION 14
SEWAGE TREATMENT: PLANNING & DESIGN
1. MICROBIOLOGY OF SEWAGE
Bacteria
Single-celled plants which metabolize soluble food and reproduce by
binary fission.
In the presence of adequate and a suitable environment, bacteria will
produce and behave in the graph shown:
INTRODUCTION 15
SEWAGE TREATMENT: PLANNING & DESIGN
Algae
Are photosynthetic microorganisms which can produce oxygen and
organic cell mass from inorganic chemicals.
Algae are not important in most waste treatment process, but play a
role in oxidation ponds.
Protozoa
are single celled protists which reproduce by binary fission. They can
be aerobic, anaerobic, or facultative.
Their major food source is the bacteria.
Protozoa of importance to sanitary engineers include amoebas,
flagellates, and free-swimming stalked ciliates.
Fungi
are multicellular nonphotosynthetic plants. Most fungi are aerobic, but
anaerobic species are known.
They tend to predominate over bacteria in wastes which are deficient
in nitrogen or low in pH.
Their large filamentous shape makes them to settle poorly and are thus
difficult to remove by sedimentation.
Rotifers
Are the simplest multicellular animal. They feed on bacteria and small
protozoa, thus further stabilizing the waste.
Since they require a high level of DO, their presence is a good
indication of the relative stability of a treated waste.
Crustaceans
Any of various types of animal that live in water and have a hard outer
shell.
Their presence is also a good indication of a stabilized wastewater.
INTRODUCTION 16
SEWAGE TREATMENT: PLANNING & DESIGN
Enough nutrients
Enough oxygen to breath
Coliform Organisms
are rod shaped bacteria thriving inside the intestinal tract of man.
Each person discharges from 100 to 400 billion coliform organisms per
day.
They are harmless to man and are, in fact, useful in destroying organic
matter in biological waste treatment processes.
The presence of coliform organisms is taken as an indication that the
water is free from disease producing organisms.
Coliform Organisms bacteria include the genera Escherichia and
Aerobacter.
Other genera: Citrobacter, Hafnia, and Klebsiella
There is difficulty in determining E.coli to the exclusion of soil
coliforms, as a result, the entire coliform group is used as an
indicator of fecal pollution.
E. coli is the preferred pathogen indicator.
Note: this is not the pathogenic E.coli O157:H7 strain
Properties of E.coli are:
o Found in much higher concentrations than most
pathogens in fecal matter.
o Non pathogenic
o Easy detect, relatively fast and inexpensive analysis.
o Its absence indicates absence of enteric pathogens.
Total Coliform
all aerobic, facultative and anaerobic gram-negative, non-spore
forming, rod-shaped bacteria that ferment lactose with gas
formation within 48 hours.
INTRODUCTION 17
SEWAGE TREATMENT: PLANNING & DESIGN
2. SAMPLING TECHNIQUES
Objective of Sampling:
Evaluate performance efficiency of WTP
Compliance to DENR requirements
GRAB SAMPLING
Sample is taken at random with no particular time.
It may be taken from the discharge of a pump, be manually dipped
from the flow, or be automatically dipped or siphoned from the
stream.
COMPOSITE SAMPLING
It is a mixture of grab samples taken over a period of time, with the
volume of individual samples usually being proportional to the flow at
the time the sample is taken.
Composite samples are most useful for analyses of average
characteristics such as daily waste loads.
CONTINUOUS SAMPLING
Sample represents diversion of a small fraction of the total flow over
some period of time.
Continuous samplers are usually not flow proportional. Rather, they
extract the sample at a constant rate.
Continuous samplers are most suitable for instrumental measurements
which can be performed virtually instantaneously, such as
temperature, pH, DO, etc.
INTRODUCTION 18
SEWAGE TREATMENT: PLANNING & DESIGN
INTRODUCTION 19
SEWAGE TREATMENT: PLANNING & DESIGN
Important elements:
Flowsheet is a graphical representation of a particular combination of unit
operation and processes.
Process loading criteria key criteria used as a basis for sizing the
individual unit operation and processes.
INTRODUCTION 20
SEWAGE TREATMENT: PLANNING & DESIGN
INTRODUCTION 21
SEWAGE TREATMENT: PLANNING & DESIGN
PRELIMINARY TREATMENT
Provides protection to the wastewater treatment plant equipment that
follows.
This includes:
Screening
Flow measurement
Solids grinding
Grit removal
Equalization
SCREENING
Treatment used for the removal of coarse and settleable solids by
inception.
Purpose: To remove material which would
1. Damage equipment
2. Interfere with the satisfactory operation of a process
3. Cause objectionable shoreline condition
Types of Screens
Racks or bar screen - composed of parallel bars or rods which maybe
hand cleaned or mechanically cleaned
Fine screens wire/cloth mesh; perforated plate
Screening
Mechanically Static
Hand cleaned Drum type Step type
cleaned wedgewire
Static
Drum type Step type
wedgewire
FLOW MEASUREMENT
Flow rate needed for efficient operation, chemical addition, etc.
Several operations need flow rate data for good operations (I.e.
chlorination, pH adjustment, etc.)
Legislative requirement
Various Types of Wastewater Flowrate used in Process design:
Average Daily Flowrate (ADF) average flowrate over a period of
time.
Peak Hourly Flowrate (PHF) highest flowrate measured in 24-hour
PRELIMINARY TREATMENT 22
SEWAGE TREATMENT: PLANNING & DESIGN
period
Maximum Daily Flowrate (MDDF) maximum daily design flow over a
period of time
GRIT REMOVAL
Purpose: To remove grit (sand, broken glass, silt, and pebbles) to avoid
wears of pump and other mechanical devices.
Grit chamber is an enlarged channel where the velocity of wastewater
flow is controlled to allow only the heavier solids to settle out.
The downward slope of a sewer line must be sufficient to maintain a
minimum velocity of 2 feet per second in the pipe. This velocity is
maintained until the flow enters the treatment plant. The grit is removed
from the flow as it passes through a grit chamber. The velocity in the grit
chamber is reduced to about 1 foot per second.
Horizontal-flow grit chamber
Aerated grit chamber
Circular grit chamber
FLOW EQUALIZATION
Equalization basin maintains a constant volumetric flow of wastewater
from pretreatment to other downstream operation. It dampens hydraulic
or flowrate variations.
Specific objectives of equalization:
Smooth out fluctuations in flow rate
Dampens the variation in the concentration of BOD5
Decrease fluctuations in flow rate, to provide more consistent
treatment. Done by storing excess wastewater during high flow
periods. Results in more consistent treatment.
PRELIMINARY TREATMENT 23