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Isocineticasycalculos

The document contains data from experiments on isokinetic curves. It provides rate constants k1 and k2, which were calculated based on temperature, as well as conversion x values over a range of temperatures and flow rates. Graphs are presented showing the relationship between conversion, temperature, and flow rate. The data can be used to analyze reaction kinetics and conversion under different conditions.

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Jonhatan Pierre Aparicio Ventura
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48 views8 pages

Isocineticasycalculos

The document contains data from experiments on isokinetic curves. It provides rate constants k1 and k2, which were calculated based on temperature, as well as conversion x values over a range of temperatures and flow rates. Graphs are presented showing the relationship between conversion, temperature, and flow rate. The data can be used to analyze reaction kinetics and conversion under different conditions.

Uploaded by

Jonhatan Pierre Aparicio Ventura
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLS, PDF, TXT or read online on Scribd
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Curvas isocinéticas: x = [k1(T)-v/CoA]/[k1(T)+k2(T)] k1 = 3,1·1e7 · exp( - 5850

k2 = 1,7·1e18·exp(-14900
CoA = 1 mol/l Velocidad = 1.000

T (ºC) k1 (1/min) k2 (1/min) v (mol/l·min) x


0.0 0.01531 0.00000 1.000 -64.2912 1.0000
5.0 0.02251 0.00001 1.000 -43.4017

Conversión, x
10.0 0.03265 0.00002 1.000 -29.6059 0.9000
15.0 0.04675 0.00006 1.000 -20.3665
0.8000
20.0 0.06611 0.00014 1.000 -14.0956
25.0 0.09242 0.00033 1.000 -9.7851 0.7000
30.0 0.12778 0.00075 1.000 -6.7861
35.0 0.17482 0.00166 1.000 -4.6758 0.6000
40.0 0.23679 0.00360 1.000 -3.1749
45.0 0.31767 0.00761 1.000 -2.0976 0.5000

50.0 0.42233 0.01572 1.000 -1.3187


0.4000
55.0 0.55662 0.03176 1.000 -0.7536
60.0 0.72755 0.06281 1.000 -0.3447 0.3000
65.0 0.94347 0.12176 1.000 -0.0531
70.0 1.21422 0.23152 1.000 0.1482 0.2000
75.0 1.55139 0.43217 1.000 0.2780
0.1000
80.0 1.96848 0.79257 1.000 0.3508
85.0 2.48113 1.42910 1.000 0.3788 0.0000
90.0 3.10743 2.53534 1.000 0.3735 0.0 10.0 20.0 30.0 40.0
95.0 3.86808 4.42836 1.000 0.3457
100.0 4.78675 7.62002 1.000 0.3052 Tempe
k1 = 3,1·1e7 · exp( - 5850/T)
k2 = 1,7·1e18·exp(-14900/T)

0000

9000 v (mol/l.min).
8000

7000

6000

5000

4000

3000

2000

1000

0000
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0 100.0

Temperatura (ºC)
Conversión, x
1.0000

T (ºC) v=0 v=0,002 v=0,005 v=0,01 v=0,02 v=0,05


0.9000
0.0 0.9998 0.8692 0.6733 0.3469 -0.3060 -2.2648
5.0 0.9996 0.9108 0.7776 0.5556 0.1116 -1.2205
10.0 0.9993 0.9381
0.8000 0.8463 0.6932 0.3872 -0.5310
15.0 0.9988 0.9560 0.8919 0.7851 0.5715 -0.0695
20.0 0.9979 0.9677
0.7000 0.9224 0.8470 0.6960 0.2432
25.0 0.9965 0.9749 0.9426 0.8886 0.7808 0.4574
30.0 0.9942 0.9786 0.9553 0.9164 0.8386 0.6052
35.0 0.9906 0.6000
0.9792 0.9622 0.9339 0.8773 0.7073
40.0 0.9850 0.9767 0.9642 0.9434 0.9018 0.7770
45.0 0.9766 0.9705
0.5000 0.9612 0.9459 0.9151 0.8229
50.0 0.9641 0.9596 0.9527 0.9413 0.9185 0.8500
55.0 0.9460 0.9426 0.9375 0.9290 0.9120 0.8610
0.4000
60.0 0.9205 0.9180 0.9142 0.9079 0.8952 0.8573
65.0 0.8857 0.8838 0.8810 0.8763 0.8669 0.8388
70.0 0.8399 0.3000
0.8385 0.8364 0.8329 0.8260 0.8053
75.0 0.7821 0.7811 0.7796 0.7771 0.7720 0.7569
80.0 0.7129 0.7122
0.2000 0.7111 0.7093 0.7057 0.6948
85.0 0.6345 0.6340 0.6332 0.6320 0.6294 0.6217
90.0 0.5507 0.5503 0.5498 0.5489 0.5471 0.5418
0.1000
95.0 0.4662 0.4660 0.4656 0.4650 0.4638 0.4602
100.0 0.3858 0.3857 0.3854 0.3850 0.3842 0.3818
0.0000
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0
Temperatura, ºC
velocidad
(mol/l·min)
v=0,1 v=0,2 v=0,5 v=1 v=2
-5.5293 -12.0584 -31.6457 -64.2912 -129.5822
v=0
-3.4405 -7.8807 -21.2010 -43.4017 -87.8030
v=0,0
-2.0612 -5.1218 -14.3033 -29.6059 -60.2112
02
-1.1378 -3.2743 -9.6839 -20.3665 -41.7318
v=0,0
-0.5115 -2.0208 -6.5488 -14.0956 -29.1890
05
-0.0817 -1.1598 -4.3943 -9.7851 -20.5666
v=0,0
0.2161 -0.5619 -2.8960 -6.7861 1-14.5664
0.4239 -0.1427 -1.8426 -4.6758 -10.3421
v=0,0
0.5690 0.1530 -1.0950 -3.1749 2 -7.3349
0.6692 0.3618 -0.5605 -2.0976 -5.1718
v=0,0
0.7358 0.5076 -0.1773 -1.3187 5 -3.6015
0.7761 0.6061 0.0962 -0.7536 -2.4531
v=0,1
0.7940 0.6675 0.2879 -0.3447 -1.6099
v=0,2
0.7918 0.6979 0.4163 -0.0531 -0.9918
v=0,5
0.7707 0.7015 0.4940 0.1482 -0.5435
0.7317 0.6813 0.5301 0.2780 v=1
-0.2262
0.6767 0.6405 0.5319 0.3508 v=2-0.0114
0.6089 0.5834 0.5067 0.3788 0.1230
0.5330 0.5152 0.4621 0.3735 0.1963
0.4542 0.4421 0.4060 0.3457 0.2252
0.3778 0.3697 0.3455 0.3052 0.2246

40.0 50.0 60.0 70.0 80.0 90.0 100.0


Temperatura, ºC
isotérmico (T = 62ºC)
x T (ºC) k1 k2 v CoA/v
0.00 54.0 0.5271 0.0276 0.8080 1.2376
0.05 55.0 0.5566 0.0318 0.7635 1.3098
0.10 56.0 0.5876 0.0365 0.7190 1.3908
0.15 57.0 0.6202 0.0418 0.6745 1.4826
0.20 58.0 0.6543 0.0479 0.6300 1.5873
0.25 59.0 0.6901 0.0549 0.5855 1.7079
0.30 60.0 0.7276 0.0628 0.5410 1.8484
0.35 61.0 0.7668 0.0718 0.4965 2.0141
0.40 62.0 0.8080 0.0820 0.4520 2.2124
0.45 63.0 0.8511 0.0937 0.4075 2.4540
0.50 64.0 0.8962 0.1068 0.3630 2.7548
0.55 65.0 0.9435 0.1218 0.3185 3.1397
0.60 66.0 0.9929 0.1387 0.2740 3.6496
0.65 67.0 1.0446 0.1578 0.2295 4.3573
0.70 68.0 1.0986 0.1795 0.1850 5.4054
0.75 69.0 1.1552 0.2039 0.1405 7.1174
0.80 70.0 1.2142 0.2315 0.0960 10.4167
0.85 71.0 1.2759 0.2627 0.0515 19.4175
8.0000 10.0000
0.90 72.0 Régimen
1.3404
isotérmico 0.2978
(T = 62ºC). 0.0070 142.8571 Régimen a
0.95 73.0 1.4077 0.3374 -0.0375 -26.6667
1.00 74.0 1.4780 0.3820 -0.0820 -12.1951
6.0000

CoA/v
4.0000 5.0000

2.0000

0.0000 0.0000
0.00 0.10 0.20 0.30Conversión,
0.40x 0.50 0.60 0.70 0.80 0.00 0.10 0.20 0.
adiabático (To = 54ºC)
t (min) v CoA/v t (min)
0.064 0.5271 1.8973 0.095
0.068 0.5272 1.8968 0.095
0.072 0.5252 1.9040 0.096
0.077 0.5209 1.9199 0.097
0.082 0.5138 1.9461 0.098
0.089 0.5038 1.9848 0.101
0.097 0.4904 2.0390 0.104
0.106 0.4733 2.1128 0.108
0.117 R=1 0.4520 2.2125 0.114
0.130 0.4260 2.3476 0.122
0.147 0.3947 2.5336 0.133
0.170 0.3576 2.7965 0.150
0.200 0.3140 3.1852 0.175
0.244 0.2630 3.8019 0.218
0.313 t= 0.2040 4.9025 0.307
0.438 3.519 0.1359 7.3606 0.618
2.413 0.0576 17.3534 2.628
-0.0319 -31.3553
10.0000
-0.1340
Régimen adiabático (To = 54ºC). -7.4626
-0.2502 -3.9974
-0.3820 -2.6178

5.0000
CoA/v

0.0000
0.00 0.10 0.20 0.30Conversión,
0.40x 0.50 0.60 0.70 0.80
Análisis de estabilidad: reactor de mezcla completa (t = 8,3 min)
Conversión, x =
q (kcal/molA) =
T(ºC) k1 k2 x (1) x (2)
-20.0 0.0028143 0.00000005 0.0228 Balance de materia:
-15.0 0.0044054 0.00000014 0.0353 Balance de energía:
-10.0 0.0067795 0.00000042 0.0533
-5.0 0.0102666 0.00000122 0.0785
0.0 0.0153127 0.00000337 0.1128
5.0 0.0225129 0.00000898 0.1574

Conversión, x
10.0 0.0326510 0.00002316 0.2132 Balances de materia
15.0 0.0467471 0.00005778 0.2794 1
20.0 0.0661141 0.00013969 0.3541 0 1
x (1)
25.0 0.0924234 0.00032789 0.4334 0.0952 1
x (2)
30.0 0.1277816 0.00074826 0.5132 0.1905 1
35.0 0.1748182 0.00166245 0.5887 0.2857 1
40.0 0.2367861 0.00360053 0.6562 0.3810 1
45.0 0.3176743 0.00761081 0.7126 0.4762 0
50.0 0.4223346 0.01571922 0.7561 0.5714 0
55.0 0.5566225 0.03175614 0.7852 0.6667 0
60.0 0.7275520 0.06281353 0.7988 0.7619 0
65.0 0.9434664 0.12176281 0.7957 0.8571 0
70.0 1.2142228 0.23152364 0.7753 0.9524 -20.0 0.0 20.0
Temper
75.0 1.5513925 0.43217182 0.7373
80.0 1.9684763 0.79257210 0.6831
85.0 2.4811338 1.42910474 0.6156
90.0 3.1074277 2.53534055 0.5392
95.0 3.8680814 4.42836079 0.4596
100.0 4.7867498 7.62002178 0.3821
0.80
26.0

ance de materia: v(x,T) = Co·x(1)/t


ance de energía: x(2) = Cp(T-To)/(q/x-DHr)

Balances de materia (1) y energía (2)

x (1)
x (2)

0.0 0.0 20.0 40.0 60.0 80.0 100.0


Temperatura, T(ºC)

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