B.Sc. Chemistry (Hons.) Curriculum
B.Sc. Chemistry (Hons.) Curriculum
) CURRICULUM
(2015 batch)
DEPARTMENT OF CHEMISTRY
B.Sc. CHEMISTRY (Hons.) CURRICULUM
OBJECTIVES:
The course contents have been proposed as per suggestions of the faculty
members of department of Chemistry, Manipal University Jaipur. The syllabus
contents are duly arranged in such a manner so that the importance is given to
requisite intellectual and laboratory skills.
(i) To teach the fundamental concepts of Chemistry and their applications.
(ii) To make students aware of advantages of eco-friendly chemical processes and
impact of chemistry on health and environment.
(iii) To enthuse the students for the subject and make them capable of accepting
any challenges in chemistry.
(iv) To make students aware of advantages of eco-friendly chemical processes
and impact of chemistry on health and environment.
(v) To motivate students to do good research work in chemistry and opt for
research career.
(vi) To educate the students with respect to skills and knowledge to practice
chemistry and imbibe the concept of sustainable developments.
Candidates who have passed (10+2) examination of any recognized Board or its
equivalent examination with minimum of 45% marks with Physics, Chemistry,
Mathematics or Biology as core subjects.
2
Course Structure of the B.Sc. (Hons) Chemistry Programme
(2015-2018)
Major course: Chemistry; Subsidiary: Mathematics/Bio
Science/Bio technology; Ancillary: Physics
8 CS 1102 Fundamental of 2 0 0 2 - - 10 - 40 50 -
Computers
9 EN 1101 General English 2 1 0 3 3 0 10 - 40 50 -
10 CS1132 Fundamental of 0 0 2 1 - 2 - 60 - - 40
Computers
Laboratory
Total 15 6 6 24
3
II Semester Exam Duration (Hrs) Relative
Weightage
(%)
1. 1
CY1212 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II
2. 2CY1213 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II
3. 3CY1214 Physical 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II
4. CY1231 Chemistry 0 0 2 1 2 - 60 - - 40
(Hons.)
Laboratory-II
5. MA 1211 Algebra 3 1 0 4 3 - 10 - 40 50 -
6. 6VE1201 Value 2 0 0 2 3 - 10 - 40 50 -
Education
7. 7CY1120 Environmental 2 1 0 3 3 - 10 - 40 50 -
Science
8. PY 1211 Oscillations 2 1 0 3 3 - 10 - 40 50 -
and wave
Optics
Total 18 6 4 26
4
III Semester Exam Duration (Hrs) Relative
Weightage
(%)
1 CY 1313 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-
III
2 CY 1315 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-
III
3 CY 1316 Physical 3 1 0 4 3 10 40 50
Chemistry
4 CY1331 Chemistry 0 0 4 2 - 2 - 60 - - 40
(Hons.)
laboratory-
III
5 CY 1332 Computer 0 0 4 2 2 - 60 - - 40
application
in
Chemistry
8 MA 1311 Differential 3 1 0 4 3 - 10 - 40 50 -
Equations
7 MA 1312 Solid 3 1 0 4 3 1 10 - 40 50 -
Geometry
and Vector
Calculus
Total 15 5 8 24
5
IV Semester Exam Duration (Hrs) Relative
Weightag
e (%)
1 CY 1413 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry -IV
2 CY 1414 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-IV
3 CY 1415 Physical 3 1 0 4 3 - 10 - 40 50 -
Chemistry
4 CY 1431 Chemistry 0 0 4 2 0 2 - 60 - - 40
(Hons.)
Laboratory-IV
5 MA 1411 Linear 3 1 0 4 3 - 10 - 40 50 -
Programming
Problems and
its application
5 MA1412 Dynamics 3 1 0 4 3 - 10 - 40 50 -
Total 18 5 4 25
6
V Semester Exam Duration (Hrs) Relative
Weightage
(%)
1 CY 1513 Chemistry 3 1 0 4 3 - 10 - 40 50 -
of
Biomolecul
es
2 CY 1514 Quantum 3 1 0 4 3 - 10 - 40 50 -
Chemistry
and its
Application
to Molecular
Spectroscop
y
3 CY 1515 Green 2 1 0 3 3 - 10 - 40 50 -
Chemistry
5 CY 1531 Chemistry 0 0 4 2 - 2 - 60 - 40
(Hons.)
Laboratory-
V
6 CY1570 Seminar 0 0 4 2 - - - 60 - - 40
5 MA 1511 Real 3 1 0 4 3 - 10 - 40 50 -
Analysis
6 MA 1512 Numerical 3 1 0 4 3 - 10 - 40 50 -
Analysis and
Probability
Theory
Total 16 6 8 26
7
VI Semester Exam Duration (Hrs) Relative
Weightage
(%)
1 CY Organic 3 1 0 4 3 - 10 - 40 50 -
1613 Spectroscopy
2 CY 1614 Molecular 3 1 0 4 3 - 10 - 40 50 -
Statistics and
photo chemistry
3 CY 1615 Organometallic 2 1 0 3 3 - 10 - 40 50 -
Chemistry and
Industrial
Chemistry
4 CY 1631 Chemistry 0 0 6 3 2 60 - 40
(Hons.)Laborat
ory-VI
5 CY 1670 Project 0 0 6 3 - - - 60 - - 40
6 MA 1611 Complex 3 1 0 4 3 - 10 - 40 50 -
Analysis
7 MA 1612 Discrete 3 1 0 4 3 - 10 - 40 50 -
Mathematics
Structure
Total 14 5 12 25
8
CY1112 Inorganic Chemistry-I [3 1 0 4]
Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008.
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007.
2. C. Housecroft and A. G. Sharpe, Inorganic Chemistry, Pearson India,
2012.
9
and flying wedge formulae; Alkanes and Cycloalkanes: IUPAC nomenclature of
branched and unbranched alkanes, methods of synthesis of alkanes, physical
properties and chemical reactions of alkanes, nomenclature of cycloalkanes,
methods of synthesis of cycloalkanes; Baeyer’s strain theory and its limitations;
Alkenes, Cycloalkenes, Dienes and Alkynes: Nomenclature, synthesis and
reactions of alkenes, cycloalkenes, dienes and alkynes.
Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.
Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley India, 2012.
Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
10
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.
CY1132 Chemistry(Hons.)laboratory I [0 0 2 1]
Text Books:
11
imperfect crystals: Intrinsic and extrinsic defects, point defects, line and plane
defects, vacancies-Schottky and Frenkel defects. Thermodynamics of Schottky
and Frenkel defect, band theory, band structure of metals, nnsulators and
semiconductors, intrinsic and extrinsic semiconductors, doping semiconductors,
p-n junctions, High temperature super conductors.
Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008.
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India,
2012.
Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
12
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.
Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley India, 2012.
Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.
13
CY1231 Chemistry (Hons.) Laboratory-II [0 0 2 1]
Inorganic qualitative Analysis: Qualitative analysis of inorganic mixtures
containing not more than six radicals including interfering radicals like phosphate,
oxalate, tartrate; Inorganic quantitative Analysis: various volumetric analyses.
Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012.
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.
Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.
14
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012.
3. F. A. Cotton, Chemical Applications of Group Theory, Wiley India, 2010.
Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.
Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.
15
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.
Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.
16
water and a non aqueous solvent; Surface Phenomena: Adsorption of some
organic acids on charcoal; Colorimetery: Verification of Lambert-Beer law;
Thin Layer and Column Chromatography: Determination of Rf value and
purity of organic compounds by use of thin layer chromatography, separation of
organic compound by column chromatography; Qualitative organic analysis:
Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.
3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale
Preparations Part 1, Pearson India, 2010.
4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva
Books, 2012.
5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013.
6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative
Organic Analysis Part 3, Pearson India, 2010.
Text Book:
1. T. Engel and P. Reid, Physical Chemistry, Chapter on Computational
Chemistry. Pearson India, 2013.
Reference Books:
1. S. M. Venit, Programming in Basic: Problem solving with structure and
style. Jaico Publishing House, 1996.
2. J. H. Noggle, Physical chemistry on a Microcomputer, Little Brown & Co.
1985.
17
CY1413 Inorganic Chemistry-IV [3 1 0 4]
Chemistry of 2nd and 3rd row d-block elements: Comparison of the chemistry
of elements of second and third row series with that of elements of the first
transition series. Mo-Mo and Re-Re quadrupole bonds. Chemistry of complexes
of Rh(III), Pt(II) and Pd(II); Chemistry of f-block elements: Chemistry of
Lanthanide elements, their isolation from one another, their coordination
chemistry; Coordination Compounds: Various definitions, types of ligands, The
Chelate and Macrocylic effects, Multidentate ligands, isomerism in coordination
compounds, nomenclature, stability of coordination compounds, stability
constants and chelate effect; Theories for bonding in complexes: Valence bond
theory for bonding in coordination compounds. Concept of multiple bonding and
back bonding; Crystal field theory: The splitting of d-orbitals in different fields,
Consequences, factors affecting and applications of orbital splitting, crystal field
stabilization energy (CFSE), magnetic properties, spectrochemical series and
colour of transition metal complexes. Jahn-Teller effect in octahedral and
tetrahedral complexes. Evidence of covalence and adjusted crystal field theory.
Molecular orbital treatment of octahedral, tetrahedral and square planar
complexes.
Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012.
18
thiophene and pyridine), Mechanism of electrophilic and nucleophilic substitution
reactions, Comparison of basicity, five and six-membered heterocycles.
Preparation and reactions of indole, quinoline and isoquinoline with special
reference to Fischer indole synthesis, Skraup synthesis and Bischler-Napieralski
synthesis. Mechanism of electrophilic substitution reactions of indole, quinoline
and isoquinoline; Fats, Oils and Detergents: Natural fats, edible and industrial
oils of vegetable origin, common fatty acids, glycerides, hydrogenation of
unsaturated oils. Saponification value, iodine value, acid value. Soaps, synthetic
detergents; Synthetic Dyes: Colour and constitution (electronic concept),
Classification of dyes. Chemistry and synthesis of Methyl orange, Congo red,
Malachite green, Crystal violet, Phenolphthalein, Fluorescein, Alizarin and
Indigo.
Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.
Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
and Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
and Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.
19
macromolecules, Addition and condensation polymerization, Molecular weight
heterogeneity, number average and weight average molecular weights,
Determination of molecular weights.
Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.
Text Books:
1. B.P. Levitt, Findlays Practical Physical Chemistry, Longman Group Ltd.
2003.
20
2. B.D. Khosla, V.C. Garg and A. Gulati, Senior Practical Physical
Chemistry, R. Chand & Co. 2005.
3. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012.
4. R.C. Das and R.C. Behera, Experimental Physical Chemistry, Tata
McGraw Hill Publishing Co. Ltd. 2001.
Text Books:
1. D.L. Nelson, M.M. Cox, Lehninger’s Principles of Biochemistry, W. H.
Freeman, 2011.
2. J.M. Berg, J.L. Tymoczko, and L. Stryer, Biochemistry, W. H. Freeman,
2009.
21
its solution, wave functions for hydrogen atom, electron spin, concept of spin
orbitals, spectral selection rules for one-electron atoms, spectrum of hydrogen
atom; Molecular spectroscopy: Electromagnetic radiation, absorption co-
efficient, Einstein coefficient, transition moment and oscillator strength and
Lasers. Microwave absorption, rotational Spectra, rotational Raman Spectra,
infrared absorption, Vibrational spectra of diatomic molecules; UV-Visible and
Nuclear Spectroscopy: Visible-Ultraviolet Absorption, Electronic spectra:
Electronic energy levels of molecules, selection rules for electronic spectra of
molecules, Frank-Condon principle, Beer-Lambert Law, electronic spectra of
polyatomic molecules, Photoelectron spectroscopy.
Text Books:
1. I.N. Levine, Quantum Chemistry, Oxford University Press , 2000.
2. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
3. I.N. Levine, Physical Chemistry, McGraw Hill Education (India) Private
Limited, 2011.
4. D.C. McQuarre, Physical Chemistry, University Science Books, 2005.
5. A.K. Chandra, Introductory Quantum Chemistry, McGrew Hill Education
(Indial) Pvt. Ltd. 2009.
6. C.N. Banwell and E. M. McCash, Fundamentals of Molecular
Spectroscopy, , McGrew Hill Education (Indial) Pvt. Ltd. 2013.
22
Text Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
and Synthesis (Part B), Springer India Private Limited, 2007.
2. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.
3. V.K. Ahluwalia, Green Chemistry: Greener Alternatives to Synthetic
Organic Transformations, Narosa Publishing House, 2011.
Text Books:
1. H. J. Arnikar, Essentials of Nuclear Chemistry, Wiley-Blackwell, 1987.
23
2. G. Friedlander, J.W. Kennedy, E.S. Macias and J.M. Miller, Nuclear and
Radiochemistry, Wiley India, 1981.
3. G.D. Christian, Analytical Chemistry, John Wiley 2004.
4. D.A. Skoog, D.M. West, F.J. Holler, S.R. Crouch, Fundamentals of
Analytical chemistry, Brooks/Cole, 2004.
5. D.A. Skoog., Principles of Instrumental Analysis, Holt-Saunders
International edition 2004.
24
Organic Chemistry Practicals
Multistep preparations and estimations: (i) Preparation of p-bromoaniline from
acetanilide (protection, aromatic electrophilic substitution and deprotection), (ii)
Preparation of anthranilic acid from phthalic anhydride (nucleophilic addition of
Hoffman degradation), (iii) Preparation of o-chlorobenzoic acid from anthranilic
acid (diazotization and Sandmeyer reaction), (iv) Preparation of benzopinacol
from benzophenone (photoreduction), (v) Preparation of benzopinacolone from
benzopinacol (pinacol – pinacolone rearrangement), (vi) Preparation of triphenyl
methane from benzopinacolone (nucleophilic cleavage of C-C bond), (vii)
Preparation of triphenylmethyl bromide from triphenyl methane (free radical
bromination by use of NBS), (viii) Preparation of 1,5-Diphenyl-1,4-pentadiene-3-
one from benzaldehyde and acetone (cross aldol condensation), (ix) Preparation
of E/Z-a-phenylcinnamic acid from benzaldehyde and phenylacetic acid (Perkin
reaction), (x) Preparation of 1,3,5-tribromobenzene from aniline (diazotization,
aromatic electrophilic substitution and deamination), (xi) Preparation of 2,5-
dihydroxy acetophenone from hydroquinone (Fries reaction), (xii) Preparation of
3,5-diethoxycarbonyl-2,4-dimethylpyrrole from ethylacetoacetate (Knorr
synthesis), (xiii) To estimate the strength of given glucose solution (Fehling
method), (xiv) To estimate acid value, iodine value and soaponification value of a
given oil, (xv) To estimate percentage of sulphur in given organic compound by
Messenger’s method.
Text Books:
1. D. J. Woollins, Inorganic Experiments, Wiley-VCH, 2003
2. J. Bassett, R.C Denney, G.H Jeffery, J. Mendham, Vogel’s Textbook of
Quantitative Inorganic Analysis (revised), Orient Longman,2003.
3. R. J. Angelici, Synthesis and techniques in inorganic chemistry, SGS series
London, 1999.
4. G. Pass, Practical Inorganic Chemistry, Chapman & Hall London, 1968
5. M. A. Malati, Experimental Inorganic/Physical Chemistry, Horwood
Publishing, Chichester, 1999
25
interpretation of 1H NMR spectra of simple organic molecules such as ethyl
bromide, ethanol, acetaldehyde, 1,1,2-tribromoethane, ethyl acetate, toluene and
acetophenone basics of 13C NMR; Mass Spectroscopy: Introduction,
instrumentation, Methods of ionization, separation. Fragmentation, McLafferty
rearrangement, Problems pertaining to the structure elucidation of simple organic
compounds using UV, IR and 1H NMR spectroscopic techniques.
Text Books:
1. W. Kemp, Organic Spectroscopy, Palgrave Macmillan, 1991.
2. R.M. Silverstein, F.X. Webster, D. Kiemle, Spectrometric Identification of
Organic Compounds, John Wiley & Sons, 2005.
3. D.L. Pavia, G.M. Lampman, G.S. Kriz, J.A. Vyvyan, Introduction to
Spectroscopy, Cengage Learning, 2008.
Text Books:
1. T. Engel and P. Reid, Thermodynamics, Statistical Thermodynamics, &
Kinetics, Pearson India, 2007.
2. B.R. Puri, L.R. Sharma and M.S. Pathania, Principles of Physical
Chemistry, Vishal Publishing Co., 2013.
26
compounds, preparation of Grignard reagent and organo lithium compound,
importance of organometallic chemistry in modern times, definition and
terminologies, preparation of metal carbonyls, binary carbonyls, mixed metal
polynuclear carbonyls, metal-olefin complexes: Zeises salt, Ferrocene, Hapticity
(η) of organometallic ligands, Simple examples of fluxional molecules,
Coordinative unsaturation, and homogeneous catalysis by organometallic
compounds, and polymerization of alkenes (Ziegler-Natta catalysis); Bonding
and Structure: Molecular hydrogen compounds, metal-hydrogen interactions
with C-H groups, carbonyl halides, Metal nitrosyl compounds, nitrosyl carbonyls.
Dinitrogen and dioxygen complexes, tertiary phosphines as ligand;
Organotransition metal Chemistry: Synthesis, structure and bonding aspects of
complexes of two, three, four and six electrons cyclic and acyclic ligands. Alkyl
and aryls of Transition metals, transition metal-carbon multiple bonds; alkylidene
complexes and alkylidyne complexes. Water and its treatment: Sources of
water, impurities in water, hardness of water and hardeness removal; Coal
Chemicals: Ultimate and proximate analysis of coal and their significance,
coking of coal by high temperature (By-product coke-oven) and low temperature
process. Plastics and Rubber:Classification of plastics, manufacture, properties
and uses of nylon 6 and nylon 6 6. manufacture of natural rubber from latex,
introduction about synthetic rubbers; Sugar Industry: Extraction of juice from
sugar cane. Manufacture and refining of sugar. Uses of molasses and
bagasse.Cellulose Industry:Study of raw materials for the manufacture of paper.
Manufacture of wood pulp by different (soda, sulphite and sulphate) processes.
Multistage bleaching of wood pulp. Conversion of pulp into thin paper by
Fourdrinier machine.Petroleum Industry: Composition and classification of
crude petroleum. Refining of petroleum and brief introduction regarding each
refining product. Thermal and catalytic cracking of petroleum products.
Significance of octane number and cetane number. Paints Industry: Introduction,
classification of paints, manufacture of paints, requirements of a good paint.
Text Books
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India,
2012
3. B.D. Gupta and A. J. Elias, Basic Organometallic Chemistry, University
Press, 2010.
4. A.G. Massey, Main Group Chemistry, Ellis Horwood,1999.
5. J. A. Kent, Riegel’s Handbook of Industrial Chemistry, CBS, 1997.
27
CY 1631 Chemistry (Hons.) Laboratory-VI [0 0 2 2]
Physical Chemistry:
Conductometry: (i) Determination of the solubility of a sparingly soluble
substance, determination of the degree of hydrolysis of NH4Cl and CH3COONa,
(ii) To study the kinetics of saponification of ethyl acetate by sodium hydroxide;
Potentiometry:Potentiometric titrations of diabasic acid, oxalic acid and malonic
acid with base. (iii) To determine potentiometerically the solubility and solubility
product of a sparingly soluble salt; Polarimetry: (i) To study the kinetics of
inversion of cane sugar by means of polarimetry; Chemical Kinetics: (i) To
determine activation energy of a reaction by studying its temperature dependence,
(ii) To study the reaction between potassium iodide and potassium
peroxodisulphate; pH-metry: (i) To titrate a weak base against a strong acid and
determine the ionization constant of the weak base.
Inorganic Chemistry:
(i) Strong acid-strong base titration in a non-aqueous solvent using visual,
conductometric/potentiometric methods, (ii) Study of reactions of the elements of
first transition series: a) Iron, b) Cobalt, c) Nickel, d) Copper, (iii) Preparation of
chromium (II) acetate, Cr(CH2COO)2, H2O (Use of inert atmosphere technique)
and measurement of its magnetic susceptibility; (iv) Preparation and Identification
of any suitable inorganic/organometallic compounds involving the use of
techniques available in the department; Qualitative Analysis: To perform
qualitative analysis of a given binary mixture (i) Separation by ether, sodium
hydroxide, sodium bicarbonate and dil. Hydrochloric acid, (ii) Test for elements
(Other than C,H,O), (iii) Functional group determination, (iv) Melting point,
derivative preparation TLC for checking the purity and effectiveness of
separation.
Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.
3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale
Preparations Part 1, Pearson India, 2010.
4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva
Books, 2012.
5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013.
6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative
Organic Analysis Part 3, Pearson India, 2010.
28
SYLLABUS
Mathematics
[Subsidiary Course]
MA1211 ALGEBRA [3 1 0 4]
Algebra: Algebraic structure, Definition of a group with examples and simple
properties. Subgroups.Cyclicgroups.Cosetdecomposition.Lagrange’s theorem and
its consequences.Fermat’s and Euler’s theorems.Homomorphism and
Isomorphism. Normal subgroups: Quotient groups. The fundamental theorem
of homomorphism.Permutationgroups.Even and odd permutations.The alternating
groups An.Cayley’stheorem.Introduction to rings, subrings, integral domains and
fields.
29
Text Book:
I. N. Heristein, Topics in Algebra, Wiley Eastern Ltd., New Delhi, 1975.
References:
H. S. Hall and S. R. Knight, Higher Algebra, Elibron.com, 1999.
General Linear Higher order differential equations: First order and first
degree differential equation. Linear homogeneous and non-homogeneous
equations with constant coefficients, inverse differential operators and method of
variation of parameters.Solution of Cauchy’s homogeneous linear equations,
solution of simple simultaneous linear differential equations.Linear equations and
equations reducible to linear form. First order higher degree equations solvable
for x, y, p. Clairaut's form and singular solutions. Orthogonal trajectories.Linear
differential equations with constant coefficients.Homogeneous linear ordinary
differential equations.Linear differential equations of second
order.Transformation of the equation by changing the dependent variable and the
independent variable.
Text Books:
1. Simmons, Differential Equations, Tata McGraw-Hill Education, 2006.
2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi,
2006.
3. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006.
References:
1. D.Murray, Introductory Course in Differential Equations for students in
classical and engineering colleges. Longmans, Green, 1898.
2. Boyce and Diprima, Elementary Differential Equations and Boundary Value
Problems, Wiley, 9th Edition, 2008.
30
Text Books:
1. Marsden, J., and Tromba, Vector Calculus., 5th Edition, W. H. Freeman,2003.
2. G.F. Simmons, Introduction to Topology and Modern Analysis, Krieger
Publishing Company, 2003.
3. Kreyszig, Advanced Engineering Mathematics, 8th Edition, Wiley India Pvt.
Ltd., 2010.
References:
1. S. L.Loney, Elements of Coordinate Geometry, Scholarly Publishing Office,
University of Michigan Library, 2005.
2. Shanti Narayan, Analytical Geometry, S. Chand, 2010.
3. R.Bell,Elementary Treatise on Coordinate Geometry of Three Dimensions,
Third Edition Mac Millan & Co, Ltd, 1963.
MA1412 DYNAMICS [3 1 0 4]
Kinematics: Radial, Transverse, tangential, normal velocities and accelerations,
simple harmonic motion; Repulsion from a fixed pint, Motion under inverse
square, Law, Hooke’s law, Horizontal and vertical elastic strings. Motion of a
projectile on an inclined plane. Work energy and impulse, conservation of li
near momentum, uniform circular motion, motion on a smooth curve in a vertical
plane, motion on the inside of a smooth vertical circle, Cycloidal motion, Motion
in the resisting medium: Resistance varies as velocity and acquire of velocity.
Central forces.Stability of nearly circular orbits.Motion under the inverse square
law.Kepler’slaws.Time of describing an arc and area of any orbit.Slightly
31
disturbed orbits.Tangential and normal accelerations.Motion of a particle on a
smooth curve.Principle of conservation of energy.
References:
1. A. S.Ramsey,Dynamics (Part I)., The English Language Book Society and
Cambridge University Press, 1962.
2. J.Kar, M.t Hydrostatics. , Globe Library, 2nd Edition, 1957.
3. W. H.Besant, A. S.Ramsey, A Treatise on Hydromechanics (Part I). , G. Bell
and Sons, Ltd, London, 1960.
MA1511 REAL ANALYSIS [3 1 0 4]
Real Numbers: Real numbers as a complete ordered field. Limit point, Bolzano
Weierstrass theorem, closed and open sets, union and intersection of such sets,
concept of compactness, Heine Borel theorem, connected sets. Real Sequences,
Limit and convergence of a sequence, monotonic sequences, Cauchy’s sequence,
subsequence, Cauchy’s general principle of convergence. Improper integrals
Convergence of improper integrals and their properties, convergence of Beta and
Gamma functions. Differentiation and integration of a function under the sign of
integral.Infinite Series: Definition regarding convergence, divergence of infinite
series. Tests: Comparison test, ratio test, Cauchy’s root test, Raabe’s test,
logarithmic test, integral test, Cauchy’s condensation test, Gauss’s test, with
proofs, alternating series, Leibnitz’s theorem, absolute and conditional
convergence. Taylor’s and Maclaurin’s expansion of functions.
Text Books:
1. Walter Rudin, Principles of Mathematical Analysis, McGraw-Hill, 1976
2 S.Shastri, Real Analysis, Springer, 2010
3. Shanti Narayan,Elements of Real Analysis, S. Chand Limited, 2003
References:
A. N.Kolmogorov, and S. V.Fomin, Elements of the Theory of Functions and
Functional Analysis, Vol 1, Dover,New York, 1961.
32
Raphson Method, Gauss elimination and Iterative method for solving linear
algebraic and transcendental equations. Solution of ordinary differential equations
of first order with initial and boundary conditions using Picard’s and modified
Euler’s method.
Probability Theory: Definitions, Sample space, events, algebra of events, joint &
conditional probability, dependent events.Bernoulli’s trials, Probability &Baye’s
theorem. Discrete & continuous distributions, Probability distribution &
probability densities: Binomial, Poisson, normal and uniform distribution &
density functions.Correlation& Regression Correlation & regression: Linear
regression, Rank correlation, Method of least squares Fitting of straight lines &
second degree parabola.
Text Books:
1. G. Haribhaskaran, Numerical Methods, Laxmi Publications, Delhi, 2008.
2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi,
2006.
Reference Books:
1. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006.
2. Srimanta Pal, Numerical Methods, Oxford university Press, Delhi 2012.
33
MA1612 DISCRETE MATHEMATICS STRATURE [3 1 0 4]
Propositional Calculus: Logical connectives, Truth tables, Tautologies and
contradictions, Contrapositive, Logical equivalences and implications, De
Morgan’s Laws, Normal forms, Rules of inference, Arguments, Validity of
arguments. Predicate Calculus: Free and bound variables, Quantifiers, Theory
of inference, The rules of universal specification and generalization, Validity of
arguments. Set Theory: Types of relations on sets and their properties, Relational
matrix and the graph of a relation, Partitions, Equivalence relations, Poset, Hasse
diagram. Definitions & Classification of functions, Characteristic function of a
set, Hashing functions, Recursive functions, Permutation functions.
Combinatorics: Discrete numeric function, Basic counting principles, Generating
functions, Recurrence relations, Inclusion and exclusion principle, Euler’s
function and its applications to Cryptography. Graph Theory:Graphs
:Definition and examples of graphs,Incidence and degree, Handshaking lemma,
Isomorphism Sub-graphs, Weighted Graphs, Eulerian Graphs, Hamiltonian
Graphs Walks, Paths and Circuits. Trees : Definition and properties of trees
Pendent vertices, centre of a tree Rooted and binary tree, spanning trees,
minimum spanning tree algorithms Fundamental circuits, cutsets and cut vertices,
fundamental cutsets, the four color theorem Directed Graphs :Types of
digraphs, directed paths and connectedness, Euler digraphs, Directed trees,
Text Books:
1. Trembly J.P and Manohar R, Discrete Mathematical Structures with
Applications to Computer Science, Tata McGraw–Hill Pub. Co. Ltd, New
Delhi, 2003.
2. Ralph. P. Grimaldi, Discrete and Combinatorial Mathematics: An Applied
Introduction, Fourth Edition, Pearson Education Asia, Delhi, 2002.
3. T. Veerarajan, Discrete Mathematics, Tata McGraw Hill, 2010.
References:
1. J. A.Bondy& U. S. R. Murty, Graph Theory with Applications, MacMillan,
1976.
2. G. R. E.Polya, Tarjan& D. R. Woods, Notes on Introductory Combinatorics,
BirkHauser, 1983.
3. M. N. S.Swamy, & K. Tulsiram, Graph, Networks and Algorithms, John
Willey, 1981.
4. Bernard Kolman, Robert C. Busby, Sharan Cutler Ross, Discrete Mathematical
Structures, Fourth Indian reprint, Pearson Education Pvt Ltd., New Delhi,
2003.
34
SYLLABUS
Physics
[Ancillary Course]
Oscillations
Potential well and periodic oscillations, harmonic oscillations, differential
equation and its solution, kinetic and potential energy, examples of simple
harmonic oscillations, spring and mass system, simple and compound pendulum,
torsional pendulum, LC circuit, oscillations of two masses connected by a spring.
Motion of two coupled oscillators, normal modes, N coupled oscillators, damped
harmonic oscillator, power dissipation, quality factor, driven harmonic oscillator,
transient and steady states, power absorption, resonance in systems with many
degrees of freedom.
Wave Optics
Interference: The principle of superposition. Two-silt interference, coherence
requirement for the sources, Localized fringes; thin films and applications,
Fringes of equal inclination, Newton’s Ring Experiment, Michelson
interferometer and its application for precision determination of wavelength,
wavelength difference and the width of spectral lines.
Lasers: Laser systems: Purity of a spectral line, coherence length and coherence
time, spatial coherence of a source, Einstein’s A and B coefficients, Spontaneous
and induced emissions, conditions for laser action, population inversion, spatial
coherence and directionality, He- Ne Laser, Pulsed lasers and tunable lasers,
Applications of Lasers
35
References:
1. Khandelwal D P, Oscillations and Waves,Himalaya Publishing House,
Bombay.
2. Ghosh R K; The Mathematics of Waves and Vibrations,,Macmillan, (1975)
3. Berkeley Physics Courses; Vol. III , Waves and Oscillations.
4. Jain H J; The Physics of Vibrations and Waves, Macmillan (1975)
5. Ghatak A K , Physical Optics, Mc-Graw Hill
6. Khandelwal D P, Optics and Atomic Physics, Himalaya Publishing House,
Bombay, (1988)
7. Smith F and Thomson J H, Manchester Physics series; Optics, English
Language Book Society and John Wiley, (1977)
8. Laud B B, Laser and Non-liner Optics, Wiley Eastern, (1985).
9. Smith and Thomson; Optics, John Wiley and Sons.
36