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B.Sc. Chemistry (Hons.) Curriculum

The document outlines the curriculum for a B.Sc. in Chemistry (Hons.) program from 2015-2018. It includes 6 objectives for the program which focus on teaching fundamental chemistry concepts, creating awareness of green chemistry and its impacts, and motivating students for research. Candidates must have passed 10+2 exams with 45% marks in Physics, Chemistry, Maths or Biology. The curriculum spans 5 semesters and includes courses in inorganic, organic, physical chemistry as well as labs, mathematics, physics, computer science, and open electives. Exams are assessed through theory, practical, continuous weightage, projects and term-end exams.

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Miguel Saavedra
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Download as DOCX, PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
988 views36 pages

B.Sc. Chemistry (Hons.) Curriculum

The document outlines the curriculum for a B.Sc. in Chemistry (Hons.) program from 2015-2018. It includes 6 objectives for the program which focus on teaching fundamental chemistry concepts, creating awareness of green chemistry and its impacts, and motivating students for research. Candidates must have passed 10+2 exams with 45% marks in Physics, Chemistry, Maths or Biology. The curriculum spans 5 semesters and includes courses in inorganic, organic, physical chemistry as well as labs, mathematics, physics, computer science, and open electives. Exams are assessed through theory, practical, continuous weightage, projects and term-end exams.

Uploaded by

Miguel Saavedra
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 36

B.Sc. CHEMISTRY (Hons.

) CURRICULUM
(2015 batch)

SCHEME AND SYLLABUS

DEPARTMENT OF CHEMISTRY
B.Sc. CHEMISTRY (Hons.) CURRICULUM

OBJECTIVES:

The course contents have been proposed as per suggestions of the faculty
members of department of Chemistry, Manipal University Jaipur. The syllabus
contents are duly arranged in such a manner so that the importance is given to
requisite intellectual and laboratory skills.
(i) To teach the fundamental concepts of Chemistry and their applications.
(ii) To make students aware of advantages of eco-friendly chemical processes and
impact of chemistry on health and environment.
(iii) To enthuse the students for the subject and make them capable of accepting
any challenges in chemistry.
(iv) To make students aware of advantages of eco-friendly chemical processes
and impact of chemistry on health and environment.
(v) To motivate students to do good research work in chemistry and opt for
research career.
(vi) To educate the students with respect to skills and knowledge to practice
chemistry and imbibe the concept of sustainable developments.

ELIGIBILITY OF THE CANDIDATES:

Candidates who have passed (10+2) examination of any recognized Board or its
equivalent examination with minimum of 45% marks with Physics, Chemistry,
Mathematics or Biology as core subjects.

2
Course Structure of the B.Sc. (Hons) Chemistry Programme
(2015-2018)
Major course: Chemistry; Subsidiary: Mathematics/Bio
Science/Bio technology; Ancillary: Physics

I Semester Exam Duration (Hrs) Relative


Weightage
(%)

Sr.No. Course Course Name L T P C


Code Theor Pract CW ET
PRS MTE PRE
y ical S E

1 CY1112 Inorganic Chemistry- 2 1 0 3 3 - 10 - 40 50


I

2 CY1113 Organic chemistry –I 2 1 0 3 3 - 10 - 40 50

3 CY1114 Physical Chemistry-1 2 1 0 3 3 - 10 - 40 50 -

4 CY1132 Chemistry (Hons.) 0 0 2 1 0 2 - 60 - - 40


Laboratory-1

5 MA 1111 Differential Calculus 3 1 0 4 4 - 10 - 40 50 -


and Integral Calculus

6 BS1156 Basic Biology 2 1 0 3 3 - 10 - 40 50 -

7 BS1141 Basic Biology Lab 0 0 2 1 - 2 - 60 - - 40

8 CS 1102 Fundamental of 2 0 0 2 - - 10 - 40 50 -
Computers
9 EN 1101 General English 2 1 0 3 3 0 10 - 40 50 -

10 CS1132 Fundamental of 0 0 2 1 - 2 - 60 - - 40
Computers
Laboratory
Total 15 6 6 24

3
II Semester Exam Duration (Hrs) Relative
Weightage
(%)

Sr.No Course Course Name L T P C


. Code
Th Pra
CW PR MT PR
eor ctic ETE
S S E E
y al

1. 1
CY1212 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II
2. 2CY1213 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II

3. 3CY1214 Physical 3 1 0 4 3 - 10 - 40 50 -
Chemistry-II

4. CY1231 Chemistry 0 0 2 1 2 - 60 - - 40
(Hons.)
Laboratory-II

5. MA 1211 Algebra 3 1 0 4 3 - 10 - 40 50 -

6. 6VE1201 Value 2 0 0 2 3 - 10 - 40 50 -
Education

7. 7CY1120 Environmental 2 1 0 3 3 - 10 - 40 50 -
Science

8. PY 1211 Oscillations 2 1 0 3 3 - 10 - 40 50 -
and wave
Optics

9. 8PY 1231 Optics Lab 0 0 2 1 - 3 - 60 - - 40

Total 18 6 4 26

4
III Semester Exam Duration (Hrs) Relative
Weightage
(%)

Sr. Course Course L T P C


No. Code Name T
he Practica CW PR MT ET PR
or l S S E E E
y

1 CY 1313 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-
III

2 CY 1315 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-
III
3 CY 1316 Physical 3 1 0 4 3 10 40 50
Chemistry

4 CY1331 Chemistry 0 0 4 2 - 2 - 60 - - 40
(Hons.)
laboratory-
III

5 CY 1332 Computer 0 0 4 2 2 - 60 - - 40
application
in
Chemistry

8 MA 1311 Differential 3 1 0 4 3 - 10 - 40 50 -
Equations

7 MA 1312 Solid 3 1 0 4 3 1 10 - 40 50 -
Geometry
and Vector
Calculus

Total 15 5 8 24

5
IV Semester Exam Duration (Hrs) Relative
Weightag
e (%)

Sr.No. Course Course Name L T P C


Code
Theo Practic CW PR MT ET PR
ry al S S E E E

1 CY 1413 Inorganic 3 1 0 4 3 - 10 - 40 50 -
Chemistry -IV

2 CY 1414 Organic 3 1 0 4 3 - 10 - 40 50 -
Chemistry-IV

3 CY 1415 Physical 3 1 0 4 3 - 10 - 40 50 -
Chemistry

4 CY 1431 Chemistry 0 0 4 2 0 2 - 60 - - 40
(Hons.)
Laboratory-IV

5 MA 1411 Linear 3 1 0 4 3 - 10 - 40 50 -
Programming
Problems and
its application

5 MA1412 Dynamics 3 1 0 4 3 - 10 - 40 50 -

6 ***** Open Elective 3 0 0 3 3 - 10 - 40 50 -

Total 18 5 4 25

6
V Semester Exam Duration (Hrs) Relative
Weightage
(%)

Sr.N Course Course L T P C


o. Code Name
Theor Practica CW PR MT ET PR
y l S S E E E

1 CY 1513 Chemistry 3 1 0 4 3 - 10 - 40 50 -
of
Biomolecul
es
2 CY 1514 Quantum 3 1 0 4 3 - 10 - 40 50 -
Chemistry
and its
Application
to Molecular
Spectroscop
y

3 CY 1515 Green 2 1 0 3 3 - 10 - 40 50 -
Chemistry

4 CY 1516 Nuclear and 2 1 0 3 3 - 10 - 40 50 -


Analytical
Chemistry

5 CY 1531 Chemistry 0 0 4 2 - 2 - 60 - 40
(Hons.)
Laboratory-
V

6 CY1570 Seminar 0 0 4 2 - - - 60 - - 40

5 MA 1511 Real 3 1 0 4 3 - 10 - 40 50 -
Analysis
6 MA 1512 Numerical 3 1 0 4 3 - 10 - 40 50 -
Analysis and
Probability
Theory

Total 16 6 8 26

7
VI Semester Exam Duration (Hrs) Relative
Weightage
(%)

Sr. Course Course Name L T P C


No. Code
Theor Practica CW PR MT ET PR
y l S S E E E

1 CY Organic 3 1 0 4 3 - 10 - 40 50 -
1613 Spectroscopy
2 CY 1614 Molecular 3 1 0 4 3 - 10 - 40 50 -
Statistics and
photo chemistry

3 CY 1615 Organometallic 2 1 0 3 3 - 10 - 40 50 -
Chemistry and
Industrial
Chemistry

4 CY 1631 Chemistry 0 0 6 3 2 60 - 40
(Hons.)Laborat
ory-VI

5 CY 1670 Project 0 0 6 3 - - - 60 - - 40

6 MA 1611 Complex 3 1 0 4 3 - 10 - 40 50 -
Analysis

7 MA 1612 Discrete 3 1 0 4 3 - 10 - 40 50 -
Mathematics
Structure

Total 14 5 12 25

L = Number of Lectures hrs/week T= Number of Tutorials hrs/week


P = Number of practical hours/week C= Number of Credits.
CWS: Class Work Sessionals PRS: Practical Sessionals
MTE: Mid-Term Exam ETE: End Term Exam
PRE: End Term Practical Exam

8
CY1112 Inorganic Chemistry-I [3 1 0 4]

Atomic Structure: Schrodinger’s wave equation, significance of Ψ and Ψ2, four


quantum numbers and their significance, radial and angular probability, shapes of
s, p, d and f orbitals, fundamental properties of atoms such as atomic volume, the
sizes of atoms, ionization energy, electron affinity and their periodic trends;
Electronegativity and Polarity of bond: Electronegativity, different scales and
methods of determination, dipole moments, percentage of ionic character form
dipole moment and electronegativity difference; Valence Bond theory and
Molecular Orbital Theory: Valence bond (VB) approach, molecular orbitals
(MO) approach of bonding (LCAO Method) bonding in homo-nuclear and hetero-
nuclear molecules; The Periodic Table and Chemical Periodicity: The
relationship between chemical periodicity and electronic structure of the atom, the
long form of the periodic table, classification of elements in s, p, d and f block of
elements, diagonal behaviour between elements; Acids-bases: various definitions
of acids and bases, a generalized acid-base concept, measurement of acid-base
strength, Lewis interactions, Pearson’s HSAB concept.

Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008.
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.

Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007.
2. C. Housecroft and A. G. Sharpe, Inorganic Chemistry, Pearson India,
2012.

CY1113 Organic Chemistry-I [3 1 0 4]


Structure and Bonding: Hybridization, bond lengths and bond angles, bond
energy, van der Waals interactions, resonance, hyperconjugation, aromaticity,
inductive and field effects, hydrogen bonding; Mechanism of Organic
Reactions: Curved arrow notation, drawing of electron movements with arrows,
half-headed and double-headed arrows, electrophiles and nucleophiles, reactive
intermediates: carbocations, carbanions, free radicals, carbenes, arynes and
nitrenes, isotope effects, kinetic and stereochemical studies; Stereochemistry of
Organic Compounds: Concept of isomerism, optical isomerism, molecular
chirality, enantiomers, stereogenic center, relative and absolute configuration,
Sequence rules, D & L and R & S systems of nomenclature, geometric isomers, E
& Z system of nomenclature, Newman projection and Sawhorse formulae, Fischer

9
and flying wedge formulae; Alkanes and Cycloalkanes: IUPAC nomenclature of
branched and unbranched alkanes, methods of synthesis of alkanes, physical
properties and chemical reactions of alkanes, nomenclature of cycloalkanes,
methods of synthesis of cycloalkanes; Baeyer’s strain theory and its limitations;
Alkenes, Cycloalkenes, Dienes and Alkynes: Nomenclature, synthesis and
reactions of alkenes, cycloalkenes, dienes and alkynes.

Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.

Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley India, 2012.

CY1114 Physical Chemistry-I [3 1 0 4]


Equation of State: Kinetic molecular theory of gases, derivation of kinetic gas
equation, imperfection in real gases, the compressibility of real gases, isotherms
of real gases, equations of state, van der Waal’s equation, liquification of gases,
critical phenomenon, P-V isotherms of carbon dioxide, principle of continuity of
state; .Properties of Liquids: The Kinetic molecular description, intermolecular
forces in liquids, density and methods for its measurements, vapour pressure and
its determination, surface tension and its determination, viscosity and
measurement of viscosity; The First Law of Thermodynamics: Thermodynamic
terms and basic concepts, intensive and extensive properties, state functions and
differentials, thermodynamic processes, reversibility, irreversibility, various
statements of first law, internal energy (U) and enthalphy (H);
Thermochemistry: The reaction enthalpy, standard enthalpies, Hess’s law and
reaction enthalpies, Kirchoff’s equation, relation between H and U for reactions,
calorimetric measurements, varieties of enthalpy changes.

Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.

10
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.

CY1132 Chemistry(Hons.)laboratory I [0 0 2 1]

Determination of some physical parameters: Calibration of thermometer,


determination of melting points and boiling points of some organic compounds;
Distillation: Simple distillation of ethanol-water mixture, distillation of
nitrobenzene and aniline; Crystallization: Crystallization of some organic and
inorganic compound.

Text Books:

1. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale


Preparations Part 1, Pearson India, 2010.
2. A. I. Vogel, Elementary Practical Organic Chemistry: Qualitative
Organic Analysis Part 2, Pearson India, 2010.
3. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative
Organic Analysis Part 3, Pearson India, 2010.
4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva
Books, 2012.

CY1212 Inorganic Chemistry-II [3 1 0 4]

Hydrogen: Position in the periodic table, isotopes, industrial production,


properties, reactions and isotopes; The s-block elements: Production and uses of
alkali and alkaline earth metals, chemical reactivity, structure and properties of
oxides, halides and hydroxides, coordination complexes; The p-block elements -
I: Chemical reactivity of B, Al, Ga, In and Tl, compounds of boron and
aluminum, chemical reactivity and group trends of C, Si, Ge, Sn and Pb,
allotropes of carbon, compounds of Si, Ge, Sn and Pb; Ionic bond: Factors
affecting the stability of ionic compounds, lattice energy, Born Lande equation
and its applications, Madelung constant, Born-Haber cycle, Fazan’s rules, ionic
radii, factors affecting the radii of ions, Structure of crystal lattices, predictive
power of thermochemical calculations on ionic compounds; Intermolecular
forces and metallic bond: Van der Waals forces (Keesom, Debye & London
Interactions). Structure of metals, valence bond and band model; Perfect and

11
imperfect crystals: Intrinsic and extrinsic defects, point defects, line and plane
defects, vacancies-Schottky and Frenkel defects. Thermodynamics of Schottky
and Frenkel defect, band theory, band structure of metals, nnsulators and
semiconductors, intrinsic and extrinsic semiconductors, doping semiconductors,
p-n junctions, High temperature super conductors.

Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008.
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.

Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India,
2012.

CY1213 Organic Chemistry-II [3 1 0 4]

Arenes and Aromaticity: Nomenclature of benzene and derivatives, Kekule


structure, carbon-carbon bond lengths of benzene, resonance structure, MO
picture, Aromatic electrophilic substitution, activating and deactivating
substituents, orientation and ortho/para ratio; Alkyl and Aryl
Halides:Nomenclature and classes of alkyl halides, methods of formation,
chemical reactions and mechanisms; Alcohols: Classification and nomenclature
of monohydric, dihydric and trihydric alcohols, methods of formation and
reactions of alcohols; Phenols: Nomenclature, structure and bonding of phenols,
synthesis and reactions of phenols, physical properties and acidic character;
Ethers and Epoxides: Nomenclature of ethers and methods of their preparation,
physical properties, chemical reactions, cleavage and autoxidation, synthesis of
epoxides, acid and base catalyzed ring opening of epoxides.

Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.

12
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.

Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley India, 2012.

CY1214 Physical Chemistry-II [3 1 0 4]


Partial Molar Properties and Fugacity: Partial molar properties, chemical
potential of a perfect gas, dependence of chemical potential on temperature and
pressure, Gibbs-Duhem equation, real gases, fugacity, Clausius Clapeyron
equation and its application to solid-liquid, liquid-vapour and solid-vapour
equilibria; Thermodynamics of Simple Mixtures: Thermodynamic functions for
mixing of perfect gases, chemical potential of liquids. Raoult’s law, Henry’s law;
Physical Transformation of Pure Materials: First and second order phase
transitions, attainment of low temperature and energetics of refrigeration,
adiabatic demagnetization; Phase Equilibria: Phase rule and its thermodynamic
derivation, one component systems, two component systems, eutectics, freezing
mixtures, ultra purity, zone refining; Chemical Equilibrium: Direction of
spontaneous change in a chemical reaction, extent of reaction, stoichiometric
coefficients, equilibrium constant in terms of G. temperature and pressure
dependence of equilibrium constant, homogeneous and heterogeneous equilibria;
Thermodynamics of Electrolytic Solutions: Activities of ions in solutions,
model of ions in a solution, qualitative idea of Debye-Huckel theory, ionic
strength, mean ionic activity coefficient and the Debye-Huckel limiting law for
activity coefficients; Colligative Properties: Solutions of non-volatile solutes,
colligative properties, elevation in boiling point, depression in freezing point,
osmosis and osmotic pressure; Electrochemical Cells: Interfacial potential
difference, the electrodes, potential at interfaces, electrode potentials, galvanic
cells, emf, direction of spontaneous reactions, measurements of solubility product,
potentiometric titrations, pK and pH measurements.

Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.

13
CY1231 Chemistry (Hons.) Laboratory-II [0 0 2 1]
Inorganic qualitative Analysis: Qualitative analysis of inorganic mixtures
containing not more than six radicals including interfering radicals like phosphate,
oxalate, tartrate; Inorganic quantitative Analysis: various volumetric analyses.

Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012.
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.

CY1313 Inorganic Chemistry-III [3104]

The p-Block Elements-II: Chemical reactivity and group trends of N, P, As, Sb


& Bi, compounds of of N, P, As, Sb & Bi, some organometallic compounds;
Oxygen, S, Se and Te Family: Chemical Reactivity, group trends and
stereochemistry, dioxygen as a ligand , structure of O3 and H2O2, clathrate
hydrates allotropic forms of S & Se, structures of halides, oxides and oxyacids of
S, Se & Te, liquid SO2 and polyatomic cations of S, Se & Te; The Halogen
Family:
Chemical reactivity, group trends, chemistry of preparation of fluorine, hydrogen
halides, HF as a solvent, inter-halogen compounds, polyhalide and polyhalonium
ions, polyatomic cations of halogens, oxides and oxyacide of halogens; Noble
gases: Chemical reactivity and group trends, Clathrate compounds; preparation,
structure and bonding of noble gas compounds; Symmetry and group theory
(Part I): Symmetry elements and symmetry operations, point groups, definitions
of group, subgroup relation between orders of a finite group and its subgroup,
group multiplication tables, conjugacy relation and classes; Schoenflies symbols,
representation of groups, character of a representation; Symmetry and group
theory (Part II): Properties of irreducible representations, the great orthogonality
theorem and its importance. Character Tables, Symmetry criteria for optical
activity, symmetry restrictions on dipole moment, and hybridization schemes of
orbitals.

Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.

14
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012.
3. F. A. Cotton, Chemical Applications of Group Theory, Wiley India, 2010.

CY1315 Organic Chemistry-III [3 1 0 4]

Stereochemical principles, conformation, steric and stereoelectronic effects:


Enantiomeric relationships, diastereomeric relationships, dynamic
stereochemistry, prochiral relationships, conformations of acyclic molecules,
cyclohexane derivatives, rings other than six membered, conformational effects
on reactivity; Free radical reactions: Generation and characterization of free
radicals, characteristics of reaction mechanisms involving electron transfer
reactions; Carbanions and other nucleophilic carbon species and their
reactions: Acidity of hydrocarbons, carbanions stability by functional groups,
Generation of carbon nucleophiles by deprotonations, reactions involving
carbanions; Aldehydes and Ketones: Nomenclature and structure of the carbonyl
group; Synthesis of aldehydes and ketones, physical properties, of aldehydes and
ketones reactions of aldehydes and ketones with mechanism, introduction to ∞, β
-unsaturated aldehydes and ketones; Carboxylic Acids: Nomenclature, structure
and bonding, physical properties, acidity of carboxylic acids, effects of
substituents on acid strength. Preparation of carboxylic acids. Reactions of
carboxylic acids; Carboxylic Acid Derivatives: Structure and nomenclature of
acid chlorides, esters, amides (urea) and acid anhydrides, relative stability of acyl
derivatives.

Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.

Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
And Synthesis (Part B), Springer India Private Limited, 2007.

15
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.

CY 1316 Physical Chemistry-III [3 1 0 4]


Kinetic theory of gases and transport properties: Kinetic molecular theory of
gases, kinetic energy and temperature, distribution of molecular speeds in an ideal
gas, distribution in one dimension, distribution of speeds in three dimensions,
derivation of Maxwell-Boltzmann distribution law, thermal conductivity, kinetic
theory of thermal conductivity in gases; Thermodynamics of diffusion:
Thermodynamic view of diffusion, relation between transport properties, Einstein
relation, Nernst-Einstein relation, Stoke’s Einstein relation; Equilibrium
Electrochemistry: Transport of ions in solution, conductivity, Kohlrausch’s law,
Ostwald dilution law, mobilities of ions, transport number and its measurement,
arrhenius theory of Conductivity, Debye-Huckel-Onsager theory of conductivity;
Dynamic Electrochemistry: Processes at electrodes, double layer at the
interface, non-equilibrium electrode potentials, over potential, derivation of
Butler-Volmer equation, Tafel plot, applications of dynamic electrochemistry;
Chemical Kinetics: Rate of reaction, rate constant and rate laws, the order of
reaction, first, second and third and zero order reactions, half-lives; determination
of reaction order, temperature dependence of reaction rates, reaction mechanism,
rate-determining step approximation, steady-state approximation,
explosive/branched chain reactions, catalysis, homogeneous catalysis,
autocatalysis, oscillation reactions, bistability, enzyme catalysis, heterogeneous
catalysis.

Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.

CY1331 Chemistry (Hons.) Laboratory-III [0 0 2 1]


Treatment of Experimental Data: Accuracy, precision and error analysis;
Liquids and Solutions: Determination of viscosity of different solvents and
solutions; Thermochemistry: Determination of heat of reaction of various
processes; Distribution Law: Determination of partition coefficient of a solute in

16
water and a non aqueous solvent; Surface Phenomena: Adsorption of some
organic acids on charcoal; Colorimetery: Verification of Lambert-Beer law;
Thin Layer and Column Chromatography: Determination of Rf value and
purity of organic compounds by use of thin layer chromatography, separation of
organic compound by column chromatography; Qualitative organic analysis:

Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.
3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale
Preparations Part 1, Pearson India, 2010.
4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva
Books, 2012.
5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013.
6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative
Organic Analysis Part 3, Pearson India, 2010.

CY1332 Computer Application in Chemistry [3 1 0 4]

Computer programming: Constants, variables, bits, bytes, binary and ASCII


formats, arithmetic expressions, hierarchy of operations, inbuilt functions,
elements of the BASIC language, BASIC keywords and commands, logical and
relative operators, strings and graphics, Compiled versus interpreted languages.
Debugging. Simple programs using these concepts. conceptual background of
molecular modelling, potential energy surfaces, elementary ideas of molecular
mechanics and practical MO methods; Use of computational tools to plot and
analyze data.

Text Book:
1. T. Engel and P. Reid, Physical Chemistry, Chapter on Computational
Chemistry. Pearson India, 2013.
Reference Books:
1. S. M. Venit, Programming in Basic: Problem solving with structure and
style. Jaico Publishing House, 1996.
2. J. H. Noggle, Physical chemistry on a Microcomputer, Little Brown & Co.
1985.

17
CY1413 Inorganic Chemistry-IV [3 1 0 4]
Chemistry of 2nd and 3rd row d-block elements: Comparison of the chemistry
of elements of second and third row series with that of elements of the first
transition series. Mo-Mo and Re-Re quadrupole bonds. Chemistry of complexes
of Rh(III), Pt(II) and Pd(II); Chemistry of f-block elements: Chemistry of
Lanthanide elements, their isolation from one another, their coordination
chemistry; Coordination Compounds: Various definitions, types of ligands, The
Chelate and Macrocylic effects, Multidentate ligands, isomerism in coordination
compounds, nomenclature, stability of coordination compounds, stability
constants and chelate effect; Theories for bonding in complexes: Valence bond
theory for bonding in coordination compounds. Concept of multiple bonding and
back bonding; Crystal field theory: The splitting of d-orbitals in different fields,
Consequences, factors affecting and applications of orbital splitting, crystal field
stabilization energy (CFSE), magnetic properties, spectrochemical series and
colour of transition metal complexes. Jahn-Teller effect in octahedral and
tetrahedral complexes. Evidence of covalence and adjusted crystal field theory.
Molecular orbital treatment of octahedral, tetrahedral and square planar
complexes.

Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry:
Principles of Structure and Reactivity, Pearson India, 2008
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press,
2011.
4. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Elsevier,
2010.

Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson, 2012.

CY1414 Organic Chemistry-IV [3 1 0 4]


Organic Compounds of Nitrogen: Preparation, Chemical reactions and
Mechanisms of nucleophilic substitution of nitroalkanes and nitroarenes in
difffrent media, Picric acid, Halonitroarenes, Stereochemistry of amines,
Separation of a mixture of primary, secondary and tertiary amines, Gabricl-
phthalimide reaction, Hoffmann bromamide reaction; Organosulphur
Compounds: Nomenclature, structural features, methods of formation and
chemical reactions of thiols, thioethers, sulphonic acids, sulphonamides and
sulphaguanidine; Heterocyclic Compounds: Introduction (pyrrole, furan,

18
thiophene and pyridine), Mechanism of electrophilic and nucleophilic substitution
reactions, Comparison of basicity, five and six-membered heterocycles.
Preparation and reactions of indole, quinoline and isoquinoline with special
reference to Fischer indole synthesis, Skraup synthesis and Bischler-Napieralski
synthesis. Mechanism of electrophilic substitution reactions of indole, quinoline
and isoquinoline; Fats, Oils and Detergents: Natural fats, edible and industrial
oils of vegetable origin, common fatty acids, glycerides, hydrogenation of
unsaturated oils. Saponification value, iodine value, acid value. Soaps, synthetic
detergents; Synthetic Dyes: Colour and constitution (electronic concept),
Classification of dyes. Chemistry and synthesis of Methyl orange, Congo red,
Malachite green, Crystal violet, Phenolphthalein, Fluorescein, Alizarin and
Indigo.

Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry,
Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India,
2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson
India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.

Reference Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Structure
and Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
and Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.

CY1415 Physical Chemistry- IV [3 1 0 4]


Surface Chemistry: Bulk phases and interfacial region, types of interfaces;
Surface tension and interfacial tension, Surface tension of solutions, Gibbs
adsorption equation and its thermodynamic derivation, Surfactants, Surface films
on liquids; X-ray diffraction: Definition of space lattice, unit cell. Miller indices,
Symmetry elements in crystals. X-ray diffraction by crystals. Bragg equation.
Dimension and contents of unit cell; Adsorption: Adsorption of gases on solids,
chemisorption and physi-sorption, desorptoin. Adsorption isotherms; Colloids:
The colloidal state, preparation of colloidal dispersions, dialysis, ultrafiltration,
physical & optical properties, ultra-microscope, Electro kinetic phenomena. Zeta
potential. Precipitation of sols by electrolytes, Hardy Schulz rules, other methods
of precipitation. Emulsions, Association colloids/colloidal surfactants/micelle
systems; Macromolecules: Introduction, nomenclature and classifications of

19
macromolecules, Addition and condensation polymerization, Molecular weight
heterogeneity, number average and weight average molecular weights,
Determination of molecular weights.

Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley
India, 2006.

CY1431 Chemistry (Hons.) Laboratory-IV [0 0 2 2]


Physical Chemistry:
Treatment of experimental data: Recording of experimental data. Significant
number, accuracy and precision, error analysis; Liquids and Solutions: (i) To
determine surface tensions of solutions of amyl alcohol in water at different
concentrations and to calculate surface excess, (ii) To determine refractive index
and molar refractivity of some organic liquids; Thermichemistry: (i) To
determine heat of neutralization of a strong acid by a strong base. (ii) To
determine heat of ionization of a weak acid from heat of neutralization;
Distribution Law: (i) To determine the equilibrium constant of the reaction
I2+KI =KI3 by the partition method and the corresponding free energy change, (ii)
To determine distribution coefficient between water and a non-aqueous solvent of
a solute which associates or dissociates in one of the solvents; Colorimetery: (i)
To determine the composition of a complex by Job’s method of continuous
variations (Ferric-salicylate Complex), (ii) To titrate copper with EDTA
photometrically.

Inorganic Chemistry: (i) Gravemetric Methods, Estimation of Ba2+ as BaSO4


and Ni2+ as Nickel dimethylglyoxime Complex and Co2+ gravimetrically.
Determination of two metal ions, Cu-Ni and Cu-Fe. (ii) Preparation of anhydrous
stannous chloride, (iii) Complexometric titrations involving EDTA for
quantitative determination of individual
cation/mixture of cations, (iii) Chromatography: Separation of cations and anions
by Paper Chromatography

Text Books:
1. B.P. Levitt, Findlays Practical Physical Chemistry, Longman Group Ltd.
2003.

20
2. B.D. Khosla, V.C. Garg and A. Gulati, Senior Practical Physical
Chemistry, R. Chand & Co. 2005.
3. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012.
4. R.C. Das and R.C. Behera, Experimental Physical Chemistry, Tata
McGraw Hill Publishing Co. Ltd. 2001.

CY1513 Chemistry of Biomolecules [3 1 0 4]


Carbohydrates: Classification and nomenclature, Monosaccharides, mechanism
of ozone formation, interconversion of glucose and fructose, Configuration of
monosaccharides, Conversion of glucose into mannose. Formation of glycosides,
ethers and esters, Cyclic structure of D(+)-glucose, mutarotation, Structures of
ribose and deoxyribose. An introduction to disaccharides and polysaccharides;
Amino Acids, Peptides, Proteins Nucleic Acids, Lipids, Terpines and
Terpeniods: Classification, structure and stereochemistry of amino acids. Acid-
base behavior, isoelectric point and electrophoresis. Preparation and reactions of
α-amino acids. Structure and nomenclature of peptides and proteins.
Classification of proteins, Classical peptide synthesis, solidphase peptide
synthesis, Structures of peptides and proteins. Protein denaturation, Nucleic acids.

Text Books:
1. D.L. Nelson, M.M. Cox, Lehninger’s Principles of Biochemistry, W. H.
Freeman, 2011.
2. J.M. Berg, J.L. Tymoczko, and L. Stryer, Biochemistry, W. H. Freeman,
2009.

CY1514 Quantum Chemistry and its Application to [3 1 0 4]


Molecular Spectroscopy

Elementary Quantum Chemistry: Historical background, classical ideas of


energy and particle trajectory. Blackbody radiation and Planck’s hypothesis of
quantization of energy, photoelectric effect, De Broglie’s relation Heisenberg’s
uncertainty principle, Schrödinger-wave equation, concept of wave function (ψ)
physical significance of ψ and ψ2, normalization, Free particle, particle in a one
dimensional box, translational energy, energy levels, quantization of energy, wave
functions for particle in a box, in a three dimensional box, Operators, Postulates
of quantum mechanics, time dependent Schrödinger equation, expectation values,
and applications of particle in a box model, Vibrational motion, classical one-
dimensional harmonic oscillator. Quantum mechanical harmonic oscillator,
rotational motion, spherical harmonics, applications to diatomic molecule (rigid
rotator). Schrödinger equation for hydrogen-like atoms, elementary discussion of

21
its solution, wave functions for hydrogen atom, electron spin, concept of spin
orbitals, spectral selection rules for one-electron atoms, spectrum of hydrogen
atom; Molecular spectroscopy: Electromagnetic radiation, absorption co-
efficient, Einstein coefficient, transition moment and oscillator strength and
Lasers. Microwave absorption, rotational Spectra, rotational Raman Spectra,
infrared absorption, Vibrational spectra of diatomic molecules; UV-Visible and
Nuclear Spectroscopy: Visible-Ultraviolet Absorption, Electronic spectra:
Electronic energy levels of molecules, selection rules for electronic spectra of
molecules, Frank-Condon principle, Beer-Lambert Law, electronic spectra of
polyatomic molecules, Photoelectron spectroscopy.

Text Books:
1. I.N. Levine, Quantum Chemistry, Oxford University Press , 2000.
2. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University
Press, 2011.
3. I.N. Levine, Physical Chemistry, McGraw Hill Education (India) Private
Limited, 2011.
4. D.C. McQuarre, Physical Chemistry, University Science Books, 2005.
5. A.K. Chandra, Introductory Quantum Chemistry, McGrew Hill Education
(Indial) Pvt. Ltd. 2009.
6. C.N. Banwell and E. M. McCash, Fundamentals of Molecular
Spectroscopy, , McGrew Hill Education (Indial) Pvt. Ltd. 2013.

CY1515 Green Chemistry [2 1 0 3]


Principles of Green chemistry-I: (i) Prevention of waste/byproducts. (ii)
Maximum incorporation of materials used in process in to the final product (Atom
economy): Green metrics (iii) Prevention/Minimization of hazardous/toxic
products (iv) Designing safer chemicals-different basic approaches (v) selection
of appropriate auxiliary substances (solvents, separation agents etc). (vi) Energy
requirements for reactions-use of microwave, ultrasonic energy; Principles of
Green chemistry-II: (vii) Selection of stating materials-use of renewable
starting materials. (vii) Avoidance of unnecessary derivation-careful use of
blocking/protection groups (ix) use of catalytic reagents (wherever
possible) in preference to stoichiometric reagents (x) Designing
biodegradable products (xi) prevention of chemical accidents. (xii)
Strengthening/development of analytical techniques to prevent and
minimize the generation of hazardous substances in chemical processes.
Development of accurate and reliable sensor and monitors for real time in
process monitoring. Example of Green synthesis/reaction, The chemistry
behind Green Chemistry, Future trend in green chemistry, biomimetic,
multifunctional reagents, combinatorial green chemistry, biomass
conversion, emission control, biocatalysts.

22
Text Books:
1. F. A. Carey and R. J. Sundberg, Advanced Organic Chemistry: Reaction
and Synthesis (Part B), Springer India Private Limited, 2007.
2. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions,
Mechanisms and Structure, Wiley, 2012.
3. V.K. Ahluwalia, Green Chemistry: Greener Alternatives to Synthetic
Organic Transformations, Narosa Publishing House, 2011.

CY1516 Nuclear & Analytical Chemistry [2 1 0 3]

Nuclear Chemistry: Introduction to Atomic Nucleus, Radioactive Decay; α, β


and γ, Nuclear Stability, Liquid drop Model and Shell model, Nuclear Reactions,
Nuclear Fission and Fusion; Elementary Concepts of Analytical Chemistry:
Qualitative and quantitative analysis, concepts important to quantitative analysis
classification of methods for quantitative analysis, choice of method for analysis,
sampling and theories of sampling, Preparation of samples for analysis,
calibration standards, solution concentration in terms of various conventions,
simple equilibrium calculations; Volumetric and Gravimetric Methods of
Analysis: Theory of volumetric and gravimetric methods of analysis, equivalent
points, standard solutions, Primary and Secondary standards, end point detection,
optimum conditions for precipitation, washing and filtration of precipitates,
Determination of inorganic salts in mixtures, Introduction to DSC, TGA, DTA;
Acid-Base Equilibria: Preparation of standard solutions of acids and bases,
mono and poly functional acids and bases and their pH titration curves, typical
applications of neutralization titrations in elemental analysis; Precipitation
Equilibria: Solubility of precipitates, effect of competing equilibria on solubility
of precipitates, separation of ions by control of concentration of precipitating
reagents, effect of electrolyte concentration on solubility, solubility product;
Complexation Equlibria: Complexation, Formation constants, EDTA equilibria,
Use of indicators, Applications of complexometric equilibria; Principles of
automation: Instrumental parameters for automation; Atomic X-ray
spectrometry: Fundamentals. Brief description of instrumentation. X-ray
fluorescence methods and applications. Quantitative X-ray florescence analysis.
Coating and film thickness measurements. Electron probe microanalysis. X-ray
absorption spectrometry; Solvent Extraction and Ion-Exchange Separation:
Basic principles of solvent extraction, solvent extraction of metals, extraction
process, separation efficiency of metal chelates, ion-exchange processes, ion-
exchange resins, techniques and applications of ion-exchange separation; Atomic
Spectrometric Methods: Emission spectroscopy, Flame emission spectrometry
Plasma emission spectrometry, Distribution between ground and excited states,
Atomic absorption spectrophotometry.

Text Books:
1. H. J. Arnikar, Essentials of Nuclear Chemistry, Wiley-Blackwell, 1987.

23
2. G. Friedlander, J.W. Kennedy, E.S. Macias and J.M. Miller, Nuclear and
Radiochemistry, Wiley India, 1981.
3. G.D. Christian, Analytical Chemistry, John Wiley 2004.
4. D.A. Skoog, D.M. West, F.J. Holler, S.R. Crouch, Fundamentals of
Analytical chemistry, Brooks/Cole, 2004.
5. D.A. Skoog., Principles of Instrumental Analysis, Holt-Saunders
International edition 2004.

CY1531 Chemistry (Hons.) Laboratory-V [0 0 2 2]

Physical chemistry practical


Conductometry: (i) To study the effect of concentration of electrolyte on specific
and molar conductance of a strong and weak electrolyte, (ii) Determination of
degree of dissociation and dissociation constant of weak acid, (iii)
Conductometeric titration of a strong acid, a weak acid, mixture of a strong and
weak acid and a dibasic acid with alkali, (iv) To compare the relative strengths of
weak acids like acetic acid and monochloroacetic acid by conductivity
measurements; Potentiometry: (i) Potentiometric titration of monobasic acids
(HCl & CH3COOH) with NaOH, (ii) Determination of mean ionic activity co-
efficient of hydrochloric acid at different concentrations, (iii) To study the effect
of ionic strength on mean ionic activity coefficient of hydrochloric acid in a given
solution and verify Debye-Huckel limiting law; Polarimetry: (i) To determine
the specific and molecular rotations of an optically active substance, (ii) To
determine the composition of an unknown solution with a polarimeter, (iii)
Chemical Kinetics: (i) To study the kinetics of hydrolysis of methyl acetate in
the presence of hydrochloric acid, (ii) To study the effect of ionic strength
(primary salt effect) on the kinetics of a reduction of toluidine blue with sodium
sulfite; (iii) Determination of Molecular Masses by Cryoscopy: (i) To
determine the molecular weight of a non-volatile substances by a cryoscopic
method; (ii) pH-metry: (i) To titrate a strong acid against a strong base pH-
metrically, (ii) To titrate a weak acid against a strong base and determine the
ionization constant of the weak acid.

Inorganic Chemistry Practicals


(i) Preparation and characterization of K3[Cr(C2O4)3] 3H2O and NH4[Cr(NH2)2
(NCS)4]. H2O and their charactersation by conductivity, (ii) Strong acid-strong
base titration in a non-acqueous solvent using visual,
conductometric/potentiometric methods, (iii) Study of reactions of the elements of
first transition series: (a) Titanium, (b) Vanadium, (c) Chromium, (d) Manganese,
(iv) Synthesis and characterization of any suitable inorganic/organometallic
compounds involving the use of techniques available in the department, (v) Ion
exchange separation of oxidation states of vanadium.

24
Organic Chemistry Practicals
Multistep preparations and estimations: (i) Preparation of p-bromoaniline from
acetanilide (protection, aromatic electrophilic substitution and deprotection), (ii)
Preparation of anthranilic acid from phthalic anhydride (nucleophilic addition of
Hoffman degradation), (iii) Preparation of o-chlorobenzoic acid from anthranilic
acid (diazotization and Sandmeyer reaction), (iv) Preparation of benzopinacol
from benzophenone (photoreduction), (v) Preparation of benzopinacolone from
benzopinacol (pinacol – pinacolone rearrangement), (vi) Preparation of triphenyl
methane from benzopinacolone (nucleophilic cleavage of C-C bond), (vii)
Preparation of triphenylmethyl bromide from triphenyl methane (free radical
bromination by use of NBS), (viii) Preparation of 1,5-Diphenyl-1,4-pentadiene-3-
one from benzaldehyde and acetone (cross aldol condensation), (ix) Preparation
of E/Z-a-phenylcinnamic acid from benzaldehyde and phenylacetic acid (Perkin
reaction), (x) Preparation of 1,3,5-tribromobenzene from aniline (diazotization,
aromatic electrophilic substitution and deamination), (xi) Preparation of 2,5-
dihydroxy acetophenone from hydroquinone (Fries reaction), (xii) Preparation of
3,5-diethoxycarbonyl-2,4-dimethylpyrrole from ethylacetoacetate (Knorr
synthesis), (xiii) To estimate the strength of given glucose solution (Fehling
method), (xiv) To estimate acid value, iodine value and soaponification value of a
given oil, (xv) To estimate percentage of sulphur in given organic compound by
Messenger’s method.

Text Books:
1. D. J. Woollins, Inorganic Experiments, Wiley-VCH, 2003
2. J. Bassett, R.C Denney, G.H Jeffery, J. Mendham, Vogel’s Textbook of
Quantitative Inorganic Analysis (revised), Orient Longman,2003.
3. R. J. Angelici, Synthesis and techniques in inorganic chemistry, SGS series
London, 1999.
4. G. Pass, Practical Inorganic Chemistry, Chapman & Hall London, 1968
5. M. A. Malati, Experimental Inorganic/Physical Chemistry, Horwood
Publishing, Chichester, 1999

CY1613 Organic Spectroscopy [3 1 0 4]


Electromagnetic Spectrum & Absorption Spectroscopy: Ultraviolet (UV)
absorption spectroscopy–absorption laws (Beer-Lambert law), chromophore and
auxochrome, bathochromic, hypsochromic, hyperchromic and hypochromic
shifts, UV spectra of conjugated enes and enones. Infrared (IR) absorption
spectroscopy – molecular vibrations, Hooke’s law, selection rules, intensity and
position of IR bands, measurement of IR spectrum, fingerprint region,
characteristic absorptions of various functional groups and interpretation of IR
spectra of simple organic compounds; NMR Spectroscopy: Nuclear magnetic
resonance (NMR) spectroscopy. Proton magnetic resonance, 1 H (1H NMR)
spectroscopy, nuclear shielding and deshielding, chemical shift and molecular
structure, spin-spin splitting and coupling constants, areas of signals,

25
interpretation of 1H NMR spectra of simple organic molecules such as ethyl
bromide, ethanol, acetaldehyde, 1,1,2-tribromoethane, ethyl acetate, toluene and
acetophenone basics of 13C NMR; Mass Spectroscopy: Introduction,
instrumentation, Methods of ionization, separation. Fragmentation, McLafferty
rearrangement, Problems pertaining to the structure elucidation of simple organic
compounds using UV, IR and 1H NMR spectroscopic techniques.

Text Books:
1. W. Kemp, Organic Spectroscopy, Palgrave Macmillan, 1991.
2. R.M. Silverstein, F.X. Webster, D. Kiemle, Spectrometric Identification of
Organic Compounds, John Wiley & Sons, 2005.
3. D.L. Pavia, G.M. Lampman, G.S. Kriz, J.A. Vyvyan, Introduction to
Spectroscopy, Cengage Learning, 2008.

CY1614 Molecular statistics and Photochemistry [3 1 0 4]


Statistical Thermodynamics: Types of statistics, Molecular energy levels and
the Boltzmann distribution, Maxwell distribution, configurations and weights,
most probable configuration, the molecular partition function, physical
interpretation of the partition function. The canonical ensemble, canonical
partition function and its relation to molecular partition function for independent
particles, the statistical entropy, entropy and partition function, entropy of a
monoatomic gas, Factorization of partition function, calculation of translational,
rotational vibrational and electronic contributions, the overall partition function;
Photochemistry: General principles about light absorption, electronic transition,
Jablonski diagram, intersystem crossing, singlet and triplet states, Fluorescence,
Phosphorescence, Quantum yield, Brief introduction and description of
photochemical reactions of simple carbonyl compounds, alkenes and aromatic
compounds, Barton Reaction, Norrish type I reactions and Norrish type II
reactions, Hofmann-Loffler-Freytag reaction.

Text Books:
1. T. Engel and P. Reid, Thermodynamics, Statistical Thermodynamics, &
Kinetics, Pearson India, 2007.
2. B.R. Puri, L.R. Sharma and M.S. Pathania, Principles of Physical
Chemistry, Vishal Publishing Co., 2013.

CY1617 Organometallic Compounds and Industrial [3 1 0 4]


Chemistry

Organometallics: Definition and classification of organometallic compounds, EAN


rule. Organometallic compounds of Mg and Li–Use in synthesis of organic

26
compounds, preparation of Grignard reagent and organo lithium compound,
importance of organometallic chemistry in modern times, definition and
terminologies, preparation of metal carbonyls, binary carbonyls, mixed metal
polynuclear carbonyls, metal-olefin complexes: Zeises salt, Ferrocene, Hapticity
(η) of organometallic ligands, Simple examples of fluxional molecules,
Coordinative unsaturation, and homogeneous catalysis by organometallic
compounds, and polymerization of alkenes (Ziegler-Natta catalysis); Bonding
and Structure: Molecular hydrogen compounds, metal-hydrogen interactions
with C-H groups, carbonyl halides, Metal nitrosyl compounds, nitrosyl carbonyls.
Dinitrogen and dioxygen complexes, tertiary phosphines as ligand;
Organotransition metal Chemistry: Synthesis, structure and bonding aspects of
complexes of two, three, four and six electrons cyclic and acyclic ligands. Alkyl
and aryls of Transition metals, transition metal-carbon multiple bonds; alkylidene
complexes and alkylidyne complexes. Water and its treatment: Sources of
water, impurities in water, hardness of water and hardeness removal; Coal
Chemicals: Ultimate and proximate analysis of coal and their significance,
coking of coal by high temperature (By-product coke-oven) and low temperature
process. Plastics and Rubber:Classification of plastics, manufacture, properties
and uses of nylon 6 and nylon 6 6. manufacture of natural rubber from latex,
introduction about synthetic rubbers; Sugar Industry: Extraction of juice from
sugar cane. Manufacture and refining of sugar. Uses of molasses and
bagasse.Cellulose Industry:Study of raw materials for the manufacture of paper.
Manufacture of wood pulp by different (soda, sulphite and sulphate) processes.
Multistage bleaching of wood pulp. Conversion of pulp into thin paper by
Fourdrinier machine.Petroleum Industry: Composition and classification of
crude petroleum. Refining of petroleum and brief introduction regarding each
refining product. Thermal and catalytic cracking of petroleum products.
Significance of octane number and cetane number. Paints Industry: Introduction,
classification of paints, manufacture of paints, requirements of a good paint.

Text Books
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced
Inorganic Chemistry, Wiley India, 2007
2. C. Housecroft and A, G. Sharpe, Inorganic Chemistry, Pearson India,
2012
3. B.D. Gupta and A. J. Elias, Basic Organometallic Chemistry, University
Press, 2010.
4. A.G. Massey, Main Group Chemistry, Ellis Horwood,1999.
5. J. A. Kent, Riegel’s Handbook of Industrial Chemistry, CBS, 1997.

27
CY 1631 Chemistry (Hons.) Laboratory-VI [0 0 2 2]

Physical Chemistry:
Conductometry: (i) Determination of the solubility of a sparingly soluble
substance, determination of the degree of hydrolysis of NH4Cl and CH3COONa,
(ii) To study the kinetics of saponification of ethyl acetate by sodium hydroxide;
Potentiometry:Potentiometric titrations of diabasic acid, oxalic acid and malonic
acid with base. (iii) To determine potentiometerically the solubility and solubility
product of a sparingly soluble salt; Polarimetry: (i) To study the kinetics of
inversion of cane sugar by means of polarimetry; Chemical Kinetics: (i) To
determine activation energy of a reaction by studying its temperature dependence,
(ii) To study the reaction between potassium iodide and potassium
peroxodisulphate; pH-metry: (i) To titrate a weak base against a strong acid and
determine the ionization constant of the weak base.
Inorganic Chemistry:
(i) Strong acid-strong base titration in a non-aqueous solvent using visual,
conductometric/potentiometric methods, (ii) Study of reactions of the elements of
first transition series: a) Iron, b) Cobalt, c) Nickel, d) Copper, (iii) Preparation of
chromium (II) acetate, Cr(CH2COO)2, H2O (Use of inert atmosphere technique)
and measurement of its magnetic susceptibility; (iv) Preparation and Identification
of any suitable inorganic/organometallic compounds involving the use of
techniques available in the department; Qualitative Analysis: To perform
qualitative analysis of a given binary mixture (i) Separation by ether, sodium
hydroxide, sodium bicarbonate and dil. Hydrochloric acid, (ii) Test for elements
(Other than C,H,O), (iii) Functional group determination, (iv) Melting point,
derivative preparation TLC for checking the purity and effectiveness of
separation.

Text Books:
1. G. Svehla and B. Sivasankar, Vogel's Qualitative Inorganic Analysis,
Pearson India, 2012
2. J. Mendham, R.C. Denney, M.J.K Thomas and D. J. Barne, Vogel's
Quantitative Chemical Analysis, Pearson India, 2009.
3. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale
Preparations Part 1, Pearson India, 2010.
4. B. Vishwanathan and P.S. Raghavan, Practical Physical Chemistry, Viva
Books, 2012.
5. F. Alexander, Practical Physical Chemistry, Hardpress Publishing, 2013.
6. A. I.Vogel, Elementary Practical Organic Chemistry: Quantitative
Organic Analysis Part 3, Pearson India, 2010.

28
SYLLABUS
Mathematics
[Subsidiary Course]

MA1111 DIFFERENTIAL CALCULUS AND INTEGRAL [3 1 0 4]


CALCULUS
Differential Calculus: Differentiability and differentials. Successive
differentiation and Leibnitz Theorem.Statement of Rolle's Theorem. Mean Value
Theorem, Taylor and Maclaurin's Theorems, indeterminate forms. Limits and
continuity of functions of two variables.Partial Differentiation: Definition of
Partial derivatives. Euler’s Theorem on homogeneous functions, total derivative
of composite & implicit functions, Errors and approximations,
Applications.Asymptotes.Curvature, Concavity, convexity and points of
inflection.ExtremePoints.Envelopes.Curve tracing, Tracing of Cartesian, Polar
Curves, Integral Calculus: Instigation, Beta and Gamma Functions and its
application. Application of Integral Calculus, Quadrature.Area and length of a
curve.Arc length as a parameter.Multiple Integrals: Definitions, Double
integrals, Triple Integral
Text Books:
1. Shanti Nayaran, Differential Calculus, ShyamLal Charitable Trust, Delhi,
2002.
2. Shanti Nayaran, Integral Calculus, ShyamLal Charitable Trust, Delhi, 2002.
3. N. Piskunov, Differential Calculus & Integral Calculus, Vol. 1 and II, Mir
Pub., 1981.
References:
1. C.B. Thomas, Calculus and Analytical Geometry, Narosa Pub., Delhi, 1996.
2. N. Piskunov, Differential Calculus & Integral Calculus, Vol. 1 and II, Mir
Pub., 1981.
3. R.Courant, and JohnF.,Introduction to Calculus and Analysis, Volume I,
Springer, 2000.

MA1211 ALGEBRA [3 1 0 4]
Algebra: Algebraic structure, Definition of a group with examples and simple
properties. Subgroups.Cyclicgroups.Cosetdecomposition.Lagrange’s theorem and
its consequences.Fermat’s and Euler’s theorems.Homomorphism and
Isomorphism. Normal subgroups: Quotient groups. The fundamental theorem
of homomorphism.Permutationgroups.Even and odd permutations.The alternating
groups An.Cayley’stheorem.Introduction to rings, subrings, integral domains and
fields.

29
Text Book:
I. N. Heristein, Topics in Algebra, Wiley Eastern Ltd., New Delhi, 1975.

References:
H. S. Hall and S. R. Knight, Higher Algebra, Elibron.com, 1999.

MA1311 DIFFERENTIAL EQUATIONS [3 1 0 4]

General Linear Higher order differential equations: First order and first
degree differential equation. Linear homogeneous and non-homogeneous
equations with constant coefficients, inverse differential operators and method of
variation of parameters.Solution of Cauchy’s homogeneous linear equations,
solution of simple simultaneous linear differential equations.Linear equations and
equations reducible to linear form. First order higher degree equations solvable
for x, y, p. Clairaut's form and singular solutions. Orthogonal trajectories.Linear
differential equations with constant coefficients.Homogeneous linear ordinary
differential equations.Linear differential equations of second
order.Transformation of the equation by changing the dependent variable and the
independent variable.

Text Books:
1. Simmons, Differential Equations, Tata McGraw-Hill Education, 2006.
2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi,
2006.
3. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006.

References:
1. D.Murray, Introductory Course in Differential Equations for students in
classical and engineering colleges. Longmans, Green, 1898.
2. Boyce and Diprima, Elementary Differential Equations and Boundary Value
Problems, Wiley, 9th Edition, 2008.

MA1312 SOLID GEOMETRY AND VECTOR CALCULUS [3 1 0 4]


Solid Geometry: Sphere. Cone.Cylinder. Centralconicoids, Ellipsoids,
Hyperboloid of one and two sheet, paraboloids, plane sections of conicoids.
Generating lines.Reduction of second degree equations to normal form;
classification of quadrics.VectorCalculus : Vector differentiation. Total
differential, Gradient, Divergence and curl, Directional derivatives.Vector
integration: Path, line, surface, and volume integrals. Line integrals of linear
differential forms, integration of total differentials, conservative fields.Theorems
of Green, Gauss, Stokes, and problems based on these.

30
Text Books:
1. Marsden, J., and Tromba, Vector Calculus., 5th Edition, W. H. Freeman,2003.
2. G.F. Simmons, Introduction to Topology and Modern Analysis, Krieger
Publishing Company, 2003.
3. Kreyszig, Advanced Engineering Mathematics, 8th Edition, Wiley India Pvt.
Ltd., 2010.

References:
1. S. L.Loney, Elements of Coordinate Geometry, Scholarly Publishing Office,
University of Michigan Library, 2005.
2. Shanti Narayan, Analytical Geometry, S. Chand, 2010.
3. R.Bell,Elementary Treatise on Coordinate Geometry of Three Dimensions,
Third Edition Mac Millan & Co, Ltd, 1963.

MA1411 LINEAR PROGRAMMING PROBLEMS & ITS [3 1 0 4]


APPLICATIONS
The Linear programming problem.Mathematical Formulation of the Problem-
.Types of solutions.Linear programming in matrix notation.Graphical solution of
linear programming problems.-Some Exceptional Cases.General Linear
Programming Problem (General L.P.P) – Slack and Surplus Variables, Theory
and application of the simplex method of solution of a linear programming
problem, Charne's M-technique. The two phase method. Transportation &
Assignment Problems.
Text Book:
G.Hadley, Linear Programming ,Narosa Publishing House, 1995.
References:
1.S. I.Gass, Linear Programming, Methods and Applications(4th edition), Mc
Graw- Hill, New York, 1975.
2.S. D. Sharma, Operation Research, Kedarnath and Ram Nath Publication, 1972.

MA1412 DYNAMICS [3 1 0 4]
Kinematics: Radial, Transverse, tangential, normal velocities and accelerations,
simple harmonic motion; Repulsion from a fixed pint, Motion under inverse
square, Law, Hooke’s law, Horizontal and vertical elastic strings. Motion of a
projectile on an inclined plane. Work energy and impulse, conservation of li
near momentum, uniform circular motion, motion on a smooth curve in a vertical
plane, motion on the inside of a smooth vertical circle, Cycloidal motion, Motion
in the resisting medium: Resistance varies as velocity and acquire of velocity.
Central forces.Stability of nearly circular orbits.Motion under the inverse square
law.Kepler’slaws.Time of describing an arc and area of any orbit.Slightly

31
disturbed orbits.Tangential and normal accelerations.Motion of a particle on a
smooth curve.Principle of conservation of energy.
References:
1. A. S.Ramsey,Dynamics (Part I)., The English Language Book Society and
Cambridge University Press, 1962.
2. J.Kar, M.t Hydrostatics. , Globe Library, 2nd Edition, 1957.
3. W. H.Besant, A. S.Ramsey, A Treatise on Hydromechanics (Part I). , G. Bell
and Sons, Ltd, London, 1960.
MA1511 REAL ANALYSIS [3 1 0 4]
Real Numbers: Real numbers as a complete ordered field. Limit point, Bolzano
Weierstrass theorem, closed and open sets, union and intersection of such sets,
concept of compactness, Heine Borel theorem, connected sets. Real Sequences,
Limit and convergence of a sequence, monotonic sequences, Cauchy’s sequence,
subsequence, Cauchy’s general principle of convergence. Improper integrals
Convergence of improper integrals and their properties, convergence of Beta and
Gamma functions. Differentiation and integration of a function under the sign of
integral.Infinite Series: Definition regarding convergence, divergence of infinite
series. Tests: Comparison test, ratio test, Cauchy’s root test, Raabe’s test,
logarithmic test, integral test, Cauchy’s condensation test, Gauss’s test, with
proofs, alternating series, Leibnitz’s theorem, absolute and conditional
convergence. Taylor’s and Maclaurin’s expansion of functions.
Text Books:
1. Walter Rudin, Principles of Mathematical Analysis, McGraw-Hill, 1976
2 S.Shastri, Real Analysis, Springer, 2010
3. Shanti Narayan,Elements of Real Analysis, S. Chand Limited, 2003

References:
A. N.Kolmogorov, and S. V.Fomin, Elements of the Theory of Functions and
Functional Analysis, Vol 1, Dover,New York, 1961.

MA1512 NUMERICAL ANALYSIS AND PROBABILITY [3 1 0 4]


THEORY
Numerical Analysis : Differences, Relation between differences and derivatives,
Differences of a polynomial, Newton’s formulae for forward and backward
interpolation, Divided difference, Newton’s divided difference, Interpolation
formula, Lagrange’s interpolation formula. Central differences, Gauss’s, Stirling’s
and Bessel’s interpolation formulae. Numerical Differentiation.Derivatives from
interpolation formulae. Numerical Integration, Newton – Cote’s formula,
Trapezoidal rule, Simpson’s one- third rule, Simpson’s three – eighth rule and
Gauss’s quadrature formulae. Numerical solution of algebraic and transcendental
equations. Bisection method, RegulaFalsi Method, Method of iteration, Newton

32
Raphson Method, Gauss elimination and Iterative method for solving linear
algebraic and transcendental equations. Solution of ordinary differential equations
of first order with initial and boundary conditions using Picard’s and modified
Euler’s method.
Probability Theory: Definitions, Sample space, events, algebra of events, joint &
conditional probability, dependent events.Bernoulli’s trials, Probability &Baye’s
theorem. Discrete & continuous distributions, Probability distribution &
probability densities: Binomial, Poisson, normal and uniform distribution &
density functions.Correlation& Regression Correlation & regression: Linear
regression, Rank correlation, Method of least squares Fitting of straight lines &
second degree parabola.

Text Books:
1. G. Haribhaskaran, Numerical Methods, Laxmi Publications, Delhi, 2008.
2. B. S. Grewal, Higher Engineering Mathematics, Khanna Publishers, Delhi,
2006.

Reference Books:
1. E. Kreyzig, Advanced Engineering Mathematics, Wiley Eastern, 2006.
2. Srimanta Pal, Numerical Methods, Oxford university Press, Delhi 2012.

MA1611 COMPLEX ANALYSIS [3 1 0 4]


Calculas:Limits, Continuity, differentiability, Complex plane, connected and
compact sets, Statement of Jordan curve theorem. Extended complex plane, and
stereographic projection. Complex valued function, the extended plane. Analytic
functions, CR equations (Cartesian and polar form), Harmonic functions,
construction of an analytic function, conformal mappings, Bilinear transformation
and its properties. Power series: absolute convergence, Cauchy Hadamard
theorem, radius of convergence, analyticity of sum function of a power series.
Complex integration, complex line integrals, Cauchy’s integral theorem,
Indefinite integral, fundamental theorem of Integral calculus for complex
functions, Cauchy’s integral formula, Analyticity of the derivative of analytic
function, Liouville’s theorem, Poisson’s Integral formula, Morera’s theorem,
Taylor’s and Laurent’s series. Maximum modulus principle.Singularities, Brach
points, Meromorphic functions and Entire functions, Reimann’s theorem,
Cauchy-Weierstrass theorem.
Text Book:
1. R.V. Churchill, J.W.Brown, Complex Variables and Applications, 5thedn.,
McGraw Hill Series, 2000.
References:
1. J. B. Conway, Functions of one complex variable, Springer International
Student edition, Narosa Publishing House, New Delhi, 2000.

33
MA1612 DISCRETE MATHEMATICS STRATURE [3 1 0 4]
Propositional Calculus: Logical connectives, Truth tables, Tautologies and
contradictions, Contrapositive, Logical equivalences and implications, De
Morgan’s Laws, Normal forms, Rules of inference, Arguments, Validity of
arguments. Predicate Calculus: Free and bound variables, Quantifiers, Theory
of inference, The rules of universal specification and generalization, Validity of
arguments. Set Theory: Types of relations on sets and their properties, Relational
matrix and the graph of a relation, Partitions, Equivalence relations, Poset, Hasse
diagram. Definitions & Classification of functions, Characteristic function of a
set, Hashing functions, Recursive functions, Permutation functions.
Combinatorics: Discrete numeric function, Basic counting principles, Generating
functions, Recurrence relations, Inclusion and exclusion principle, Euler’s 
function and its applications to Cryptography. Graph Theory:Graphs
:Definition and examples of graphs,Incidence and degree, Handshaking lemma,
Isomorphism Sub-graphs, Weighted Graphs, Eulerian Graphs, Hamiltonian
Graphs Walks, Paths and Circuits. Trees : Definition and properties of trees
Pendent vertices, centre of a tree Rooted and binary tree, spanning trees,
minimum spanning tree algorithms Fundamental circuits, cutsets and cut vertices,
fundamental cutsets, the four color theorem Directed Graphs :Types of
digraphs, directed paths and connectedness, Euler digraphs, Directed trees,
Text Books:
1. Trembly J.P and Manohar R, Discrete Mathematical Structures with
Applications to Computer Science, Tata McGraw–Hill Pub. Co. Ltd, New
Delhi, 2003.
2. Ralph. P. Grimaldi, Discrete and Combinatorial Mathematics: An Applied
Introduction, Fourth Edition, Pearson Education Asia, Delhi, 2002.
3. T. Veerarajan, Discrete Mathematics, Tata McGraw Hill, 2010.

References:
1. J. A.Bondy& U. S. R. Murty, Graph Theory with Applications, MacMillan,
1976.
2. G. R. E.Polya, Tarjan& D. R. Woods, Notes on Introductory Combinatorics,
BirkHauser, 1983.
3. M. N. S.Swamy, & K. Tulsiram, Graph, Networks and Algorithms, John
Willey, 1981.
4. Bernard Kolman, Robert C. Busby, Sharan Cutler Ross, Discrete Mathematical
Structures, Fourth Indian reprint, Pearson Education Pvt Ltd., New Delhi,
2003.

34
SYLLABUS
Physics
[Ancillary Course]

PY 1211 Oscillations and Wave Optics [2 1 0 3]

Oscillations
Potential well and periodic oscillations, harmonic oscillations, differential
equation and its solution, kinetic and potential energy, examples of simple
harmonic oscillations, spring and mass system, simple and compound pendulum,
torsional pendulum, LC circuit, oscillations of two masses connected by a spring.
Motion of two coupled oscillators, normal modes, N coupled oscillators, damped
harmonic oscillator, power dissipation, quality factor, driven harmonic oscillator,
transient and steady states, power absorption, resonance in systems with many
degrees of freedom.

Wave Optics
Interference: The principle of superposition. Two-silt interference, coherence
requirement for the sources, Localized fringes; thin films and applications,
Fringes of equal inclination, Newton’s Ring Experiment, Michelson
interferometer and its application for precision determination of wavelength,
wavelength difference and the width of spectral lines.

Diffraction: Fresnel and Fraunhoffer diffraction, Fraunhoffer diffraction due to


single silt, Diffraction due to N parallel silts, intensity distribution, plane
diffraction grating, reflection grating and blazed gratings. Resolving power of a
grating and its comparison with resolving power of prism, Raleigh criterion,
resolving power of telescope and microscopic systems, outline of phase contrast
microscopy

Polarization: Double refraction and optical rotation, phase retardation plates,


double image prism, Rotation of plane of polarization, origin of optical rotation in
liquids and in crystals, Specific rotation, Polarimeters

Lasers: Laser systems: Purity of a spectral line, coherence length and coherence
time, spatial coherence of a source, Einstein’s A and B coefficients, Spontaneous
and induced emissions, conditions for laser action, population inversion, spatial
coherence and directionality, He- Ne Laser, Pulsed lasers and tunable lasers,
Applications of Lasers

35
References:
1. Khandelwal D P, Oscillations and Waves,Himalaya Publishing House,
Bombay.
2. Ghosh R K; The Mathematics of Waves and Vibrations,,Macmillan, (1975)
3. Berkeley Physics Courses; Vol. III , Waves and Oscillations.
4. Jain H J; The Physics of Vibrations and Waves, Macmillan (1975)
5. Ghatak A K , Physical Optics, Mc-Graw Hill
6. Khandelwal D P, Optics and Atomic Physics, Himalaya Publishing House,
Bombay, (1988)
7. Smith F and Thomson J H, Manchester Physics series; Optics, English
Language Book Society and John Wiley, (1977)
8. Laud B B, Laser and Non-liner Optics, Wiley Eastern, (1985).
9. Smith and Thomson; Optics, John Wiley and Sons.

PY 1231 Optics Lab [0 0 4 2]


1. Interference Expt. Lloyd’s mirror
2. Interference at an air wedge
3. Newton’s Rings experiment.
4. Diffraction at a straight edge
5. Diffraction grating (Determination of wavelengths of the Hg spectral lines)-
Minimum deviation method
6. Diffraction grating - Normal incidence method.
7. L-B Photometer
8. Optical activity- Polarimeter.
9. Biprism Experiment.
10. Moduli of elasticity- Cornue’s fringes
11. Determination of Brewster’s angle and R.I of glass surface using
spectrometer and a polaroid.

36

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