Zyme-Flow Technology

Single-Step Decontamination of
Hydrocarbon Processing Units
 Zyme-Flow Process ®

Eliminates benzene, LEL, H2S, and

pyrophoric iron sulfides

Safe, biodegradable and

compatible with metallurgy
and wastewater system

A Versatile Solution
The Zyme-Flow Process offers the most
®
The Zyme-Flow Process eliminates contaminants not only in liquid or
complete decontamination solution for sludge but also vapors within process equipment. Active in liquid and
refining and petrochemical applications. vapor, Zyme-Flow UN657 can be applied as an aqueous solution in
In a single step, the Zyme-Flow Process circulation or through a proprietary Vapour-Phase® steaming process.
removes residual oil, gas, LEL, hydrogen Vapour-Phase is the most utilized process using the plant’s existing
sulfide (H2S), benzene and pyrophoric steam out procedures and injecting the chemistry directly into the
iron sulfides. steam source. Zyme-Flow’s unique water based formula allows it to
The patented formulation is highly effective, travel with steam throughout the entire unit using a minimum of one
fast-acting and safe for personnel, plant injection point. The Vapour-Phase Process is the fastest method for
equipment and the environment. As a result, entering process equipment and avoids the costs of temporary circu-
Zyme-Flow treatment dramatically reduces lation pumps, while reducing the amount of waste generated.
the time required to prepare equipment for
entry while increasing safety.
Benefits
100
90 Effective. The Zyme-Flow Process reduces hydrogen
80 sulfide to near zero, LEL’s to near zero and benzene
H2S
70 to less than 1 ppm. It eliminates pyrophoric iron sulfide
Benzene
60 and other reacting sulfides as an integral part of the
Scale

50 LEL
Temp (°C) decontamination process. Excessive steamout times
40
are no longer necessary. The light emulsion formed
30
separates quickly without the need for a breaker.
20
10 Efficient. The Zyme-Flow Process drastically reduces
0 turnaround cleaning time with minimum equipment
0 2 4 6 8 10 12
Hours and personnel. Zyme-Flow Process technology can
be merged into shut down operations, minimizing
Actual performance chart of a Zyme-Flow project (shape turnaround time and often reducing outside
and values of curve will vary by applicaction). contract costs.

C R U D E U N I T S VA C U U M U N I T S S AT G A S U N I T S C O K E R U N I T S
HYDROCRACKER UNITS REFORMER UNITS REFORMERS ETHYLENE UNITS CAUSTIC
F L A R E D R U M S H Y D R O F I N E R U N I T S A M I N E T R E AT E R U N I T S P I P E L I N E S O D O R C O N T R O L
 Safe. Zyme-Flow chemistry is non-toxic, non-haz- parameters, including H2S, benzene, LEL, sulfide in
ardous, and biodegradable. It contains no volatile water, pH, temperature and chemical concentration.
compounds and has no flammability concerns. The end point is accurate and verifiable.
The Material Safety Data Sheet hazard rating is
0-0-0. Unlike other chemicals, it does not form toxic Decontamination Planning
by-products of sulfides during the decontamination Zyme-Flow Decon Technology provides the industry’s
process. All reactions with sulfides are non-exo- most comprehensive pre-project planning services.
thermic and safe with hydrocarbons. Extensive consultation with refinery personnel
and onsite inspection of all equipment and piping
Environmentally Friendly. CEFAS and REACH is conducted. Detailed procedures are specified,
compliant, Zyme-Flow meets the most stringent including chemical injections points, required fluid
environmental standards on the globe. Zyme- volumes and all necessary refinery preparations.
Flow chemistry is not a solvent. It is a completely The final planning package includes everything
biodegradable, aqueous based formula that is free needed to ensure safe and fast vessel entry.
of volatile organic compounds. When applied in
the Vapour-Phase Process, it also eliminates odor Global Technical Support
problems associated with conventional steaming.
Zyme-Flow Decon Technology provides services
Plant Compatible. Zyme-Flow chemistry has a and support to over 50 countries. Services include
near neutral pH, and is compatible with all common engineered decontamination, planning, project
metals of containment and construction. It is safe management, technical training, execution and
for plant wastewater treatment systems and the follow-up. Services are provided by engineers and
chemical constituents are not a threat for chemists with extensive experience in refining and
reprocessing recovered hydrocarbons. wastewater treatment.
Zyme-Flow specialists are available to
Reliable. The progress of benzene and sulfide
answer questions and discuss your specific
elimination is measured and documented during
requirements. Call today at +1 281.443.0300
a project, allowing results to be accurately predicted.
Throughout the process, Zyme-Flow Decon EnvirAware ™
This product is specially
Technology personnel monitor all key project designed to maximize
cleaning performance
without harm to the
environment.

F C C U N I T S D E S A LT E R S V I S - B R E A K E R S F L A R E S Y S T E M S
T R E AT E R S G A S C O M P R E S S O R S Y T E M S S O U R WAT E R S T R I P P E R S M E R O X U N I T S
S T O R A G E TA N K S O I L F I E L D P R O D U C T I O N S Y S T E M S O I LY WAT E R S E PA R AT O R S H D S U N I T S
 Dynamic Range of Products for Light-Ends to Heavy Oil, Single Units to Full Shutdowns

Zyme-Flow® UN657
Water based surfactant and oxidizer. Simultaneously eliminates, benzene, LEL, and residual hydrocarbon from
vessels while safely oxidizing H2S and pyrophoric iron sulfide. Applied in Vapour-Phase® or water based applications.
Designed to allow fast and clean separation of oil from water without emulsion breakers or chlorides.

HOB® K61 Heavy Oil Blender

An additive that quickly penetrates heavy-oils, tar and asphalt, breaking them up for quick removal.

REZYD-X® Z67
An internal cleaner that dissolves heavy hydrocarbon and polymeric
deposits in vessels, heat exchangers, process lines and tanks.

ZYME-OX® Plus Z50

Oxidizes sulfides and pyrophorics even at a high pH and cold temperatures. Also effective in
neutralizing residual ammonia such as in hydrotreaters or sulfur recovery units,
even when heat or steam may not be viable.

Zyme-HT® Z11
Rids units of ammonia, neutralizes sulfides and pyrophorics and removes residual oil and gas.

Super Tank Zyme® Z21

Excellent for use in tanks for safely treating sour water and pyrophorics especially when de-oiling/washing
is also required. Non-exothermic and versatile in application method and temperature.

K19
The most efficient and safe way to eliminate high levels of H2S and pyrophorics found in
sour water tanks. Direct application eliminates the need for batch treatments and mix tanks.

FastEntry® K15
An innovative tank cleaning product that effectively separates paraffinic hydrocarbons, water,
and inorganic solids into three distinct phases to maximize recovered hydrocarbons and
significantly increase the ease and speed of final cleaning.

Worldwide Leader in Refinery Decontamination

United Laboratories International, LLC
A TriStar Global Energy Solutions Company
Tel: +1 281.443.0300
Fax: +1 713.672.3988
Toll Free: 877.332.6648
www.zymeflow.com

EnvirAware. Heavy Oil Breaker, HOB, REZYD-X, Super Tank-Zyme,

Vapour-Phase, Zyme-Flow, Zyme-HT, Zyme-Flow Process,
and ZYME-OX are marks of United Laboratories International, LLC

©2014 United Laboratories International, LLC

All Rights Reserved.