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Ammonia Converter Mass Balance

- The document provides input data for an ammonia converter over a 10 day period, including flow rates and composition percentages of argon, methane, nitrogen, hydrogen, and ammonia. - It then calculates the mass balance for the ammonia converter, showing the input and expected output masses of each component based on chemical reactions and conversion rates within the converter. - The calculation shows the mass of nitrogen converted to ammonia is balanced, with total input and output masses equaling 529.706 kg/hr.

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wahyudi s gultom
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278 views4 pages

Ammonia Converter Mass Balance

- The document provides input data for an ammonia converter over a 10 day period, including flow rates and composition percentages of argon, methane, nitrogen, hydrogen, and ammonia. - It then calculates the mass balance for the ammonia converter, showing the input and expected output masses of each component based on chemical reactions and conversion rates within the converter. - The calculation shows the mass of nitrogen converted to ammonia is balanced, with total input and output masses equaling 529.706 kg/hr.

Uploaded by

wahyudi s gultom
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Neraca Massa Ammonia Converter 105-D di Unit Amoniak Pusri IB

Gambar 1.1 Ammonia Converter (105-D) Pusri IB

Data Komposisi Input Ammonia Converter 105-D dari Pabrik PUSRI Unti Amoniak IB

Data Diambil setiap jam 7 pagi selama 10 hari dari tanggal 20 Juli sampai 29 Juli 2016

Tanggal Ar (Argon) CH4 (Metana) N2 (Nitrogen) H2 (Hidrogen) NH3 (Amoniak)


%vol/hr %vol/hr %vol/hr %vol/hr %vol/hr
20-07-2016 2.18 5.78 22.42 68.25 1.37
21-07-2017 2.22 5.58 23.69 67.14 1.37
22-07-2016 2.17 5.08 24.04 67.37 1.34
23-07-2016 2.07 5.60 21.34 69.47 1.31
24-07-2016 2.1 5.68 22.97 67.7 1.31
25-07-2016 2.00 5.14 21.90 70.85 1.34
26-07-2016 2.08 4.95 22.93 68.75 1.39
27-07-2016 2.01 4.93 22.46 69.21 1.39
28-07-2016 2.19 4.77 23.77 67.88 1.39
29-07-2016 2.00 4.92 20.41 69.87 1.26
Rata-rata 2.10 5.28 22.59 68.68 1.35
Data Flowrate Input pada Ammonia Converter 105-D

Tanggal Flowrate
(Kg/hr)
20-07-2016 544.076
21-07-2016 527.146
22-07-2016 524.416
23-07-2016 521.451
24-07-2016 533.920
25-07-2016 518.312
26-07-2016 535.504
27-07-2016 532.430
28-07-2016 530.101
Rata-rata 529.706

Perhitungan Neraca Massa Ammonia Converter 105-D

T = 450oC
Flowratein = 529.706 Kg/hr P = 145 atm Output
Ammonia Converter
Ar = 2.10 % Ar = ..... ?
CH4 = 5.28 % CH4 = .... ?

N2 = 22.59 % N2 = ...... ?

H2 = 68.68 % H2 = ....... ?
NH3 = 1.35 % NH3 = .... ?

Diketahui :
Mr : (Ar = 18, CH4 = 16, N2 = 28, H2 = 2, NH3 = 17)
a. Massa Input
Ar = 2.10% x 529.706 kg/hr = 11.135 kg/hr : 18 = 0.618 kmol/hr
CH4 = 5.28% x 529.706 kg/hr = 27.798 kg/hr : 16 = 1,748 kmol/hr
N2 = 22.59% x 529.706 kg/hr = 119.66 kg/hr : 28 = 4.273 kmol/hr
H2 = 68.68% x 529.706 kg/hr = 363.802 kg/hr : 2 = 181.901 kmol/hr
NH3 = 1.35% x 529.706 kg/hr = 7.151 kg/hr : 17 = 0.421 kmol/hr
Total Massa Input = (11.134 + 27.796 + 119.66 + 363.802 + 7.151) kg/hr
= 529.706 kg/hr

Note: N2 yang terkonversi menjadi NH3 didalam reaktor adalah 31%

N2 yang bereaksi = 31/100 x 4.273 kmol/hr = 1.324 kmol/hr

Reaksi : N2 + 3H2 2NH3

M: 4.273 181.901 0.421


R: 1.324 3.974 2.648
S: 2.949 177.927 3.069

Mol N2 sisa = Mol N2 mula-mula – Mol N2 bereaksi


= 4.273 kmol/hr – 1.324 kmol/hr
= 2.949 kmol/hr
Massa N2 output = 2.949 kmol/hr x BM
= 82.572 kg/hr
Mol H2 bereaksi = (Koefisien H2/Koefisian N2) x Mol N2 bereaksi
= (3/1) x 1.324 kmol/hr
= 3.974 kmol/hr
Mol H2 sisa = Mol H2 mula-mula – Mol H2 bereaksi
= 181.795 kmol/hr – 3.974 kmol/hr
= 177.927 kmol/hr
Massa H2 output = 177.927 kmol/hr x BM
= 355.854 kg/hr
Mol NH3 terbentuk = (Koefisien NH3/Koefisian N2) x Mol N2 bereaksi
= (2/1) x 1.324 kmol/hr
= 2.648 kmol/hr
Mol NH3 akhir = Mol NH3 mula-mula + Mol NH3 terbentuk
= 0.421 kmol/hr + 2.648 kmol/hr
= 3.069 kmol/hr
Massa NH3 output = 3.069 kmol/hr x BM
= 52.173 kg/hr

b. Massa output
Total massa output = (82.572 + 52.173 + 355.854 + 11.135 + 27.798) kg/hr
= 529.702 kg/hr

Komponen Input Output

Ar 11.135 kg/hr 11.135 kg/hr

CH4 27.798 kg/hr 27.798 kg/hr

N2 119.66 kg/hr 82.572 kg/hr

H2 363.802 kg/hr 355.854 kg/hr

NH3 7.151 kg/hr 52.173 kg/hr

Total 529.706 Kg/hr 529.702 kg/hr

Neraca Massa
Massa Input = Massa Output
529.706 Kg/hr = 529.702 kg/hr ....... Balance

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