Chapter 1
Chapter 1
DIODESANIDTHEIR CHARACTERISTICS
In this chapteryou will study the atomic structureof a semiconductor,a material that is
neither a good conductornor a good insulator.Diodes, transistors,and integratedcircuits
(ICs) are all made from semiconductormaterials such as germanium (Ge) and silicon
(Si). You will also study the diode, which is the most basic semiconductordevice. A
diode is an unidirectional device that allows current to flow through it in one direction
only. You will learn what is meant by the termsforward and reversebias and also be-
come familiar with important diode characteristics,approximations,and ratings.
1-1 SEMICONDUCTORMATERIALS
Semiconductorsconduct less than metal conductors but more than insulators. Some
common semiconductormaterialsare silicon (Si), germanium(Ge), and carbon (C). Sil-
icon is the most widely used semiconductormaterial in the electronicsindustry.Almost
all diodes, transistors,and ICs manufacturedtoday are made from silicon.
Intrinsic semiconductorsare semiconductorsin their purest form. An example
would be a semiconductorcrystal with silicon atoms only. Extrinsic semiconductorsare
semiconductorswith other atomsmixed in. Theseother atomsare called impuri|, atoms.
The processof adding impurity atoms is called doping. The doping alters the character-
istics of the sendconductor,mainly its conductivity. The impurity atoms have either
fewer than four valenceelectronsor more than four valenceelectrons.At room temper-
ature (about 25'C) an intrinsic semiconductoracts more like an insulator than a conduc-
tor. The conductivity of an extrinsic semiconductoris greater than that of an intrinsic
semiconductor.The level of conductivity is dependentmainly on the number of impurity
atoms that have been addedduring the doping process.
Atomic Structure
Figure l-l shows the atomic structurefor a silicon atom. The atomic number for silicon
is 14, meaningthat there are 14 protonsin its nucleus,balancedby 14 orbiting electrons.
Notice in Figure l-l(a) that the first shell (ft-shell)surroundingthe nucleushas two
electrons,the secondshell (/-shell) has eight electrons,and the third shell (n-shell) has
four electrons.The outermost ring of an atom is called the valence ring, and the elec-
trons in this ring are called valence electrons.All semiconductorshave four valence
electrons.The number of valence electronspossessedby an.vatom determinesits elec-
trical conductivity. The number of valenceelectronsin an atom also determineshow it
will combine with other atoms. The best conductors have only one valence electron,
while the best insulatorshave complete shells.
The simplified drawing of a silicon atom is shown in Figure l-l(b). The core rep-
resentsthe nucleus and inner electrons.The outer four electronsrepresentthe valence
(b)
electronsof the silicon atom. As you will see, the nucleus and inner electronsare not
Figure l-l that important when analyzinghow atomscombine with eachother; hencethe reasonfor
Atomic structureof a silicon the simplified drawing. One more point: the Si core has a net charge of *4 becauseit
atom. (a) Atomic structure of an contains14 protonsand l0 inner electrons.
atom showing the nucleus and
its orbital rings of electrons.(b) Forming a Crystal
Simplified drawing of a silicon
atom.The core includes the When silicon atoms are groupedtogether,somethingvery interestinghappens.Each sil-
nucleusand inner electrons. icon atom sharesits four valence electronswith other nearby atoms, thereby forming a
-
Figure 1-2
Bonding diagram of a silicon
crystal.
@ (si) tsi) (si)
@
(sr)
@ (si)
@ @
{sit
@ o @ @
@ @ @ o o Flgure 1-4
Doping a sil
pentavalent :
solid crystalline structure.For the six inner silicon atoms in Figure l-2, eachatom has (As) is shou
eight valenceelectronsas a result of the electron sharing,which is the amount required but other per
for maximum electrical stability. Notice in Figure 1-2 that only the core and valence such as antir
electronsare shown for each atom. phosphorous
used.
This sharing of valence electronsis called covalent bonding. The covalent bonds
betweeneach silicon atom produce the solid crystalline structure.
r Free electron doped with impurity atoms to increasetheir conductivity. An extrinsic semiconductor
material, then, is one that has been doped with impurity atoms.
tsi)
( v n-type Semiconductors
/,,--)){f,-.\ A pentavalentatom is one that has five valenceelectrons.Some examplesare antimony
( s i) | | ( n s )| | ( s i) (Sb), arsenic (As), and phosphorous(P). A silicon crystal doped with a large number of
1v-f{fur pentavalentimpurity atoms results in many free electronsin the material. This occurs
becauseat the location of each pentavalentatom there is one electron that is not used in
,-\ )
e, the covalent bond structureof the material. Remember,only eight electronscan exist in
the valencering of a silicon atom. Therefore,one of the valenceelectronsin the penta-
valent impurity atom is not neededin the covalent bond structureand can float through
figurr l-4
the material as a free electron.This is illustrated in Figure 1-4. The free electron shown
Dopinga silicon crystal with a actually belongs to the arsenic atom, but since the covalent bond is already complete
pentavalentimpurity. Arsenic with eight valenceelectrons,the electron is extra, or not needed.When millions of pen-
(As)is shown in this illustration, tavalentimpurity atomsare addedto an intrinsic silicon crystal, there are millions of free
but other pentavalent impurities electronsthat can float through the material. Since the electron is the basic particle of
suchas antimony (Sb) or negativecharge,we call this n-type semiconductormaterial.The net chargeof the n-type
phosphorous(P) could also be material is still neutral, however,since the total number of electronsis equal to the total
used.
number of protons. n-type semiconductorsalso contain a few holes becausethermal en-
ergy still createsa few electron-holepairs in the crystal. The few valenceelectronsthat
do absorb enough energy to leave their respectivecovalent bonds increasefurther the
number of free electronsin the material. The vacancies,or holes, createdin the crystal
act like positive chargesbecauseif a free electron passesby, it will be attractedto the
hole and fill it. since there are many more free electronsthan holes in an n-type semi-
conductor material, the electronsare called the majority current carriers and the holes
are called the minority current carriers.
There are many positive ions present in n-type semiconductormaterial because
when the fifth valenceelectron of the pentavalentatom leavesits home or parent atom,
an imbalanceis createdin the number of positive and negativechargesthat exist for that
atom" In this case,the nucleusof the impurity atom will contain one more proton than
its number of orbiting electrons.The positive ions are fixed chargesin the crystal that
Hole (si) are unable to move.
I p-type Semiconductors
I
( s i)
t, (si)
A trivalent atom is one that has only three valenceelectrons.Some examplesare alumi-
num (Al), boron (B), and gallium (Ga). A silicon crystaldopedwith a large numberof
trivalent impurity atoms results in many holes, or vacancies,in the covalent bond struc-
(si)
ture of the material. This happensbecauseat the location of each trivalent atom in the
crystal one more valence electron is neededto obtain the maximum electrical stability
with eight electrons,as shown in Figure l-5. When millions of trivalent impuritiesare
Figurt 1-5
added to an intrinsic semiconductormaterial, millions of holes are createdthroughout
Dopinga silicon crystal with a
trivalentimpurity. Aluminum the material. Since a hole exhibits a positive charge,we call this p-type semiconductor
(Al) is shownin this material. The net charge of the p-type material is still neutral, however, since the total
illustration,but other trivalent number of electronsis equal to the total number of protons.
impuritiessuch as boron (B) or p-type semiconductorsalso contain a few free electrons,becausethermal energy
gallium(Ga) could also be still produces a few electron-hole pairs. Electrons are the minority carriers in p-type
used. semiconductormaterial, while holes are the maiority current carriers.
Figure 1-7
pn junction. (a) pn junction Barrier Potential, V"
showing the electrons1-) in the
The ions createa potential difference atthe pnjunction as shown in Figure l-7(b). This
n side and holes (O) in the p
side. (b) Formation of depletion
potential difference is called the barrier potential and is usually designatedVu. For sil-
zone with positive ions at the icon, the barrier potential at thepn junction is approximately0.7V. For germanium,V, is
left edge of the n material and about 0.3V. The barrier potential cannot be measuredexternally with a voltmeter, but it
negative ions at the right edge does exist at the pn junction. The barrier potential causesthe diffusion of the current
of the p material. carriers to stop.
4 . CHAPTER1
I
Figurel-E
Forwardbiasedpn junction.
(a) External voltage forces free o o o
electronsfrom the n side across o o o
the depletion zone to the p side o o o
wherethe electron falls into a o o o
hole.Once on the p side the
electronsjump from hole to
hole in the valence band.
(b) Electron flow is against the
anow, whereasconventional
cunent is in same direction as
itrTow.
(a)
Electron flow
Conventionalflow
(,(')
(b)
against the arrow on the diode symbol. The arrow on the diode symbol points in the
direction of conventionalcurrent flow. Either current direction works well when analyz-
ing diode circuits. In this book, however,we will use electron flow when analyzing cir-
cuits containing diodes.
Figure l*9
Reverse-biased pn junction.
(a) Extemal voltage pulls ooooo
majority current carriers away
ooooo
from the pn junction. This
ooooo
widens the depletion zone.
ooooo
(b) Schematicsymbol showing
how a diode is reverse-biased
with the external voltage, V
Figurt 1-10
(a)
Volt-ampere
of a silicon
(b)
6 . CHAPTER I
Leakage Current
Even a reverse-biaseddiode conductsa small amount of current, called leakagecurrent.
The leakagecurrent is mainly due to the minority current carriersthat exist in both sec-
tions of the diode. The minority cunent carriersare holes in the n side and free electrons
in the p side. The minority current carriersexist as a result of thermal energy producing
many electron-hole pairs. Since temperaturedetermines the number of electron-hole
pairs generated,the leakagecurrent is also affectedby temperature.Any increasein the
temperatureof the diode causesthe leakagecurrent in the diode to increase.Thesemi-
nority current carriersmove in a direction that is oppositeto the direction provided with
forward bias.
Figure1-10 1p (mA)
Volt-amperecharacteristiccurve
of a silicon diode.
Vp (Volts;<-
DC Resistanceof a Diode
Examine the forward-biasregion for the graph shown in Figure l-10.
The graph of Vo versus 1o shows that a diode is a nonlinear device becausethe
diode current, 1o, does not increasein direct proportion with the diode voltage, Vo. For
example,the diode voltage does not have to be doubled to double the diode current.The
dc resistanceof a forward-biaseddiode can be calculatedusing Equationl-1.
VO
R ', : (1-1)
IF
* 0'q5Y = 0.1J-
11mA 22.5mA Figure 1-11
First appror
* 59O = 31.1,fl
(a) Forward
. Noticethat asthe diodeconductsmoreheavily,the forwardresis- like a close
(b) Reverse
tance,R," decreases.
treated like
(c) Graph s
Using an Ohmmeter to Check a Diode and reverse
8 . CHAPTER I
If the diode is shorted, it will measurea low resistancein both directions. If the
diode is open, it will measurea high resistancein both directions.
A word of caution. when using analog ohmmetersto check a diode, do not use the
R X 1 range. The reasonis that the current forced through the diode by the meter may
exceedthe current rating of the diode. The R x 100 range is usually the best range on
which to check a diode.
First Approximation
The first approximationtreats a fcrward-biaseddiode like a closed switch with a voltage
drop of zero volts, as shownin Figure l-l l(a). Likewise,the first approximationtreatsa
(b)
(c,
reverse-biaseddiode like an open switch with zero current, as shown in Figure l-ll(b). Figure 1-13
The graph in Figure l-11(c) indicatesthe ideal forward- and reverse-biascharacteristics.'' Third apprc
The first approximationof a diode is often usedif all that is neededis a rough idea (a) Forwarc
of what the circuit voltagesand currents should be. including tl
Vr, and the
The first approximationis sometimescalled the ideal diode approximation.
(b) Reverse
showing hi1
Second Approximation infinite) of
The second approximation treats a forward-biaseddiode like an ideal diode in series condition. (
with a battery, as shown in Figure l-12(a). For silicon diodes the battery voltage is as- forward an
characteris
sumed to be 0.7 V the same as the barrier potential, V", at a silicon pn junction.
Forward-biased
YB
_t+_+ -
*Jf r l r
Reverse-biased
- +
----)--
(b)
{c}
Figurr 1-12
Secondapproximation of a diode. (a) Forward-biaseddiode treated like an ideal diode in series
with a battery. (b) Reverse-biaseddiode treatedlike an open switch. (c) Graph showing forward
and reversecharacteristics.
Third Approximation
The third approximationof a diode includes somethingcalled the bulk resistance,desig-
nated r". ru is the resistanceof the p and n materials.Its value is dependenton the dop-
ing level and the physical size of the p and n materials.
The third approximationof a forward-biaseddiode is shown in Figure 1-13(a). The
total diode voltage drop using the third approximationis calculatedusing Equation l-2.
Vr: Vn * Io16 (r-2)
IO . CHAPTERI
Egun l-13 Forward-biased
lhird approximation of a diode. vB rB
(a)Forward-biased diode
includingthe barrier potential,
___-)t__
+ -
**"|rlnnn-
V", andthe bulk resistance,rr.
(a)
(b)Revene-biased diode
showinghigh resistance(not
infinite)of the reverse-bias Reverse-biased
condition. (c) Graph showing
forwardand reverse
characteristics.
____)+
- +
Reverseleakage
Reverse-biasresistance
(b)
(c)
The bulk resistance,rB, causes the forward voltage across a diode to increase
slightly with increasesin the diode current.
Figure l-13(b) shows the third approximationof a reverse-biaseddiode. The resis-
tance across the open switch illustrates the high leakageresistancethat exists for the
reverse-biascondition. Notice the small leakagecurrent in the graph of Figure l-13(c)
when the diode is reverse-biased.This is a result of the high resistancethat exists when
the diode is reversebiased.
AV
(l-3)
N
where AVrepresents the changein diode voltage producedby the changesin diode cur-
rent. 4L
rB = 2.5 {l
Figure 1-14
Circuits usedto illu$trate the use of the first, second,and third diode approximationsin calculatingthe circuits' voltage and current val-
ues.(a) Original circuit. (b) First approximationof a diode. (c) Secondapproximationof a diode. (d) Third approximationof a diode.
12 . CHAPTERI
1-8 DIODE RATINGS
The following is a list of maximum ratings and electrical characteristicsfor semiconduc-
tor diodes.
reversevoltage, V^, of 100 V. With this data, the reverseresistance,R*, of the diode can
be calculated:
R-:f
100v
0.05 pA
= 2 x l } eO o r 2 G O
SUMMARY
Semiconductoratoms have four valenceelectrons.Germanium (Ge) and Silicon (Si) are
both examplesof semiconductormaterials.Most diodes, transistors,and integratedcir-
cuits (ICs) are made fronr silicon. Semiconductorssuch as silicon are neither good con-
ductors nor good insulators.An intrinsic semiconductoris a pure semiconductormaterial
without any impurity atoms added to it. An extrinsic semiconductormaterial is a semi-
conductor material that has impurity atoms added to it during a process called doping.
Doping increasesthe conductivity of the semiconductormaterial.N-type semiconductors
have many free electronsas a result of the doping processwhile p-type semiconductors
have many holes.
A diode is a unidirectional device that allows current to flow through it in one di-
rection only. Diodes that are forward-biasedhave a low resistance,while diodes that are
reverse-biasedhave a very high resistance.When checking a silicon diode with an ana-
log ohmmeter,the ratio of reverseresistance,R^, to forward-resistance,R,o should be at
least 1000:1. The first approximation of a diode heats a forward-biaseddiode like a
closed switch with a voltage drop of zero volts. The secondapproximation of a diode
includes the barrier potential, Vr. For silicon diodes Va : 0.7 V. Both the first and sec-
ond approximationsof a diode treat a reverse-biaseddiode like an open switch with in-
finite resistance.The third approximationof a diode includes both the barrier potential,
Vo and the bulk resistance,rB, when forward-biased.The bulk resistance,rr, of a diode
is the resistanceof the p and n materials.The third approximation of a reverse-biased
diode also includes the reverseresistance,R^.
14 . CHAPTERI