100% found this document useful (1 vote)
595 views2 pages

Cbse Test Paper-05 CLASS - XII CHEMISTRY (Alcohols, Phenols and Ethers) (Answers) Topic:-Miscellaneous Question

The document is a CBSE test paper containing 10 multiple choice questions about alcohols, phenols, and ethers. It provides answers and explanations for each question. The questions cover topics such as: 1) denaturing alcohol with methanol, 2) uses of methanol, 3) relative solubility of alcohols, 4) products of phenol bromination reactions, 5) tests for detecting peroxides in ethers, 6) oxidation reactions of primary, secondary, and tertiary alcohols, 7) using Lucas reagent to distinguish alcohol types, 8) preparation of picric acid, 9) identifying wood spirit, and 10) ethanol production via fermentation.

Uploaded by

Shreyash Kolekar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
100% found this document useful (1 vote)
595 views2 pages

Cbse Test Paper-05 CLASS - XII CHEMISTRY (Alcohols, Phenols and Ethers) (Answers) Topic:-Miscellaneous Question

The document is a CBSE test paper containing 10 multiple choice questions about alcohols, phenols, and ethers. It provides answers and explanations for each question. The questions cover topics such as: 1) denaturing alcohol with methanol, 2) uses of methanol, 3) relative solubility of alcohols, 4) products of phenol bromination reactions, 5) tests for detecting peroxides in ethers, 6) oxidation reactions of primary, secondary, and tertiary alcohols, 7) using Lucas reagent to distinguish alcohol types, 8) preparation of picric acid, 9) identifying wood spirit, and 10) ethanol production via fermentation.

Uploaded by

Shreyash Kolekar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

CBSE TEST PAPER-05

CLASS - XII CHEMISTRY (Alcohols, phenols and Ethers)

[ANSWERS]
Topic:- Miscellaneous Question

1. Industrial alcohol (ethyl alcohol) is made unfit for drinking purpose by addition of a small
quantity of poisonous substance, methanol. This is called denatured alcohol. For denaturation,
copper sulphate or pyridine can also be added.

2. Uses of methanol:-
i) It is used for denaturing alcohol.
ii) It is used as a solvent for paints & varnishes.

3. The order is C2H5OH< H2O <C6H5OH.

4. The main product will be 2,4,6-tribromophenol.

5. Presence of peroxides in ethers is detected by addition of freshly prepared FeSO4 and KCNS.
Appearance of blood red colour confirms the presence of peroxide. They can be removed by
shaking ethers well with FeSO4 solution.

6. Primary tertiary and secondary alcohols can be distinguished by oxidation reaction.


Primary alcohols give aldehyde with CrO3

R C H 2 O H  C
rO 3
→ RCHO

Secondary alcohols give ketone with CrO3.

R 2 C H O H  C
rO 3
→ R 2CO

Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in


Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks
Tertiary alcohol do not get oxidized with CrO3

R3COH CrO
3 → No reaction

7. Lucas test is used for distinguishing between primary secondary and tertiary alcohols. When a
tertiary alcohol is dissolved in Lucas reagent (Conc. HCl + ZnCl2) it produces turbidity
immediately where as secondary alcohols produce turbidity after some time and primary
alcohols do not react at all and no turbidity is product.

8. Picric acid is 2,4,6 – trinitrophenol

It is prepared from phenol by nitration with conc. HNO3.

9. Wood spirit is methanol. It is so called because earlier it was obtained from destructive
distillation of wood only.

10. Ethanol can be prepared by fermentation of sugar –

C12 H 22 O11 + H 2 O  Invertase


 
enzymes
→ C 6 H 12 O 6 +C 6 H 12 O 6
Sugar Glucose fructose

C 6 H 1 2 O 6  en
 → 2C 2 H 5 O H + 2 C O 2
Z ym a se
zym es

E hano l
Material downloaded from http://myCBSEguide.com and http://onlineteachers.co.in
Portal for CBSE Notes, Test Papers, Sample Papers, Tips and Tricks

You might also like