Protective Coatings For Metals
Protective Coatings For Metals
COATINGS FOR
METALS
Presentation by : Ar. Navneet Singh
PROTECTIVE COATINGS
• Protective coatings and films on metals serve as barriers
between the environment and the underlying substance,
preventing the metal from corrosion and abrasion.
• Hot Dipping
Also known as galvanizing, this process involves dipping steel into hot zinc to form
a coating of zinc oxide layer.
This layer is resistant to rust, and will not flake off due to a metallurgic bond
between the substrate and the coating.
If later welded, the steel must be painted with a zinc paint to prevent rusting of the
joints.
• Electroplating
Involves immersing a metal component into a bath containing a dissolved metal –
typically cadmium, chromium, or nickel – and running an electrical current through
it.
This coats the item with a thin layer of metallic particles.
Uniform thickness is difficult to achieve with this method, and parts subject to
abrasion will need to be repeatedly coated.
• Chemical Process
Sometimes used for paint priming, metal coloring, and corrosion protection.
Involves creating a thin film of sulfide and oxide on a metal surface though
chemical reaction.
• Porcelain Enamel
Popular on cast-iron cookware and restroom partitions, as it protects against
both scratches and graffiti.
• Painting
Most popular of the different types of coatings, paints can be applied via a
handful of popular methods : e-coatings, powder coatings, and liquid coatings.
GALVANIZING
• Galvanizing is a process by which a layer of zinc is
applied to a ferrous metal to prevent corrosion.
• Zinc metal is generally used as a coating for protecting
iron and steel products from corrosion because it has
excellent corrosion resistance.
• The excellent field performance of zinc coatings results
from their ability to form dense, adherent corrosion
product films and a rate of corrosion considerably below
that of ferrous materials, some 10 to 100 times slower,
depending upon the environment.
• While a fresh zinc surface is quite reactive when
exposed to the atmosphere, a thin film of corrosion
products develops rapidly, greatly reducing the rate of
further corrosion (typically takes approximately 6-12
months to fully develop).
GALVANIZING
• In the hot dip galvanizing process, steel is dipped into hot zinc,
which forms a durable and thick layer on its surface to protect
it from corrosion.
• During galvanizing, the molten zinc reacts with the iron in the steel to
form a series of zinc/iron alloy layers.
ADVANTAGES
• Lower Initial Cost
• Durability
• Longevity
• Availability
• Sustainability
• Aesthetics
GALVANIZING
• Prior to immersion in the zinc bath, the steel is chemically
cleaned to remove all oils, greases, soil, mill scale, and
oxides.
• Surface preparation is critical as zinc will not react with
unclean steel.
• After surface preparation, the steel is immersed in the
molten (830 F) zinc bath.
• The bath consists of more than 98% pure zinc and the
remaining 2% or less consists of additives most commonly
aluminum, nickel.
• These additives help with zinc fluidity and consumption,
coating appearance, and other efficiencies.
• While in the galvanizing kettle, the molten zinc
metallurgically reacts with the iron in the steel to form the
coating.
GALVANIZING
• Hot-dip galvanized coatings are used on many
materials in construction sectors from electric
utility to artistic sculptures.
• Ranging in size from small parts such as nuts,
bolts and nails to large structural shapes,
galvanizing is integral to infrastructure.
• Most commonly batch hot-dip galvanizing is
used in atmospherically exposed steel; however,
it is also used in fresh and salt water
applications, buried in soil, embedded in
concrete, and much more.
• Size can be a limitation to the application of
hot-dip galvanizing; however, the average
length of zinc baths in is 40 feet and 55-60 foot
kettles are common.
Coating Characteristics
• The batch hot-dip galvanized coating consists of a series of
zinc-iron alloy layers with a surface layer of pure zinc.
• The unique intermetallic layers are tightly bonded (3,600
psi) to and harder than the base steel, offering excellent
abrasion resistance.
• The zinc-iron alloy layers, metallurgically bonded to the
steel, become an integral part of the steel rather than just a
surface coating.
• Another unique characteristic of the batch hot-dip
galvanized coating is its uniform, complete coverage.
• During the diffusion reaction in the kettle, the zinc-iron
alloy layers grow perpendicular to all surfaces.
• Additionally because hot-dip galvanizing is a total
immersion process, all interior surfaces of hollow structures
and difficult to access recess of complex pieces are coated.
• This complete, uniform coverage ensures critical points
where corrosion commonly starts have the same protection
as accessible, flat exterior surfaces.
GALVANIZING- Process
• There are three fundamental steps in the hot-dip
galvanizing process; surface preparation, galvanizing,
and inspection
Surface Preparation
• Pre-treatment is performed to provide a chemically clean surface.
• The steel then goes through a series of three cleaning steps; degreasing,
pickling, and fluxing.
• The final surface preparation step, fluxing, will remove any remaining
oxides and coat the steel with a protective layer to prevent any further
oxide formation prior to galvanizing.
• Proper surface preparation is critical, as zinc will not react with unclean
steel.
Galvanizing
• After surface preparation, the steel is
dipped in the molten (830 F) bath of at
least 98% zinc.
• The immersion time determines the
thickness of the zinc layer, which is
generally 1 to 2 min.
• Although the melting point of pure zinc is
419.5°C, the bath is maintained at 440–
470°C due to the operating conditions and
the additions of the other metals (nickel,
aluminium, copper, lead, iron, cadmium
and tin).
• The steel is lowered into the kettle at an angle that allows air to escape from tubular
shapes or other pockets, and the zinc to flow into, over, and through the entire piece.
• While immersed in the kettle, the iron in the steel metallurgically reacts with the
zinc to form a series of zinc-iron intermetallic layers and an outer layer of pure zinc.
Inspection
• The final step is an inspection of the coating.
• A very accurate determination of the quality of the coating can be achieved by a
visual inspection, as zinc does not react with unclean steel, which would leave an
uncoated area on the part.
• Additionally, a magnetic thickness gauge can be used to verify the coating thickness
complies with specification requirements.
Duplex Systems
• The combination of hot-dip galvanized steel
and paint or powder coating provide a
combined effect.
• The paint/powder extends the life of the
coating by providing an additional barrier
coating to the zinc layers, while the galvanized
steel prolongs the life of the paint coating by
preventing underfilm corrosion and peeling.
• The service life of a duplex system is 1.5 to 2.3
times the sum of the individual systems.
• For example, if the life of the galvanized
coating in a particular environment is 70
years, and the expected life of the paint is 10
years, the expected life of the duplex system
would be at least 120 years (1.5 x (70+10)).
Electroplating
• Electroplating can be defined as the deposit of a very thin layer of metal onto a base
metal in order to enhance or change its appearance.
• Unlike painting, where the new deposit is sprayed on, the chrome (and associated
materials) are applied through the use of an electrical current, hence the term
‘electroplating.’
• The baths are filled with a liquid that contains the desired metal dissolved within it —
which could be silver, gold, nickel or another metal.
• The metal item that is to be plated is submerged in the plating bath, and a low-voltage
DC current is applied to the bath.
• The electrolytic process then causes the dissolved metal ions to attach to the surface of
the metal to be plated.
• The thickness of the electroplated layer is determined by the time the item spends in the
plating bath while the current is being applied, and the amount of current used.
• Sometimes the shape and contour of the item can affect the thickness of the plated layer.
• Metal objects with sharp corners and edges will tend to have thicker plating on the
outside corners and thinner plating in the recessed areas. This is due to the corners
being more exposed, therefore attracting more particles.
Chrome Plating
• Chrome is a metal and one of the naturally occurring
chemical elements, otherwise known as Chromium.
• Firstly, the quality of the base material is assessed as well as the desired result of the finish.
• Then the base materials are stripped to reveal the bare metal and all dirt, oil, paint, rust and old
plating is removed.
• After that the bare metal is polished using sanding belts and abrasive wheels to remove any
pitting, scratches and impurities for a smooth finish.
• Subsequently the surgical cleaning process is applied using soap, acid and water solutions which
is essential before plating as any foreign matter can cause the plating to reject.
• Then the object is placed into the chrome plating vat, where it warms to solution temperature and
the electroplating process takes place.
• Chrome plating uses an electrolytic process that applies chromium plating to a metal component
in an electrolytic bath at a rate of about 25 to 30 microns per hour. The substrate first gets
cleaned thoroughly and, if necessary, treated with chemicals to improve the adhesion of the
plating.
• The component then goes into a chrome plating vat, where an electric current deposits chromium
onto the substrate.
• The length of time it is placed in the solution corresponds to the desired thickness of plating.
• Lastly, the parts are cleaned and polished again and inspected for quality and finish.
Applications
Chrome plating is typically applied to everyday household
items and automotive parts including:
• Door knobs, handles and letterboxes
• Shower fittings, bathroom taps and toilet flush, chains,
towel rings and roll holders.
• Interior and exterior lighting
• Interior and exterior car parts
• Motorcycle parts
• Moulds and press tools
• Valves and pumps
• In summary, chrome plating is essential for objects that
need to resist rusting, scratches and other imperfections.
Types of chrome plating
• HARD CHROME PLATING : With hard chrome plating, a thick
deposit of chromium metal is plated onto steel components to
improve surface hardness and wear resistance. Hard chrome
plating is often used on tools and dies where increasing tool life
through improved wear resistance is important.
• DECORATIVE CHROME PLATING a thin layer of chromium is
applied as a decorative topcoat to stainless steel and nickel-plated
components. In this plating application, the thin chromium layer
protects the nickel from oxidation and tarnish while providing the
bright bluish tint as bright decorative chrome.
DECORATIVE (BRIGHT) CHROME PLATING PROCESS
• Decorative chrome plating is the process of depositing a thin
layer of chromium over nickel-plated components as a decorative
(bright) finish. The nickel surface keeps its intended finish longer,
increases its wear ability, provides another layer of protection and a
simpler cleaning process.
• Decorative chrome electroplating is sometimes referred to as nickel-
chrome plating, as it always involves electroplating nickel on the
object before plating chrome.
• Chrome electroplating is an exceptionally thin layer (sometimes 50
millionth of an inch) applied over the nickel.
Common Applications of Hard Chrome
Plating
• Steel
• Stainless Steel
• Cast Iron
• Copper
• Brass
• Bronze Alloys
• Nickel Alloys
Decorative Chrome Plating
• Decorative chrome plating is primarily an aesthetic feature, though it also protects
against corrosion and wear.
• However, because decorative chrome is so thin — ranging from about five to eight
micrometers when applied over nickel plating — it does not offer as much durability
as hard chrome plating.
• Provide a thin protective coating when applied to automobile parts, tools and
utensils
• Protects against rust and wear when products get exposed to wet or corrosive
conditions
Common Applications
Car parts
Tools
Kitchen utensils
Musical instrument hardware
Knobs
Hardware
Bathroom accessories
Tiles
Decorative Chrome Plating
• It requires nickel plating (up to two layers) prior to the
application of the chromium plating.
• While it’s called “chromium plating”, the underlying
layer of nickel is what provides this coating with
practically all of its trademark reflectivity, smoothness,
and much of its corrosion resistance.
• Nickel adheres extremely well to copper, so it’s not
uncommon to have copper and nickel plating before the
final layer of chromium is added.
Advantages
Improved appearance
Corrosion resistance
Easy cleaning
Some wear resistance ( as compared to base metal)
DIFFERENT CHROME PLATING FINISHES
ANODIZING
• Anodizing is an electrolytic process which provides a
metal with a protective and decorative surface,
enhancing its visual appeal and working qualities.
• This reaction causes the crystal structure on the anode’s surface to change
and a layer of oxide is deposited on the surface of the metal, or in other words
anode.
• The process also allows a user to have control over it, allowing for
manipulation of the thickness of the film formed and other features of the end
result anodized metal.
• As the metal plays the role of an anode in the process, the entire process is
therefore known as anodizing.
• Anodized metals tend to be porous due to their thick coatings, and therefore
require a sealing process to ensure that they are corrosion resistant.
• Anodic films are used to make anodized finishes more durable, which allows
the metals to be post treated with paints and dyes.
POWDER COATING
• Preparation
• The process for preparing each part will depend on the base material,
metals, and other materials like fiberglass.
• In general, the part will be thoroughly cleaned to remove any oil or grease
on the surface, and then rinsed.
• Next, the part is etched. This helps remove any surface oxides and
provides more surface area for the powder coating to stick to.
• Safety – Safely applying powder coating requires precautionary measures to avoid breathing in the
powder and getting it on one’s skin. This is an easier task to manage since the product is a solid and
inert (it doesn’t pose a health risk when not being sprayed). The product does not contain harmful
chemicals such as solvents or volatile organic compounds (VOC) that are often found in wet paint.
• Environmental – Since there are no solvents or VOCs, there is no damage to the environment
during application. The waste is also not hazardous and can be disposed in the landfill. Wet paint
contains harmful chemicals that have been proven to deplete the ozone and produces hazardous
waste that needs to be disposed of in an appropriate manner.
• Mechanical – Powder coating generally produces a coating twice as thick as standard paint. The
real advantage is its flexibility and ability to bend and yield with the material it is applied to.
• Production Advantages – The main advantage from a production point of view is that when the
powder coated product comes out of the oven it is completely cured within 20min and ready to be
put to work. Standard liquid paints can take days to completely cure and depend on the
atmospheric conditions.
• Aesthetics: Powder coating allows for much thicker coatings than liquid paint, without running or
sagging. With liquid paint, horizontal and vertical painted surfaces often have differences in
appearances, but powder coating typically provides a uniform visual appearance regardless of
orientation.
POWDER COATING-
Disadvantages
The main concerns with powder coating are:
• These hybrids remain closely related to pure epoxies but offer superior
weather degradation properties.
• The polyester will enhance the overbake resistance when compared with a
straight epoxy and they also create ultra-smooth, thin films.
• The combination of the resins can also make them more economical than a
pure epoxy.
• The polyester does reduce the corrosion and chemical resistance of the
epoxies and doesn’t really add any outdoor weatherability to the product.
• Hybrids are widely used on items that require good cosmetic appeal along
with good functional properties. Hybrids can be used in some of the same
areas that epoxies are used, but are typically found on indoor appliances
and other household items like furniture, shelving, interior lighting, and
power tools.
POWDER COATING
Fluoropolymers
• Fluoropolymers are typically used in architectural markets due to
their phenomenal weathering properties and color and gloss
retention.
• Their corrosion resistance and excellent weatherability make them
extremely popular for exterior architectural applications like
curtain wall, windows, doors and more.
• The two most common types of Fluoropolymers found in powder
coatings are FEVE and PVDF.
• PVDF Fluoropolymers always need a primer beneath them –
whether liquid or powder and are much more difficult to bond
when creating metallic powders.
• FEVE resins are the most popular within the powder community
for their superior one coat capability and incredible exterior
performance.
• FEVE based Fluoropolymer metallics can also be bonded so
that when applied, the metallic flake is more evenly distributed
throughout the powder for a more consistent appearance.
POWDER COATING
Urethanes
• They are used on door knobs, oven knobs and other such
applications because fingerprints are not as visible.
• Steel is one of the most commonly used metals in overhead cranes and material handling systems.
That’s because metals like steel are strong, cost effective, and easy to manipulate. However, steel is
also prone to rust in almost any environment, especially when used for caustic applications or if
exposed to harsh conditions.
• To protect your crane system from rust and corrosion, most manufacturers provide options for
protective coatings and paint finishes. Knowing which protective coating will best suit your operation
is important to extend the lifetime of your new system. Here, we will explore several protective
coating and paint finish options for overhead crane systems, and outline the advantages and
recommended applications for each.
• To begin, it can be helpful to know that there are three main paint classifications, which we will
reference in this post: primers, intermediates, and finish coats. Primers are used to wet and adhere
to the substrate (the steel surface or underlying metal) and act as an inhibitor to hinder corrosion.
Intermediates are used to build film thickness. And, the finish coat offers aesthetic value, but it also
provides surface resistance. Depending on the conditions of exposure, it must act as the first line of
defense against weather and sunlight, open exposure and condensation.
• In addition, there are also four types of protective coatings for metal: barrier, inhibitive, sacrificial,
and combination.
• Barrier coatings protect metal by preventing water, oxygen, and electrolyte from coming in contact
with the underlying metal. Inhibitive coatings contain chemicals that hinder corrosion. They react
with the cathode, anode, or other components (oxygen, electrolyte, acid). Sacrificial coatings provide
galvanic protection. In other words, they corrode (sacrifice) instead of the underlying metal,
providing electrons, which reverses the corrosion cell and transforms anodes to cathodes.
• POWDER COATING
• Powder coating involves the application of a dry powdered paint compound made of pigments,
specialized resins, and fillers that melt and fuse together during the curing process to form a painted
finish. The solid powder particles are electrostatically charged using a low-velocity air powered spray
gun. This electrostatic charge attracts paint particles to the substrate surface and holds them in
place during the high temperature curing process. Conventional liquid paint requires a solvent to
keep the binder and filler parts in a liquid suspension form. But, dry powder is applied
electrostatically and cured under heat to allow it to form a protective barrier around the metal
substrate. The powder is usually used to create a hard finish that is tougher than conventional paint.
• Powder coating can be relatively expensive, but it is high impact resistant, which means that it
eliminates chipping and scratching. It is most commonly used for applications that involve impact
and particle abrasion, and it extends the life of your crane in caustic environments.
• Powder coating does offer the added benefit of decorative variety because it comes in standard or
custom colors. It also comes in various textures including smooth, wrinkled, matte, and rough.
Powder coating systems are resistant to heat, corrosion, impact, abrasion, most chemicals, and
solvents. They are also resistant to fading from sunlight and UV exposure.
• Powder coating is environmentally friendly because it doesn’t contain volatile organic compounds
(VOC’s), which are pollutants found in the solvents used in liquid paint finishes. They eliminate the
need for users to buy and maintain costly pollution control equipment, which saves money in the long
run.
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Liquid paints
When it comes to paints, liquid is still beneficial in many cases. In spite
of advances in coatings technology, liquid paint remains the optimal
choice for several situations, such as when:
• The project requires lower cure temperatures
• A process requires faster color changes
• A project requires more color variation
• Products require special masking
• Smoother coats are desired
• The most obvious benefit for wet coatings is probably the fact that this
method affords so much color variety. Especially useful in specialty
markets, the many shades and specialty coatings create far more
choices. Indeed, using liquid paint means you have the option for Teflon
and even glow-in-the-dark coatings
Powder Coating
• Some situations require the advantages of powder coatings, a
technique which involves electrostatically charging the paint
pigment powder to cause adhesion to the substrate.
• The powder coating process allows for little-to-no waste. Any powder
not adhered to the target surface is collected and re-used. Because
the paint contains no solvents, virtually no Volatile Organic
Compounds (VOCs) are released into the atmosphere as the paint
ages.
• The technology requires less training than other methods, but the
associated operation and energy costs are higher. However, this
method allows more control over the film thickness. Additionally,
this application is an excellent choice where durability and scratch
resistance is important.
NON-METALLIC COATINGS
• These are available in a wide variety of colours and include:
Paints
Baked Epoxy Finishes
Vinyl Coatings
Bituminous Coatings
Vitreous Enamel Coatings
• Baked epoxy finishes are applied to zinc-aluminium coated steel
which is chemically treated to assist bonding. An epoxy primer and
then the final colour coat are baked on separately. This type of
finish is popular for domestic and commercial roofing and wall
cladding for normal conditions.
• In marine and polluted industrial conditions steel can be coated
with a tough vinyl which is laminated to the steel substrate. The
vinyl coating locks out moisture, making an extremely corrosion-
resistant finish.
• Vitreous enamel coatings comprise a layer of glass fused to a
properly prepared steel base.
• Painting should be considered as a complete system that includes
surface preparation, pre-treatment to facilitate adhesion, primer,
intermediate coat or coats and finish coat. Different types of steel
require different pre-treatments and coatings.
• Bituminous coatings are based on bituminous resins such as coal
tar or asphalt. The bituminous resins perform well underground
and in contact with water but do not have good weather durability
when exposed to sunlight.
• Surface working
• cleaning blasting the surface with sand, grit, or steel shot through a nozzle by
air pressure.