Page 1/6

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Product name: DPD No.1
· Catalog number:
00511051, 511001BT, 511002BT, (4)511050BT, (4)511051BT, (4)511052BT, 511000BT, 00511059BT, 00511009BT
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Application of the substance / the preparation: Reagent for water analysis
· 1.3 Details of the supplier of the safety data sheet
· Supplier:
Tintometer GmbH
Schleefstr. 8-12
DE-44287 Dortmund phone: +49 (0) 231 945100
Made in Germany E-Mail: [email protected]
www.lovibond.com
· Informing department:
e-mail: [email protected]
Product Safety Department
· Contact for technical details:
Technical Department
e-mail: [email protected]
· 1.4 Emergency telephone number:
Poison Center Berlin, Germany
phone: 0049-30 30686 790
Languages: English and German

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The product is not classified as hazardous according to the CLP regulation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· 2.3 Other hazards No further relevant information available.
· Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be persistent, bioaccumulative and toxic (PBT) or very
persistent and very bioaccumulative (vPvB), according to the criteria given in Annex XIII of Regulation (EC) No. 1907/2006.

SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of organic and inorganic compounds
· Dangerous components: Void

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation Supply fresh air.
· After skin contact Instantly wash with water and soap and rinse thoroughly.
(Contd. on page 2)
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 Page 2/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

Product name: DPD No.1

(Contd. of page 1)
· After eye contact
Rinse opened eye for several minutes under running water (at least 15 min). If symptoms persist, consult doctor.
· After swallowing
Rinse out mouth and then drink 1-2 glasses of water.
In case of persistent symptoms consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed:
after swallowing:
thirst
gastric or intestinal trouble
sickness
gastric pain
general feeling of sickness
irritations
cardiovascular disorders
· 4.3 Indication of any immediate medical attention and special treatment needed: No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents Use fire fighting measures that suit the environment.
· 5.2 Special hazards arising from the substance or mixture
The product is not combustible.
Formation of toxic gases is possible during heating or in case of fire.
nitrous gases
Sulphur oxides (SOx)
nitrogen oxides (NOx)
Phosporus oxides (PxOx)
Dipotassium oxide
Sodium oxide
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
· Additional information
Collect contaminated fire fighting water separately. It must not enter drains.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Ambient fire may liberate hazardous vapours.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
· Advice for non-emergency personnel: No special measures required.
· Advice for emergency responders: Protective equipment: see section 8
· 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies.
· 6.3 Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Collect mechanically.
Dispose of contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
· Advice on safe handling: No special precautions necessary if used correctly.
· Hygiene measures:
The usual precautionary measures should be adhered to general rules for handling chemicals.
Wash hands during breaks and at the end of the work.
Do not eat, drink or smoke when using this product.
(Contd. on page 3)
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 Page 3/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

Product name: DPD No.1

(Contd. of page 2)

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage
· Requirements to be met by storerooms and containers: Store in cool location.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Storage class 13
· Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
Protect from the effects of light.
Store under dry conditions.
Protect from humidity and keep away from water.
This product is hygroscopic.
· Recommended storage temperature: 20 °C +/- 5 °C
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the
workplace.
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Engineering measures:
Technical measures and appropriate working operations should be given priority over the use of personal protective
equipment.
See item 7.
· Personal protective equipment
· Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
· Recommended filter device for short term use: Filter P1
· Protection of hands:
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves
nitrile rubber, NBR
Recommended thickness of the material: ≥ 0.11 mm
· Penetration time of glove material
Value for the permeation: Level = 1 ( < 10 min )
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
Safety glasses
use against the effects of fumes / dust
· Body protection: Protective work clothing.
· Limitation and supervision of exposure into the environment: No further relevant information available.

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· Appearance:
· Form / Physical state: Tablets
· Colour: White
· Odour: Odourless
· Odour threshold: Not applicable
· pH-value (13.5 g/l) at 20 °C: 6.3
· Melting point/Freezing point: Not determined
· Initial boiling point and boiling range: Not determined
(Contd. on page 4)
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 Page 4/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

Product name: DPD No.1

(Contd. of page 3)

· Flash point: Not applicable

· Flammability (solid, gas): The product is not combustible.
· Ignition temperature: Not applicable
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not self-igniting.
· Explosive properties: Product is not explosive.
· Flammability or explosive limits:
· Lower: Not applicable
· Upper: Not applicable
· Oxidising properties: none
· Vapour pressure: Not applicable.
· Density: Not determined
· Relative density: Not determined.
· Vapour density: Not applicable.
· Evaporation rate: Not applicable.
· Solubility(ies):
· Water: Soluble
· Partition coefficient (n-octanol/water): Not applicable.
· Viscosity: Not applicable.
· Solvent content:
· Organic solvents: 0.0 %
· Solids content: 100.0 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity Dust can combine with air to form an explosive mixture.
· 10.2 Chemical stability Stable at ambient temperature (room temperature).
· 10.3 Possibility of hazardous reactions
Reacts with acids, alkalis and oxidizing agents
--> forms heat
Reacts with ammonia (NH₃).
· 10.4 Conditions to avoid Strong heating (decomposition)
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: see section 5

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Information on components: CAS 6283-63-2: DPD may cause allergic skin reaction
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Information on components: CAS 6283-63-2: Sensitization possible in predisposed persons.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) The following statements refer to the mixture:
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT (specific target organ toxicity) -single exposure Based on available data, the classification criteria are not met.
· STOT (specific target organ toxicity) -repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
(Contd. on page 5)
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 Page 5/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

Product name: DPD No.1

(Contd. of page 4)

· Additional toxicological information:

When used and handled according to specifications, the product does not have any harmful effects according to our
experience and the information provided to us.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· Bacterial toxicity: sulphates toxic > 2.5 g/l
· Other information:
Toxic for fish:
sulphates > 7 g/l
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· 12.5 Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be persistent, bioaccumulative and toxic (PBT) or very
persistent and very bioaccumulative (vPvB), according to the criteria given in Annex XIII of Regulation (EC) No. 1907/2006.
· 12.6 Other adverse effects
Depending on the concentration, phosphorus and/or nitrogen compounds may contribute to the eutrophication of water supplies.
· Water hazard:
Mixture (Self-assessment acc. VwVwS Annex 4, German regulation):
Water hazard class 2: hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Danger to drinking water if even small quantities leak into soil.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
16 05 09 discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR,RID, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR,RID, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR,RID, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR,RID, IMDG, IATA Void
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of Marpol and
the IBC Code Not applicable.
(Contd. on page 6)
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 Page 6/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 13.05.2016 Version number 4 Revision: 13.05.2016

Product name: DPD No.1

(Contd. of page 5)

· Transport/Additional information: Not dangerous according to the above specifications.

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Regulation (EC) No 689/2008 concerning the export and import of dangerous chemicals:
None of the ingredients is listed.
· Regulation (EC) No 1005/2009 on substances that deplete the ozone layer:
None of the ingredients is listed.
· Directive 2012/18/EU (SEVESO III):
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Information about limitation of use: Not required.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
· Training hints Provide adequate information, instruction and training for operators.
· Abbreviations and acronyms:
OECD: Organisation for Economic Co-operation and Development
STOT: specific target organ toxicity
SE: single exposure
RE: repeated exposure
EC50: half maximal effective concentration
IC50: hallf maximal inhibitory concentration
NOEL or NOEC: No Observed Effect Level or Concentration
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous
Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of
Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
SVHC: Substances of Very High Concern

· Sources Data arise from safety data sheets, reference works and literature.
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