AZAS TEKNIK KIMIA II

PERTEMUAN KE EMPAT TENTANG VAPORIZATION AND

COOLING OF MIXTURE
DODY GUNTAMA, ST., M.ENG
Kerjakan di kelas: campuran senyawa
Tentukan Panas yang diperlukan untuk menaikkan
suhu 100 mol/jam campuran 50% Air dan 50 %
etanol dari 25 oC menjadi 150 oC.
Data dari Tabel B.1:

Senyawa bp (oC) ΔHv (kJ/mol)

Air 100 40,656
etanol
Data 78,5
dari Tabel B.2: 38,58

Senyawa a b c d
Air (l) 75,4x10-3
Air (g) 33,46x10-3 0,688x10-5 0,7604x10-8 -3,593x10-12
Etanol (l) 103,1x10-3
Etanol (g) 61,34x10-3 15,72x10-5 -8,749x10-8 19,83x10-12
Jawaban slide 2
n= 100 mol
T1 = 25 oC

T2 = 150 oC

100 150
ΔH𝑎𝑖𝑟 = n 25
𝐶𝑝 𝑑𝑇 + 𝑛. Δ𝐻𝑣 + 𝑛 100
𝐶𝑝 𝑑𝑇

78,5 150
ΔH𝑎𝐿𝐾𝑂𝐻𝑂𝐿 = n 25
𝐶𝑝 𝑑𝑇 + 𝑛. Δ𝐻𝑣 + 𝑛 78,5
𝐶𝑝 𝑑𝑇

Q1 = n.cp dT (kJ) Q2 = n.ΔHv (kJ) Q3 = n.cp dT (kJ) Qi = Q1+Q2+Q3

Senyawa

H2O 282,75 2032,8 86,08274596 2401,632746

C2H5OH 275,7925 1929 279,3979877 2484,190488

Q= 4886
Example: vaporization and cooling of mixture:
An equimolar liquid mixture of benzene (B) and toluene (T) at 10 oC is
fed continuously to a vessel in which the mixture is heated to 50 oC.
The liquid product is 40.0 mole% B, and the vapor product is 68.4
mole% B. How much heat must be transferred to the mixture per mole
of feed?
Substances bp (oC) ΔHv (kJ/mol)
From
C6H6 the Table B.1: 80,1 30,765
C7H8 110.62 33,47

Substances a b c d
From
C6H6(l)the Table B.2: -3
126,5x10 23.4x10-5 0 0
C7H8(l) 148,8x10-3 32,4x10-5 0 0
C6H6(v) 74,06x10-3 32,95x10-5 -25,20x10-8 77,57x10-12
C7H8(v) 94,18x10-3 38x10-5 -27,86x10-8 80,33x10-12
 50 bp 50
Q  H  n  Cpm (l ).dT  n  Cpm (l ).dT  n  Cpm (v).dT
10 10 bp
50 50 bp 50
 n  cp.dTbenzen ( l )  n  cp.dTtoluen ( l )  n  cp.dTbenzen ( l )  n.H v ,benzen  n  cp.dTbenzen ( v )
10 10 10 bp
bp 50
 n  cp.dTtoluen ( l )  n.H v ,toluen  n  cp.dTtoluen ( v )
10 bp
Mass Balance:
V mol50°C, 34.8 mm Hg =0,46 atm
0.684 C6H6
Basis : 1 mol feed 0.316 C7H8

Subtitusi (1) ke (2):

Feed , 1 mol, 10°C 0,5 = 0,684 (1-L) + 0,4L
Distilatio 0,5 = 0,684 – 0,684L+0,4L
0,184 = 0,284 L
0.5 C6H6 n L = 0,648 mol
0.5 C7H8
V =0,352 mol

Neraca Total:
1=V+L L mol 50°C, 34.8 mm Hg
V=1–L (1) 0.4 C6H6
Neraca Benzen 0. 6 C7H8
0,5 = 0,684V + 0,4 L (2)
Energy Balance
Basis 1mol T reference = 10 oC

input output
Senyawa
n(mol) H (kJ/mol) n(l) (mol) H kJ n(v) (mol) H,KJ n.ΔHv,KJ H,KJ ΔH TOTAL

C6H6 (l) 0,5 0 0,2592 H1

C7H8 (l) 0,5 0 0,3888 H2

C6H6 (v) 0,240768 H3 H7 H5 H3+H7+H5=(A)

C7H8 (v) 0,111232 H4 H8 H6 H4+H8+H6=(B)

0,648C=H1+H2 0,352 A+B

QTOTAL A+B+C

input output
Senyawa
n(mol) H (kJ/mol) n(l) (mol) H ,kJ n(v) (mol) H ,kJ n. ΔHv , kJ H,KJ ΔH TOTAL
C6H6 (l) 0,5 0 0,2592 1,3843354
C7H8 (l) 0,5 0 0,3888 2,465303
C6H6 (v) 0,240768 2,31296745 7,4072275 -0,68435325 9,03584172
C7H8 (v) 0,111232 1,88409379 3,722935 -0,82845184 4,778576984
SUM 3,8496384 4,19706123 11,130163 -1,51280509 13,8144187
Steam 17,6640571
SOAL TUGAS DIKUMPUL MELALUI EMAIL KARENA EXCEL
Campuran cair equimolar dari benzene (B) dan toluene pada 10 °C
diumpankan terus menerus ke menara distilasi di mana campuran
dipanaskan sampai 50 °C. Produk vapor yang di inginkan 100 mol terdiri
dari 70 mole% B dan 30 % mol toluene, produk cair sebesar 40 mole % B
dan sisanya merupakan toluen. Berapa banyak panas yang harus
ditransfer ke campuran per mol umpan?
From the Table B.1:
Substances bp (oC) ΔHv (kJ/mol)
C6H6 80,1 30,765
C7H8 110.62 33,47
From the Table B.2:
Substances a b c d
C6H6(l) 126,5x10-3 23.4x10-5 0 0
C7H8(l) 148,8x10-3 32,4x10-5 0 0
C6H6(v) 74,06x10-3 32,95x10-5 -25,20x10-8 77,57x10-12
C7H8(v) 94,18x10-3 38x10-5 -27,86x10-8 80,33x10-12
SOAL: Kerjakan Di kelas
100 mol
0.7 C6H6
0.3 C7H8

F1 mol,
Distilation
0.5 C6H6
0.5 C7H8

F2 mol
0.4 C6H6
0.6 C7H8