Material Safety Data Sheet
Carbol Fuchsin
ACC# 91760
Section 1 - Chemical Product and Company Identification
MSDS Name: Carbol Fuchsin
Product Grade :
Catalog Numbers: 39164
Synonyms: Carbol Fuchsin Powder
Company Identification:
Fisher Scientific
Part of Thermo Fisher Scientific
THERMO ELECTRON LLS INDIA PVT.LTD.
Godrej Coliseum, 101A-101B, Somaiya Hospital Road,
Off Eastern Express Highway, Sion (East), Mumbai-400 022, India
For information, call: 022 – 6680 3001/2, Call India Toll Free – 1 800 209 7001
Emergency Number: 022-66803004/14
For CHEMTREC assistance, call: 800-424-9300 [International]
For International CHEMTREC assistance, call: 703-527-3887 [International]
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
108-95-2 Phenol 8.0 203-632-7
4197-24-4 Carbol Fuchsin Balance 224-086-6
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: dark green crystalline powder.
Danger! Toxic if absorbed through the skin. Toxic if swallowed. Corrosive. Causes
severe eye and skin irritation with possible burns. May cause severe respiratory tract
irritation with possible burns. May cause severe digestive tract irritation with possible
burns. Light sensitive. May cause liver and kidney damage.
Target Organs: Kidneys, liver.
Potential Health Effects
Eye: Causes severe eye irritation and possible burns. May cause chemical conjunctivitis
and corneal damage.
Skin: Toxic in contact with skin. Causes severe skin irritation and possible burns. May
cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion: May cause severe and permanent damage to the digestive tract. Poison by
ingestion. Causes gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation: Causes severe irritation of upper respiratory tract with coughing, burns,
breathing difficulty, and possible coma. Aspiration may lead to pulmonary edema. May
cause systemic effects.
Chronic: Prolonged or repeated skin contact may cause dermatitis. May cause liver and
kidney damage. May cause cancer according to animal studies. Effects may be delayed.
Section 4 - First Aid Measures
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash clothing before
reuse. Destroy contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of
milk or water. Never give anything by mouth to an unconscious person. Get medical aid
immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration using oxygen and a
suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media: Use water fog, dry chemical, carbon dioxide, or regular foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from
light. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store protected from light. Store in a
cool, dry area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
5 ppm TWA; Skin -
potential significant
5 ppm TWA; 19 mg/m3 5 ppm TWA; 19 mg/m3
Phenol contribution to overall
TWA 250 ppm IDLH TWA
exposure by the
cutaneous r oute
Carbol Fuchsin none listed none listed none listed
OSHA Vacated PELs: Phenol: 5 ppm TWA; 19 mg/m3 TWA Carbol Fuchsin: No OSHA
Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and
ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever
workplace conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
Physical State: Crystalline powder
Appearance: dark green
Odor: phenol-like
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Light, dust generation, excess heat.
Incompatibilities with Other Materials: Oxidizing agents, strong bases, strong acids.
Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon
monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
RTECS#:
CAS# 108-95-2: SJ3325000
CAS# 4197-24-4 unlisted.
LD50/LC50:
CAS# 108-95-2:
Draize test, rabbit, eye: 5 mg Severe;
Draize test, rabbit, skin: 500 mg/24H Severe;
Draize test, rabbit, skin: 100 mg Mild;
Inhalation, mouse: LC50 = 177 mg/m3;
Inhalation, mouse: LC50 = 177 mg/m3/4H;
Inhalation, rat: LC50 = 316 mg/m3;
Inhalation, rat: LC50 = 316 mg/m3/4H;
Oral, mouse: LD50 = 270 mg/kg;
Oral, rat: LD50 = 317 mg/kg;
Oral, rat: LD50 = 512 mg/kg;
Skin, rabbit: LD50 = 630 mg/kg;
Skin, rat: LD50 = 669 mg/kg;
Skin, rat: LD50 = 1500 mg/kg;
.
CAS# 4197-24-4:
.
Carcinogenicity:
CAS# 108-95-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 4197-24-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:
Section 12 - Ecological Information
Ecotoxicity: Fish: Pseudomonas putida:
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 108-95-2: waste number U188.
Section 14 - Transport Information
US DOT Canada TDG
DOT regulated - small quantity
Shipping Name: No information available.
provisions apply (see 49CFR173.4)
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 108-95-2 is listed on the TSCA inventory.
CAS# 4197-24-4 is not listed on the TSCA inventory. It is for research and
development use only.
Health & Safety Reporting List
CAS# 108-95-2: Effective 6/1/87, Sunset 6/1/97
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 108-95-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 108-95-2: 500 lb lower threshold TPQ; 10000 lb upper threshold TP Q
SARA Codes
CAS # 108-95-2: immediate, delayed, fire.
Section 313
This material contains Phenol (CAS# 108-95-2, 8.0%),which is subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 108-95-2 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 108-95-2 is listed as a Hazardous Substance under the CWA. CAS# 108-95-2
is listed as a Priority Pollutant under the Clean Water Act. CAS# 108-95-2 is listed as
a Toxic Pollutant under the Clean Water Act.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 108-95-2 can be found on the following state right to know lists: California,
New Jersey, Pennsylvania, Minnesota, Massachusetts.
CAS# 4197-24-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 34 Causes burns.
R 24/25 Toxic in contact with skin and if swallowed.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 108-95-2: 2
CAS# 4197-24-4: No information available.
Canada - DSL/NDSL
CAS# 108-95-2 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all of the information required by those
regulations.
Canadian Ingredient Disclosure List
CAS# 108-95-2 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
MSDS Creation Date: 3/13/2001
Revision #5 Date: 3/25/2008
The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
