Safety Data Sheet

HEMPADUR ZP PRIMER 17309

Globally Harmonized System of Classification and Labelling of Chemicals - Middle East

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : HEMPADUR ZP PRIMER 17309
Product identity : 1730921780
Product type : epoxy primer (base for multi-component product)

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry buildings, ships and shipyards.
Ready-for-use mixture : 17300 = 17309 5 vol. / 95010 1 vol.
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Hempel Paints (Saudi Arabia) W.L.L. Hempel Paints (Qatar) W.L.L. Emergency telephone number
P.O. Box 1077, Dammam 31431 Block 212, Street 16, Salwa Industrial Area (with hours of operation)
Kingdom of Saudi Arabia P.O. Box 3484, Doha, State of Qatar
Tel.: +966 3 8471616 Tel: +974 44 55 9000 The Regional Poison Control Center, Dammam
(DPCC) Tel.: +966 55 388 0087 (24 hrs)
Hempel Paints (Saudi Arabia) W.L.L. Hempel Paints (Kuwait) K.S.C.C.
P.O. Box 6783, Jeddah 21452 P.O. Box 3400, Safat 13034, Kuwait HAAD Poison and Drug Information Center
Kingdom of Saudi Arabia Tel.: +965 4813366 / 808828 Tel.: 800-424 (7:00 - 15:00 Sunday - Thursday)
Tel.: + 966 12 257 4567
Hempel Paints (Abu Dhabi) L.L.C. See Section 4 of the safety data sheet (first aid
Hempel Paints (Emirates) L.L.C. Plot No 37, Sector M-15, measures).
Interchange 8, Al Dhaid Road, Mussafah Industrial Area,
Plot 698/G, Saja’a Area, P.O. Box 47006, Abu Dhabi,
P.O. Box 2000, Sharjah, United Arab Emirates
United Arab Emirates Tel: +971 2 555 2279
Tel: +971 6 531 0140
[email protected] Hempel (Oman) L.L.C.
Ghala Industrial Area, Besides Komatsu,
Hempel Paints (Bahrain) S.P.C. Building No 1280, Way No 5217
P.O.. Box 997, Manama P.O. Box 1260, PC 112, Muscat
Kingdom of Bahrain Sultanate of Oman
Tel.: +973 17 728 668 Tel: +968 24592759

Date of issue : 4 November 2019

Date of previous issue : 23 October 2019.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
GHS Classification
FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 2
AQUATIC HAZARD (ACUTE) - Category 3
AQUATIC HAZARD (LONG-TERM) - Category 2
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

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SECTION 2: Hazards identification

Hazard statements : H226 - Flammable liquid and vapor.
H318 - Causes serious eye damage.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H361 - Suspected of damaging the unborn child.
H373 - May cause damage to organs through prolonged or repeated exposure. (hearing organs)
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Keep cool.
Hazardous ingredients : middle molecular epoxy resin MMW 700-1200
butan-1-ol
ethylbenzene
toluene

2.3 Other hazards

Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
.

Product/ingredient name Identifiers % GHS Classification

middle molecular epoxy resin MMW 25068-38-6 ≥10 - ≤25 SKIN CORROSION/IRRITATION - Category 2
700-1200 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
xylene 1330-20-7 ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
Solvent naphtha (petroleum), light 64742-95-6 ≥5 - ≤7.5 FLAMMABLE LIQUIDS - Category 3
arom. SKIN CORROSION/IRRITATION - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
butan-1-ol 71-36-3 ≥5 - ≤7.5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
1,2,4-trimethylbenzene 95-63-6 ≥3 - ≤4.9 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
AQUATIC HAZARD (LONG-TERM) - Category 2
ethylbenzene 100-41-4 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
(hearing organs) - Category 2
ASPIRATION HAZARD - Category 1
trizinc bis(orthophosphate) 7779-90-0 ≤1 AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
toluene 108-88-3 ≤0.3 FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3

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SECTION 3: Composition/information on ingredients

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
- Category 2
ASPIRATION HAZARD - Category 1
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 or 999 and give
immediate treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

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SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated
compounds metal oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and
amine containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

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SECTION 7: Handling and storage

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

solvent naphtha (petroleum), light arom. EU OEL (Europe).

TWA: 120 mg/m³ 8 hours. Form: Tentativ
TWA: 25 ppm 8 hours. Form: Tentativ
xylene EU OEL (Europe, 2/2017). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
ethylbenzene EU OEL (Europe, 2/2017). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
toluene EU OEL (Europe, 2/2017). Absorbed through skin.
TWA: 192 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
STEL: 384 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)

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SECTION 8: Exposure controls/personal protection

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : 1580°C This is based on data for the following ingredient: barium sulphate
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 26°C (78.8°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Flammable in the presence of the following materials or conditions: oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Lower and upper explosive 0.8 - 11.3 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.637 g/cm³
Solubility(ies) : Partially soluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: 280 - 470°C (536 - 878°F) (Solvent naphtha (petroleum), light arom.).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Testing not relevant or not possible due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 27 %
Water % by weight : Weighted average: 0 %
VOC content : 438.7 g/l
TOC Content : Weighted average: 352 g/l
Solvent Gas : Weighted average: 0.104 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

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SECTION 10: Stability and reactivity

10.3 Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides sulfur oxides halogenated compounds metal oxide/oxides

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure
period.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
middle molecular epoxy resin LD50 Dermal Rat >2000 mg/kg -
MMW 700-1200
solvent naphtha (petroleum), light LC50 Inhalation Vapor Rat 6193 mg/m³ 4 hours
arom.
LD50 Dermal Rabbit 3160 mg/kg -
LD50 Oral Rat 8400 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
trizinc bis(orthophosphate) LD50 Oral Rat >5000 mg/kg -
toluene LC50 Inhalation Vapor Rat >20 mg/l 4 hours
LD50 Oral Rat 636 mg/kg -

Acute toxicity estimates

Route ATE value
Oral 15034.28 mg/kg
Dermal 12701.17 mg/kg
Inhalation (gases) 57732.6 ppm
Inhalation (vapors) 573.31 mg/l
Irritation/Corrosion

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SECTION 11: Toxicological information

Product/ingredient name Result Species Score Exposure

solvent naphtha (petroleum), light Eyes - Mild irritant Rabbit - 24 hours 100 microliters
arom.
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
butan-1-ol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams
Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams

Sensitizer
Product/ingredient name Route of exposure Species Result
middle molecular epoxy resin MMW skin Guinea pig Sensitizing
700-1200

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
Solvent naphtha (petroleum), light arom. Category 3 Not applicable. Narcotic effects
Category 3 Not applicable. Respiratory tract irritation
butan-1-ol Category 3 Not applicable. Narcotic effects
Category 3 Not applicable. Respiratory tract irritation
1,2,4-trimethylbenzene Category 3 Not applicable. Respiratory tract irritation
toluene Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 Not determined hearing organs
toluene Category 2 Not determined Not determined

Aspiration hazard
Product/ingredient name Result
Solvent naphtha (petroleum), light arom. ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Product/ingredient name Carcinogenic effects Mutagenic effects Developmental effects Fertility effects
toluene - - Repr. 2, H361d (Unborn -
child)
Sensitization : Contains middle molecular epoxy resin MMW 700-1200. May produce an allergic reaction.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
middle molecular epoxy resin MMW Acute EC50 >100 mg/l Daphnia 48 hours
700-1200
Acute LC50 >100 mg/l Fish 96 hours
solvent naphtha (petroleum), light Acute EC50 19 mg/l Algae - Pseudokirchneriella subcapitata 96 hours
arom. (green algae)
Acute EC50 6.14 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 9.22 mg/l Fish - Oncorhynchus mykiss (rainbow 96 hours
trout)
butan-1-ol Acute EC50 1328 mg/l Daphnia 96 hours
Acute LC50 1.376 mg/l Fish 96 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
trizinc bis(orthophosphate) Acute EC50 0.8 mg/l Algae 72 hours

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SECTION 12: Ecological information

Acute EC50 2.44 mg/l Daphnia 48 hours
toluene Chronic NOEC <500000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
solvent naphtha (petroleum), light - >70 % - Readily - 28 days - -
arom.
xylene - >60 % - Readily - 28 days - -
butan-1-ol OECD 301D Ready 92 % - 20 days - -
Biodegradability - Closed Bottle Test
ethylbenzene - >70 % - Readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

solvent naphtha (petroleum), light - - Readily
arom.
xylene - - Readily
butan-1-ol - - Readily
ethylbenzene - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
middle molecular epoxy resin MMW 700-1200 2.64 - 3.78 31 low
solvent naphtha (petroleum), light arom. - 10 - 2500 high
xylene 3.12 8.1 - 25.9 low
butan-1-ol 1 3.16 low
ethylbenzene 3.6 - low
trizinc bis(orthophosphate) - 60960 high
toluene 2.73 90 low

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 III Yes.

Class

IMDG UN1263 PAINT. (Solvent naphtha 3 III Yes. The marine pollutant mark is
Class (petroleum), light arom.) not required when
transported in sizes of ≤5 L
or ≤5 kg.
Emergency schedules F-E,
S-E

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Safety Data Sheet
HEMPADUR ZP PRIMER 17309

SECTION 14: Transport information

IATA UN1263 PAINT 3 III Yes. The environmentally
Class hazardous substance mark
may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
PBT = Persistent, Bioaccumulative and Toxic
vPvB = Very Persistent and Very Bioaccumulative
GHS Classification

Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 2 Calculation method
AQUATIC HAZARD (ACUTE) - Category 3 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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