Safety Data Sheet according to (EC) Nr.

1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================

1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY

1.1. Product identifier

Trade name:
Substance name: herbagreen®fluisan

Designation: Biostimulant and Plant strengthener

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Use as Plant strengthener on crops, lawns, trees and ornamental shrubs.

Uses advised against:

Use product only appropriate.

1.3. Details of the supplier of the safety data sheet

Supplier / Manufacturer/Distributor
Sanovita Produktions- und Vertriebs GmbH

Street:
Bahnhofstr. 71

Nationality/Postal code/ Town

D- 78532 Tuttlingen
Germany

Contact for technical Information

Sanovita Produktions- und Vertriebs GmbH
Bahnhofstr. 71
D- 78532 Tuttlingen

Telephon / Telefax / E-Mail

Telefon: +49-(0) 7461/93350 (08:30 - 16:30 Uhr)
Telefax: +49-(0) 7461/933544
E-Mail: [email protected]

1.4. Emergency Telephone number 24/24hrs

Counseling center for poisoning. Emergency no.
Telephon : 0761 - 19240
Telephon of the manufacturer/distributer
Telefon : +49-(0) 7461/93350 (08:30 - 16:30)

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) Nr. 1272/2008, Annex VII (Substance):
EG Index: The substance is not classified as hazardous according to the Regulation (EC) Nr.1272/2008 [CLP]

Classification according to Directive 67/548/EEC or Directive 1999/45/EC (substances and mixtures): The
substance is not classified as hazardous according to the Regulation (EC) Nr.67/548/EU

Additional information

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
2.2 Label elements

Labeling according to Regulation (EC) No. 1272/2008 (Substances)

Regulation EC 1999/45 (Mixtures)
EC Index: Not applicable

Label elements
Label elements according to Regulation (EC) no. 1272/2008 (substances) / Directive 1999/45 / EC (mixtures)
Hazard designation: Xi
Pictogram / Hazard Symbol:

Signal word / Hazard description: Attention

Hazardous ingredients for labeling contains:

Hazard statements:
H315 Causes skin irritation
H319 Causes serious eye irritation

Safety Instructions
P102 Keep out of reach of children
P264 Wash hands thoroughly after handling
P280b Wear protective gloves / protective clothing / eye protection / face protection.
P302 + P352b In case of contact with skin: Wash with plenty of soap and water
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove any contact
lenses if possible. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice / attention help. Remove contaminated clothing
and wash before reuse
P337 + P313 If skin irritation occurs: Get medical advice / help.

Additional Information
Do not breathe spray
Use only in well-ventilated areas

2.3 Other hazards

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Main component of the substance:
Contaminants, stabilizing additives or individual constituents:
None

3.2. This product is to be considered as a mixture in conformance to EC directives.

(- Hazardous to health or environmental hazard,
- Components with EU limit values for occupational exposure,
- Substances which are persistent in accordance with the criteria in Annex XIII of the REACH Regulation,
bio accumulative and toxic or very persistent and very bio accumulative,
- Substances for reasons other than those specified in Article 31 paragraph 1 letter a of the REACH
Regulation hazards listed in the list established in accordance with Article 59, paragraph 1 of the REACH
Regulation (List of candidates) were included)

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
Substances: Hops Extract (tanning extract)
EC No: -. / CAS NO: -. / Index No: -. / REACH registration. -
Percentage: 79% w / w
Classification according to Directive 67/548/EEC:
(The wording of the listed risk phrases refer to section 16)

Name of substance: Water 21%

3.3 Additional information

None

4. FIRST AID MEASURES

4.1. Description of first aid measures

General informations

Following inhalation
After inhalation of decomposition products or dust in case of accidental go to fresh air

Following skin contact

Brush away dry dust from the skin. In case of skin reactions go to doctor

Following eye contact

Rinse thoroughly with plenty of water, also under the eyelids. If necessary, consult a doctor.
Remove contact lenses, if possible.

Following ingestion
Rinse mouth with water and drink afterwards plenty of water. Do not induce vomiting. Don’t eat or drink
anything.

4.2. Most important symptoms and effects, both acute and delayed
None

4.3. Indication of any immediate medical attention and special treatment needed
Symptomatic treatment

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

The product does not burn. Extinguishing measures to suit the situation and environment
Suitable: Water
Not suitable: No restrictionse extinguishing media

5.2. Special hazards arising from the substance or mixture

In case of fire, carbon oxides may be formed

5.3. Advice for fire-fighters

Fighting measures that suit the environment. In case of fire: Wear adequate respirators.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment, and emergency procedures

Avoid generation of dusts. Do not inhale dust. Ensure adequate ventilation.
See No. 8.2.2 Personal Protective Equipment.

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================

6.2. Environmental precautions

Take up contaminated material and pass on for further processing or transfer to containers and
disposed properly.

6.3. Methods and material for containment and cleaning up

No special advice

6.4. Reference to other sections

None

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Protective measures
Measures for protection against fire and explosion
No special measures required

Measures to prevent dusts and aerosols

Store product in sealed containers

Measures to protect the environment

Open container only in application

General hygiene measures

Wash hands after use

7.2. Conditions for safe storage, including any incompatibilities

Information on storage conditions
Keep container tightly closed and dry

Requirements for storage rooms and container

No special measures required

Storage class:
No data available.

7.3. Specific end use(s)

No data available

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Product does not contain substances above concentration limits. Occupational exposure limit has
been fixed.

8.1.1Occupational exposure limits in the workplace and / or biological limit values

8.1.2 DNEL and PNEC values

Value: DNEL / PNEC value is not relevant

8.1.3 Control banding (for example, ILO, EMKG)

Relevant classification parameters /
Relevant control guidance

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
8.2. Exposure controls

8.2.1 Appropriate technical controls

None

8.2.2 Individual protection measures - personal protective equipment

Eye / face protection
Glasses with side protection DIN / EN standards: EN 166

Skin protection
Recommended glove DIN EN standards: DIN EN 374
In case of reutilization, clean gloves before taking off and store in well-ventilated.

Gloves
Splash contact:
Glove material: NBR (nitrile rubber) 112-0998 VWR
Layer thickness (mm) : 0.38 mm
Penetration time (min.) :> 480 min .

Full contact:
Glove material: NBR (nitrile rubber) VWR 112-3717/112-1381
Layer thickness (mm) : 0.12 mm
Penetration time (min.) :> 480 min .

Other skin protection

According to DIN 32 781 "Protective clothing - Protective suits against pesticides"

Respiratory Protection
No personal respiratory protection required additionally

Heat / cold protection

No special protection required

8.2.3 Exposure to the environment

Use only according to application advice

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance
- State of aggregation : liquid
- Color: Brown - black
Odour: Aromatic
Odor threshold: No information available
pH: 8-9
Melting point / freezing point: No information available
Initial boiling point and boiling range: 106 ° C
Flash point: Not applicable
Evaporation rate: No information available
Flammability ( solid, gas ): Not applicable
Upper / lower flammability or Explosion limits: No information available
Vapor Pressure: Not applicable
Vapor density: No information available
relative density : 1.25 g/cm3
Solubility: Soluble in / with water
Partition coefficient: No information available
n-octanol/water: No information available

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
Auto-ignition temperature: Not flammable Not even self-igniting
Decomposition temperature: Not applicable Not applicable
Viscosity: 48.2 mm²/s
Explosive properties : No
Oxidizing properties : No

9.2. Other safety information

No

10. STABILITY AND REACTIVITY

10.1. Reactivity
No data available

10.2. Chemical stability

The product is chemically stable under normal ambient conditions (temperature)

10.3. Possibility of hazardous reactions

No data available

10.4. Conditions to avoid

No special hazards

10.5. Incompatible materials

No data available

10.6. Hazardous decomposition products

No decomposition if used properly, according to intended use,

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

For substances for the following hazard classes (including a short summary of the present
test results and information on the process)

acute toxicity
- Oral: No known information
- Dermal: LD50 rat> 2000 mg / kg

Skin corrosion
No data available

Serious eye damage / eye irritation

No data available

Respiratory sensitization / skin

No data available

Germ cell mutagenicity

No data available

Carcinogenicity
No evidence of carcinogenicity in humans

Reproductive toxicity

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
No evidence of reproductive toxicity in humans

Specific target organ toxicity-single exposure

Not relevant

Specific target organ toxicity after repeated exposure

Not relevant

Aspiration
Not relevant

12. ECOLOGICAL INFORMATION

12.1. Toxicity
No data available. Quantitative data on the ecological effect of this product are not available

12.2. Persistence and degradability

The methods for determining biodegradability are not applicable to inorganic substances.

12.3. Bioaccumulative potential

No data available

12.4. Mobility in soil

No data available

12.5. Results of PBT and vPvB assessment

No data available

12.6. Other adverse effects

Unknown

12.7 Additional information

None

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Treatment of contaminated packaging

Eliminate in accordance with local regulations. About waste disposal consult the local waste
disposal company.

Waste code according to European Waste Catalogue (EWC)

Special precautions
No data available

Relevant EU or other provisions

In addition comply with the regional authorities.

13.2 Additional information

None

14. TRANSPORT INFORMATION

14.1. Land transport (ADR/RID/GGVSE)

No hazardous material as defined in the above regulations

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
14.2. Sea transport (IMDG-Code/GGVSee)
No hazardous material as defined in the above regulations

14.3. Air transport (ICAO-IATA/DGR)

No hazardous material as defined in the above regulations

14.4. Special precautions for user

No specific advice

14.5. Transport in bulk according to Annex II of MARPOL 73/78 and the ICB Code
Features environmentally hazardous substances
ADR / RID / IMDG Code / ICAO-TI / IATA-DGR: 0 yes / no X
Marine Pollutant: 0 yes / no X

14.6 Additional information

None

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EC legislation such as
Regulation (EC) No 2037/2000 (substances that deplete the ozone layer):
Not applicable

Regulation (EC) No 850/2004 (Persistent Organic Pollutants):

Not applicable

Regulation (EC) No 689/2008 (export and import of dangerous chemicals):

Not applicable

Regulation (EC) No 648/2004 (Detergents):

Not applicable

Restrictions under Title VIII of Regulation (EC) 1907/2006:

Not applicable

National legislation such as

Water hazard class
Water hazard class 1 (Self-assessment): slightly hazardous for water

Solvent Regulation (31 BlmSchV)

Not applicable

Incident Regulation (12 BlmSchV)

Not applicable

Technical Instructions on Air Quality (TA Air)

Not applicable

Other relevant regulations

Hops Tannin Extract: Permitted as additive in fruit juice Regulation and fruit nectar and fruit syrup
Regulation.

15.2 Chemical Safety Assessment

Not performed. Production <10 ton / year

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 Safety Data Sheet according to (EC) Nr. 1907/2006 REACH
(and EC Regulation (EU) Nr. 453/2010) EC Organic Regulation 834/2007
Herbagreen ®fluisan EC Organic Regulation 889/2008
Print date: 09.03.2014 Revision date: 06.03.2015
Valid from: 09.03.2014 Version: 2
===============================================================================
16. OTHER INFORMATION

16.1 Indications of Changes

16.2 Abbreviations and acronyms

LD50 median lethal dose
MAK Maximum workplace concentration

16.3 Key literature references and sources for data

Safety data sheets
Weck, M., Grote, H., Matthes, K. (2009): Zusatzstoffe und Enzyme. Fragen und Antworten.
Behr’s Verlag Hamburg, ISBN 978-3-89947-532-6

16.4 Further information

This EC-Safety Data Sheet was developed in cooperation with
DEKRA Consulting GmbH, Hanomagstr. 12, D-30449 Hannover,
Tel.: (+49) 511 42079 311, [email protected].

The information in this SDS is correct to the best of our knowledge at the time of creation it does not have
the meaning of guarantees on properties. The information provides guidance for safe handling, use of the
product for storage, processing, transport and disposal. The details are not transferable to other products.
As far as the product is mixed with other materials cannot be transferred easily to the new material,
according to the information in this SDS.
Such data may not be altered nor transferred to other products. Reproduction in unaltered state is allowed

Sanovita Produktions- und Vertriebs GmbH D-78532 Tuttlingen-Bahnhofstr. 71

Tel. 0049 (0)7461/9335 0, Fax. 0049 (0)7461/9335 44, [email protected]

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