MATERIAL SAFETY DATA SHEET

For Chemical Emergency

Spray Foam Polymers, LLC Spill Leak Fire Exposure or Accident
PO Box 1182 Call CHEMTREC Day or Night
New Canaan, CT 06840
Phone/fax – 800-853-1577 DOMESTIC NORTH AMERICA
www.sprayfoampolymers.com 800-424-9300
INTERNATIONAL, CALL 703-527-3887
(collect calls accepted)

SECTION 1 - PRODUCT IDENTIFICATION

PRODUCT NAME: Thermoseal A-Side

CHEMICAL FAMILY: Aromatic Isocyanate

CHEMICAL NAME: POLYMETHANE POLYPHENYL ISOCYANATE

SYNONYMS: Polymeric Diphenylmethane Diisocyanate (PMDI), Polymethylene Polyphenyl

Isocyanate

CAS NUMBER: 9016-87-9

FORMULA: Not Applicable

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT NAME/CAS NUMBER EXPOSURE LIMITS CONCENTRATION

**HAZARDOUS (%)
INGREDIENTS**
Polymeric Diphenylmethane Upper Bound 55%
Diisocyanate
9016-87-9
Methylene Diphenyldiisocyanate Upper Bound 45%
101-68-8
Percentage is dependent on the monomer content of the product which will vary from lot to lot.

SECTION 3 - HAZARDS IDENTIFICATION

Emergency Overview
Color: Brown Liquid Odor: Musty

Sprayed or heated material is harmful if inhaled. Avoid skin and eye contact. Skin and lung
sensitizer - may cause allergic skin and respiratory reactions including possible lung injury.

Avoid temperatures above 410C (1050F) – closed containers may rupture due to material
decomposition. Toxic and or flammable fumes may be released during burning or thermal
decomposition.

Slowly reacts with water forming carbon dioxide and possibly rupturing closed containers. Elevated
temperatures accelerate this reaction.

POTENTIAL HEALTH EFFECTS:

EYE:
Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.
Prolonged exposure may cause temporary corneal injury.
SKIN:
Can cause skin irritation. Symptoms may include redness and burning of skin, and other skin
damage. Additional symptoms of skin contact may include: allergic skin reaction (delayed skin rash
which may be followed by blistering, scaling and other skin effects)
SWALLOWING:
Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and intestinal
irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material
may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and
shock may occur as a result of severe tissue injury. This material can get into the lungs during
swallowing or vomiting. This results in lung inflammation and other lung injury.
INHALATION:
At room temperature vapor concentrations are low due to the low volatility of this material and are not
likely to cause harmful effects. At concentrations above the TLV or PEL, vapors may cause respiratory
irritation or other adverse effects. Symptoms may include runny nose, sore throat, coughing, chest
discomfort, shortness of breath, and reduced lung function. Acute exposure may result in irritation of
the upper respiratory tract and lungs and cause pulmonary edema (fluid in the lungs). Some individuals
may become permanently sensitized to this material and experience asthma-like symptoms even at
levels well below recommended exposure guidelines. These effects may be delayed and may be life
threatening. Overexposure may result in fibrosis and permanent decreased lung function.
SYMPTOMS OF EXPOSURE:
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the
material through the skin may include: irritation (nose, throat, airways), allergic reaction (causes
narrowing of the air passages of the lungs, sweating, flushing, hives, rapid heart rate and lowered blood
pressure).
TARGET ORGAN EFFECTS:
Overexposure to this material (or its components) has been suggested as a cause of the following
effects in humans: skin sensitization, respiratory sensitization.
DEVELOPMENTAL INFORMATION:
None Found
CANCER INFORMATION:
In a two-year inhalation study in rats, exposure to polymeric methylene bisphenylisocyanate (MDI)
aerosol caused a significant increase in benign (non-carcinogenic) lung tumors, along with a single
carcinogenic lung tumor, at the highest dose only (6 mg/m3). The tumors occurred along with irritation
of the respiratory tract and the accumulation of a yellow material in the lungs. There was irritation only
at 1.0 mg/m3 and no effect at 0.2 mg/m3. MDI is not listed as carcinogenic by IARC, NTP or OSHA.
OTHER HEALTH EFFECTS:
None Found
PRIMARY ROUTE(S) OF ENTRY:

Inhalation, Skin contact

SECTION 4 - FIRST AID MEASURES

FIRST AID FOR EYES:

If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes
gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
FIRST AID FOR SKIN:
Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged,
seek immediate medical attention. Launder clothing before reuse.
FIRST AID FOR INHALATION:
If symptoms develop, immediately move individual away from exposure and into fresh air. Seek
immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial
respiration. If breathing is difficult, administer oxygen. Monitor individual for the development of
asthmatic symptoms, which may be immediate or develop after several hours.
FIRST AID FOR SWALLOWING:
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place
individual on left side with the head down. Contact a physician. medical facility, or poison control center
for advice about whether to induce vomiting. If possible, do not leave individual unattended.
NOTE TO PHYSICIANS:
This material is an aspiration hazard. Potential danger from aspiration must be weighed against
possible oral toxicity (See Section 3-Swallowing) when deciding whether to induce vomiting. Preexisting
disorders of the following organs (or organ systems) may be aggravated by exposure to this
material: respiratory tract, skin, lung (for example, asthma-like conditions).

SECTION 5 - FIRE FIGHTING MEASURES

FLASH POINT: 2300C

EXPLOSIVE LIMIT: No Data

AUTOIGNITION TEMPERATURE: No Data

HAZARDOUS PRODUCTS OF COMBUSTION:

May form: carbon dioxide and carbon monoxide, hydrogen cyanide, nitrogen compounds and
various hydrocarbons.

OTHER FLAMMABILITY INFORMATION:

Isocyanates react with water. This reaction may produce heat and or gasses. This reaction may be
violent. Closed containers (tanks, drums, etc.) may rupture from gases generated during the fire
situation. Violent steam generation may occur upon direct application of a water stream to the hot
liquids. Burning product produces dense smoke.

FIRE AND EXPLOSIVE HAZARDS:

Never use welding or cutting torch on or near drum (even empty) because product (even just
residue) can ignite explosively.

EXTINGUISHING MEDIA:
Dry chemical; Carbon Dioxide; Foam; Water spray for large fires.
SPECIAL FIRE FIGHTING PROCEDURES:
Water or foam may cause frothing which can be violent and possibly endanger the life of the
firefighter. Full emergency equipment with self-contained breathing apparatus and full protective
clothing should be worn by firefighters. During a fire, MDI vapors and other irritating, highly toxic gases
may be generated by thermal decomposition or combustion. (See Stability and Reactivity). At
temperatures greater than 400 F (204 0C), polymeric MDI can polymerize and decompose which can
cause pressure build-up in closed containers. Explosive rupture is possible. Therefore, use cold water
to cool fire-exposed containers.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

SPILL OR LEAK PROCEDURES:

Evacuate and ventilate the spill area; dike spill to prevent entry into water system; wear full protective
equipment, including respiratory equipment during clean-up. (See Employee Protection
Recommendations).

MAJOR SPILL: If temporary control of isocyanate vapor is required, a blanket of protein foam
(available at most fire departments) may be placed over the spill. Large quantities may be pumped into
closed, but not sealed, container for disposal.

MINOR SPILL: Absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed
containers, transport to well ventilated area (outside) and treat with neutralizing solution: mixture of
water (80%), with non-ionic surfactant Tergitol TMN-10 (20%), or; Water (90%), concentrated ammonia
(3-8%) and detergent (2%). Add about 10 parts of neutralizer per part of isocyanate, with mixing. Allow
to stand uncovered for 48 hours to let CO2 escape.
CLEAN-UP: Decontaminate floor with decontamination solution letting stand for at least 15 minutes.

SECTION 7 - HANDLING AND STORAGE

STORAGE TEMPERATURE (MIN/MAX): 200C / 250C

SHELF LIFE: 6 Months

SPECIAL SENSITIVITY:
If container is exposed to high heat, 4000F (2040C) it can be pressurized and possibly rupture. MDI
reacts slowly with water to form CO2 gas. This gas can cause sealed containers to expand and possibly
rupture.
HANDLING/STORAGE PRECAUTIONS:
Containers of this material may be hazardous when emptied. Since emptied containers retain product
residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be
observed. Store in tightly closed containers to prevent moisture contamination. Do not reseal if
contamination is suspected. Avoid contact with skin and eyes. Do not breathe aerosols or vapors.
Warning properties (irritation of the eyes, nose and throat or odor) are not adequate to prevent chronic
overexposure from inhalation. This material can produce asthmatic sensitization upon either a single
inhalation exposure to relatively high concentrations or repeated exposures to low concentrations.
Exposure to vapors of heated MDI can be extremely dangerous.

SECTION 8 - PERSONAL PROTECTION

EYE PROTECTION REQUIREMENT:

Liquid chemical goggles. Vapor resistant goggles should be worn when contact lenses are in use. In a
splash hazard environment chemical goggles should be used in combination with a full face-shield.
SKIN PROTECTION REQUIREMENTS:
Permeation resistant gloves (butyl rubber, nitrile rubber, polyvinyl alcohol). However, please note that
PVA degrades in water. Cover as much of the exposed skin area as possible with appropriate clothing.
If skin creams are used, keep the area covered by the cream to a minimum.
VENTILATION REQUIREMENTS:
Local exhaust should be used to maintain levels below the TLV whenever MDI is processed, heated or
spray applied. Standard reference sources regarding industrial ventilation (i.e., ACGIH Industrial
Ventilation) should be consulted for guidance about adequate ventilation.
RESPIRATOR REQUIREMENTS:
Concentrations greater than the TLV can occur when MDI is sprayed, heated or used in poorly
ventilated area. In such cases, or whenever concentrations of MDI exceed the TLV or are not known,
respiratory protection must be worn. A supplied air respirator (either positive pressure or continuous
flow type) is required. In an emergency situation, a self contained breathing apparatus may be used.
MDI has poor warning properties, since the concentration at which MDI can be smelled is substantially
higher than the maximum exposure limit. Observe OSHA regulations for respirator use (29 CFR
1910.134).
MONITORING:
Isocyanate exposure levels must be monitored. Monitoring of airborne isocyanates in the breathing
zone of individuals should become part of the overall employee exposure characterization program.
Monitoring techniques have been developed by NIOSH, and OSHA.
MEDICAL SURVEILLANCE:
Medical supervision of all employees who handle or come in contact with isocyanates is recommended.
These should include pre-employment and periodic medical examinations with pulmonary function tests
(FEV, FVC as a minimum). Persons with asthmatic-type recurrent skin eczema or sensitization should
be excluded from working with isocyanates. Once a person is diagnosed as sensitized to an
isocyanate, no further exposure can be permitted.
ADDITIONAL PROTECTIVE MEASURES:
Safety showers and eyewash stations should be available. Educate and train employees in safe use of
product. Follow all label instructions.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: Liquid

COLOR: Dark Brown Viscous Liquid
ODOR: Musty
VISCOSITY: 200+50 mPas
SOLUBILITY IN WATER: Not soluble. Reacts slowly with water to liberate CO2 gas.
SPECIFIC GRAVITY: 1.25 @ 770F. (250C.)
NCO% Wt 30.5-32.0
VAPOR PRESSURE(: 10-4 MAX mm Hg/400 C
Acid content(HCL): max 0.05%

SECTION 10 - STABILITY AND REACTIVITY

STABILITY: This is a stable material under recommended storage conditions.

HAZARDOUS POLYMERIZATION: May occur: Contact with moisture, other materials will react with
isocyanates, or temperatures above 4000F. (2040C.) may cause polymerization.

INCOMPATIBILITIES: Water, amines, strong bases, alcohols and polyols will react with MDI
generating heat and possible off-gasses (carbon dioxide, in the case of water). If allowed to
continue, these reactions may become increasingly exothermic and cause closed-container rupture.
Avoid contact with metals such as copper alloys, tin, zinc and aluminum: corrosion may result.

INSTABILITY CONDITIONS: Contamination with water and high temperatures (greater than 4000F.
(2040C)
DECOMPOSITION PRODUCTS: By high heat and fire: carbon monoxide, oxides of nitrogen, traces
of HCN, MDI vapors or aerosols.

SECTION 11 - TOXICOLOGICAL INFORMATION

LD50-LC50 Mixture: LD50 RAT ORAL 10,000 mG/KG

SECTION 12 - ECOLOGICAL INFORMATION

No Data

SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD:

Waste must be disposed of in accordance with federal, state, and local environmental control
regulations. Incineration is the preferred method.
EMPTY CONTAINER PRECAUTIONS:
Empty containers must be handled with care due to product residue. Decontaminate containers prior to
disposal. Empty decontaminated containers should be crushed to prevent reuse. Do NOT HEAT OR
CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. (See Fire Fighting Measures and
Stability and Reactivity). Gases may be highly toxic.

SECTION 14 - TRANSPORTATION INFORMATION

DOT Non-Bulk
Not Regulated

Land Transportation (DOT):

Proper Shipping Name: Other regulated substances, liquid, n.o.s. (contains 4,4’-diphenylmethane
diisocyanate (MDI))
Hazard Class or division : 9
UN/NA Number: NA3082
Packaging Group: III
Hazard Label (s): Class 9

IMDG
Proper Shipping Name: Environmentally Hazardous Substances, Liquid, NOS
Technical Name: MDI
Hazard Class: 9 ID number: UN3082 Packing Group: PG III
EMS Number: F-A, S-F
Marine pollutant: No
ICAO/IATA
Not Regulated

Additional Information
Reportable Quantity: 5,000 lb

SECTION 15 - REGULATORY INFORMATION

OSHA STATUS:
This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29
CFR 1910.1200.
TSCA STATUS:
TSCA (United States) The intentional ingredients of this product are listed.
SARA TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: NONE

SECTION 311/312 HAZARD CATEGORIES:

Acute Health Hazard; Chronic Health Hazard
SECTION 313 TOXIC CHEMICALS:

Polymeric Diphenylmethane Diisocyanate, CAS# 9016-87-9, 100% Contained in this polymeric MDI
product is 4,4- Diphenylmethane Diisocyanate, CAS# 101-68-8; Upper Bound 45%

EPA ACCIDENTAL RELEASE PREVENTION 40 CFR 68:

None Listed

STATE RIGHT-TO-KNOW INFORMATION:

Massachusetts, New Jersey or Pennsylvania Right-to-Know Substance Lists:

Weight % Components CAS-No.

40-55% Polymeric Diphenylmethane Diisocyanate (Polymeric 9016-87-9

MDI

35-45% 4,4’ -Diphenylmethane Diisocyanate (MDI) 101-68-8

1-15% Diphenlylmethane Diisocyanate (MDI) 26447-40-5

INTERNATIONAL REGULATIONS INVENTORY STATUS:

DSL (Canada) The intentional ingredients of this product are listed.

SECTION 16 - COMMENTS

WHILE SPRAY FOAM POLYMERS BELIEVES THE DATA SET FORTH HEREIN ARE ACCURATE
AS OF THE DATE HEREOF, SPRAY FOAM POLYMERS MAKES NO WARRANTY WITH RESPECT
THERETO AND EXPRESSLY DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. SUCH DATA
ARE OFFERED SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION.