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Polyacrylic Acid

Polyacrylic acid is a polymer made from acrylic acid monomers. It absorbs large amounts of water and is used in diapers and other personal care products to absorb liquids. It was first patented in 1966 and used commercially in diapers in 1982. Polyacrylic acid is a white powder that swells when it absorbs water or other liquids. It has low toxicity but may cause mild irritation upon contact with eyes or skin. It is regulated for use in various products and food additives.

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274 views3 pages

Polyacrylic Acid

Polyacrylic acid is a polymer made from acrylic acid monomers. It absorbs large amounts of water and is used in diapers and other personal care products to absorb liquids. It was first patented in 1966 and used commercially in diapers in 1982. Polyacrylic acid is a white powder that swells when it absorbs water or other liquids. It has low toxicity but may cause mild irritation upon contact with eyes or skin. It is regulated for use in various products and food additives.

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Bassam M. Alameddine
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POLYACRYLIC ACID

Introduction

Poly(acrylic acid) or PAA (CAS number 9003-1-04) is a type of polymer. The monomer of poly(acrylic
acid) is Acrylic Acid. In a water solution at neutral pH, many of the side chains of PAA will lose their
protons and acquire a negative charge.
Dry PAA is a white solid. It is capable of absorbing many times its weight in water, and hence is used in
disposable diapers. Indiapers it is a fine powder - see picture of material form a diaper.

Chemical Properties

Polyacrylic acid is a large-molecular-weight compound called a polymer, which consists of small repeating
units called monomers. The polyacrylate polymer used in diapers is constructed from the acrylic acid and
sodium acrylate monomers. The length of the polymer chain and the properties of the polymer may be
changed by varying the reaction conditions. The reaction conditions can affect the the length of the chains
and can change the characteristics of the polymer. The polyacrylate is dried and formed into
microparticles of irregular shape that are stable for extended periods. The particles quickly swell and
absorb water, urine, or other aqueous solutions.
History

A super-absorbent (SAP) or polyacrylic acid was patented in 1966 by Gene Harper of Dow Chemical and
Carlyle Harmon of Johnson & Johnson. It was first used in diapers in 1982 in Japan.

Uses

Polyacrylic acid is found in a wide variety of household and personal care products:

§ Diapers
§ Hand sanitizer
§ Mascara
§ Aftershave
§ Toothpaste
§ Hair-styling products (gels, dyes, sprays)
§ Moisturizer
§ Pet shampoo
§ Metal polish

Toxicity

Human Health Effects

Products containing polyacrylic acid warn of a mild irritation if eye or skin exposure occurs. Not meant for
skin contact.

Material Safety Data Sheets (MSDSs) for Polyacrylic Acid

A common statement on MSDSs is "To the best of our knowledge the chemical, physical & toxicological
properties have not been thoroughly investigated."

§ Fisher Scientific - MSDS CAS# 9003-01-4 - indicates benzene as possible contaminant


§ Chemical book CAS# 9007-20-9 - minimal information
§ [] - indicates benzene as possible contaminant
§ Poly(acrylic acid) Sodium Salt - 9003-04-7
§ American Polymer Standards Corporation - 9003-04-7
Manufacture

Note that the polyacrylic acid contains some of the monomer acrylic acid.

Information from Chemquat and their website on Polyacrylic acid


Polyacrylic Acid
IUPAC Name: acrylic acid
CAS Number: 9003-01-4
Chemical Formula: C3H4O2
Appearance: colorless to pale yellow transparent solution
Solid content, % 25-42
Free monomers as acrylate: 0.5% max
Molecular weight 1200-100000
pH of 1% solution: 3.0 max
Specific gravity; g/cm3:1.15 min
Packing 200l plastic drum
Gross weight 260kg
Net weight 250kg

Regulation

§ Polyacrylic acid is regulated under the US EPA Toxic Substances Control Act (TSCA).
§ Polyacrylic acid is monitored by the International Agency for Research on Cancer, an agency of the World
Health Organization.
§ Polyacrylic acid, sodium salt is listed as a food additive by the US Food and Drug Administration (FDA).

Source : http://www.toxipedia.org/display/toxipedia/Polyacrylic+Acid

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