CPP: CHEMICAL BONDING

IONIC BOND AND COVALENT BOND

 
1. An ionic compound x y is formed if
(A) ionization enthalpy of ' x ' is high, election gain enthalpy of ’y’ is low
(B) ionisation enthalpy of ‘x’ is low, election gain enthalpy is high
(C) ionisation enthalpy of ‘x’ is low, election gain enthalpy ‘y’ is high
(D) ionisation enthalpy of ‘x’ is low, election gain enthalpy ‘y’ is low

2. In which of the following species the bonds are non-directional?

(A) NCl3 (B) RbCl
(C) BeCl2 (D) BCl3

3. Which compound among the following does not contain ionic bond?
(A) HCl (B) KBr
(C) CaCl2 (D) nAoh

4. Which of the following species does not have coordinate bonds?

 2
(A) NO 3 (B) CO 3
(C) CO (D) CH3NC

5. In [Ag(CN)2] the number of   bonds is

(A) 2 (B) 3
(C) 4 (D) 6

6. Which of the following sets does not contain any ionic species:
(A) NH4Cl, OF2, H2S (B) CO2, Cl2, CCl4
(C) BF3, AlF3, TiF3 (D) I2, CaO, CH3Cl

FORMAL CHARGE, DIPOLE- MOMENT, RESONANCE, H-BOND, VANDERWALLS FORCE.

7. In bisulphate ion, the formal charge on sulphur atom is

(A) +1 (B) + 2
(C) + 4 (D) + 6

8. Carbonyl group has following resonating structures

   
(i)  C O (ii)  C O (iii)  C  O
The correct order of stability of these structures is
(A) I > II > III (B) I > III> II
(C) III > I > II (D) III > II > I

9. The compound which has zero dipole moment

(A) CH2Cl2 (B) H2O
(C) BF3 (D) SF4

10. Which pair of molecules will have zero dipole moment for both members?
(A) NO2 and O3 (B) SiF4 and CO2
(C) SiF4 and NO2 (D) NO2 and CO2

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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11. The value of  0 for a molecule AB3 . Which of the following pair of species represents AB3.
(A) PH3, ICl3 (B) SO2, ICl3
(C) PCl3, SO3 (D) SO3, BCl3

12. Which of the following liquid is miscible with water?

(A) CS2 (B) C2H5Cl
(C) CCl4 (D) C2H5OH

13. The type of bonds which explain the solubility of sucrose in water is
(A) Ion-dipole interactions (B) Hydrogen bonds
(C) Covalent bonds (D) Dispersion forces

14. Possible structure of monothio carbonate ion is

C C
(A) (B)
S S
O O O O
S S
(C) (D)
C C
O O O O

15. CH3Cl has more dipole moment than CH3F because

(A) Electron affinity of chlorine is greater than Fluorine
(B) Change separation is large in CH3Cl than CH3F
(C) Chlorine has higher electronegativity than fluorine
(D) Repulsion between the bonds pairs and non–bonds pairs of electrons is grater in CH3Cl then CH3F.

16. In which type of molecule, the dipole moment may be non zero
A central atom, B Bonded atom, C  lone pair
(A) AB4 (B) AB4L4
(C) AB2L3 (D) AB2L2

17. The Hydrogen bond is strongest in

(A) O  H  S (B) S  H  O
(C) F  H  F (D) F  H  O

18. Which factors are responsible for vander waal forces.

(A) Instantaneous dipole-induced dipole interaction
(B) Dipole – induced dipole interaction and ion0nduced dipole interaction
(C) Dipole- Dipole interaction and non-induced dipole interaction
(D) All of these

19 Which of the following are polar.

(A) XeF4 (B) SO3

(C) XeOF4 (D) ICl 4

20. Of the following molecule, the one which has permanent dipole moment.
(A) SiF4 (B) BF3
(C) PF3 (D) PF5

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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21. Which of the following is incorrect for dipole moment?
(A) Lone pair of electrons present on central atom can give rise to dipole moment
(B) Dipole moment is vector quantity
(C) CO2 molecule has dipole moment
(D) Difference in electronegativities of combining atoms can lead to dipole moment

22. Which of the following compound will have significant intermolecular H-bonding?
HF, CH3OH, N2O4, CH4, NH3  l 
(A) HF, N2O4, NH3  l  (B) HF, CH4, CH3OH
(C) HF, CH3OH, NH3  l  (D) CH3OH, CH4, NH3  l 

23. Which of the following has lowest boiling point?

(A) HCl (B) HF
(C) HI (D) HBr

VSEPR AND HYBRIDISATION

24. In the Lewis formula of SOCl2, the total number of bond pairs and lone pairs of electrons around sulphur are
(A) 2, 1 (B) 2, 2
(C) 4, 1 (D) 3, 0


25. State of hybridization on chlorine in ClO 4 is
(A) sp3 (B) sp2
(C) sp3d (D) sp

26. Which one of the following will have a tetrahedral nature?

(A) SO2 (B) SO3
2 2
(C) SO 4 (D) SO 3

27. Which of the following is not tetrahedral

 
(A) BF 4 (B) NH 4
2 2
(C) CO 3 (D) SO 4

28. The number of lone pairs is same in PCl3 and

(A) BCl3 (B) NCl3
(C) CCl4 (D) PCl5

29. Which of the following has shortest carbon - carbon bond length
(A) C6H6 (B) C2H6
(C) C2H4 (D) C2H2

30. Which of the following is iso-structural with CO2?

(A) SnCl2 (B) NO2
(C) SnCl4 (D) C2H2

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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31. Among the following species, identify the iso-structural pars

NF3, NO 3 , BF3, H3O+, NH3

(A) [NF3, NO 3 ] and [BF3, H3O+] (B) [NF3, HN3] and [NO 3 , BF3]
(C) [NF3, H3O+] and [NO 3 , BF3] (D) [NF3, H3O+] and [HN3, BF3]


32. The type of hybrid orbitals used by the chlorine atom in ClO 2 is
(A) sp3 (B) sp2
(C) sp (D) None of these

33. Pair of species with different shape, among the following is


(A) [PF5, BrF5] (B) [Br 3 , CO2]
 
(C) [CIF 2 , CIF 2 ] (D) [SF4.XeOF2]

34. HBH bond angle in BH 4 is
(A) 180 (B) 120
(C) 109 (D) 90

35. The species having pyramidal shape is

(A) SO3 (B) BrF3
(C) PCl5 (D) OSF2

36. sp3 hydridization is not found in

(A) H2O (B) CH4
(C) BCl3 (D) NH3

37. The percentage d-character in the hybrid orbitals of ICl5 is

(A) 20 % (B) 33 %
(C) 43 % (D) 50 %

38. Which is linear in shape?

(A) SO2 (B) SF2
 
(C) I3 (D) I 3

39. Matching

List-I List-II
(A) (CH3)3B (P) Square planar
(B) ICl 4
 (Q) Tetrahedral
(C) NH4Cl (R) Trigonal bipyramidal
(D) PCl5 (S) Trigonal planar

40. The compound in which carbon used its sp3 –hybrid orbital for bond formation is
(A) HCOOH (B) (H2N)2CO
(C) HCHO (D) CH3CHO

41. The hbybridisation of carbon in CC single bond in the molecule HCCCHCH2 is
(A) sp3sp2 (B) sp3sp3
2
(C) spsp (D) sp2sp2

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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42. In which of the following, there is a change in hybridisation
 
(A) NH3 + H+  NH 4 (B) CH3Cl  CH 3 + Cl

(C) NH3  NH 2 + H+ (D) H2O + H+  H3O+

43. The octet rule is not valid for which of the following molecules?
(A) CO2 (B) NO
(C) O2 (D) H2O

44. The geometry of H2S an its dipole moment are

(A) Angular and zero (B) Angular and non-zero
(C) Linear and non zero (D) Linear and zero

45. Which of the following molecules have non-bonding electrons pairs on the central atom
(i) SF4 (ii) ICl3 (iii) SO2
(A) (i) & (ii) (B) (i) & (iii)
(C) (ii) & (iii) (D) All

46. Select the incorrect option regarding bond angles

  
(A) PCl 4 > PCl 6 (B) PCl3 > PCl 4

(C) I 3 = CO2 (D) CF4 > XeF4

47. The bond angle is maximum in

(A) H2O (B) BF3
(C) OF2 (D) Cl2O

48. The molecular shapes of SF4, SiF4 and XeF4 are

(A) The same with 2, 0 and 1 lone pair of electrons respectively
(B) The same with 1, 1 and 1 lone pair of electrons respectively
(C) Different with 0, 1 and 2 lone pair of electrons respectively
(D) Different with 1, 0 and 2 lone pair of electrons respectively

49. Which of the following is T-shaped?

(A) XeOF2 (B) XeO3
(C) XeOF4 (D) XeF6

50. Among the following which has bond angle very close to 90
(A) NH3 (B) XeF4
(C) BF3 (D) H2O

51. Carbon atom in C2(CN)4 are

(A) sp hybridised (B) sp2 hybridised
(C) sp and sp2 hybridised (D) sp, sp2 and sp3 hybridised

52 Which among the following has smallest bond angle

(A) H2S (B) NH3
(C) SO2 (D) H2O

53. The states of hybridization of boron and oxygen atoms in boric acid (H3BO3) are respectively
(A) sp3 and sp3 (B) sp2 and sp3
3 2
(C) sp and sp (D) sp2 and sp2

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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54. Which species is electron deficient?
(A) PCl3 (B) PCl5
(C) BCl3 (D) NH3

3
55. The hybridization of P and PO 4 is same as in

(A) l and lCl 4 (B) S in SO3
 2
(C) N in NO 3 (D) S in SO 4


56. The shape of ClO 4 is
(A) square planar (B) square pyramidal
(C) Tetrahedral (D) Trigonal bipyramidal

57. Which among the following species does have angular shape?
  
(i) ICl 2 (ii) NH 2 (iii) I 3 (iv) H2Se
(A) 1, III (B) only III
(C) I, II (D) only IV

58. The total number of lone pair of electron around Xe in XeOF2 is

(A) 0 (B) 1
(C) 2 (D) 3

59. Which of the following represents the given mode of hybridization sp2, sp2, sp, sp from left to right?
(A) CH2 CH C N (B) HC C C CH

CH2
(C) CH2 C C CH2 (D) H2C


60. State of hybridization on phosphorus in PCl 4 is
3
(A) sp (B) sp3d
(C) dsp2 (D) sp2

61. State of hybridization on phosphorus PCl 6 is
(A) sp2 (B) sp3d
(C) sp3d2 (D) sp3p2

62. State of hybridization on central iodine atom in tri iodide ion I 3 is
(A) sp3d (B) sp3
(C) sp2 (D)dsp2
63. State of hybridization on nitrogen in NH4Cl is
(A) sp3 (B) sp2
(C) sp2d (D) sp

64. State of hybridization on boron in BF 4 is
(A) sp3 (B) sp2
(C) sp3d (D) sp3d2
65. State of hybridization on xenon in XeO2 is
(A) sp3d (B) sp3d2
(C) sp3 (D) sp2

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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 Answers
1. C 2. B 3. A 4. B
5. C 6. B 7. B 8. C
9. C 10. B 11. D 12. D
13. B 14. D 15. B 16. D
17. C 18. D 19. C 20. C
21. C 22. C 23. A 24. C
25. A 26. C 27. C 28. B
29. D 30. D 31. C 32. A
33. A 34. C 35. D 36. C
37 B 38. C 39. 40. D
41. C 42. B 43. B 44. B
45. D 46. B 47. B 48. D
49. A 50. B 51. C 52. A
53. B 54. C 55. D 56. C
57. C 58. C 59. A 60. A
61. C 62. A 63. A 64. A
65. A

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FIITJEE Ltd. PLOT NO. 128, INSTITUTIONAL AREA, SECTOR 44, GURGAON, PH. 0124-4628400
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