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Chemistry Topic Wise Important Questions

This document provides chemistry questions on various topics including solid state, chemical kinetics, coordination compounds, d-block and f-block elements, aldehydes ketones and carboxylic acids, and p-block elements. Some example questions are on calculating packing efficiencies in different crystal structures, factors that affect reaction rates, postulates of Werner's theory of coordination compounds, lanthanide and actinide contractions, and preparation and reactions of aldehydes, ketones, and carboxylic acids.

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Parvathamma H N
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439 views3 pages

Chemistry Topic Wise Important Questions

This document provides chemistry questions on various topics including solid state, chemical kinetics, coordination compounds, d-block and f-block elements, aldehydes ketones and carboxylic acids, and p-block elements. Some example questions are on calculating packing efficiencies in different crystal structures, factors that affect reaction rates, postulates of Werner's theory of coordination compounds, lanthanide and actinide contractions, and preparation and reactions of aldehydes, ketones, and carboxylic acids.

Uploaded by

Parvathamma H N
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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CHEMISTRY

Topic Wise important Questions


Topic : Solid State
1) Calculate the packing efficiency in simple cubic unit cell?
2) Calculate the packing efficiency in the face centered cubic lattice?
3) Calculate the packing efficiency in body centered cubic lattice?
4) Calculate the number of particles in i) simple cubic unit ii) body centered lattice iii)
face centered lattice
5) What is i) Schotky defect. ii) Frenkel defect. How does its effect the density of
solid.
Or
6) Give any three differences between Schotky and Frenkel defect with example.
7) Give any four differences between crystalline and amorphous solids.
8) What is F-Centre.
9) Define i) Ferromagnetic substances with an example.
ii) Ferrimagnetic substances with an example.

 Zm 
10) Numericals on density  d  
 a3 N A 

Topic : Chemical kinetics.


1) Mention the factors affecting the rate of reaction.
2) Define molecularity of a reaction.
3) Give any four differences between order and molecularity
4) What is Pseudo-first order reaction? Give an example.
5) Derive an integrated rate equation for zero order reaction.
6) Derive integrated rate equation for rate constant of a first order reaction.
7) Show that for a first order reaction. Half life period is independent of initial
concentration of the reactants.
8) Define i) temperature co-efficient of a reaction.
ii) threshold energy
iii) effective collisions.
iv) collision frequency.
9) Write Arrhenius equation and explain the terms.
10) Explain the effect of a catalyst on the rate of a reaction using graph.
11) What is the unit of i) Rate constant
ii) Zero order
iii) First order
iv) Second order
12) Mention the factors that lead to effective collisions.
13) Problems based on the formulas

0.693  K2  Ea  T  T1 
a) t1/2  b) log   log  2 
K  K1  2.303R  T1T2 

2.303 P  R 0  R 
c) K  log   d) K 
t R  t

14) Explain simple Collision theory of reaction rates.

Topic : Co-Ordination compounds


1) Mention the prostulates of werner’s theory of co-ordination.
2) Define the following with an example.
1) Homoleptic complexes 4) Linkage isomerism
2) Heteroleptic complexes 5) Solvate or hydrate
3) Ionization isomerism 6) Co-ordination isomerism
3) On the basis of VBT explain hybridization, Geometry and magnetic property of

i) [Co( NH 3 )6 ]3 ii) [CoF6 ]3 iii) [( NiCl4 ]2 iv) [ Ni(CN )4 ]2
4) What is spectro chemical series.
5) What are metal carbonyls. Give an example.
6) Energy level diagram of crystal field crystal field splitting in Octahedral complex.

Topic : ‘d’ and ‘f’ – block elements.


1) Give reason Transition metals i) forms interstitial compounds.
ii) show catalytic property
iii) forms alloys
iv) forms coloured compounds
2) What is lanthanoid contraction. Mention the cause for it.
3) Give any three consequences of lanthanoid contraction.
4) What is actinoid contraction.
5) Give any four differences between lanthanoids and actinoids.

Topic : Aldehydes, Ketones and Carboxylic acids


1) How do you prepare aldehydes from nitriles or
Explain stephen’s reduction with an example
2) Explain Rosemund reduction with an example.
3) What is Etard’s reaction, Give equation.
4) Explain Gattermann-Koch-reaction with an example.
5) Explain the mechanism of addition of HCN to aldehyde or Ketone.
6) How does Aldehydes and Ketones reacts with ammonia and the derivatives of
ammonia.
7) What is Clemmensen reduction. Give an example.
8) What is Wolf-Kishner reduction. Give an example.
9) What is aldol condensation. Give an example.
10) What is Cannizaro’s reaction. Give an example.
11) What is effect of EDG and EWG on the acidity of Carboxylic acids.
12) Explain Hell-Volhard – Zelinsky reaction. Give an example.

P - block elements
1. In the manufacture of ammonia by Haber’s process write the flow chart and chemical
equations with optimum conditions.
2. i) Mention any two reasons for the anomalous behaviour of oxygen.
ii) Write the balanced chemical equation for the action of conc H2SO4 on copper metal.
3. i) Complete the following equations

a) 2NaOH  Cl2  b) Cl2  3F2 

ii) Write the structure of chlorous acid [HoClO].


4. Write the balanced chemical equation with condition involved in manufacture of nitric acid
by Ostwald’s process.
5. a) How is chlorine prepared using KMnO4?
b) Why is I2 less reactive ICl?
6. Complete the following chemical equations.

i) pbS  HO3  PbSO4     

ii) Cu  2H 2SO4  CuSO4      2H 2O

iii) Cl2  2H 2O  SO2      2HCl

7. a) How does hot and concentrated sodium hydroxide reacts with chlorine? Write equation.
b) How does electronegativity of Halogens vany down the group?
8. Complete the following equations

i) CH 4  2O2  iii) C12H22O11  H2SO4 


3
ii) 2Fe  SO2  2H 2O 

9. a) Which is the strongest acid among the hydrogen halides? Give one reason (X=F, Cl, Br, I)
b) Write the structure of chloric acid (HClO3)
10. a) Name the gas liberated when zinc reacts with dil. HNO 3.
b) Give reason
i) PH3 has lower boiling point than NH3.
ii) Nitrogen gas is less reactive at room temperature.

11. a) Complete the reaction Cl2  2H 2O  SO2    

b) i) Which halogen has highest electron affinity (or) electron gain enthalpy?
ii) Give the structure of perchloric acid (HClO4).
12. Write the equation far
i) the action of SO2 with chlorine in the presence of charcoal.
ii) the action of SO3 with conc. Sulphuric acid.
iii) the action of ozone with lead sulphide.
13. Describe the preparation of ozonised oxygen with an equation. Name the ozonised product
obtained when the ozone react with lead sulphide.
14. Complete the following equations:

i) 2Al  3Cl2  ii) H2S  Cl2  iii) 8NH 3  3Cl2  .

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