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TUTORIAL CHAPTER 1 by DR - Kavirajaa

This document contains 20 practice problems about thermo chemistry concepts like standard enthalpy of formation and combustion, endothermic and exothermic reactions, heat capacity, enthalpy changes of various chemical reactions, and calculating enthalpy using thermochemical data. The problems involve defining terms, classifying reactions as endothermic or exothermic, calculating energy and temperature changes, and determining enthalpy of reactions using standard enthalpies of formation and combustion from tables.

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athirah ashikin
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146 views4 pages

TUTORIAL CHAPTER 1 by DR - Kavirajaa

This document contains 20 practice problems about thermo chemistry concepts like standard enthalpy of formation and combustion, endothermic and exothermic reactions, heat capacity, enthalpy changes of various chemical reactions, and calculating enthalpy using thermochemical data. The problems involve defining terms, classifying reactions as endothermic or exothermic, calculating energy and temperature changes, and determining enthalpy of reactions using standard enthalpies of formation and combustion from tables.

Uploaded by

athirah ashikin
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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CHM 213 PHYSICAL CHEMISTRY

TUTORIAL CHAPTER 1 : THERMOCHEMISTRY

1. Define the following the terms:


a. Standard enthalpy of formation
b. Standard enthalpy of combustion
c. Endothermic reaction
2. Justify the following processes are exothermic or endothermic with suitable explanation.
a. When acetone get mixed in water, the solution gets colder.
b. Butane gas burned in portable stove.
3. The specific heat capacity in liquid water is 4.18 JK -1g-1. Calculate the energy required to heat 1.0
mol of water from 298 K to 362 K.
Ans: 4.9kJ
4. The specific heat capacity of copper metal is 0.38 J K -1g-1. Calculate the temperature rise
of a 100 g bar of copper when 250 J of heat are transferred to it.

Ans: 6.58 K

5. The standard enthalpy change of vaporization of ethanol is +43.5 kJ mol -1. Calculate the
enthalpy change when 0.5g of ethanol vaporizes at its boiling point at 1 bar.
Ans: 0.47 kJ

6. In a chemistry experiment, 10 g of urea NH 2CONH2(s) is dissolved in 150 ml of water in a


simple calorimeter. A temperature decrease of 3.7 OC is measured. Calculate the molar
enthalpy of solution for urea.
Ans: + 13.9 kJ mol-1

7. A laboratory technician initially adds 43.1 mL of concentrated 11.6 mol/L hydrochloric


acid to water to form 500 mL of dilute solution. The final temperature of the solution
shows an increase of 2.6 OC. Calculate the molar enthalpy of dilution of hydrochloric
acid.
Ans: - 11 kJ mol-1

8. 1.922 g methanol (CH3OH) was burned in a constant-volume bomb calorimeter.


Consequently, the temperature of the water rose by 4.20 °C. If the quantity of water

Prepared by Dr.KAVIRAJAAPage 1
CHM 213 PHYSICAL CHEMISTRY

surrounding the calorimeter was exactly 2000 g and the heat capacity of the
calorimeter was 2.02 kJ°C-1, calculate the molar heat of combustion of methanol.
Assume the specific heat capacity of CH3OH is 4.184 Jg-1°C-1. (Relative atomic mass of
C=12; 0=16; H=1)
Ans: -725 kJ mol-1

9. A 50.0 mL solution of 1.2 M HCl at 24.1 oC is mixed with 50.0 mL of 1.2 M NaOH, also at
24.1 oC in a coffee cup calorimeter. After the reaction occurs, the temperature of the
resulting mixture is 29.8 oC. The density of the final solution is 1.05 g/ mL. Calculate the
molar heat of neutralization. Assume the specific heat of the solution is 4.184 J g -1 oC-1.
The heat capacity of the calorimeter is 32.5 J oC-1
Ans: 42.8 kJ mol-1
10. The standard enthalpy change of vaporization of water is +40.7 kJ mol -1. An electric
kettle is rated at 3kW (1kW = 1 kJ s -1). How long will it take to evaporate 1.0 kg of water
at 100°C? Give the answer in minutes.
Ans: 12.5 min
11. Assuming that 400 J of energy is absorbed by 7.50 g of iron, calculate the change in
temperature (ΔT) in the iron? If the initial temperature (T 1) of the iron is 30.0°C, what
will be its final temperature (T2) in unit °C? The heat capacity of iron (C) is 0.450Jg -1K-1.
Ans: 421.5 K

12. A 10.0 g sample of pure acetic acid (CH3COOH) is completely burned. The heat released
from the combustion is used to warm 2.00 L of water from 22.3 ℃ to 39.6 ℃. Assuming
no heat was lost to the surroundings, what is the enthalpy of combustion of acetic acid?
Express your answer in kJ/g and kJ/mole.
Ans: -852 kJ/mol and -14.5 kJ/g

13. Calculate the enthalpy for this reaction: (Ans : +226.7 kJ)

2C(s) + H2(g) ---> C2H2(g) ΔH° = ??? kJ

Given the following thermochemical equations:

C2H2(g) + (5/2)O2(g) ---> 2CO2(g) + H2O(ℓ) ΔH° = -1299.5 kJ


C(s) + O2(g) ---> CO2(g) ΔH° = -393.5 kJ
H2(g) + (1/2)O2(g) ---> H2O(ℓ) ΔH° = -285.8 kJ

14. Using the following data


Li(l) + ½Cl2(g)  LiCl(l) ΔrHo298 = -386.49 kJ
Li(l) + ½Cl2(g)  LiCl(s) ΔrHo298 = -406.29 kJ

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CHM 213 PHYSICAL CHEMISTRY

Predict the enthalpy of fusion for LiCl(l) at 883K


Ans. 19.80 kJ
15. Calculate the enthalpy change for reaction (a), given the data in equations (b), (c), and
(d).
(a) 2 C(graphite) + 2 H2 (g)  C2H4(g) ∆H = ?
(b) C(graphite) + O2 (g)  CO2 (g) ∆H = -393.5 kJ
(c) C2H4(g) + 3 O2(g)  2CO2(g) + 2H2O(l) ∆H = -1410.9 kJ
(d) H2(g) + ½ O2(g)  H2O(l) ∆H = -285.8 kJ
Ans. 52.3 kJ
16. Calculate the standard enthalpy change for the reaction,
C2H2 (g) + 2 H2 (g)  C2H6 (g)

Given that:

i) 2 C2H2 (g) + 5 O2 (g)  4 CO2 (g) + 2 H2O (l) ΔHo = - 2599 kJ


ii) 2 C2H6 (g) + 7 O2 (g)  4 CO2 (g) + 6 H2O (l) ΔHo = - 3119 kJ
iii) 2 H2 (g) + O2 (g)  2 H2O (l) ΔHo = - 572 kJ
Ans: -312.0 kJ

17. Calculate the enthalpy of reaction for the process:


C2H4(g) + HCl(g)  C2H5Cl(g)
Given that:-
ΔHf°298/ (kJ/mol) : C2H5Cl : -112.17
HCl: -92.31
C2H4: +52.26
Ans: -72.12 kJ/mol
18. Synthesis gas is a mixture of carbon monoxide and hydrogen that is used to synthesize a
variety of organic compounds. One reaction for producing synthesis gas is
3 CH4(g) + 2H2O(l) + CO2(g)  4CO(g) + 8 H2(g) ΔHo = ?

Use standard enthalpies of formation from table 6.2 to calculate the standard enthalpy
change for this reaction

Ans. +747.5 kJ/mol

19. Use data form table 6.2 to calculate ΔHo for the combustion of butane gas, C4H10 , to
produce gaseous carbon monoxide and liquid water
Ans. -1996.7 kJ/mol

20. The combustion of isopropyl alcohol, common rubbing alcohol, is represented by the
equation
2 (CH3)2CHOH(l) + 9 O2 (g)  6 CO2(g) + 8 H2O(l) ΔHo = -4011 kJ

Use this equation and data from Table 6.2 to establish the standard enthalpy of

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CHM 213 PHYSICAL CHEMISTRY

formation for isopropyl alcohol.


Ans. -318 kJ/mol

Prepared by Dr.KAVIRAJAAPage 4

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