SAFETY DATA SHEET

HEAVY DUTY TYRE MARK REMOVER/CLEANER

Page: 1
Compilation date: 11/09/2017
Revision No: 2

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: HEAVY DUTY TYRE MARK REMOVER/CLEANER

Product code: EN701
1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Company name: Bio8 Limited

Unit 8
Markham Vale Environment Centre
Chesterfield
Derbyshire
S44 5HY
UK
Tel: 01246 240880
Fax: 01246 240880
Email: [email protected]
1.4. Emergency telephone number

Emergency tel: 01246 240880

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Eye Irrit. 2: H319

Most important adverse effects: Causes serious eye irritation.
2.2. Label elements

Label elements:
Hazard statements: H319: Causes serious eye irritation.
Hazard pictograms: GHS07: Exclamation mark

Signal words: Warning

Precautionary statements: P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists: Get medical attention.

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2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

(2-METHOXYMETHYLETHOXY)PROPANOL - REACH registered number(s): 01-2119450011-60

EINECS CAS PBT / WEL CLP Classification Percent
252-104-2 34590-94-8 Substance with a Community - 10-30%
workplace exposure limit.
PROPAN-2-OL
200-661-7 67-63-0 - Flam. Liq. 2: H225; Eye Irrit. 2: H319; 1-5%
STOT SE 3: H336
ETHOXYLATED ALCOHOLS C9/11
605-233-7 160875-66-1 - Acute Tox. 4: H302; Eye Dam. 1: H318 1-5%
ACETIC ACID
200-580-7 64-19-7 - Flam. Liq. 3: H226; Skin Corr. 1A: H314 1-5%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of
water to drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.
4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: Nausea and stomach pain may occur. There may be vomiting and diarrhoea.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray
to cool containers.

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5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Do not attempt to take action without suitable protective clothing - see section 8 of SDS.
Turn leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for
disposal by an appropriate method.
6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Avoid the formation or spread of mists in the air.
7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

(2-METHOXYMETHYLETHOXY)PROPANOL

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL
UK 50ppm(sk) - - -
PROPAN-2-OL
UK 999 mg/m3 1250 mg/m3 - -

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DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratory protection: Not required.
Hand protection: Protective gloves.
Eye protection: Ensure eye bath is to hand. Safety glasses with side-shields.
Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid
Colour: Pale green
Odour: Pleasant
Evaporation rate: Slow
Oxidising: Not applicable.
Solubility in water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: 100 Melting point/range°C: 0
Flammability limits %: lower: Not applicable. upper: Not applicable.
Flash point°C: Not applicable. Part.coeff. n-octanol/water: No data available.
Autoflammability°C: Not applicable. Vapour pressure: No data available.
Relative density: 1.045 pH: Approx. 7
VOC g/l: Not applicable.
9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

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10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

(2-METHOXYMETHYLETHOXY)PROPANOL
DERMAL RBT LD50 9150 mg/kg
ORAL RAT LD50 >5000 mg/kg

PROPAN-2-OL
ORAL RAT LD50 5045 mg/kg
VAPOURS RAT 4H LC50 10000 ppmV

ETHOXYLATED ALCOHOLS C9/11

ORAL RAT LD50 500 mg/kg

ACETIC ACID...100%
IVN MUS LD50 525 mg/kg
ORL RAT LD50 3310 mg/kg

Relevant hazards for substance:

Hazard Route Basis
Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: Nausea and stomach pain may occur. There may be vomiting and diarrhoea.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

(2-METHOXYMETHYLETHOXY)PROPANOL
DAPHNIA 48H EC50 1919 mg/l
FISH 96H LC50 >1000 mg/l
GREEN ALGA (Selenastrum capricornutum) 96H ErC50 >969 mg/l

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ETHOXYLATED ALCOHOLS C9/11

Daphnia magna 48H EC50 >10-100 mg/l
Scenedesmus Subspicatus 72H ErC50 >10-100 mg/l

12.2. Persistence and degradability

Persistence and degradability: The surfactant(s) contained in this preparation complies (comply) with the
Biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents, (or
are undergoing testing to obtain a derogation within the terms of the directive). Data to
support this assertion are held at the disposal of the competent authorities of the
Member States and will be made available to them, at their direct request or at the
request of a detergent manufacturer.
12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil. Soluble in water.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal
company.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
453/2010.
* indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H225: Highly flammable liquid and vapour.

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H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. This company shall not be held liable for any
damage resulting from handling or from contact with the above product.

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