Page Revision No.

Date of Issuance Effective Date

1 of 8 2 August 2013 3 Years

Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Booster - Pentex

Other Names: Pentex CD 150, Pentex CD 225, Pentex CD 450, Pentex CD 900
Pentex CO 450, Pentex CO 900, Pentex CO 1350
Recommended Use: Initiating explosive charges.
Supplier: Orica Chile S.A.
Address: Camino a Mejillones Km. 18 Antofagasta, Chile
Phone No.: +55 2 565 600
Facsimile: +56 55 2 565 633
Emergency Number: Calls from Chile: 55 2 565 600 / 9 873 47 84
Calls from other countries:+56 55 2 565 600 / +56 99 873 47 84

2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Nature: Solid mix of TNT and a sensitizer like PETN.

Components Synonym CAS Number UN Number Composition (%) Risk Phrases

Pentaerythritol
PETN 78-11-5 0150 <60 R3
Tetranitrate
R3, R33, R53,
Trinitrotoluene TNT 118-96-7 0209 <50
R23/24/25

Risk Phrases:

R3 High risk of explosion by shock, friction, fire or other sources of ignition.

R 33 Danger of cumulative effects.
R 53 May cause long-term adverse effects in the aquatic environment.
R 23/24/25 Toxic by inhalation, ingestion and skin contact.

3. HAZARDS IDENTIFICATION

Risk Label : EXPLOSIVE

1.1D
1

Risk Class: Class 1 – EXPLOSIVE

Risk Class and Division: 1.1D

UN Number: 0042

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A) Hazards to People's Health:

Effects of Acute Over Exposure (for once):

 Inhalation: High concentrations of this product are irritating to airways

and cause headaches.

 Skin Contamination: It may cause irritation and/or dermatitis, it may be absorbed

through the skin.

 Eye Contact: It may cause irritation. (Conjunctivitis)

 Ingestion: It may cause nausea and vomiting.

TNT: It causes headaches, weakness, anemia.
PETN: It is a vasodilator.

Effects over chronic exposure (long-term):

 Inhalation: Loss of appetite.

 Skin Contamination: Dermatitis and sensitization.

 Eye Contact: No information available.

 Ingestion: Liver damage, cyanosis.

b) Environmental Risks: Explosion damage.

c) Substance Special Risks: It is a high explosive. In case of ingestion, perform gastric

lavage and then saline cathartics.
Perform a blood transfusion if necessary.
Always seek immediate medical attention.

4. FIRST AID MEASURES

The construction of this product avoids contact with explosive component, however, in case of contact or accidental exposure, provide
the proper first aid treatment to the current symptoms.

Leave the area in case fire affects the product directly as there is a risk of mass explosion.

Inhalation: Move the victim to fresh air. Provide artificial respiration or cardiopulmonary resuscitation ONLY if the
victim has stopped breathing and has no pulse. Oxygen must be administered by properly trained
personnel.

Skin: Wash the affected area with large amounts of water and soap. Remove contaminated clothing. If
irritation persists, seek immediate medical attention. TNT may be absorbed through the skin.

Eyes: Wash with water for at least 20 minutes, seek for medical attention immediately.

Ingestion: Rinse mouth and do not induce vomiting. Seek medical attention immediately. Do not administer
anything if the person is unconscious.

Notes to Physician: Administer oxygen in case of cyanosis symptoms. There is no specific treatment, treat symptomatically.

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5. FIRE FIGHTING MEASURES

Specific Hazard: Explosive material, avoid all kinds of ignition. Risk of explosion by shock, sparks,
friction, fire or other sources of ignition. A fire may cause risk of explosion. There
is a mass explosion risk also. DO not fight fire.

Fire Extinction Means: Do not fight fire.

Procedure to fight fire: Isolate the affected area and move all the personnel immediately. Let it burn
completely. Avoid toxic fumes that could emanate from fire. There is a high risk
of explosion.

Personal Protective Equipment: Firemen must use self-contained breathing apparatus (SCBA) approved by
NIOSH or equivalent if there is risk of vapor and gas exposure and also use
protective or fireproof clothing that isolates pollutants or toxic substances
generated from combustion.

6. MEASURES TO CONTROL LEAKS OR SPILLS

General Emergency Information:

The following information shows potential risks associated with the ingredients in this product. We believe that, under normal working
conditions, this product should pose no risk for the user. The main risks result from an explosion caused by shock, friction, fire, or any
other source of ignition. For a more detailed risk evaluation, please read this Safety Data Sheet thoroughly.

Emergency Measures to be Taken in Case of Material Leakage or Spillage:

 In case of a transport accident, notify Orica Mining Services Chile immediately by dialing Emergency Number
+56 55 2 565 600 / +56 99 873 47 84.
 Organize and signal the affected area.
 Eliminate all sources of ignition possible.
 Follow all the procedures for the collection of waste or elements and their provisions only with trained and qualified personnel.
 Notify authorities in accordance with emergency response procedures.
 Just the personnel which has been trained in emergency response shall respond.
 Normal precautionary measures may be taken when handling explosives as long as there is no fire hazard and product isn't
damaged or contaminated.

Personal Protective Equipment to Attack the Emergency:

 Glasses, gloves, proper work clothing (overall).

Precautions to be Taken to Avoid Environmental Damage:

 Do not drain the material to rivers, lakes, tributaries, etc. Do not drain to sewage system.

Waste Cleaning and Disposal Method:

 Controlled burning under strict safety procedures.
Do not drain the material to rivers, lakes, tributaries, etc. Do not drain to sewage system. Contact Orica Mining services in case of
any questions on final disposal. Containment and cleaning methods and material: Collect with non-metallic implements. Use an
anti-spark shovel. Collect and seal the labeled containers hermetically.

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Waste Disposal Method:

Residual material disposal must comply with legal regulations. If the product becomes waste, it will be regulated as potentially
dangerous. Review the requirements and procedures for hazardous waste disposition with a person who is properly informed of the
existing environmental law before disposing any explosive material or hazardous waste.

7. HANDLING AND STORAGE

Technical Recommendations for Safe Handling:

 Place away from heat, sparks or flame sources.
 Do not expose the material to impacts, friction between hard surfaces or any form of heat.
 For any reason or purpose, do not try to drill, disarm, divide or extract product content as it contains explosives.
 Handling is only permitted to trained and authorized personnel.

Recommendations for Safe Handling:

 Handle carefully and use the proper personal protective elements.
 Do not smoke when handling the product or in storage areas.
 Handling is only permitted to trained and authorized personnel.
 Based on Arms Control and Explosives Law No. 17.798.

Recommendations for Storage:

 Store in a magazine authorized by the audit authorities in accordance with Law No. 17.798.
 Keep away from incompatible materials. Combustible materials, oxidizing agents, reducing agents and alkali (corrosive agents).
 Comply with all the local and international regulations that rule transportation, storage and use of explosives.
 Keep in their original boxes and closed inside magazines.

Used and Recommended Packages:

 Packaging and hauling in cardboard boxes.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

 Measures to Reduce the Number of Exposures:

 Usage conditions, engineering controls, real exposure situations and other tests will determine the need of specific protective
devices at your workplace.
 Make sure there is a good ventilation during product manufacturing. This is not required for its normal handling.
 Use personal protective elements.
 It can just be handled by qualified personnel.
 Keep packages labeled in their respective boxes.
 Respect restrictions of smoking, eating and drinking at the workplace. Wash your hands and face carefully after handling
compounds and/or product, before smoking and at the end of the day. Do not eat, drink or smoke in contaminated areas.
Control Parameters:

 Permissible Exposure Limit (PEL): TNT = 0.4 mg/m³ (skin); PETN = Not established. (According to DS 594 from the Chilean
Ministry of Health).
 Temporary Exposure Limit (TEL): Not applicable

 Absolute Exposure Limit (AEL): Not applicable

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Protections:

 Ventilation:
Not required for its normal handling.

 Breathing Protection:
Not required for its normal handling. It must be ventilated after use in underground mines or other nearby areas. A good ventilation
is required during its manufacturing process.

 Protective Clothing:
Use of cotton is recommended. Coveralls are needed if there is any possibility of exposure.

 Skin Protection:
Gloves and cotton-made clothing should provide proper protection.

 Visual Protection:
It is recommended the use of safety glasses with side protection when handling the product.

9. PHYSICAL AND CHEMICAL PROPERTIES

 Physical State: Solid.

 Appearance / Odor: Pale yellow, crystalline melted solid explosive coated by a plastic container
for Pentex CD (cylindrical) and a cardboard one for Pentex CO (conical).
 Color: Container's outer coating = Orange.
 Odor: Odorless.
 Solubility: Not soluble in water, it is soluble in acetone.
 Density: 1.62 g/ml
 pH: 6 to 7
 Concentration: Not applicable.
 Auto-ignition Temperature: No information available.
 Decomposition Temperature: > 120 °C
 Ignition Temperature: Not applicable.
 Explosion Point: > 180 °C
 Flash Point: Not applicable.
 Upper Flammable Limit Not applicable.
 Lower Flammability Limit: Not applicable.
 Explosive Properties: Yes.
 Fire or Explosion Risks: Yes.
 Flame Propagation Speed: Not applicable.

10. STABILITY AND REACTIVITY

Stability: Explosive material. Avoid ignition sources, discharge static electricity and
avoid friction. Detonation could occur due to impact, sparks, friction or
overheating, particularly under containment. It is stable when kept humid
and in a cool place.

Conditions to be Avoided: Keep away from heat, impact, ignition sources, flames, electrostatic
discharges. Temperature must not be more than 66 °C.

Hazardous Products from Decomposition: Nitrous gases (NO X) and (CO X).

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Hazardous Products from Combustion: Nitrous gases (NO X) and (CO X).

Incompatibility: Incompatible with combustible materials, oxidizing agents, reducing

agents, acids and alkali (corrosive agents).

Hazardous Reactions: Explosive material. Detonation could occur by strong impact or

overheating, particularly under containment.There will be no dangerous
polymerization.

11. TOXICOLOGICAL INFORMATION

The construction of these articles should prevent any chemical contamination. No adverse health effects expected if the product is
handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is
mishandled and overexposure occurs are:

Short-term Toxicity: TNT: LD50 (oral in mice) = 607 mg/kg

PETN: LD50 (oral in mice) = 1660 mg/kg

Long-term Toxicity: Substances contained in this product may cause damage to the following organs:
blood, kidneys, liver, cardiovascular system, high respiratory tract, skin, central nervous
system, corneas.

Eye Contact: May be an eye irritant. However, it is not a possible exposure route.

Skin Contact: Prolonged contact with the contents of this product could cause dermatitis and could be a
significant source of exposure.

Ingestion: Ingestion may cause nausea, vomiting, weakness, dizziness, headaches, cyanosis, pallor,
liver damage, blood effects and convulsions. May have effects on the central nervous
system.

12. ECOTOXICOLOGICAL INFORMATION

Instability: Product is stable under normal temperature conditions.

Persistence / Degradability: No information available..

Bioaccumulation: Bioaccumulation is not expected.

Effects on the Environment: No information available for this product.

PETN: Chemically stable in a non-acid environment. May be dangerous if in contact with
drinking water network. Highly soluble in water.

Ecotoxicity: Avoid contamination of waterways.

Aquatic Toxicity: Dangerous to the environment; very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.

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13. FINAL DISPOSAL CONSIDERATIONS

Product Disposal Method: Damaged or deteriorated explosives must be destroyed under strict
procedures of controlled burning, or notify Orica Mining Services in
Chile. (All methods recommended by the Chilean and international
standards for disposing residues or waste shall be complied).

Disposal of Contaminated Containers and Packaging: Containers and packages contaminated with explosive residues
shall be removed immediately to an intermediate storage place to
proceed to its subsequent destruction safely, under strict
procedures of controlled burning. Product and package are
considered hazardous residues. (All methods recommended by the
Chilean and international standards for disposing residues or waste
shall be complied).

14. TRANSPORT INFORMATION

UN Number 0042

Risk Class and Division 1.1D

Transport Name BOOSTERS

Mark on Risk Label 1.1D / EXPLOSIVE

15. REGULATORY INFORMATION / EXISTING STANDARDS

This product is an 'explosive' and shall comply with the local regulations for the transportation of dangerous goods; in case of transport, it
will be based on the 'International Maritime Dangerous Goods Code” (IMDG Code) and the 'IATA Dangerous Goods Regulations'.

Air Transport:
TRANSPORT IS FORBIDDEN by the 'International Air Transport Association' (IATA) - Dangerous Goods Regulations in air transport on
airliners and cargo planes.

 International Standards Applicable:

IMDG: International Maritime Dangerous Goods Code from the International Maritime Organization.
IATA: Dangerous Goods Regulations for the air transport of dangerous goods.

 National Standards Applicable:

NCh382 / NCh2120 / NCh2190 / NCh2245

 This product is an 'explosive' and shall comply with the "General Regulations on the Transport of Valid Dangerous Goods' and with
the 'National Law on Arms and Explosives'.

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16. OTHER INFORMATION

Data reported in this datasheet were obtained from reliable sources. However, they are provided with no express or implicit warranty
regarding their accuracy or correction. Opinions expressed in this form are from trained professionals. Information provided in it is the one
known currently on this matter. Considering that the use of this information and the products is beyond the control of the supplier, no
liability is assumed by the company on this purpose. The establishment of conditions on the safe use of the product is the user's
responsibility. The purpose of this document is to be used as a summarized data source for employees and employers, owners, chief
security officers, doctors, hygienists and other professionals that could need it. It is not intended to provide all the specialized information
on this regard, but the most important data.

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