0% found this document useful (0 votes)
1K views10 pages

PU Foam Safety Guide

This safety data sheet provides information on an aerosol foam product. It lists the product name and code, identifies the manufacturer, and provides the manufacturer's contact information. It also summarizes the product's hazards, including that it is extremely flammable, may cause cancer, skin and eye irritation, and respiratory issues. The main hazardous ingredient is identified as an isocyanate compound.

Uploaded by

Emin Mešić
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
1K views10 pages

PU Foam Safety Guide

This safety data sheet provides information on an aerosol foam product. It lists the product name and code, identifies the manufacturer, and provides the manufacturer's contact information. It also summarizes the product's hazards, including that it is extremely flammable, may cause cancer, skin and eye irritation, and respiratory issues. The main hazardous ingredient is identified as an isocyanate compound.

Uploaded by

Emin Mešić
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

805 MULTI PURPOSE PU FOAM

Safety Data Sheet


according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Trade name : 805 MULTI PURPOSE PU FOAM
Product code : 805
Type of product : Aerosol
Vaporizer : Aerosol
Product group : Trade product

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Main use category : Industrial use,Consumer use,Professional use

1.2.2. Uses advised against


No additional information available
1.3. Details of the supplier of the safety data sheet
AKKİM YAPI KİMYASALLARI SANAYİ ve TİCARET A.Ş.
Yeşilbayır mahallesi Şimşir sokak No:22
34555 İSTANBUL - TURKEY
T +90 2127711371 - F +90 2127713888
[email protected] - www.akfix.com
1.4. Emergency telephone number
Emergency number : +90 2127711371 (9:00 am - 17:00 pm GMT+2)
Country Organisation/Company Address Emergency number Comment
United Kingdom National Poisons Information Claremont Place 0844 892 0111 (UK
Newcastle-upon-Tyne
Service (Newcastle Centre) NE1 4LP Newcastle only, Monday to Friday,
Regional Drugs and Therapeutics Centre 08.00 to 18.00 hours)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830
(REACH Annex II)
Aerosol, Category 1 H222;H229 On basis of test data
Acute toxicity (inhalation:gas) Category 4 H332 Calculation method
Skin corrosion/irritation, Category 2 H315 Calculation method
Serious eye damage/eye irritation, Category 2 H319 Calculation method
Sensitisation — Respiratory, Category 1 H334 Calculation method
Sensitisation — Skin, Category 1 H317 Calculation method
Carcinogenicity, Category 2 H351 Calculation method
Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H335 Calculation method
Specific target organ toxicity — Repeated exposure, Category 2 H373 Calculation method
Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects


Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through
prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

2/19/2016 EN (English) 1/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

2.2. Label elements


Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS07 GHS08


Signal word (CLP) : Danger
Hazardous ingredients : Isocyanic acid, polymethylenepolyphenylene ester
Hazard statements (CLP) : H222 - Extremely flammable aerosol
H229 - Pressurised container: May burst if heated
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 - May cause respiratory irritation
H351 - Suspected of causing cancer
H373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements (CLP) : P102 - Keep out of reach of children
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking
P211 - Do not spray on an open flame or other ignition source
P251 - Do not pierce or burn, even after use
P280 - Wear eye protection, protective clothing, protective gloves, face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P302+P352 - IF ON SKIN: Wash with plenty of water
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P342+P311 - If experiencing respiratory symptoms: Call a doctor, a POISON CENTER
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation
P261 - Avoid breathing gas, spray, vapours
EUH-statements : EUH204 - Contains isocyanates. May produce an allergic reaction
Child-resistant fastening : Not applicable
Tactile warning : Applicable

2.3. Other hazards


No additional information available

SECTION 3: Composition/information on ingredients


3.1. Substance
Not applicable

3.2. Mixture

Name Product identifier % Classification according to


Regulation (EC) No.
1272/2008 [CLP]
Isocyanic acid, polymethylenepolyphenylene ester (CAS No) 9016-87-9 20 - 35 Acute Tox. 4 (Inhalation), H332
(REACH-no) 01-2119457014-47 Skin Irrit. 2, H315
Eye Irrit. 2, H319
Resp. Sens. 1, H334
Skin Sens. 1, H317
Carc. 2, H351
STOT SE 3, H335
STOT RE 2, H373
isobutane (CAS No) 75-28-5 2.5 - 10 Flam. Gas 1, H220
(Note C)(Note U) (EC no) 200-857-2
(EC index no) 601-004-00-0
(REACH-no) 01-2119485395-27
dimethyl ether (CAS No) 115-10-6 2.5 - 10 Flam. Gas 1, H220
2/19/2016 EN (English) 2/10
805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0
(Note U) (EC no) 204-065-8 Press. Gas
(EC index no) 603-019-00-8
(REACH-no) 01-2119472128-37
propane (CAS No) 74-98-6 2.5 - 10 Flam. Gas 1, H220
(Note U) (EC no) 200-827-9 Press. Gas
(EC index no) 601-003-00-5
(REACH-no) 01-2119486944-21

Note C : Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. In this case the supplier
must state on the label whether the substance is a specific isomer or a mixture of isomers.
Note U : When put on the market gases have to be classified as ‘Gases under pressure’, in one of the groups compressed gas, liquefied gas,
refrigerated liquefied gas or dissolved gas. The group depends on the physical state in which the gas is packaged and therefore has to be assigned
case by case.
Full text of H-statements: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you
feel unwell.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.
First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs:
Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
Symptoms/injuries after skin contact : Irritation. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Extremely flammable aerosol.
Explosion hazard : Pressurised container: May burst if heated.
Hazardous decomposition products in case of : Toxic fumes may be released.
fire
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe
dust/fume/gas/mist/vapours/spray. Avoid contact with skin and eyes.

6.1.2. For emergency responders


Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.

2/19/2016 EN (English) 3/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

6.3. Methods and material for containment and cleaning up


Methods for cleaning up : Recover mechanically the product. Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not
pierce or burn, even after use. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Wear personal protective equipment. Do
not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area.
Avoid contact with skin and eyes.
Hygiene measures : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed
out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands
after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Store locked
up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
805 MULTI PURPOSE PU FOAM
Germany Local name pMDI(alsMDIberechnet)
Germany TRGS 900 Occupational exposure limit value (mg/m³) 0.05 mg/m³
Germany Remark (TRGS 900) DFG,H,Sah,Y,12

805 MULTI PURPOSE PU FOAM


DNEL/DMEL (Workers)
Acute - systemic effects, dermal ≈ mg/kg bodyweight/day

8.2. Exposure controls


Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
Environmental exposure controls : Avoid release to the environment.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Liquid under pressure.
Colour : light yellow.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
2/19/2016 EN (English) 4/10
805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

Flash point : 0 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Extremely flammable aerosol
Vapour pressure : 5 bar
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 19 - 25 kg/m³
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Pressurised container: May burst if heated.
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
VOC content : < 2 g/l

SECTION 10: Stability and reactivity


10.1. Reactivity
Extremely flammable aerosol. Pressurised container: May burst if heated.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity : Inhalation:gas: Harmful if inhaled.
ATE CLP (gases) 12857.143 ppmv/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.

Reproductive toxicity : Not classified


Specific target organ toxicity (single exposure) : May cause respiratory irritation.

Specific target organ toxicity (repeated : May cause damage to organs through prolonged or repeated exposure.
exposure)
Aspiration hazard : Not classified
805 MULTI PURPOSE PU FOAM
Vaporizer Aerosol

2/19/2016 EN (English) 5/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.

12.2. Persistence and degradability


No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available

12.6. Other adverse effects


No additional information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1950
UN-No. (IMDG) : 1950
UN-No. (IATA) : 1950
UN-No. (ADN) : 1950
UN-No. (RID) : 1950
14.2. UN proper shipping name
Proper Shipping Name (ADR) : AEROSOLS
Proper Shipping Name (IMDG) : AEROSOLS
Proper Shipping Name (IATA) : Aerosols, flammable
Proper Shipping Name (ADN) : AEROSOLS
Proper Shipping Name (RID) : AEROSOLS
Transport document description (ADR) : UN 1950 AEROSOLS, 2.1, (D)
Transport document description (IMDG) : UN 1950 AEROSOLS, 2.1
Transport document description (IATA) : UN 1950 Aerosols, flammable, 2.1
Transport document description (ADN) : UN 1950 AEROSOLS, 2.1
Transport document description (RID) : UN 1950 AEROSOLS, 2.1
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 2.1
Danger labels (ADR) : 2.1

IMDG
Transport hazard class(es) (IMDG) : 2.1

2/19/2016 EN (English) 6/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

Danger labels (IMDG) : 2.1

IATA
Transport hazard class(es) (IATA) : 2.1
Hazard labels (IATA) : 2.1

ADN
Transport hazard class(es) (ADN) : 2.1
Danger labels (ADN) : 2.1

RID
Transport hazard class(es) (RID) : 2.1
Danger labels (RID) : 2.1

14.4. Packing group


Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : 5F
Special provisions (ADR) : 190, 327, 344, 625
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E0

2/19/2016 EN (English) 7/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

Packing instructions (ADR) : P207, LP02


Special packing provisions (ADR) : PP87, RR6, L2
Mixed packing provisions (ADR) : MP9
Transport category (ADR) : 2
Special provisions for carriage - Packages : V14
(ADR)
Special provisions for carriage - Loading, : CV9, CV12
unloading and handling (ADR)
Special provisions for carriage - Operation : S2
(ADR)
Tunnel restriction code (ADR) : D

- Transport by sea
Special provisions (IMDG) : 63, 190, 277, 327, 344, 959
Limited quantities (IMDG) : SP277
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P207, LP02
Special packing provisions (IMDG) : PP87, L2
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Stowage category (IMDG) : None
Stowage and handling (IMDG) : SW1, SW22
Segregation (IMDG) : SG69
MFAG-No : 126

- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Y203
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 203
PCA max net quantity (IATA) : 75kg
CAO packing instructions (IATA) : 203
CAO max net quantity (IATA) : 150kg
Special provisions (IATA) : A145, A167, A802
ERG code (IATA) : 10L

- Inland waterway transport


Classification code (ADN) : 5F
Special provisions (ADN) : 190, 327, 344, 625
Limited quantities (ADN) : 1L
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01, VE04
Number of blue cones/lights (ADN) : 1

- Rail transport
Classification code (RID) : 5F
Special provisions (RID) : 190, 327, 344, 625
Limited quantities (RID) : 1L
Excepted quantities (RID) : E0
Packing instructions (RID) : P207, LP02
Special packing provisions (RID) : PP87, RR6, L2
Mixed packing provisions (RID) : MP9
Transport category (RID) : 2
Special provisions for carriage – Packages : W14
(RID)
2/19/2016 EN (English) 8/10
805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

Special provisions for carriage - Loading, : CW9, CW12


unloading and handling (RID)
Colis express (express parcels) (RID) : CE2
Hazard identification number (RID) : 23
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions


Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

VOC content : < 2 g/l

15.1.2. National regulations

Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex
4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling

Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F <Aerosol 1>; Emergency management guidelines for the storage of flammable liquids must
be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with the
product
Persons suffering from asthma or eczema and persons who have chronic lung diseases, skin
or respiratory allergies to isocyanates should not work with the material
The requirements from the Danish Working Environment Authorities regarding work with epoxy
resins and isocyanates must be observed during use and disposal
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal

15.2. Chemical safety assessment


No chemical safety assessment has been carried out

SECTION 16: Other information

Full text of H- and EUH-statements:


Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
Aerosol 1 Aerosol, Category 1

2/19/2016 EN (English) 9/10


805 MULTI PURPOSE PU FOAM
Safety Data Sheet
according to Regulation (EU) 2015/830
Date of issue: 1/29/2016 Revision date: Supersedes: Version: 0.0

Carc. 2 Carcinogenicity, Category 2


Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Gas 1 Flammable gases, Category 1
Press. Gas Gases under pressure
Resp. Sens. 1 Sensitisation — Respiratory, Category 1
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Sensitisation — Skin, Category 1
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H220 Extremely flammable gas
H222 Extremely flammable aerosol
H229 Pressurised container: May burst if heated
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H351 Suspected of causing cancer
H373 May cause damage to organs through prolonged or repeated exposure
EUH204 Contains isocyanates. May produce an allergic reaction

SDS EU AKFIX

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

2/19/2016 EN (English) 10/10

You might also like