SAFETY DATA SHEET

Komatsu Coolant 50/50

Section 1. Identification
GHS product identifier Komatsu Coolant 50/50
-Product code 465252-AUXX
SDS no. 465252
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/ Engine Coolant
mixture For specific application advice see appropriate Technical Data Sheet or consult our
company representative.
Manufacturer
Supplier BP Australia Pty Ltd
Level 17, 717 Bourke Street
Docklands, Victoria 3008
ABN 53 004 085 616
www.bp.com.au

Tel: +61 (03)9268 4111

Fax: +61 (03) 9268 3321
EMERGENCY TELEPHONE +61 2801 44558 {or 180014 14 74 within Australia)
NUMBER
OTHER PRODUCT Technical Helpline Number: 1300139 700
INFORMATION

Section 2. Hazard(s) identification

Classification of the ACUTE TOXICITY (oral) - Category 4
substance or mixture

GHS label elements

Hazard pictograms

Signal word WARNING

Hazard statements H302 - Harmful if swallowed.
Precautionary statements
General P103 - Read label before use.
P102 - Keep out of reach of children.
P101 - If medical advice Is needed, have product container or label at hand.
Prevention P270 - Do not eat, drink or smoke when using this product.
P264 • Wash hands thoroughly after handling.
Response P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if
you feel unwell. Rinse mouth.
Storage Not applicable.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,
national and International regulations.
Supplemental label Not applicable.
elements

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Section 2. Hazard(s) identification
Other hazards which do not None known,
result Jn classification

Section 3. Composition and ingredient information

Substance/mixture Mixture
Ethylene glycol solution.
Ingredient name %-(w/w) CAS number
Ethylene glycol &60 - <75 107-21-1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First-aid measures

Description of necessary first aid measures
Eye contact Jn case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.
Check for and remove any contact lenses. Get medical attention if symptoms occur.
Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur,
Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get
medical attention if symptoms occur.
Ingestion If ingested, call a physician or Poison Control Center immediately. Get medical
attention urgently informing the doctor that a product containing ethylene glycol has
been Ingested and specific treatment may be required. Transport casualty together
with the product container, its label, or the safety data sheet urgently to hospital. Do
not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person, if unconscious, place in recovery
position and get medical attention immediately

Most important svmptoms/effects. acute and delayed

See Section 11 for more detailed Information on health effects and symptoms.
Indication of Immediate medical attention and special treatment needed. If necessary
Specific treatments Ethylene Glycol: Gastric irrigation, ethanol or fomepizole may have value in
treatment. Consult physician.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide
media extinguisher or spray.
Unsuitable extinguishing Do not use water jet. .
media

Specific hazards arising In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal Combustion products may include the following:
decomposition products carbon dioxide
carbon monoxide

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Section 5. Fire-fighting measures
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus
equipment for fire-fighters (SCBA) and full turnout gear.

Section 6. Accidental release measures

Personal precautioTisTPTotective equipment and emergency procedures
For non-emergency No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or
mist. Provide adequate ventilation. Put on appropriate personal protective
equipment. Floors may be slippery; use care to avoid falling. Contact emergency
personnel.
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist
or fume is extremely hazardous without the correct respiratory protective equipment
and a safe system of work. Wear self-contained breathing apparatus. Wear a
suitable chemical protective suit. Chemical resistant boots. See also the
information in "For non-emergency personnel".

Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authon'ties if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning UP

Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Contain and collect spillage with non-combustible, absorbent material e.g.
sand, earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Contaminated absorbent material may pose the
same hazard as the spilt product. Dispose of via a licensed waste disposal
contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid breathing
vapour or mist. Avoid contact with eyes, skin and clothing. Do not ingest. Empty
containers retain product residue and can be hazardous. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Do not reuse container.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove
contaminated clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage, Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and weli-ventilated area, away from incompatible
Incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Store and use only in equipmentfcontainers designed for
use with this product. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination.
Not suitable Prolonged exposure to elevated temperature

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Section 7. Handling and storage

Section 8. Exposure controls and personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Ethylene glycol Safe Work Australia (Australia). Absorbed
through skin.
TWA: 10 mg/m3 8 hours. Issued/Revised:
8/2005 Form: Particulate
STEL: 104 mg/m315 minutes. Issued/
Revised: 8/2005 Form: Vapour
STEL: 40 ppm 15 minutes. Issued/Revised:
8/2005 Form: Vapour
TWA: 52 mg/ma 8 hours. Issued/Revised:
8/2005 Form: Vapour
TWA: 20 ppm 8 hours. Issued/Revised:
8/2005 Form: Vapour

Appropriate engineering At) activities involving chemicals should be assessed for their risks to health, to
controls ensure exposures are adequately controlled. Personal protective equipment should
only be considered after other forms of control measures (e.g. engineering controls)
have been suitably evaluated. Personal protective equipment should conform to
appropriate standards, be suitable for use, be kept in good condition and properly
maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards.
Provide exhaust ventilation or other engineering controls to keep the relevant
airborne concentrations below their respective occupational exposure limits.
The final choice of protective equipment will depend upon a risk assessment. It is
important to ensure that all items of personal protective equipment are compatible.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection Safety glasses with side shields.
Skin protection
Hand protection Wear protective gloves if prolonged or repeated contact is likely. Wear chemical
resistant gloves. Recommended: Butyl gloves. Neoprene gloves. The correct
choice of protective gloves depends upon the chemicals being handled, the
conditions of work and use, and the condition of the gloves {even the best
chemically resistant glove will break down after repeated chemical exposures). Most
gloves provide only a short time of protection before they must be discarded and
replaced. Because specific work environments and material handling practices vary,
safety procedures should be developed for each intended application. Gloves
should therefore be chosen in consultation with the supplier/manufacturer and with a
full assessment of the working conditions.

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Section 8. Exposure controls and personal protection
Skin protection Use of protective clothing is good industrial practice.
Cotton or polyester/cotton overalls will only provide protection against light
superficial contamination that will not soak through to the skin. Overalls should be
laundered on a regular basis. When the risk of skin exposure is high (e.g. when
cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons
and/or impervious chemical suits and boots will be required.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be_appmyed-by-a-spedaiist
~b^1ofe"fiahc(fingThis product.
Other skin protection Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals being
handled, the conditions of work and use, and the condition of the respiratory
equipment. Safety procedures should be developed for each intended application.
Respiratory protection equipment should therefore be chosen in consultation with
the supplier/manufacturer and with a full assessment of the working conditions.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716
Gioves:AS/NZS 2161.1
Eye protection:AS/NZS 1336 and AS/NZS 1337

Section 9. Physical and chemical properties

Appearance ,
Physical state Liquid.
Colour Blue.
Odour Mild
Odour threshold Not available.
pH 8.5 [Cone. (% w/w): 50%]
Melting point Not available.
Boiling point 111°C (231.8°F)
Flash point Closed cup: Not applicable. [Water content interferes with flash point determination.]
[Product does not sustain combustion.]
Evaporation rate Not available.
Flammabllity (solid, gas) Not applicable. Based on - Physical state
Lower and upper explosive Not available.
(flammable) limits
Vapour pressure Not available.
Vapour density Not available.
Relative density 1070 kg/m3 (1.07 g/cm3) at 20°C
Solubility Soluble in water.
Partition coefficient: n- Not available.
octanol/vvater
Auto-ignition temperature Net available.
Decomposition temperature Not available.
Viscosity Not available.

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Section 10. Stability arid reactivity
Reactivity No specific test data available for this product. Refer to Conditions to avoid and
incompatible materials for additional information.
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur,
reactions Under normal conditions of storage and use, hazardous polymerisation will not
occur.
Conditions to avoid Avoid excessive heat.
Incompatible materials Reactive or incompatible with the following materials: oxidising materials.
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicolooical effects

Information on the likely Routes of entry anticipated; Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact No known significant effects or critical hazards.
Inhalation Vapour Inhalation under ambient conditions is not normally a problem due to low
vapour pressure.
Skin contact No known significant effects or critical hazards.
Ingestion Harmful if swallowed. Ethylene glycol: Ingestion of ethylene glycol can cause
metabolic acidosis, kidney damage, central nervous system depression, and
convulsions. The estimated human lethal dose is approximately 100 ml (3.4 ounces
for an adult).

Symptoms related to the physical, chemical and toxicolooical characteristics

Eye contact No specific data.
Inhalation May be harmful by inhalation if exposure to vapour, mists or fumes resulting from
thermal decomposition products occurs.
Skin contact No specific data.
Ingestion Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Eye contact Potential risk of transient stinging or redness if accidental eye contact occurs.
Inhalation Overexposure to the inhalation of airborne droplets or aerosols may cause irritation
of the respiratory tract.
Skin contact Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
General May cause damage to organs through prolonged or repeated exposure, (kidney)
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects Birth defects and decreased fetal weight have been observed in laboratory animals
fed ethylene glycol in large amounts repeatedly during pregnancy.
Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
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Section 11. Toxicological information
Oral 833.3 mg/kg

Section 12. Ecological information

-Persistance-and dearadabilitv
Expected to be biodegradable.

Bioaccumulative potential
This product is not expected to bioaccumulate through food chains in the environment.

Mobility in soil
Soil/water partition Not available,
coefficient (Koc)
Mobility Spillages may penetrate the soil causing ground water contamination.

Other ecological Information Miscible in water.

Section 13. Disposal considerations

Disposal methods The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foui sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways, drains and sewers. Diluted
fluid should not be discharged into sewage systems unless provided for by local
regulations. Dispose under conditions approved by the local authority or via a
licensed waste disposal contractor.
Special Precautions for No additional special precautions identified.
Landfill or Incineration

Section 14. Transport information

ADG IMDG IATA
UN number Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport hazard
class(es)

Packing group - - -
Environmental No. No. No.
hazards
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Section 14. Transport information
Additional .
information

Special precautions for user Not available.

Section 15. Regulatory information

Standard Uniform Schedule of Medicine and Poisons
5
This product also contains approximately 10 ppm of bittering agent, denatonium benzoate.
Consumer products - This material is a scheduled poison and must be stored, maintained and used in accordance
with the relevant regulations.
Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for
Industrial, laboratory or manufacturing use. However, this product is labelled iri accordance with NOSHC National
Code of Practice for labelling of workplace substances.
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status For the REACH status of this product please consult your company contact, as
identified in Section 1. .
Australia inventory (AICS) Ail components are listed or exempted.
Canada inventory At least one component is not listed.
China inventory (iECSC) At least one component is not listed.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
Philippines inventory At least one component is not listed.
(PICCS)
Taiwan inventory (CSNN) Not determined.
United States inventory At least one component is not listed.
(TSCA 8b)

Section 16. Any other relevant information

History
Date of printing 20/10/2015
Date of issue/Date of 20/10/2015
revision
Date of previous issue No previous validation
Version 1
Product Stewardship
Key to abbreviations ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978, ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
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Section 16. Any other relevant information
STEL = Short term exposure limit
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
TWA = Time weighted average
VOC = Volatile Organic Compound
SADT = Seff-Accelerating Decomposition Temperature
Varies - may contain one or more of the following 101316-69-2,101316-70-5,
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5,64741-95-3, 64741-96-4,
64744-97-5rQ4742=0'M764742-44^5T64742--45^764742-52^5764742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9,64742-65-0,64742-70-7,72623-85-9, 72623-86-0,
72623-87-1,74869-22-0, 90669-74-2
Procedure used to derive the classification
Classification Justification
Acute Tox. 4, H302 Calculation method
P Indicates Information that has changed from previously Issued version.
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental
information contained in it is accurate as of the date specified below. No warranty or representation, express or implied
is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use
the product other than for the stated application or applications without seeking advice from BP Group.

It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.
The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use
of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the
materiaf. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to
ensure that any person handling or using the product is provided with the information in this sheet. Employers have a
duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions
that should be taken. You can contact the BP Group to ensure that this document is the most current available.
Alteration of this document is strictly prohibited.

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