Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET

ARADUR® 140 BDB

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : ARADUR® 140 BDB
EC number : 500-191-5
Chemical name : fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids
and triethylenetetramine
REACH Registration number
Registration number / : 01-2119972320-44-0000
Legal entity
Huntsman Advanced Materials (Deutschland) GmbH
Ernst-Schering-Str. 14
D-59192 Bergkamen
Germany
Tel: +49 2307 20882550
Fax: +49 2307 20882407
CAS number : 68082-29-1
Product code : 00073305
Product description : Hardener for coating systems
Other means of : Not available.
identification

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Hardener for coating systems

1.3 Details of the supplier of the safety data sheet

Supplier : Huntsman Advanced Materials (Europe)BVBA
Everslaan 45
3078 Everberg / Belgium
Tel.: +41 61 299 20 41
Fax: +41 61 299 20 40
e-mail address of person : [email protected]
responsible for this SDS
E-mail address to request full REACH registration number upon EU member State
Authority request :
[email protected]

1.4 Emergency telephone number

Supplier
Telephone number : EUROPE: +32 35 75 1234
France ORFILA: +33(0)145425959
ASIA: +65 6336-6011
China: +86 20 39377888
+86 532 83889090
India: + 91 22 42 87 5333
Australia: 1800 786 152
New Zealand: 0800 767 437
USA: +1/800/424.9300

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 2/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : UVCB
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Chronic 2, H411
Classification according to Directive 67/548/EEC [DSD]
Xi; R41, R38
R43
N; R51/53
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Causes serious eye damage.
Causes skin irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary statements
General : Not applicable.
Prevention : Wear protective gloves: > 8 hours (breakthrough time): butyl rubber, Ethyl Vinyl
Alcohol Laminate (EVAL). Wear eye or face protection. Avoid release to the
environment.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Immediately call a
POISON CENTER or physician.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Supplemental label : Not applicable.
elements
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Substance meets the : PBT: No.
criteria for PBT according P: No. B: No. T: No.
to Regulation (EC) No.
1907/2006, Annex XIII

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 3/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 2: Hazards identification

Substance meets the : vPvB: No.
criteria for vPvB according vP: No. vB: No.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

3.1 Substances : UVCB

Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]
fatty acids, CAS: 68082-29-1 60-100 Xi; R41, R38 Skin Irrit. 2, H315 [1]
C18-unsatd., dimers, EC: 500-191-5 R43 Eye Dam. 1, H318
oligomeric reaction RRN: N; R51/53 Skin Sens. 1A, H317
products with tall-oil 01-2119972320-44 Aquatic Chronic 2, H411
fatty acids and
triethylenetetramine
See Section 16 for See Section 16 for the
the full text of the R- full text of the H
phrases declared statements declared
above. above.

Type
[*] Substance
[A] Constituent
[B] Impurity
[C] Stabilising additive
Other means of identification
REACH Product name CAS no. Other CAS no.
fatty acids, C18-unsatd., dimers, oligomeric 68082-29-1
reaction products with tall-oil fatty acids and
triethylenetetramine

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
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ARADUR 140 BDB 4/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 4: First aid measures

Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory
system. Exposure to decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : May cause burns to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : Symptomatic treatment and supportive therapy as indicated. Following severe
exposure the patient should be kept under medical review for at least 48 hours.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 5/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst.
substance or mixture This material is toxic to aquatic life with long lasting effects. Fire water
contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
Carbon monoxide
nitrogen oxides

5.3 Advice for firefighters

Special precautions for : Promptly isolate the scene by removing all persons from the vicinity of the incident if
fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Additional information : Not explosive

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage.

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 6/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 6: Accidental release measures

Large spill : Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the spilt product.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not breathe
vapour or mist. Do not ingest. Avoid release to the environment. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. Do not reuse
container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe : Store between the following temperatures: 2 to 40°C (35.6 to 104°F). Store in
storage, including any accordance with local regulations. Store in original container protected from direct
incompatibilities sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Use appropriate containment to avoid environmental contamination.
Storage hazard class : Storage class 10, Environmentally hazardous liquids
Huntsman Advanced
Materials

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

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ARADUR 140 BDB 7/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
Derived effect levels
No DELs available.
Predicted effect concentrations
No PECs available.

8.2 Exposure controls

Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process
controls enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or statutory limits.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
Material of gloves for : butyl rubber, Ethyl Vinyl Alcohol Laminate (EVAL)
long term application
(BTT>480min):

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Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 8: Exposure controls/personal protection

Material of gloves for : nitrile rubber, neoprene
short term/splash
application (10min
<BTT<480min):
(BTT = Break Through Time)

Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US).
Suitability and durability of a glove is dependent on usage, e.g. frequency and
duration of contact, chemical resistance of glove material and dexterity. Always
seek advice from glove suppliers. Additional information can be found for instance
at www.gisbau.de.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : In case of inadequate ventilation wear respiratory protection. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Brown.
Odour : Amine-like.
Odour threshold : Not available.
pH : 10.98 [Conc. (% w/w): 1%]
Melting point/freezing point : Not available.
Initial boiling point and : Not available.
boiling range
Flash point : Closed cup: >200°C
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Burning time : Not applicable.
Burning rate : Not applicable.
Upper/lower flammability or : Not available.
explosive limits
Vapour pressure : <0.01 kPa [room temperature]
Vapour density : Not available.
Relative density : 0.9691
Solubility(ies)
Water solubility : practically insoluble

20 deg C

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ARADUR 140 BDB 9/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 9: Physical and chemical properties

Partition coefficient: n-octanol/ : Not available.
water (LogKow)
Auto-ignition temperature : 401°C
Decomposition temperature : >250°C
Viscosity : Dynamic (75°C): 300 - 600 mPa·s
Kinematic: Not available.
Kinematic (40°C): Not available.
Explosive properties : Not explosive
Oxidising properties : None.

9.2 Other information

Density : 0.96 g/cm³ [20°C (68°F)]

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : strong acids, strong bases, strong oxidising agents

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Endpoint Species Result Exposure
fatty acids, C18-unsatd., LD50 Dermal Rat - Male, >2000 mg/kg -
dimers, oligomeric reaction Female
products with tall-oil fatty
acids and
triethylenetetramine
LD50 Oral Rat - Female >2000 mg/kg -
Conclusion/Summary : No additional information.
Irritation/Corrosion
Product/ingredient name Test Species Route of Result
exposure
fatty acids, C18-unsatd., OECD OECD 439- In Vitro Skin Human skin Skin Irritant
dimers, oligomeric reaction Irritation - Reconstructed Human model
products with tall-oil fatty Epidermis Test Method
acids and
triethylenetetramine
OECD 405 Acute Eye Irritation/ Rabbit Eyes Severe irritant
Corrosion

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SECTION 11: Toxicological information

Conclusion/Summary
Skin : fatty acids, C18-unsatd., Irritating to skin.
dimers, oligomeric
reaction products with
tall-oil fatty acids and
triethylenetetramine
Eyes : fatty acids, C18-unsatd., Severely irritating to eyes.
dimers, oligomeric
reaction products with
tall-oil fatty acids and
triethylenetetramine
Respiratory : No additional information.
Sensitiser
Product/ingredient name Test Route of Species Result
exposure
fatty acids, C18-unsatd., OECD 429 Skin skin Mouse Sensitising
dimers, oligomeric reaction Sensitisation:
products with tall-oil fatty Local Lymph
acids and Node Assay
triethylenetetramine
Conclusion/Summary
Skin : No additional information.
Respiratory : No additional information.
Mutagenicity
Product/ingredient name Test Result
fatty acids, C18-unsatd., OECD 471 Bacterial Reverse Negative
dimers, oligomeric reaction Mutation Test
products with tall-oil fatty
acids and
triethylenetetramine
OECD 476 In vitro Mammalian Cell Negative
Gene Mutation Test
OECD OECD 487- In vitro Negative
Mammalian Cell Micronucleus Test
Conclusion/Summary : No additional information.
Carcinogenicity
Conclusion/Summary : No additional information.
Reproductive toxicity
Product/ingredient name Test Species Result/Result type Target
organs
fatty acids, C18-unsatd., OECD 422 Combined Repeated Rat Oral: NOAEL -
dimers, oligomeric reaction Dose Toxicity Study with the
products with tall-oil fatty Reproduction/Developmental
acids and Toxicity Screening Test
triethylenetetramine
Conclusion/Summary : No additional information.
Teratogenicity
Conclusion/Summary : No additional information.
Specific target organ toxicity (single exposure)

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SECTION 11: Toxicological information

Not available.
Specific target organ toxicity (repeated exposure)
Not available.

Aspiration hazard
Not available.
Information on the likely : Not available.
routes of exposure
Potential acute health effects
Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory
system. Exposure to decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
Ingestion : May cause burns to mouth, throat and stomach.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Eye contact : Causes serious eye damage.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation : No specific data.
Ingestion : Adverse symptoms may include the following:
stomach pains
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Product/ingredient name Test Result type Result Target organs
fatty acids, C18-unsatd., OECD 422 Combined NOAEL - 1000 mg/ -
dimers, oligomeric reaction Repeated Dose Toxicity kg/d
products with tall-oil fatty Study with the Reproduction/
acids and Developmental Toxicity
triethylenetetramine Screening Test
Conclusion/Summary : No additional information.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.

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ARADUR 140 BDB 12/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 11: Toxicological information

Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Other information : Not available.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Test Endpoint Exposure Species Result
fatty acids, C18-unsatd., OECD 201 Alga, Growth Acute EC50 72 Algae 4.34 mg/l
dimers, oligomeric reaction Inhibition Test hours
products with tall-oil fatty Static
acids and
triethylenetetramine
OECD 209 Activated Sludge, Acute EC50 3 hours Bacteria 384 mg/l
Respiration Inhibition Test Static
OECD 202 Daphnia sp. Acute EC50 48 Daphnia 7.07 mg/l
Acute Immobilisation Test hours
Static
OECD 203 Fish, Acute Acute LC50 96 hours Fish 7.07 mg/l
Toxicity Test
OECD 201 Alga, Growth Chronic EC10 72 Algae 1.78 mg/l
Inhibition Test hours
Static
Conclusion/Summary : No additional information.

12.2 Persistence and degradability

Product/ingredient name Test Period Result
fatty acids, C18-unsatd., OECD 301B Ready Biodegradability - CO2 74 days 0 to 70 %
dimers, oligomeric reaction Evolution Test
products with tall-oil fatty
acids and
triethylenetetramine
Conclusion/Summary : No additional information.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
fatty acids, C18-unsatd., 10.34 - high
dimers, oligomeric reaction
products with tall-oil fatty
acids and
triethylenetetramine

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

PBT : PBT: No.
P: No. B: No. T: No.

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SECTION 12: Ecological information

vPvB : vPvB: No.
vP: No. vB: No.

12.6 Other adverse effects : No known significant effects or critical hazards.

12.7 Other ecological information

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : Yes.
European waste catalogue (EWC)
Waste code Waste designation
07 02 04* other organic solvents, washing liquids and mother liquors
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

14.1 UN number 14.2 UN proper shipping name
ADR/RID UN3082 Environmentally hazardous substance, liquid, n.o.s. (Dimer fatty acid (c18)
polyamidoamine resin)
IMDG UN3082 Environmentally hazardous substance, liquid, n.o.s. (Dimer fatty acid (c18)
polyamidoamine resin). Marine pollutant
IATA UN3082 Environmentally hazardous substance, liquid, n.o.s. (Dimer fatty acid (c18)
polyamidoamine resin)

Date of issue / Date of revision : 7/14/2014. 13/17

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 14/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 14: Transport information

14.3 Transport 14.4 Packing 14.5 14.6 Special Additional
hazard class(es) group Environmental precautions for information
hazards user
ADR/RID 9 III Yes. Transport within Hazard
user’s premises: identification
always transport number
in closed 90
containers that
are upright and Special
secure. Ensure provisions
that persons 274 335 601
transporting the
product know Tunnel code
what to do in the E
event of an
accident or
spillage.

IMDG 9 III Yes. Transport within Emergency

user’s premises: schedules (EmS)
always transport F-A S-F
in closed
containers that
are upright and
secure. Ensure
that persons
transporting the
product know
what to do in the
event of an
accident or
spillage.

IATA 9 III Yes. Transport within Passenger and

user’s premises: Cargo Aircraft
always transport Quantity limitation:
in closed 450 L
containers that Packaging
are upright and instructions: 964
secure. Ensure Cargo Aircraft
that persons OnlyQuantity
transporting the limitation: 450 L
product know Packaging
what to do in the instructions: 964
event of an
accident or
spillage.

14.7 Transport in bulk : Not applicable.

according to Annex II of
MARPOL 73/78 and the IBC
Code

Date of issue / Date of revision : 7/14/2014. 14/17

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 15/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
This product is compliant with the REACH Regulation EC 1907/2006.
Huntsman has pre-registered and is registering all of the substances that it manufactures in or imports into the
European Economic Area (EEA) that are subject to Title II of the REACH Regulation.
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles

Other EU regulations
Europe inventory : All components are listed or exempted.
Black List Chemicals : Not listed
Priority List Chemicals : Not listed
Integrated pollution : Not listed
prevention and control
list (IPPC) - Air
Integrated pollution : Not listed
prevention and control
list (IPPC) - Water
National regulations
References : The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is
the recognised abbreviation for the Chemicals Hazard Information and Packaging
Regulations). This is an addition to the Health and Safety at Work Act 1974.
Australia inventory (AICS) : All components are listed or exempted.
Canada inventory : All components are listed or exempted.
China inventory (IECSC) : All components are listed or exempted.
Japan inventory : All components are listed or exempted.
Korea inventory (KECI) : All components are listed or exempted.
New Zealand Inventory of : All components are listed or exempted.
Chemicals (NZIoC)
Philippines inventory : All components are listed or exempted.
(PICCS)
United States inventory : All components are listed or exempted.
(TSCA 8b)
Chemical Weapons : Not listed
Convention List Schedule I
Chemicals
Chemical Weapons : Not listed
Convention List Schedule II
Chemicals

Date of issue / Date of revision : 7/14/2014. 15/17

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 16/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 15: Regulatory information

Chemical Weapons : Not listed
Convention List Schedule III
Chemicals

15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Skin Irrit. 2, H315 Expert judgment
Eye Dam. 1, H318 Expert judgment
Skin Sens. 1A, H317 Expert judgment
Aquatic Chronic 2, H411 Expert judgment
Full text of abbreviated H : H315 Causes skin irritation.
statements H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
Full text of classifications : Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2
[CLP/GHS] Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1A, H317 SKIN SENSITIZATION - Category 1A
Full text of abbreviated R : R41- Risk of serious damage to eyes.
phrases R38- Irritating to skin.
R43- May cause sensitisation by skin contact.
Full text of classifications : Xi - Irritant
[DSD/DPD]
(M)SDS no. : 00073305
Date of printing : 7/14/2014.
Date of issue/ Date of : 7/14/2014.
revision
Date of previous issue : 7/14/2014.
Version : 3.02
Notice to reader
While the information and recommendations in this publication are to the best of our knowledge, information
and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY,
EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN
PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN
HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY

Date of issue / Date of revision : 7/14/2014. 16/17

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
ARADUR 140 BDB 17/17
Date of printing : 14 July 2014 (M)SDS no. : 00073305
Date of issue : 14 July 2014 Version : 3.02

SECTION 16: Other information

HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be
determined by the user and made known to handlers, processors and end users.
ARADUR® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more countries,
but not all countries.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO
PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.
NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY
MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO
REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER,
PRODUCT SAFETY AT THE ABOVE ADDRESS.

Date of issue / Date of revision : 7/14/2014. 17/17