oxy acids of phosphorous

-_ X#X

①
Hs Pq ( Hy Pho phosphorous acid ) ( phosphine acid)

-12*3
=
I #

EH
pig -13311%5
+ 3110 ↳

HsPq--H-→HgPq#
Anhydrous acid cannot be obtained by simple evaporation
of the water because it disproportionately on
heating .

pure anhydrous Ypg can be formed by the continuous

extraction of aqueous solutions with diethyl ether .

 ←D

(4) 31L PI ☐→ Plf -12¥ Pg

⇐ eÉñÉ→¥¥+*¥¥
It is colorless low compound which is soluble
a
-

melting ,

in water ,
dioxane and alcohols .

§ Pg -12%9 → typo + 4 Cro

① Cuomo basic )

no strong reducing agent due to two

P H -

bonds .
HEIKO
,
t
tepid + ago → itgtlgioteleng

I ,'¥+±o→
"

+ n.ae#o.7iear
(Benzene)
②
Hypo ,
( phosphorous acid )
- -
( hypo phosphoric acid )

(phosphoric acid
-

41g pong
12,06 -16110
→ -

PCOH)g -1311cL ( Industrial

Pcl ] -13110 →
Method )

/
¥ ← - Ctautomens]
file
on
no HO OH

Craig crinoid
stable due to
P'¥17B PRIG .
g-
basic ]
,

@ =-D i.
F- 0
 It acts as
reducing
CED
agent .

XD Cts)
(1-2)

2Hgdztlfpg-tfo-tlgzdz-YPE-2kdc-DHJ.dz
-1
lfPg -1110 → 2K0g -1 lfPq-121kt

③
Ps-p-H.ae'd :-( 1413%-3
¥3 "4¥É¥
zlfgpg
7£}
µI§É§-Ñ¥oH
panda
deducing agent) →

4
_t+z→HFlt
(Basicity -_
2)
 ④ ( orthophosphoric acid )
If Pq :-(phosphoric acid)
-# -_

Casted3 Cole) -151154

,
→ 31JPY tscasqt
Ho

Crydroey apatite) a

Patio -16110
→
411$04
The pure compound is a colourless solid . It is available

as a colourless syrup of 857 . concentration in water .

This

solution is a colourless odour less and non - volatile syrupy

,

liquid pKa 1=224 pka plans

.

=p .z
. -12-37
 Ñ Tribasic and non
-

reducing .

Ho
/
¥50K
-1110
tfpoq
HPO ]

@eta phosphoric acid

g
608C

12%-1-3110
1^608 C

220°C
> 114130+1-110
(Pyro phosphoric acid
 ⑤ Pyro phosphoric acid ( Hickox)

211 Pq ¥7 11,130++110
O O

H Il
ok Basicity =
¢
P o - p -

Ho
-
-

I 1
Noh
reducing
-

OH
OH

⑥ 114138 Chypho phosphoric acid)

( H¢B8
=
2

in solid state
-

It enlists
dihydrate
-

as
 P -12 Kd
Mad
02+2110 → Ng ¥1206
2 t 2

(Red)
@odium chlorite)

pH 10110 is crystallized
Nag Pag
At
.

= to .

column toform
It can be passed through ion en
change
the acid
dihydrate .

• •

11 11
P OH
Ho P -

( Reducing Agent)
- -

Non -

1
I
OH
OH

(tetrabasic )
 Meta phosphoric acid Ctepojy
I -_

It exist as
polymer (HPODN

-6%-0-1%7
( ) °%Iµ cydotetxa
-
-
-
o

.
metaapn.gs?horic
n i 11

(HPE? (HpoD¢ Ho P o -
Pok

gipon
-
-

l l
- cyclo trim meta
⑦ o
o o
phosphoric acid 1 I
/ / ° Pao
⇐
p - o -

⇐ p f- l l
l \o/ '
OH OH OH
NO
 triphos-phoricacidcks-BQDNatfpq-2.NL/lPE
ko -
ii
p - o -
i
p - o -
¥-0K
,
1011 tote N£B% -12110
OH

Per phosphoric acid ( typos ) Metaphosphoroaayacid

(HPS)
ñ
yo
-

P -0-0-11
, P
OH 0¢ 1011
?⃝
 d-D ED ED

-É¥§ Acidity

I I
0

"
A : >
II 1,5011
'
/ > ' H
no
no µ no

It 1L 1L

s
:É¥.in > -
o
¥
in
>
_o¥÷É¥
Calgon CAPED , = salt of CHPED,
I
6
Basicity -_

I
% -0-1%-0-18
°

④¥
"
P
④
- o -

p o -
-
-
- o -

" I 1 1
I
OH
oh OH OH OH OH