World Headquarters

Hach Company
P.O.Box 389 MSDS No: M00020
Loveland, CO USA 80539
(970) 669-3050

SAFETY DATA SHEET

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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: FerroVer ® Iron Reagent
Catalog Number: 92799

Hach Company Emergency Telephone Numbers:

P.O.Box 389 (Medical and Transportation)
Loveland, CO USA 80539 (303) 623-5716 24 Hour Service
(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00020

Not applicable
Chemical Name: Not applicable
CAS Number: Not applicable
Additional CAS No. (for hydrated forms): Not applicable
Chemical Formula: Not applicable
Chemical Family: Mixture
Intended Use: Laboratory Reagent Iron determination
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2. HAZARDS IDENTIFICATION
GHS Classification:
Hazard categories: Acute Toxicity: Acute Tox. 4-Orl Serious Eye Damage/Eye Irritation: Eye Dam. 1 Skin
Corrosion/Irritation: Skin Irrit. 2 Respiratory or Skin Sensitization: Resp. Sens.1 Hazardous to the Aquatic
Environment: Aquatic Chronic 3 Acute Toxicity: Acute Tox. 4-Inh
GHS Label Elements:
DANGER

Hazard statements: Harmful if swallowed. Harmful if inhaled. Causes serious eye damage. Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Harmful to aquatic life with long lasting
effects.
Contact with acids liberates toxic gas.
Precautionary statements: Wear eye protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Do no eat, drink
or smoke when using this product. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove
victim/person to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms:
Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
HMIS:
Health: 2
Flammability: 0
Reactivity: 1
Protective Equipment: X - See protective equipment, Section 8.
NFPA:
Health: 2
Flammability: 0
Reactivity: 1
Symbol: Not applicable
 WHMIS Hazard Classification: Class D, Division 2, Subdivision B - Toxic material (other toxic effects)
WHMIS Symbols: Other Toxic Effects
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3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Components according to GHS:
Sodium Metabisulfite

CAS Number: 7681-57-4

Chemical Formula: Na2S2O5
GHS Classification: Acute Tox. Orl 4, H302; Acute Tox. Derm 5, H313; Acute Tox. Inh. 4, H332; Skin Irrit. 2, H315;
Eye Dam. 1, H318; Resp. Sens. 1, H334; Aquatic Chronic 3, H412
Percent Range (Trade Secret): 40.0 - 50.0
Percent Range Units: weight / weight
PEL: 15 mg/m3 as inhalable dust; 5 mg/m3 as respirable dust
TLV: 5 mg/m3

WHMIS Symbols: Other Toxic Effects

Sodium Hydrosulfite

CAS Number: 7775-14-6

Chemical Formula: Na2S2O4
GHS Classification: Self-Heating 1, H251; Acute Tox. 4 -Orl, H302; Skin Irrit. 3, H316; Eye Irrit. 2A, H319; STOT
Single 3, H335; Aquatic Chronic 3, H412
Percent Range (Trade Secret): 25.0 - 35.0
Percent Range Units: weight / weight
PEL: 15 mg/m3 as inhalable dust; 5 mg/m3 as respirable dust
TLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust

WHMIS Symbols: Other Toxic EffectsFlammable / Combustible

Sodium Thiosulfate

CAS Number: 7772-98-7

Chemical Formula: Na2S2O3 5H2O
GHS Classification: Skin Irrit 2, H315; Eye Irrit 2, H319, STOT SE 3, H335
Percent Range (Trade Secret): 15.0 - 25.0
Percent Range Units: weight / weight
PEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dust
TLV: 10 mg/m3 as inhalable dust

WHMIS Symbols: Not applicable

1,10-Phenanthroline-p-toluenesulfonic Acid Salt

CAS Number: 92798-16-8

Chemical Formula: C19H10N2O3S
GHS Classification: Acute Tox. 3 - Orl, H301; Skin Irrit. 2, H315; Eye Irrit. 2, H319
Percent Range (Trade Secret): 1-3
Percent Range Units: weight / weight
PEL: 15 mg/m3 as inhalable dust; 5 mg/m3 as respirable dust
TLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust

WHMIS Symbols: Not applicable

Hazardous Components according to GHS: No
Sodium Citrate

CAS Number: 68-04-2

Chemical Formula: C6H5O7Na3 . 2H2O
GHS Classification: Not applicable
Percent Range (Trade Secret): 3-9
Percent Range Units: weight / weight
PEL: 15 mg/m3 as inhalable dust; 5 mg/m3 as respirable dust
TLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust
 WHMIS Symbols: Not applicable
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4. FIRST AID MEASURES
General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to a
doctor.
Advice to doctor: Treat symptomatically.
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water. Call physician if irritation develops.
Inhalation: Remove to fresh air. Give artificial respiration if necessary.
Ingestion (First Aid): Never give anything by mouth to an unconscious person. Do not induce vomiting. Give 1-2 glasses
of water. If you feel unwell, contact a physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHS
criteria.
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
Extinguishing Media: Carbon dioxide Alcohol foam. Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable
Fire / Explosion Hazards: May react violently with: strong oxidizers
Hazardous Combustion Products: Toxic fumes of: sulfur oxides. sodium oxides carbon monoxide, carbon dioxide.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill
according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan and
guidelines/procedures. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Sweep up material. Working in a large container, cautiously add small portions of the spilled
material to cold water with agitation. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium
bicarbonate. If permitted by regulation, Flush reacted material to the drain with a large excess of water. Otherwise,
Decontaminate the area of the spill with a soap solution. Dispose of in accordance with local, state and federal regulations
or laws.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
DOT Emergency Response Guide Number: Not applicable
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Store away from: oxidizers Protect from: moisture Keep container tightly closed when not in use. Storage
temperature or range may be given on the product label. Follow this label advice to preserve product quality and maximize
shelf life.
Flammability Class: Not applicable
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Use general ventilation to minimize exposure to mist, vapor or dust.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin Protection: nitrile gloves In the EU, the selected gloves must satisfy the specifications of EU Directive
89/686/EEC and standard EN 374 derived from it. lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Protect from: oxidizers moisture
 TLV: Not established
PEL: Not established
For Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White to light yellow crystals
Physical State: Solid
Molecular Weight: Not applicable
Odor: Sulfur-like
Odor Threshold: Not established
pH: of 5% solution = 5.3
Metal Corrosivity:
Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.
Steel: 0.081 in/yr
Aluminum: 0.010 in/yr
Specific Gravity/ Relative Density (water = 1; air =1): 2.21
Viscosity: Not applicable
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Partition Coefficient (n-octanol / water): Not available
Coefficient of Water / Oil: Not available
Melting Point: > 400 °C (> 752 °F)
Decomposition Temperature: Not determined
Boiling Point: Not applicable
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Evaporation Rate (water = 1): Not Applicable
Volatile Organic Compounds Content: Not applicable
Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHS
criteria.
Flash Point: Not Applicable
Method: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Autoignition Temperature: Not determined
Explosive Properties:
Not classified according to GHS criteria. Not classified according to GHS criteria.
Oxidizing Properties:
Not classified according to GHS criteria.
Reactivity Properties:
Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to
GHS criteria.
Gas under Pressure:
Not classified according to GHS criteria.
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10. STABILITY AND REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Mechanical Impact: None reported
Static Discharge: None reported.
Reactivity / Incompatibility: May react violently in contact with: oxidizers
Hazardous Decomposition: Toxic fumes of: sodium oxides sulfur oxides carbon dioxide carbon monoxide
Conditions to Avoid: Heating to decomposition.
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11. TOXICOLOGICAL INFORMATION
Toxicokinetics, Metabolism and Distribution: No information available for mixture.
 Toxicologically Synergistic Products: None reported
Acute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity Data Route Data Given Below
Outside Testing: Oral Rat LD50 = 1400 mg/kg
Dermal Rat LD50 > 4629 mg/kg
Inhalation Rat LC50 > 4.6 mg/L/4 hr
Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification
criteria are not met.
Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classification
criteria are not met.
Skin Corrosion/Irritation: Irritating to skin.
Eye Damage: Corrosive to eyes.
Sensitization: Respiratory Sensitizer Contains a sensitizing compound.
Sodium metabisulfite
CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): Based on classification principles, the
classification criteria are not met.
An ingredient of this mixture is: IARC Group 3: Non-classifiable
This product does NOT contain any NTP listed chemicals.
This product does NOT contain any OSHA listed carcinogens.
Symptoms/Effects:
Ingestion: Harmful May cause allergic respiratory reaction if swallowed or inhaled. May cause: gastrointestinal tract
irritation diarrhea circulatory disturbances central nervous system depression Very large doses may cause: colic
depression death
Inhalation: Harmful Causes: respiratory tract irritation May cause: allergic respiratory reaction difficult breathing
sweating rapid pulse and respirations blood pressure changes coughing flushing hives
Skin Absorption: May be absorbed through skin.
Chronic Effects: Chronic overexposure may cause allergic respiratory reactions Not determined
Medical Conditions Aggravated: Sulfites are strong sensitizers. Inhalation and ingestion may cause allergic respiratory
reactions in asthmatics. Persons with respiratory conditions should take special care when working with products that
contain sulfites.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
Do not place in landfil. Recycle appropriately. Do not release into the environment. No bioaccumulation potential
Ingredient Ecological Information: Sodium Hydrosulfite: 96 hr Leuciscus idus LC50 = 46 mg/L; 48 hr Daphnia magna
EC50 = 98 mg/L. Sodium Metabisulfite: 96 hr Salmo gairdneri LC50 = 15 mg/L; 96 hr Scenedesmus subspicatus EC50 =
40 mg/L; 96 hr Lepomis macrochirus = 32 mg/L.
CEPA categorization for ingredients are as follows:
Sodium Hydrosulfite, Sodium Metabisulfite: Persistent, not bioaccumulative or inherently toxic to aquatic organisms.
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13. DISPOSAL CONSIDERATIONS
EPA Waste ID Number: Not applicable
Special Instructions (Disposal): Work in an approved fume hood. Working in a large container, cautiously add small
portions of the material to cold water with agitation. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or
sodium bicarbonate. If permitted by regulation, Open cold water tap completely, slowly pour the reacted material to the
drain. Allow cold water to run for 5 minutes to completely flush the system. Otherwise, Check with national, local
municipal and state authorities and waste contractors for pertinent local information on the disposal of this article.
Empty Containers: Rinse three times with an appropriate solvent. Collect rinsate and dispose of according to local, state
or federal regulations. In the US, rinsate from empty containers is classified as hazardous waste and should be disposed of
at an E.P. A. approved facility. Dispose of empty container as normal trash.
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
D.O.T.:
D.O.T. Proper Shipping Name: Not Currently Regulated
--
 Hazard Class: NA
Subsidiary Risk: NA
ID Number: NA
Packing Group: NA
T.D.G.:
Proper Shipping Name: Not Currently Regulated
--
Hazard Class: NA
Subsidiary Risk: NA
UN Number/PIN: NA
Packing Group: NA
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
Hazard Class: NA
Subsidiary Risk: NA
ID Number: NA
Packing Group: NA
I.M.O.:
Proper Shipping Name: Not Currently Regulated
--
Hazard Class: NA
Subsidiary Risk: NA
ID Number: NA
Packing Group: NA
Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed of
various compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item IS
part of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the item
is not regulated, the Chemical Kit classification does not apply.
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15. REGULATORY INFORMATION
U.S. Federal Regulations:
O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.
(29 CFR 1910.1200)
E.P.A.:
S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard
S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reporting
requirements of Section 313 of Title III of SARA.
--
302 (EHS) TPQ (40 CFR 355): Not applicable
304 CERCLA RQ (40 CFR 302.4): Not applicable
304 EHS RQ (40 CFR 355): Not applicable
Clean Water Act (40 CFR 116.4): Not applicable
RCRA: Contains no RCRA regulated substances.
State Regulations:
California Prop. 65: No Prop. 65 listed chemicals are present in this product.
Identification of Prop. 65 Ingredient(s): Not applicable
California Perchlorate Rule CCR Title 22 Chap 33: Not applicable
Trade Secret Registry: Not applicable
National Inventories:
U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).
CAS Number: Not applicable
Canadian Inventory Status: All ingredients of this product are DSL/NDSL Listed.
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS or are placed on the
market in quantities less than 10 kg per year.
Australian Inventory (AICS) Status: Some ingredients are not listed.
New Zealand Inventory (NZIoC) Status: All components either listed or exempt.
Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound or
exempt.
Japan (ENCS) Inventory Status: All components either listed or exempt.
China (PRC) Inventory (MEP) Status: All components either listed or exempt.
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332-2983. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy,
MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire
Protection Association, 1991. In-house information. Outside Testing. Technical Judgment. TLV's Threshold Limit
Values and Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists,
1992.
Complete Text of H phrases referred to in Section 3: H302 Harmful if swallowed. H318 Causes serious eye damage.
H251 Self-heating: may catch fire. H301 Toxic if swallowed. . H315 Causes skin irritation. H319 Causes serious eye
irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects.
Revision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (
ST/SG/AC.10/36/Add.3).
Date of MSDS Preparation:
Day: 09
Month: December
Year: 2014
MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350
CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled Products
Regulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting use
of GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified and
labeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordance
with the requirements of GHS (ST/SG/AC.10/36/Add.3).
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.

HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015