SAFETY DATA SHEET
PRODUCT
NALCO® 1250
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME NALCO® 1250
OTHER MEANS OF IDENTIFICATION Not applicable
RECOMMENDED USE AND RESTRICTIONS OXYGEN SCAVENGER Refer to available product literature or
ask your local Sales Representative for restrictions on use and
dose limits.
COMPANY IDENTIFICATION PT. ECOLAB INTERNATIONAL INDONESIA
Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175
FAX: 62-21-8753167
EMERGENCY TELEPHONE NUMBER(S) +65 6542 9595
2. HAZARDS IDENTIFICATION
CLASSIFICATION
Skin corrosion/irritation - Category 2
Skin sensitization - Category 1
Acute toxicity, Oral - Category 4
GHS LABEL ELEMENTS
HAZARD SYMBOLS
SIGNAL WORD : Warning
HAZARD STATEMENTS
Causes skin irritation.
May cause an allergic skin reaction.
Harmful if swallowed.
PRECAUTIONARY STATEMENTS
Prevention:
Wash hands thoroughly after handling.
Wear protective gloves.
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Contaminated work clothing should not be allowed out of the workplace.
Do not eat, drink or smoke when using this product.
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
Response:
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
Rinse mouth.
Storage:
Store in accordance with local regulations.
Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
OTHER HAZARDS
None known
3. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE / PREPARATION :
Mixture
CHEMICAL NAME CAS NO % (w/w)
Carbohydrazide 497-18-7 10 - 30
The balance of the substances in this product are not classified as hazardous or
are present below hazard cut-off limits
4. FIRST AID MEASURES
INHALATION
Remove to fresh air, treat symptomatically. Get immediate medical attention.
SKIN CONTACT
Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention.
EYE CONTACT
Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical
attention.
INGESTION
DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. If reflexive vomiting occurs,
rinse mouth and repeat administration of water. Get immediate medical attention.
MOST IMPORTANT SYMPTOMS/ EFFECTS
Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction.
NOTE TO PHYSICIAN
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be
ignitable. Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD
Not flammable or combustible. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve oxides of
carbon (COx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.
ENVIRONMENTAL PRECAUTIONS
This product may pose a risk to the aquatic ecosystem if released. Prevent material from entering sewers or
waterways.
METHODS FOR CLEANING UP
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of
contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations).
7. HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING
Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust.
Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily
available. Ensure all containers are labeled. Use personal protective equipment recommended in Section 8
(Exposure Controls/Personal Protection). Discard contaminated shoes, belts and other articles made of leather.
SUITABLE STORAGE CONDITIONS
Store in suitable labeled containers. Store the containers tightly closed. Protect product from freezing.
UNSUITABLE CONSTRUCTION MATERIAL :
,
Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.,
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
CONTROL PARAMETERS
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
OCCUPATIONAL EXPOSURE LIMITS
This product does not contain any substance that has an established exposure limit.
APPROPRIATE ENGINEERING CONTROLS
General ventilation is recommended.
PERSONAL PROTECTION
RESPIRATORY PROTECTION
Respiratory protection is not normally needed.
EYE PROTECTION
Wear chemical splash goggles.
HAND PROTECTION
NEOPRENE, NITRILE, NATURAL RUBBER OR PVC GLOVES Gloves should be replaced immediately if signs
of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers.
SKIN PROTECTION
Wear protective overalls, chemical splash goggles and impervious gloves. A full slicker suit is recommended if
gross exposure is possible.
HYGIENE RECOMMENDATIONS
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Liquid
APPEARANCE Clear Colorless
ODOR None
ODOR THRESHOLD No data available.
pH (100 %) 8.4
FREEZING POINT -2.1 °C
BOILING POINT 99.4 °C
FLASH POINT Not flammable
EVAPORATION RATE No data available.
FLAMMABILITY (solid, gas) No data available.
LOWER EXPLOSION LIMIT No data available.
UPPER EXPLOSION LIMIT No data available.
VAPOR PRESSURE No data available.
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
VAPOR DENSITY No data available.
SPECIFIC GRAVITY 1.04 - 1.05 (25 °C)
DENSITY No data available.
SOLUBILITY IN WATER Complete
OCTANOL/WATER COEFFICIENT No data available.
(log Kow)
AUTOIGNITION TEMPERATURE No data available.
DECOMPOSITION TEMPERATURE No data available.
VISCOSITY 3 cps (23.9 °C)
Note: These physical properties are typical values for this product and are subject to change.
10. STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions.
HAZARDOUS REACTIONS
Hazardous polymerization will not occur.
CONDITIONS TO AVOID
At temperatures below 4 °C (40 °F), this product loses its stability and forms precipitates. Once formed, the
precipitate cannot be resolubilized and loss of product activity will occur.
INCOMPATIBLE MATERIALS
Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat,
splattering or boiling and toxic vapors. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric
acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS
Under fire conditions: Oxides of carbon, Oxides of nitrogen
11. TOXICOLOGICAL INFORMATION
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE
PRIMARY ROUTES OF EXPOSURE
Eye, Skin
Refer to the sections below for details of health effects via each route.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG TERM
EXPOSURE
ACUTE TOXICITY DATA
Harmful if swallowed.
SKIN CORROSION / IRRITATION
Causes skin irritation.
SERIOUS EYE DAMAGE / IRRITATION
May cause irritation with prolonged contact.
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
RESPIRATORY / SKIN SENSITIZATION
May cause sensitization by skin contact.
GERM CELL MUTAGENICITY
Not expected to be a mutagen.
CARCINOGENICITY
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH).
REPRODUCTIVE TOXICITY
No reproductive toxic effects expected.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
No adverse effects expected.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE
No adverse effects expected.
ASPIRATION HAZARD
No aspiration toxicity classification
NUMERICAL MEASURES OF TOXICITY
ACUTE TOXICITY DATA
No toxicity studies have been conducted on this product.
HUMAN HAZARD CHARACTERIZATION
Based on our hazard characterization, the potential human hazard is: High
12. ECOLOGICAL INFORMATION
ECOTOXICITY
The following results are for the product.
ACUTE INVERTEBRATE RESULTS :
Species Exposure Test Type Value Test Descriptor
Ceriodaphnia dubia 48 hrs LC50 85 mg/l Product
Chronic Invertebrate Results :
Species Exposure Test Type Value End Test Descriptor
Point
Ceriodaphnia dubia 7 Days NOEC 8.1 mg/l Product
PERSISTENCY AND DEGRADATION
The organic portion of this preparation is expected to be readily biodegradable.
MOBILITY
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air Water Soil/Sediment
<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL
This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION
Based on our hazard characterization, the potential environmental hazard is: Moderate
OTHER INFORMATION
No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of wastes in an approved waste treatment / disposal site, in accordance with all applicable regulations.
Do not dispose of wastes in local sewer or with normal garbage.
DISPOSAL CONSIDERATIONS
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
AIR TRANSPORT (ICAO/IATA)
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
MARINE TRANSPORT (IMDG/IMO)
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
Marine Pollutant : No
15. REGULATORY INFORMATION
APPLICABLE REGULATIONS, INDONESIA
GHS Chemical Classification and Labeling (87/M-IND/PER/9/2009)
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
INTERNATIONAL CHEMICAL CONTROL LAWS
AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
CANADA
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
CHINA
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines
Inventory of Chemicals & Chemical Substances (PICCS).
UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
16. OTHER INFORMATION
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM
Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™
CD-ROM Version),
Micromedex, Inc., Englewood, CO.
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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SAFETY DATA SHEET
PRODUCT
NALCO® 1250
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services,
Public Health Service.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health,
Cincinnati, OH,
(TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version),
Micromedex, Inc., Englewood, CO.
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.
First issue : 02.12.2010
Date issued : 13.11.2013
Version Number : 1.1
Prepared By: Nalco Asia Pacific, Regulatory Affairs (RA) Specialist
PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor,
Indonesia
TEL: 62-21-8753175 FAX: 62-21-8753167
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