Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name: 1,1,1,2,3,3,3-Heptafluoropropane
REACH Reg. No.: Pre-registration No. 17-211998XXXX-XX-XXXX
CAS No.: 431-89-0
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Fire extinguishing agent.
Uses advised against: No information available.
1.3 Details of the supplier of the SDS
Manufacturer: Shanghai Waysmos Fine Chemical Co., Ltd.
Address: 388 Liangle Road, Laogang Town, Pudong New Area, Shanghai, China
Postcode: 201322
E-mail:
[email protected] Telephone: +86-571-85069383
Fax: +86-571-85069385
Importer:
Address:
E-mail:
Telephone:
1.4 Emergency telephone number
+86-571-85069386
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008[CLP]
Gases under pressure, Liquefied gas; H280
Classification according to Directive 67/548/EEC[DSD] or Directive 1999/45/EC[DPD]
This product is not classified as hazardous.
Additional information
Full text of R-phrase(s)/H-statement(s): see SECTION 16.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008[CLP]
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
Hazard pictogram(s):
Signal word: Warning
Hazard statement(s): H280: Contains gas under pressure; may explode if heated.
Precautionary statement(s):
Storage: P410 + P403: Protect from sunlight. Store in a well-ventilated place.
Supplemental Hazard information (EUH):
No information available.
Special rules for supplemental label elements for certain mixtures:
No information available.
2.3 Other hazards
No information available.
SECTION 3: Composition/information on ingredients
3.1 Substance/Preparation information
Substance name: 1,1,1,2,3,3,3-heptafluoropropane
CAS No.: 431-89-0
EC No.: 207-079-2
Purity: ≥ 99.9%
SECTION 4: First aid measures
4.1 Description of first aid measures
General notes:
In all cases of doubt, or when symptoms persist, seek medical attention.
Following inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight
clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Following skin contact:
Remove and isolate contaminated clothing and shoes. In case of contact with liquefied gas, thaw frosted parts with
lukewarm water.
Following eye contact:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical attention.
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
Following ingestion:
Ingestion is not a normal route of exposure for gases.
4.2 Most important symptoms and effects, both acute and delayed
Acts as a simple asphyxiant. Contact with rapidly expanding gas may cause burns or frostbite.
4.3 Indication of the immediate medical attention and special treatment needed
No information available.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media: Heptafluoropropane is a fire extinguishing media. Use media appropriate for
surrounding material.
Unsuitable extinguishing media: No information available.
5.2 Special hazards arising from the substance or mixture
Thermal decomposition can lead to release of irritating or toxic gases/vapors: carbon oxides, halogenated
compounds.
Contains gas under pressure. In a fire or if heated, a pressure increase will occur and the container may burst or
explode.
5.3 Advice for fire-fighters
Wear self-contained breathing apparatus with a full face-piece operated in positive pressure mode and
chemical-protective clothing. Prevent fire extinguishing water from contaminating surface water or the ground water
system.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Refer to SECTION 8 for personal protective equipment. Prevention of skin and eye contact. Ensure adequate
ventilation. Remove all sources of ignition. Shut off gas supply if this can be done safely. Isolate area until gas has
dispersed.
6.2 Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3 Methods and material for containment and cleaning up
Evacuate area. Keep upwind. Stop leak if without risk. Ventilate area especially low places remove open flames and
heating elements. Disperse gas with floor level forced air.
6.4 Reference to other SECTIONs
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
See SECTION 7 for information on safe handling.
See SECTION 8 for information on personal protection equipment.
See SECTION 13 for information on disposal.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and
when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for
cylinder movement.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed and in a cool, well-ventilated place. Keep out of direct sunlight. Keep away from heat
and ignition sources.
7.3 Specific end use(s)
Apart from the uses mentioned in SECTION 1.2 no other specific uses are stipulated.
SECTION 8 : Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limit values:
Not established.
DNEL (Derived No Effect Level) for workers and the general population:
Not available.
PNEC (Predicted No Effect Concentration) values:
Not available.
8.2 Exposure controls
Appropriate engineering controls:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory limits.
Personal protective equipment:
Eye and face protection: Safety glasses/chemical splash goggles.
Skin protection: Wear protective gloves/clothing to prevent contact.
Respiratory protection: In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls:
Do not empty into drains.
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: Liquefied gas
Color: colorless
Odour: inodorous
pH: Not available.
Melting point: Not available.
Boiling point: -16.36 °C
Flash point: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not flammable.
Upper/lower flammability or explosive limits: Not available.
Vapour pressure: 457.7 Kpa (25°C)
Density: 1.388 g/cm3
Solubility(ies): Not available.
Partition coefficient: n-octanol/water: log Kow = 2.11
Auto-ignition temperature: Not available.
Viscosity: 0.226 mPa.s (25°C)
Explosive properties: Not available.
Oxidising properties: Not available.
9.2 Other information
No data available.
SECTION 10: Stability and reactivity
10.1 Reactivity
Stable under recommended storage and handling conditions (see SECTION 7, handling and storage).
10.2 Chemical stability
Stable under normal conditions of use.
10.3 Possibility of hazardous reactions
No known hazardous reactions.
10.4 Conditions to avoid
Keep away from heat and ignition sources. Protect from sunlight.
10.5 Incompatible materials
Strong oxidizing materials.
10.6 Hazardous decomposition products
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
Thermal decomposition can lead to release of irritating or toxic gases/vapors: carbon oxides, halogenated
compounds.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity Oral, LD50 : No data available.
Inhalation, LC50: 788698 ppm/4h (rat).
Dermal, LD50: No data available.
Skin corrosion/irritation: No information available.
Serious eye damage/irritation: No information available.
Respiratory or skin sensitization: No information available.
Germ cell mutagenicity: No information available.
Carcinogenicity: No information available.
Reproductive toxicity: No information available.
STOT-single exposure: No information available.
STOT-repeated exposure: No information available.
Aspiration hazard: No information available.
SECTION 12: Ecological information
12.1 Toxicity
Ecotoxicity Fish, LC50: No data available.
Crustacea, EC50: No data available.
Algae, EC50: No data available.
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
Bioaccumulation is not expected (Log Kow < 3).
12.4 Mobility in soil
No information available.
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment information is not available as chemical safety assessment not conducted.
12.6 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Disposal must be made according to local and national regulations. Empty containers should be taken for local
recycling, recovery or waste disposal.
SECTION 14: Transport information
14.1 Land transport (ADR)
Proper Shipping Name: HEPTAFLUOROPROPANE
Class: 2.2
UN-No.: 3296
14.2 Sea transport (IMDG)
Proper Shipping Name: HEPTAFLUOROPROPANE
Class: 2.2
UN-No.: 3296
Marine pollutant: No
14.3 Air transport (IATA)
Proper Shipping Name: HEPTAFLUOROPROPANE
Class: 2.2
UN-No.: 3296
14.4 Additional information
Mark/Label(s) for transport:
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulation:
Authorisations: No information available.
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
Restrictions on use: No information available.
EINECS: CAS# 431-89-0 is listed in.
DSD (67/548/EEC): CAS# 431-89-0 is not listed in.
Other chemical regulation:
USA Canada Australia Korea Japan China
CAS No.
TSCA DSL AICS ECL ENCS IECSC
431-89-0 Listed Listed Listed Listed Listed Listed
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this product.
SECTION 16: Other information
16.1 Revision Information
Date of the previous revision: Not applicable. Date of this revision: 06/08/2012.
Revision summary: The first new SDS
16.2 Abbreviations and acronyms
CLP: EU regulation (EC) No 1272/2008 on classification, labelling and packaging of chemical substances and
mixtures.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
EINECS: European Inventory of Existing Commercial Chemical Substances.
DSD: Dangerous Substance Directive (67/548/EEC).
TSCA: Toxic Substances Control Act, The American chemical inventory.
DSL: Domestic Substances List, The Canadian chemical inventory.
AICS: The Australian Inventory of Chemical Substances.
ECL: Existing Chemicals List, the Korean chemical inventory.
ENCS: Japanese Existing and New Chemical Substances.
IECSC: Inventory of existing chemical substances in China.
16.3 Key literature references and sources for data
GESTIS-database: Information system on hazardous substances of the German Social Accident Insurance.
ECHA's public database with information on registered substances.
16.4 Relevant R-phrases/H-statements
H280: Contains gas under pressure; may explode if heated.
16.5 Training advice
Provide adequate information, instruction and training for operators.
16.6 Declare to reader
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided
without any warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety
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Safety Data Sheet
According to Regulation (EU) No. 1907/2006 (REACH), Annex II
(COMMISSION REGULATION (EU) No 453/2010)
Version: 2.0/EN Revision date: 05/09/2012
Product name: 1,1,1,2,3,3,3-Heptafluoropropane Printing date: 05/09/2012
preventive measures for the users who have got professional training. The personal user who obtained this SDS
should make independent judgment for the applicability of this SDS under special conditions. In these special cases,
we do not assume responsibility for the damage. According to REACH Article 31(5), the SDS shall be supplied in an
official language of the Member State(s) where the substance or mixture is placed on the market, unless the recipient
Member State(s) concerned provide otherwise. It should also be noted that this SDS is applicable to the countries
with English as an official language.
----------------------------------------------- End of the SDS -----------------------------------------------
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