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Rikha Khusniyyah - Tugas3 CRE

The document contains the results of experiments analyzing a chemical reaction. It provides the name and student ID of the student who conducted the experiments, as well as the course and section. Kinetic parameters of the reaction were determined using two different methods. The integral method yielded values of 35.0324 for the rate constant k3 and 0.5133 mmol/liter for the Michaelis constant CM. The differential method provided values of 20.2540 for k3 and 0.2161 mmol/liter for CM.

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Muhammad Supriyadi
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53 views6 pages

Rikha Khusniyyah - Tugas3 CRE

The document contains the results of experiments analyzing a chemical reaction. It provides the name and student ID of the student who conducted the experiments, as well as the course and section. Kinetic parameters of the reaction were determined using two different methods. The integral method yielded values of 35.0324 for the rate constant k3 and 0.5133 mmol/liter for the Michaelis constant CM. The differential method provided values of 20.2540 for k3 and 0.2161 mmol/liter for CM.

Uploaded by

Muhammad Supriyadi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLSX, PDF, TXT or read online on Scribd
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Nama : Rikha Khusniyyah

NIM : 5213420044
Matkul : Chemical Reaction Engineering
Rombel : C

Jawab :
−𝑟𝐴=(𝑘_3 𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝐶_𝑀 )

CM Michaelis constant

CA0 1
CE0 0.01

k3 ? Integral Method
CM ?
−𝑟𝐴=−𝑑𝐶𝐴/𝑑𝑡 𝑇=𝐶𝑀/(𝐾3.𝐶𝐸0).(ln⁡𝐶𝐴0/𝐶𝐴−𝐶𝐴)
+𝐶𝐴0/(𝐾3.𝐶𝐸0)

=(𝐾3.𝐶𝐴,𝐶
𝐸0)/ Compare with, Y = mx+c
(𝐶𝐴+𝐶𝑀)
𝑚=𝐶𝑀/
(𝐾3.𝐶𝐸0)
=(𝐾3.𝐶𝐴,𝐶
𝐸0)/
(𝐶𝐴+𝐶𝑀)
𝑚=𝐶𝑀/
∫24_𝐶𝐴0^𝐶𝐴▒(−𝑑𝐶𝐴(𝐶𝐴+𝐶𝑀 (𝐾3.𝐶𝐸0)
))/(𝐾3.𝐶𝐴.𝐶𝑀)=∫24_0^𝑡▒𝑑𝑡
𝐶=𝐶𝐴0/
(𝐾3.𝐶𝐸0)
−(𝐶𝐴−𝐶𝐴0)−𝐶𝑀
ln⁡█(𝐶𝐴@𝐶𝐴0)=𝐾3.𝑡.𝐶𝐸0
CA (millimol/liter) t (hr) CA0 CA0/CA ln ((CA0/CA)-CA)
0.84 1 1 1.1905 -1.0485
0.68 2 1 1.4706 -0.2350
0.53 3 1 1.8868 0.3051
0.38 4 1 2.6316 0.8116
0.27 5 1 3.7037 1.2336
0.16 6 1 6.2500 1.8066
0.09 7 1 11.1111 2.3998
0.04 8 1 25.0000 3.2173
0.018 9 1 55.5556 4.0171
0.006 10 1 166.6667 5.1160
0.0025 11 1 400.0000 5.9915
12
f(x) = 1.4651986779097 x + 2.85446260254601
R² = 0.9819045217774
10

6 Column K
Linear (Column K)
4

0
-2.0000 0.0000 2.0000 4.0000 6.0000 8.0000

Slope 1.4652
intercept 2.8545

𝐶=2,8545=𝐶𝐴0/(𝐾3.𝐶𝐸0)

K3 35.0324
𝑀=𝑆𝑙𝑜𝑝𝑒=1,4652=𝐶𝑀/
(𝐾3.𝐶𝐸0)

CM 0.51329 mmol/liter

So, the konstan k3 is 35,032 and CM is 0,5133 mmol/liter.


Jawab :
−𝑟𝐴=(𝑘_3 𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝐶_𝑀 )

CM Michaelis constant

CA0 1
CE0 0.01

k3 ? Differential Method
CM ?
−𝑟𝐴=(𝑘𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝑚)

1/
(−𝑟𝐴)=(𝑚+𝐶_𝐴
)/(𝑘𝐶_𝐴 𝐶_𝐸0 )
1/(−𝑟𝐴)=𝑚/(𝐾.𝐶𝐸0.𝐶𝐴)+1/
(𝐾.𝐶𝐸0)

Ca t delta t CA0 1/CA -rA 1/-rA CA CA/rA


0.84 1 1 1 1.190476 6.25 0.16 1.086957 0.92 5.75
0.68 2 1 1 1.470588 6.25 0.16 1.315789 0.76 4.75
0.53 3 1 1 1.886792 6.666667 0.15 1.652893 0.605 4.033333
0.38 4 1 1 2.631579 6.666667 0.15 2.197802 0.455 3.033333
0.27 5 1 1 3.703704 9.090909 0.11 3.076923 0.325 2.954545
0.16 6 1 1 6.25 9.090909 0.11 4.651163 0.215 1.954545
0.09 7 1 1 11.11111 14.28571 0.07 8 0.125 1.785714
0.04 8 1 1 25 20 0.05 15.38462 0.065 1.3
0.018 9 1 1 55.55556 45.45455 0.022 34.48276 0.029 1.318182
0.006 10 1 1 166.6667 83.33333 0.012 83.33333 0.012 1
0.0025 11 1 1 400 285.7143 0.0035 235.2941 0.00425 1.214286

Differential Method slope = 1/k3CE0 =


k3 =
7
intersep = CM/k3CE0 =
6 CM =
5 f(x) = 4.93734443564535 x + 1.06708539695791
R² = 0.989318093640235 Differential Method
4 Linear (Differential
Method) So, the konstan k3 is 20,2540 and CM
3

2
6

5 f(x) = 4.93734443564535 x + 1.06708539695791


R² = 0.989318093640235 Differential Method
4 Linear (Differential
Method)
3

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
4.9373
20.2540
1.0671
0.2161

tan k3 is 20,2540 and CM is 0,2161 mmol/liter.

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