Revision date: 26/02/2016 Revision: 1

SAFETY DATA SHEET

Purolene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Purolene

Product number 7212

Internal identification GHS22643

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial Chemical.

Uses advised against Non specified unless otherwise stated within this MSDS

1.3. Details of the supplier of the safety data sheet

Supplier Morris Lubricants
Castle Foregate
Shrewsbury
SY1 2EL

08.45 - 17.00 GMT

T: (+44)(0)1743 232200
F: (+44)(0)1743 353584
[email protected]

1.4. Emergency telephone number

Emergency telephone +44(0)1743 232200 (08.45 - 17.00 GMT)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Flam. Liq. 3 - H226

Health hazards STOT SE 3 - H336 Asp. Tox. 1 - H304

Environmental hazards Not Classified

Classification (67/548/EEC or -
1999/45/EC)

Physicochemical The product is flammable. Heating will generate vapours which may form explosive vapour/air
mixtures. Vapours are heavier than air and may travel along the floor and accumulate in the
bottom of containers.

2.2. Label elements

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Pictogram

Signal word Danger

Hazard statements H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P242 Use only non-sparking tools.
P331 Do NOT induce vomiting.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501a Dispose of contents/container to hazardous or special waste collection point.

Contains NAPHTHA (PETROLEUM),

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

NAPHTHA (PETROLEUM), 60-100%

CAS number: 64742-48-9 EC number: 265-150-3 REACH registration number: 01-
2119463258-33

Classification Classification (67/548/EEC or 1999/45/EC)

Flam. Liq. 3 - H226 Xn;R65. R10,R66,R67.
Asp. Tox. 1 - H304
STOT SE 3 - H336

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention if any discomfort continues.

Inhalation If spray/mist has been inhaled, proceed as follows. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Get medical attention if any
discomfort continues.

Ingestion Get medical attention if any discomfort continues. Do not induce vomiting.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms
occur after washing.

4.2. Most important symptoms and effects, both acute and delayed
General information If aspiration into the lungs is suspected, eg when vomitting, admit to hospital immediately.

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Inhalation Upper respiratory irritation. There may be irritation of the throat with a feeling of tightness in
the chest. Drowsiness or mental confusion may occur.

Ingestion May be fatal if swallowed and enters airways.

Skin contact Prolonged contact may cause redness, irritation and dry skin.

Eye contact Irritation of eyes and mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards Heat from fire could result in drums bursting The product is flammable, and heating may
generate vapours which may form explosive vapour/air mixtures.

Hazardous combustion Oxides of carbon. Oxides of nitrogen. Fire may also create other unidentified organic gases
products some of which may be toxic.

5.3. Advice for firefighters

Protective actions during Control run-off water by containing and keeping it out of sewers and watercourses.
firefighting

Special protective equipment Wear self-contained breathing apparatus.

for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection, see Section 8. In case of spills, beware of slippery floors and
surfaces.

6.2. Environmental precautions

Environmental precautions Contain spillage with sand or earth. Avoid the spillage or runoff entering drains, sewers or
watercourses. The product is insoluble in water and will spread on the water surface.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Contain spillage with sand or earth. Collect spillage for reclamation or disposal in sealed
containers via a licensed waste contractor. Avoid water contacting spilled material or leaking
containers. Spillages or uncontrolled discharges into watercourses must be reported
immediately to the Environmental Agency or other appropriate regulatory body. In case of
spillage on water prevent the spread by use of suitable barrier equipment

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

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Usage precautions Avoid spilling. Wear suitable protective equipment, including gloves, goggles/face shield,
respirator, boots, clothing or apron, as appropriate. All handling to take place in well-ventilated
area. Do not breathe vapour. Avoid contact with skin and eyes. Do not spray at high pressure
(>3 bar) Provide good ventilation. Operate only on cold and degassed tanks in ventilated
premises to avoid risk of explosion. Ground container and transfer equipment to eliminate
static electric sparks. Take precautionary measures against static discharges. Do not use
compressed air for filling, discharging or handling. Observe good chemical hygiene practices.
Do not eat, drink or smoke when using the
product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Flammable liquid storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

NAPHTHA (PETROLEUM), (CAS: 64742-48-9)

DNEL Professional - Dermal; Long term systemic effects: 300 mg/kg/day

Professional - Inhalation; Long term systemic effects: 1500 mg/m³
Consumer - Dermal; Long term systemic effects: 300 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 900 mg/m³
Consumer - Oral; Long term systemic effects: 300 mg/kg/day

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.

Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material.

Other skin and body Use barrier creams to prevent skin contact.
protection

Hygiene measures Use engineering controls to reduce air contamination to permissible exposure level. Wash
promptly with soap and water if skin becomes contaminated.

Respiratory protection No specific recommendations. Respiratory protection must be used if the airborne
contamination exceeds the recommended occupational exposure limit.

Thermal hazards Not anticipated under normal conditions of use. The product is combustible if heated
excessively and an ignition source is applied.

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Environmental exposure Do not allow product to contaminate land.

controls

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless.

Odour Hydrocarbons.

Odour threshold Not determined.

pH Not applicable.

Melting point <-20°C

Initial boiling point and range 130-213°C @

Flash point >36°C TCC (Tag closed cup).

Upper/lower flammability or Upper flammable/explosive limit: 7 % Lower flammable/explosive limit: 0.6 %

explosive limits

Vapour pressure 3 hPa @ 20°C

Vapour density Not determined.

Relative density 0.740-0.850 @ 15°C

Solubility(ies) Insoluble in water. Soluble in the following materials: Organic solvents.

Partition coefficient Not determined.

Auto-ignition temperature >200°C

Decomposition Temperature Not determined.

Viscosity 0.8-2.1 mm2/s @ 20°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information

Molecular weight 146

Volatile organic compound The product is a complex mixture, the majority of which would not be classed as a VOC.
However it cannot be discounted that trace or low levels of VOC's may be present.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

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Possibility of hazardous Unlikely to occur under normal conditions of use. Unlikely to occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Oxides of carbon.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) Not expected to be highly toxic based on information of ingredients.

Acute toxicity - dermal

Notes (dermal LD₅₀) Not expected to be highly toxic based on information of ingredients.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Not determined.

Serious eye damage/irritation

Serious eye damage/irritation May cause mild, short lasting discomfort to eyes.

Skin sensitisation
Skin sensitisation Not expected to be a skin sensitizer based on information on components.

Reproductive toxicity
Reproductive toxicity - fertility No data available to suggest the product will cause reproductive toxicity.

Aspiration hazard
Aspiration hazard Kinematic viscosity <= 20.5 cSt @ 40 C. Entry into the lungs following ingestion or vomiting
may cause chemical pneumonitis. Poses an aspiration hazard.

Inhalation High concentrations of vapours may irritate respiratory system and lead to headache, fatigue,
nausea and vomiting.

Ingestion Swallowing significant quantities may cause discomfort, nausea, diarrhoea and irritation of the
digestive tract. Aspiaration into the lungs (e.g. through vomiting) after ingestion can be
hazardous with possible resultant chemically induced pneumonia. May be fatal if swallowed
and enters airways.

Skin contact Skin irritation should not occur when used as recommended. Repeated exposure may cause
skin dryness or cracking.

Eye contact May cause temporary eye irritation.

SECTION 12: Ecological Information

Ecotoxicity The product is not expected to be hazardous to the environment.

12.1. Toxicity
12.2. Persistence and degradability

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Persistence and degradability 80% (Exposure Time: 28d) Readily Biodegradable

Biological oxygen demand Not determined.

Chemical oxygen demand Not determined.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient Not determined.

12.4. Mobility in soil

Mobility The product evaporates readily

Henry's law constant Not determined.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Residues and empty containers should be taken care of as hazardous waste according to
local and national provisions. Do not dump in drains, water sheets or the ground.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

Waste class No waste code according to the European Waste Catalogue can be assigned for this product,
as the intended use dictates the assignment. The waste code is established in consultation
with the regional waste disposer.

SECTION 14: Transport information

General Classified for transportation.

14.1. UN number
UN No. (ADR/RID) 3295

UN No. (IMDG) 3295

UN No. (ICAO) 3295

UN No. (ADN) 3295

14.2. UN proper shipping name

Proper shipping name HYDROCARBONS, LIQUID, N.O.S.
(ADR/RID)

Proper shipping name HYDROCARBONS, LIQUID, N.O.S.

(IMDG)

Proper shipping name (ICAO) HYDROCARBONS, LIQUID, N.O.S.

Proper shipping name (ADN) HYDROCARBONS, LIQUID, N.O.S.

14.3. Transport hazard class(es)

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ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to
do in the event of an accident or spillage.

EmS F-E, S-D

ADR transport category 3

Emergency Action Code 3Y

Hazard Identification Number 30

(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Pollution Prevention and Control Act 1999.
Special Waste regulations 1996.
Control of Pollution (Oil Storage) (England) Regulations 2001
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

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EU legislation Dangerous Preparations Directive 1999/45/EC.

Dangerous Substances Directive 67/548/EEC.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

Guidance Workplace Exposure Limits EH40.

Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
All the ingredients are listed or exempt.

Canada - DSL/NDSL
All the ingredients are listed or exempt.

US - TSCA
All the ingredients are listed or exempt.

Korea - KECI
All the ingredients are listed or exempt.

China - IECSC
All the ingredients are listed or exempt.

Philippines – PICCS
All the ingredients are listed or exempt.

New Zealand - NZIOC

All the ingredients are listed or exempt.

SECTION 16: Other information

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 26/02/2016

Revision 1

SDS number 22643

Risk phrases in full Not classified.

Hazard statements in full H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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